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By L. X. Zeng

The low-grade nickel resource is very abundant in the western China. To make the best of the low grade nickel ore, we studied the process mineralogy and beneficiation process of nickel ore in the Yangliuping of Sichuan province. The grade of nickel is 0.45% in the nickel ore and the nickel exists in the sulfide including pyrrhotite, nickel pyrite, chalcopyrite primarily. The nickel distributes in pentlandite and magnetite over 90% and the copper does in the chalcopyrite over 95%. The carri-er minerals of useful elements tend to concentrate in space for concentration. As is shown in grain-size analysis of three major minerals, there are some more fine-grained grains with the percent of from 10% to 15% (<40 µm) and from 3.5% to 5.5% (<20 µm). So there will be some smaller size disseminated sulfide minerals difficulty to liberate in the process of concentration. The liberation degree of sulfide is not high and there are much associativity in the sulfides. Therefore, we should reclaim the sulfide aggregation dominating as pentlandite when concentrating. In addition, the sulphide minerals is so brittle that we should take care of preventing from crashing when grinding. The gangue mineral is mostly metamorphic mineral including serpentine, chlorite and amphibole which is easy to be argillization and difficult to concentrate.

Jan 1, 2014

By Kun Wang, Xinhui Li, Huaqing Xie, Qingbo Yu, Qin Qin

"Three typical model compounds of bio-oil (ethanol, acetone and phenol) were studied in the steam reforming process for hydrogen production. In the thermodynamic analysis, the three componds showed the similar trends. The hydrogen yields increased with the increase of steam/carbon (S/C) ratios, and the temperatures of the maximum hydrogen yields moved afterward to low temperature zone. However, the hydrogen contents were just about 70%. For improving hydrogen yield, a new system for steam reforming of bio-oil with site CO2 capture was put forward. This system required the catalst with the larger granularity having greater mechanical strength and higher abrasion resistance. So, six Ni-base catalysts loaded on Al2O3 particles prepared were used and among them, Mg-Ni/Co catalyst showed the best catalytic performance. For the simulated bio-oil (the mixture of the compounds), the hydrogen yield can attain 63% with Mg-Ni/Co catalyst with the good stability and regeneration ability.IntroductionCurrently the interest in the use of hydrogen as a clean energy carrier is increasing, and the main way for producing hydrogen is steam reforming of fossil fuels, containing steam reforming of nature gas, naphtha and coal. But this way caused substantial amounts of CO2 emitted, and these sources of hydrogen which are non-renewable energy will eventually be used up [1, 2]. As a kind of renewable energy, biomass is recognized as an attractive alternative to fossil fuels, because of its neutral CO2 emissions [3]. There are mainly two thermochemical processes using biomass to produce hydrogen, gasification and flash pyrolysis followed by steam reforming (SR) of the biooil produced in the flash pryolysis process [4]. The latter was known as one of the most promising and economically viable methods for hydrogen production [5]. In the last decades, the biomass flash pyrolysis technology was adequately developed and fairly mature [6]. But the steam reforming of bio-oil is still at the research stage and yet has been leading to more and more concerns by the researchers. In their research, the catalysts were widely studied and yet mainly were powdery[7-10], and the reactors manily were fixed bed reactors[11-13], readly causing the carbon deposition and the catalyst deactivation, against the continuous running. In this paper, a new systerm was put forward and could realize continuous production of hydrogen, yet needed catalysts with the larger granularity having greater mechanical strength and higher abrasion resistance, as well as powdery CO2 sorbents which mainly calcium oxide based ones.In this paper, the thermodynamic analysis of the steam reforming processes of three typical bio-oil model compounds (ethanol, acetone, phenol) was performed, and the effect of S/C ratio and temperature on the hydrogen yield and the compositions of gaseous products were investigated. Then, a new systerm for steam reforming of bio-oil with site CO2 capture was put forward, and the catalysts with a certain granularity were prepared and studied."

Jan 1, 2014

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By Ulrich Leiste

If the iron ore loss is 15% in the process of mining, the total iron ore loss in the world will be about 461 million tons, this is equal to the total production of 230 iron ore mines each of which produces 2 million-tons of iron ore per year. Based on a series of blast tests in the Malmberget mine, this paper shows that ore recovery can be markedly increased by improving blasting technology such as choosing a correct primer position and making use of shock wave collision. The paper further suggests that a high ore recovery can not only reduce natural resource loss and mining cost but also prolong the life of a mine. In addition, the paper shows an example of reducing blast-caused rock damage in the roofs and walls of underground drifts (tunnels) by using new blasting methods in the Malmberget mine. Finally, the paper shows how the Malmberget mine has successfully reduced the ground vibrations, without adversely affecting fragmentation and ore recovery in sublevel caving mining.

Jan 1, 2014

By J. H. Cloete, S. M. Bradshaw, D. K. Chibwe

"The primary function of a tundish in the steelmaking industry is to serve as a buffer tank, accepting molten steel from the batch ladle process and allowing it to be cast continuously. However, modern steelmaking has more stringent demands for the quality of the steel product, requiring increased control over the properties of the molten steel before casting. For this reason tundishes have been developed as metallurgical reactors to serve as the final step in refining of the molten steel by removing non-metallic inclusions, preventing the formation of new inclusions, and promoting chemical and thermal homogeneity. In this study the flow behaviour in a four-strand tundish was investigated by means of a half-scale water model as well as numerical modelling. Both the numerical study and physical model were used to characterize residence time distribution (RTD) in the vessel and calculate properties pertaining to the tundish flow regime. Three different tundish configurations were investigated: a bare tundish with no flow control devices, a tundish with a turbulence inhibitor and a tundish with both a turbulence inhibitor and a dam.The physical and numerical models showed that a tundish without flow control devices was prone to significant short-circuiting. A tundish with a turbulence inhibitor was shown to be successful in preventing short-circuiting and provided surface-directed flow, which aids inclusion removal in the slag. Despite the benefits of the use of turbulence inhibitors, it was observed that the upward-directed flow increased the maximum turbulence kinetic energy near to the surface by approximately 120% compared with the bare tundish. Therefore the potential for slag entrainment should be considered during the design and operation of tundishes utilizing turbulence inhibitors."

Jan 1, 2014

Mineral flotation is effective over a relatively narrow particle size range of approximately 10 µm to 150 µm. If the upper particle size limit can be increased, however, a run-of-mine ore may be coarse ground, and only the middlings are ground further to achieve required grades. This will result in significant energy savings and increased throughput. In this communication, methods of increasing the upper particle size limit will be discussed on the basis of a flotation model that can predict flotation from both hydrodynamic and surface chemical parameters. An example of increasing flotation recovery by control of a chemistry parameter is given.

Jan 1, 2014

By R. Kobialka

In the article results of experiments over jaws? linings in jaw crushers with different shaping of working surface were presented. Following sets of jaws were under investigation: immobile plain jaw and moving jaw with grooving surface. Grooving jaws have groves with circular, triangular and trapezoid cross section. In order to evaluate efficiency of comminution both the grain composition of product and the content of irregular grains were determined, as well as the size of crushing forces and process efficiency were measured. For the combination: plain jaw with grooved one, a good results were obtained as regards the grain composition of product and the content of irregular grains. Crushing forces were higher at crushing with mixed types of jaws (the one plain, the second grooved), in comparison to crushing with using both grooved jaws. Efficiency of the process was definitely higher for mixed jaws.

Jan 1, 2014

By David Verrelli, Melissa Kistner, Leanne Smith, Chris Aldrich, Lidia Auret, Warren Bruckard

In this investigation, different mixtures of realgar and orpiment particles were floated in a laboratory batch flotation cell and multivariate image analysis was used to estimate the arsenic content in the froths. The analysis was based on the froth colour, as well as extraction of three groups of textural features, namely those based on grey level co-occurrence matrices (GLCMs), wavelets and local binary patterns (LBPs). Collectively, these features provided better information on the arsenic content of the froths than any one of the individual groups of features. Partial least squares models could explain approximately 78% of the variance in the arsenic by using all the features combined. The colour content, particularly the green component in the red-green-blue (RGB) features, provided almost as much information as each of the three sets of texture-base features individually.

Jan 1, 2014

By Samira Rashidi, Robert Dunne, Raj Rajamani

"High Pressure Grinding Rolls (HPGR) are known for more energy saving, better particle weakening and higher tonnage compared to semi-autogenous/ball mill circuits. These machines are scaled up based on the roll diameter. Therefore, studies in lab-scale HPGRs are always preferred because less weight of feed sample is required to run batch tests. The 50-hp laboratory-scale machine at the University of Utah is the first-ever lab-scale machine designed by late Prof Schönert, the inventor of HPGR. This 200x100 mm [DxL] HPGR is equipped with a robust data acquisition system, which enables running steady state tests using a feed sample as small as 6 kg to 12 kg. This paper presents the HPGR grinding study on two different categories of ores, one hard ore and the other soft. A test series has been performed to evaluate the energy consumption and the relation with size reduction on open multi-pass and locked-cycle HPGR circuits. The effect of feed size distribution and operating conditions has been investigated. Locked-cycle tests result in higher reduction ratio and higher rate of fines (100 mesh, 48 mesh and 28 mesh) generation when compared to open multi-pass tests. Data shows that scale-up trend lines stay consistent even when the circuit configuration and operating conditions are varied."

Jan 1, 2014

By Nicolás Luis, Qi Liu, Gonzalo Montes-Atenas

"The prediction of froth flotation performance is still an unresolved topic. Classic industrial models based on particle size, elemental and mineralogical information provides recovery results with deviations that may become significant. One possible reason for this deviation may be the fact that the current liberation analysis provided by electron microscope based techniques does not take into account the outmost surface layer composition of liberated particles. In order to complete the description provided by the liberation analysis, other spectroscopy techniques measuring the extreme surface of the minerals can be tested. For instance, X-ray Photoelectron Spectroscopy (XPS) is a technique which measures the first tens of nanometers providing elemental composition over the particle surface and allows resolving the elemental associations present at the surface sample. However, this information needs to be statistically robust, reproducible and most importantly representative of what is occurring in the process. The aim of this research work is to develop a statistical model based on particle population to evaluate the feasibility of turning the XPS technique into a metallurgical tool. The model consists of classic statistical population arranged in a bed of heterogeneous particles with a known grade and mineral liberation. The simulations showed that the XPS results statistically followed a well-defined pattern. The statistical results were confronted with pilot plant results obtained from a rougher bank when processing a copper sulfide ore from a Chilean mine site. It was observed that the probability function distribution was in agreement with the experimental data. Further analysis on how the XPS results provide valuable information improve the computation of froth flotation recoveries is also discussed."

Jan 1, 2014

By T. Tumidajski

The purpose of the separation processes in coal processing is obtaining products of certain ash contents. In the most of cases it is assumed that the separation process is described by one, selected parameter, which usually is grain size or material density. The separation may be described by means of statistical distributions of random variables, what allows forecasting the separation results of certain enrichment method. There are very well known the applications of approximations of Tromp separation curves or distribution functions of Erasmus, Meloy or Weibull. It is necessary to say that if the fitness of the approximation more suitable, then the characteristics of the process itself is also better. In purpose of obtaining more appropriate results, these methods were modified by application the mathematical functions, as i.e. hyperbolic tangens function. Furthermore, on the basis of empirical data, so-called interpolations may be performed in purpose of getting more appropriate results of approximation. One of the most known techniques of interpolation is Hughes method. This method for interpolating standard data involves breaking down each interval into a number of smaller sub-intervals. The results of such one-dimensional approach not always contain the full in-formation of the searched distribution. It happens because such interpretation of the problem is not completely correct. In practice, the separation process depends not only on the one parameter (i.e. grain size), but also on many other features characterizing certain material (i.e. its density). It seems then that in some cases the application of multidimensional grain characteristics distributions will be more appropriate. In this paper, the technique of joining the distributions of grain size and density by means of so-called Morgenstern distributions is shown. The general form of these distributions is as following:

Jan 1, 2014

By M. Eraydin

Dewatering fine particles (e.g., flotation concentrates) is inefficient, energy intensive and often requires large capital and operating costs. To address these issues, a series of advanced dewatering technologies have been developed at Virginia Tech. These include novel dewatering aids and a hyperbaric centrifuge. Typically, the moistures obtained using these methods are 30% to 50% lower than those obtained using conventional methods, as demonstrated in laboratory and pilot-scale test programs. With another novel dewatering technology that has been tested in bench-scale tests, the moistures can be reduced to levels once believed to be attainable only through the use of thermal dryers. In this communication, test results obtained with these advanced dewatering technologies are presented and compared.

Jan 1, 2014

By Homero Delboni, Mauricio Guimarães Bergerman

"At the regrind or secondary grinding stages of metal ores, usually the concern about the energy efficiency is extremely important. In general, the specific energy consumption at this stage is higher than in the primary stages of grinding. In addition, it has been observed a tendency of finer grinding in the new projects of metallic ores, due to the finer mineral liberation, which leads to an increasing capital and operational costs. In Brazil, during the last 10 years, regrind P80 sizes of approximately 40 to 20 ?m have been necessary in all new iron and copper plants. The use of conventional ball mills, adequate for primary grinding, can result in low energy efficiency with products below a P80 of 50 ?m. This paper presents an overview of the regrind circuits in Brazil that operate with vertical mills and the results of industrial surveys at selected vertical mill circuits. Where possible, comparison is made between the plant results and the design criteria and laboratory regrind tests used for the mill sizing."

Jan 1, 2014

By N. Mphathiwa

When slope angles are designed during open pit optimization, there is a risk factor applied in steepening the slopes. The steepening of slope angles has implications for the safety and economics of the mining operation. The steeper the slope angles, the greater the probability of slope failure. Although a slope failure will result in added costs, the challenge is to compile an accurate cost-benefit exercise optimizing the economic benefits of the project without exposing mine workers and equipment to unacceptable risk of rockfalls. A balance between the safety of the operation and the economics of the investment is therefore required. The ideal situation is to have a slope monitoring system that will predict slope failure by detecting any ground movement before the actual failure occurs. This early warning will allow the risk factor to be applied with a high degree of confidence, knowing that the risk will be adequately mitigated. The objective of this paper is to provide guidelines on how to design an optimal survey slope monitoring system. It is the authors? view that for a survey monitoring system to yield desirable results, it should adhere to survey principles such as working from the whole to part and consistently cross-checking. The case study used is Jwaneng Mine, and the design strategy outlined can be used as a guideline for developing a new slope monitoring system or to optimize an existing one.

Jan 1, 2014

By Bianca Foggiatto, Marko Hilden, Malcolm Powell

"Since the introduction of the concept of flexible circuits (Powell and Bye, 2009), it has been further developed and refined to the definition of ‚FlexiCircuits leverage ore variability to maximise resource utilisation?. The focus of flexible circuits is to investigate processing options that provide extra capacity through sophistication rather than scale. This requires a combination of smart ore characterisation, economic modelling and innovative processing plant design. Flexible circuit design can reduce energy requirements through gangue rejection or progressive ore upgrade; and increased robustness and controllability by leveraging off ore variation. Each rock type, as characterised through Geometallurgical ore modelling, may be processed more efficiently by individually optimising processing paths. The objective of FlexiCircuits is to transform the processing capability of comminution and concentrator plants - targeting step change in performance through integrating a range of interrelated improvement opportunities. Considerable effort has been applied to developing the modelling and simulations tools required to develop and demonstrate the potential of this concept. This paper presents a practical application as a test case. A realistic application of flexible circuits is provided through a conceptual circuit design of an iron ore processing plant. It is simulated as a multi-component feed with a range of new models in the researcher’s Model Developers’ Kit (MDK) to trial the ability of different circuit designs to respond to variable ore and quantifying the potential of these circuits to transform processing capability of variable ore feed. The outcomes of the simulations are presented and discussed, providing a practical demonstration of the level of modelling and simulation required and the potential of flexible circuit design."

Jan 1, 2014

By R. Hejazi, Saghaeian. M., H. Abedini

Continuous vacuum belt filters mainly carry out an important duty in the solid-liquid separation processes such as iron ore concentrate dewatering. However as the particles become finer, the resistance to filtration and dewatering would increase and as the result cake moisture content tends to increase. So in recent decades, using additives in order to improve the filtration performance has been considered by many researchers. In the present study, the effect of several surfactants on the filtration rate and cake moisture content of Chadormalu iron ore concentrate (80% =40 micron) was investigated using a laboratory scale vacuum filter. The results of several tests indicated that a non-ionic surfactant (Lauryl Alcohol Ethoxylated, LAE) has the best performance on reducing the moisture content of the cake and reducing the cake formation time. The optimum dose of LAE was found to be 300 g/ton which reduced the concentrate cake moisture content from 13.76 to 11.28% (wet weight base). Some industrial filtration tests were performed in Chadormalu iron ore concentrate plant to prove the effectiveness of this surfactant. The surfactant is mixed with water and added to the concentrate slurry before distributing on the vacuum belt filter. The industrial and experimental results were almost similar, so that adding about 300 g/ton of LAE would reduce the final cake moisture content from 12.87 to 10.76%.

Jan 1, 2014

By Suping Yao, Chuanyu Jiang

In the last decade, the copper industry in China has witnessed a significant change. The capacity and production of refined copper has grown remarkably from 1.5 million tons in 2002 up to 5.88 million tons in 2012. And now, China has become the biggest copper producer in the world, counting about 30% of the global refined copper production. This paper summarized modern copper smelting and converting technologies employed in China copper industry, such as OT flash technology, TSL (ISA/Ausmelt), SKS bottom blowing, Jinfeng side blowing, etc…This paper also presents some key development and improvement of these technologies up to date from their practical application in China, what will contribute as great value to any new / or renovation copper smelting projects down the road. As an engineering company in China, NERIN has been involved in many of these projects in the past decade, played an important role in the engineering works and accumulated intensive experiences. NERIN is one of the best choices for the world clients in the copper industry, providing quick engineering service, delivering cost effective projects.

Jan 1, 2014

By B. Currie

Maintenance of quality electrowon copper requires an electrolyte which has suitable chemical and physical characteristics. The proper design and operation of the solvent extraction plant is essential to the quality of the electrolyte sent to electrowinning. An aspect that is not well appreciated is that the return electrolyte can have negative effects on the operation of the solvent extraction plant. Poor SX plant operation creates below optimum electrolyte conditions. High Eh in the return spent electrolyte can degrade the SX reagent with large decreases in copper transfer capacity and increases in internal entrainment. The synergistic interaction of the SX and EW plants needs a single-source design approach to address the interactions. The design elements in the SX and EW plants required to manage the electrolyte conditions are discussed.

Jan 1, 2014

By Z X. Zhang

If the iron ore loss is 15% in the process of mining, the total iron ore loss in the world will be about 461 million tons, this is equal to the total production of 230 iron ore mines each of which produces 2 million-tons of iron ore per year. Based on a series of blast tests in the Malmberget mine, this paper shows that ore recovery can be markedly increased by improving blasting technology such as choosing a correct primer position and making use of shock wave collision. The paper further suggests that a high ore recovery can not only reduce natural resource loss and mining cost but also prolong the life of a mine. In addition, the paper shows an example of reducing blast-caused rock damage in the roofs and walls of underground drifts (tunnels) by using new blasting methods in the Malmberget mine. Finally, the paper shows how the Malmberget mine has successfully reduced the ground vibrations, without adversely affecting fragmentation and ore recovery in sublevel caving mining.

Jan 1, 2014