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By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

Following a decline in direct and indirect employment in the minerals industry between 2000 and 2003, the situation reversed in 2004 and employment rose by 12 per cent. Furthermore, there are forecasts of continuing employment growth in the minerals industry in the immediate future. For those of us charged with promoting the virtues of a career in the minerals industry this is encouraging news, as it provides us with the evidence to promote the increasing employment opportunities of a healthy and vibrant industry. However, for many others û particularly the employers in this industry û the news is not so rosy. The jobs are there, and in increasing numbers, but the workers arenÆt! Employers right across the industry are finding it increasingly difficult to fill vacancies with suitably qualified and skilled employees and the competition is becoming fiercer. In the minerals and energy sector, questions are being asked and solutions sought on the industryÆs ability to attract and retain a skilled workforce. From many quarters û industry, government and the education sector, calls for urgent action are becoming louder. The reasons for this are well known û the nature of the work, the remote location, perceptions of the industry, an aging workforce, the gender imbalance, the shrinking demographic of school leavers. It is the latter I wish to focus on û the Generation Y demographic û those who have recently left school, those who are in higher education or have recently entered the workforce, or those who are still at secondary school. These young people are the next cohort of potential employees for the industry. But our need for them appears to be greater that their perceived need for us! How do we engage them so they are informed about the industry? How do we inform and advise them so they are prepared to consider further education and training in disciplines and skill areas relating to our industry? How do we guide and motivate them to give it their best shot and work in it û at least for part of their working life? These are fundamental questions that many within the industry have been grappling with for quite some time. Let me share with you some of the strategies that the Minerals Council is implementing to address this issue.

Jan 1, 2005

By Adam Pickles, Duncan Nicholson, Richard E. Prust, Hoe C. Yeow

"Moorhouse is founded on what at the time of construction were the deepest base grouted piles ever installed in London, specifically designed to accommodate settlement from the proposed development of Crossrail. This paper describes design and construction issues associated with this project with special emphasis on the construction aspects of installing these piles in a heavily congested site in Central London.INTRODUCTIONConstruction of the deepest base grouted bored piles in a congested site in Central London in 2002 posed a number of design and construction problems. To add to the complication, the new structure's footprint is within the safeguarded zone of the proposed new cross London rail link, Crossrail. Therefore the piles were required to be designed to allow for the effects of construction of the proposed Crossrail's tunnels and a new station at Moorgate. The design and construction issues associated with this project are described in this paper and methods used to address such issues are presented.MOORHOUSE DEVELOPMENTThe new nineteen storey high Moorhouse building was commissioned by Moor House Limited Partnership and will form another new Central London landmark building by the British architect Foster and Partners. Two of the four facades feature complex geometry to fulfill the city's planning requirements. The building is a steel frame structure stabilised by a reinforced concrete core. Floor plates span between the core and the perimeter with two rows of internal columns.The complex geometry of the superstructure requires a diagonal ""bandolier"" to transfer floor loads to certain perimeter columns. Another salient feature of the superstructure is the ribs that are provided to act as sloping columns to carry the loads down to the foundations."

Jan 1, 2005

By E E. Hall, S, E D. Thimons, R J. Timko

The heart of mine ventilation science and technology is the protection of the life and health of the miner. Lung diseases that result from overexposure to various mine aerosols can largely be prevented by maintaining concentrations below prescribed limits. Maintaining safe aerosol concentrations depends, in part, on our ability to know what mine aerosol concentrations are in a timely and accurate way. The Centers for Disease Control and Prevention (CDC), National Institute for Occupational Safety and Health (NIOSH) has been developing several new tools to help miners monitor respirable coal dust, silica and diesel particulate matter. This paper will discuss three main topics. First, the latest results of the person wearable dust monitor (PDM), developed by Rupprecht and Patashnick under CDC contract. The PDM was tested side-by-side with conventional samplers at a number of US coal mines and results indicated that the PDM was comparable to conventional samplers. Second, improvements to the dust dosimeter monitoring technique that includes a new pump with built-in pressure transducer and algorithm to convert differential pressure to dust concentration have shown good precision. Third, advances in the use of the detector tube technique to monitor tailpipe diesel emissions and ambient diesel particulate matter show that strong correlations exist between differential pressure measurement and elemental carbon in the samples.

Jan 1, 2005

By Philip Derbyshire, Dale J. Scheffler

"Continuous Flight Auger (CFA) piling is a variation of Augered Cast-In-Place (ACIP) or augercast piling. In both cases a continuous auger with a hollow stem is used to drill a hole and a pile is formed by injection of cementitious material through the hollow stem as the auger is withdrawn. CFA differs from conventional American ACIP by the use of concrete rather than grout to form the pile, and by the type of equipment used to advance the auger into the ground and withdraw it. CFA installation uses a European style rig (i.e. fixed mast and rotary system) which can produce greater crowd and usually has a larger rotator or drill motor than the standard augercast setup. A standard augercast setup will consist of a lattice-boom crane and a set of leads to house the drill motor and auger. The auger size will range up to 24 inches (610mm). With CFA rigs larger diameter piles can be constructed, 24 to 36 in dia. (610mm to 915mm) are common and the technique has been applied with diameters up to 48-inch (1220mm). CFA makes use of sophisticated computer controlled monitoring systems, which have more recently been introduced for conventional ACIP piling. Developments in CFA have taken place over the last 25 years in Europe and particularly in the UK, but are relatively new in the USA. One application is in the construction of secant (overlapping) piled retaining walls. D.J. Scheffler Inc. recognized the potential of the CFA system following visits to the UK and has introduced its use into California for both secant piling and other applications.BACKGROUNDThe high price of real estate in many of the favored areas of California has increasingly led owners to want to build basements under their houses to increase the floor space available on a lot. Many of these areas are by the coast where the ground conditions are predominately granular and the water table is high. Conventional shoring and dewatering systems have often caused problems with adjoining properties. Clearly tangent walls are not suitable in these conditions because of leakage and loss of ground. The secant pile system, using CFA techniques, has proved very effective at overcoming the problems experienced by other methods. Other applications for CFA secant walls have included use for an emergency job on a highway following erosion caused by unusually heavy rainfall.METHODThe concept of secanting piles, whereby primary(female) piles are installed first and then secondary (male) piles are cut into the primary piles is not new. The method has been known for more than 30 years. Originally ‘Benoto’ grabbing rigs, developed in Japan, were used together with sectionalized double skinned casing and oscillators.This early method was slow, although very effective. More recently high torque rotary machines have been used. Contractors in the UK have increasingly used CFA techniques to further improve productivity of this type of piled wall. The improved capabilities of piling rigs available, as well as developments in concrete technology and instrumentation, have made this possible."

Jan 1, 2005

By A. R. Laplante

Gold recovery early in the flowsheet, typically from the primary grinding circuit, has seen significant advances in the past three years. Some of the advances achieved under the auspices of the AMIRA P420B Gold Processing Technology project are reviewed. The areas covered are gravity-recoverable gold (GRG) characterization, GRG behaviour in classification, gravity recovery simulation and the link between gravity recovery and cyanidation.

Jan 1, 2005

By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska's North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005

By Kot F. v. Unrug

In spite of the extensive research and accumulated experience from mining operations, an appropriate pillar design remains an open issue. Due to the shrinking reserve base, present mining operations move to more challenging conditions. There are usually thinner seams and geologic conditions are often unfavorable. For instance, mine roof and floor are weak or deteriorate rapidly when exposed to moisture fluctuations in mine atmosphere. It is common that pillars of current operations are more- squat than several decades ago when the bulk of pillar research have been carried out in thicker seams. The methods of pillars calculations were developed regionally (in particular countries) to suit design needs for the most important seams, from which the majority of coal production was coming (e.g. Pittsburg or Pond Creek seams in the eastern of US). Most of the pillar formulae use similar approach by assigning weights (using constants) to the influence of coal (seam) strength and pillar widthheight ratio on its final strength. That mechanistic approach has sound theoretical base and good data supporting its validity. However, what seems to be missing is a qualification system of the mine conditions, which are outside of the data base or do not comply with the theoretical model applied in pillar strength formulae. This paper attempts to address that issue in two major categories, first when only a drill core data are available, and second during the mine development observations can be made directly on a coal seam. The composition of a coal seam is also addressed, (which often changes rapidly across the reserve), and discussed its influence on pillar's structural performance. In summary a set of practical design rules is presented.

Jan 1, 2005

By F. Stober, D. Wanblad, J. Ndlovu, L. R. Nelson, L. P. S. de Villiers

The single six-in-line furnace of the Polokwane Smelter is the largest installed high-intensity furnace for platinum group metals (PGM) base metals sulphide smelting in the world. The furnace employs state-of-the art technology to deliver a planned throughput of 650 000 t/a dry concentrate at a design 68 MW power input. This furnace, at double the capacity of previously existing PGM furnaces, offers low unit operating and capital cost through the resulting economies of scale. Key features of the design include:

Jan 1, 2005

Although the mining industry has achieved record-low fatalities and injuries for each of the last three years, there are still too many miners injured or killed in this nation ís mining operations. Many mining injuries or deaths might have been prevented by using risk assessment to identify and control or eliminate the hazards associated with a task. To focus attention on the importance of conducting risk assessments in keeping mining workplaces safe and healthful, MSHA introduced this initiative on October 12, 2004. This initiative is called SLAM. SLAM is an acronym for Stop, Look, Analyze, and Manage. The steps involved in SLAM are: Stop ñ stop and consider the work involved Look ñ look for and identify the hazards Analyze ñ analyze what needs to be done Manage ñ manage safety by developing and implementing controls Everyone should be aware of the risks of an accident before beginning a task. It may not always be obvious that performing a seemingly routine task could result in an accident. That is why conducting a risk assessment is so important. Itís important to remember that over time a mining workplace seldom remains unchanged. Risks must be assessed whenever procedures or processes change, whenever new tasks are started, or non-routine tasks are performed.

Jan 1, 2005

For various reasons, the maintenance of shaft structures is becoming an increasingly important factor in the operation of underground mines. Deterioration mechanisms related to operation of the shaft are identified as corrosion, mechanical damage, fatigue damage and wear. Deterioration mechanisms related to rock movements are identified as vertical strain, ride vertical closure and squeezing. Analytical procedures for assessing this deterioration are discussed, and it is shown how acceptance criteria are developed and implemented. In order to track the deterioration of shaft structures, shaft inspections are undertaken, but the information is often not well documented. Formalised procedures for capturing and recording information, and then processing the information are presented. Finally, two case studies are briefly described to illustrate how these procedures have been implemented in practice, and what benefit has accrued to the mines concerned.

Jan 1, 2005

Due to geographical location, AustraliaÆs economy and trading are closely related to Asia. With ChinaÆs increasing demand on resources and energy and Japan and KoreaÆs steady imports in these fields, AustraliaÆs mining industry is experiencing a so called æboomÆ period. Traditionally, engineers or skilled workers from South Africa, Britian or other parts of Europe moved to Australia for its mining industry. Now, more students from Asia are starting to choose mining engineering (similar choices include mining geology, metallurgy, geotechnical engineering and mining surveying) and expect to work in these fields. How does AustraliaÆs mining industry face such a situation? What kinds of challenges and opportunities do the mining industry and universities face? How do mining companies utilise these human resources? This paper concludes with an analysis of all these questions at an industrial level and some personal deduction as to the preferred course for international students.

Jan 1, 2005

By B. A. Cheeseman, R. Skaggs, C. F. Yen, S. Wolf

Shallow buried explosives pose a significant threat to lightweight vehicles and their onboard personnel. To date, designers of lightweight vehicles are limited in their knowledge of what occurs during the blast. The high intensity, short term loading imparted by the explosion is enormously complex and can be significantly affected by a number of parameters including the size, shape, type, detonation point and depth of burial (DOB) of the explosive and the type, density and water content of the soil. Recent advancements in numerical simulations have enabled the complex blast event to be accurately modeled by coupling Eulerian and Lagrangian analyses: the former is well suited to modeling the blast and while the latter, the structural response. Further validation of the modeling technique is considered in the current paper, which details simulations performed utilizing the coupled Eulerian-Lagrangian analysis to the study the blast output of explosives buried in saturated sand. These experiments varied explosive charge size, its depth of burial, the target stand-off (SO) distance and target plate dimension. The investigation concludes with a discussion of the accuracy of the numerical simulations when compared with the experimental observations.

Jan 1, 2005

By C. A. Young, H-H. Huang, L. G. Twidwell

Equilibrium calculational software programs can be effectively utilized to model important parameters in aqueous and aqueous/solid systems, e.g., activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation. In this regard, the calculational program ST ABCAL will be demonstrated. Illustrative examples for the creation of diagrams such as potential-pH, and activity or concentration-pH will be presented to demonstrate the fundamentals in real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Berkeley Pit water from a flooded abandoned copper open-pit mine will be used to illustrate the modeling process. According to analytical results the water contains about 20 important constituents. In addition to measured potential and dissolved oxygen, there are two distinctive oxidation/reduction couples. Concentration and other experimental parameters are seldom matched to each other and 12 different conditions have been identified. Water for each condition must be speciated in order to find the best-fit model. The STABCAL program will be used for the modeling calculations and the implication of the water chemistry to defining treatment opportunities will be discussed.

Jan 1, 2005

Although AustraliaÆs coal mining industry is currently experiencing a pleasing period of price relief, long-term trends toward lower real prices will surely continue. Higher price levels attract expansion by existing operators and market entrance by new operators. History clearly demonstrates the relentless long-term march toward ever lower real prices. Therefore, the need for economic returns applies constant pressure to improve productivity. To be sustained, high productivity requires a systematic response based on a solid understanding of critical productivity determinants. The most powerful determinant of productivity is now widely understood to be workplace culture. Culture largely comprises a combination of behaviours, symbols and attitudes. This paper will examine and review scienceÆs latest discoveries in human behaviour. It will provide a proven, practical framework for understanding behaviour and applying this knowledge. Significantly, it will highlight why conventional approaches toward improving productivity often provide disappointing economic returns. The modern understanding of behaviour factors will cover coal face operations. More importantly, because executive and managerial levels in coal mining have significantly greater impact on industry and mine productivity the paper will concentrate on leadership. Particular emphasis will be placed on use of modern systems and in particular use of what are by far the most powerful drivers of behaviours û measurement, analysis and reporting systems. The paper and presentation will show how conventional systems rooted in antiquated American legislation from the early 1900s stifle productivity improvement and drive suboptimal and even counterproductive behaviours. These commonly used systems will be compared with accurate and effective modern methods for assessing performance to improve productivity. These principles are proven in all industries and effective application in mining will be highlighted. Actual results will be used to demonstrate practical approaches successfully applied in both metal and coal mining in Australia and overseas.

Jan 1, 2005

By C Kocsis, G Baiden, Y Bissiri

CANMET-MMSL and Penguin Automation Systems Inc have been exploring how process simulation and ventilation modelling software, when combined, can be used to optimise hard-rock/metal mine ventilation systems. In combination, it is anticipated that this methodology will facilitate the exploration of mine design options that affect ventilation requirements and ultimately cost. Such integrated mine design could limit, and possibly reverse, the drivers that under current practices would generally dictate increased ventilation, power consumption, cost and greenhouse gas emissions. It is believed that the mining industry needs such process models to develop better business cases. For example, the implementation of optimised ventilation systems will undoubtedly require significant investment and mines are often reluctant to try such conservational measures unless they can be proven cost-effective. In general, Canadian hard-rock mines know their ventilation systems are providing too much air and consuming power unnecessarily. This is because their systems are designed to provide maximum production flexibility, based upon peak demand, which may be at some future time, and operated continuously at that level regardless of actual need. Simplistic analyses have shown electrical energy savings can range from 30 per cent through to 90 per cent (Hardcastle, Gangal and Leung, 1998). These savings depend upon such factors as the intensity and continuity of the production schedule as opposed to non-productive time. Where these savings occur is also important, if limited to either the primary or auxiliary ventilation systems, they could be negligible in a mineÆs total energy consumption. The problem these mines face is determining what level of ventilation is required in real-time and then the relative benefits. Such parameters as varying electricity costs, heating fuel options, different design criteria and their complex inter-relationship can effect the selection of an optimal system, depending on whether energy, environment or cost is the prime driver. The use of process simulators in underground mining is in its infancy; to date they have been used to show the benefits over the life of a mine under different mining methods, such as a comparison of tele-remote mining from surface against conventional manned operation (Baiden, 2000). This ongoing development advances the use of such simulators into a new and potentially important area, namely modelling the life-cycle ventilation requirements of a mine. This paper shows how such a life-cycle analysis as opposed to peak demand can provide the basis for optimising the design of ventilation systems and their control.

Jan 1, 2005

By R. M. S. Häggblad

The article deals with stabilisation and regeneration of Ce02 and Ce02/Zr02 based Pt water gas shift catalysts, subject to high initial deactivation. The reaction gas species effect on the catalyst deactivation was investigated by H2-TPR. Activity measurements enabled the effect of different promoters, some added to the Ce02 based catalysts and some to the Ce02/Zr02 based Pt catalysts, to be investigated. The catalysts were also characterised by BET and CO-TPR. Deactivated catalysts activity was restored by using various regeneration methods. Of the two selected carriers the Ce02/Zr02 based Pt catalyst showed the highest resilience to deactivation. For the two different carriers, Ce02 and Ce02/Zr02, Wand Re were the best promoters when the catalyst was subject to deactivation. Experiments with Hr TPR indicate a fast initial change in the platinum oxides concentration and composition. The CO-TPR was used to make conclusions about the various regeneration effects of water and oxygen on the catalyst. Finally it is suggested that not one deactivation mechanism is possible and which mechanism that dominates is dependant on the catalyst and the reaction gas composition.

Jan 1, 2005

By M. E. Austin

Many numerical models for the tubular solid oxide fuel cell (SOFC) exist, with various degrees of sophistication. However, the question of what physics must be modelled, and what can be neglected has not been resolved. A parametric model is proposed and analyzed to quantify the influence of thermal phenomena such as reaction heat generation, cathode channel convective cooling, and thermal radiation with participating media. Currently, a three-dimensional model is used to simulate the conditions of an anode supported cell in the centre of a tube bundle. The interconnect and nickel foam spacers that bridge adjacent cells in series and parallel, respectively, are neglected thus enabling a domain consisting of a 45o azimuthal section of the tube. The conservation equations for mass, energy, and species transport are solved using commercial computational fluid dynamics software, and radiation heat transfer is also modelled using a Discrete Ordinates method. Finally, temperature-dependent material properties and reaction rates are used. The model predicts lower overall temperatures than models that do not include radiative heat exchange and more moderate temperature gradients than those that ignore participating media radiation. Further, different regimes are identified, from convection dominated heat transfer to radiation dominated heat transfer. The results can be used to aid in the selection of appropriate models for a given fuel cell operating regime.

Jan 1, 2005

I once read an æarticleÆ in FHM Magazine entitled æThe Coolest Jobs There Ever WasÆ. It was about a group of guys who were pursuing careers that any person on the planet would just kill for. I distinctly remember drooling over the pages, thinking how much I would love to be Michael SchumacherÆs Chief Engineer at Ferrari, or the Principal Designer and Tester for one of the big Dutch rollercoaster companies. From that moment on, I decided that I wanted a career that was cool enough to make it into the pages of that article. Throughout my time at university, I always had that article in the back of my mind. As a result I constantly wondered about what sort of job I could end up with once I left university. More importantly, I wondered if FHM would be banging down my door to put me in the magazine! After a long and stressful job hunting process (in between completing a thesis and studying for exams) I finally managed to land myself a job with Orica Mining Services. I can honestly say I didnÆt know what to expect when I first joined Orica. Most of my friends ended up working for big mining companies, while I was offered a position with one of the biggest suppliers to these mining companies. However, I had a feeling when I was discussing the role with my future supervisor during the interview process that the job was going to be awesome. I have now spent a year working for Orica and I absolutely love it! While I feel that my job is worthy of being in that FHM article, unfortunately, I donÆt think I am going to get my opportunity to be in the magazine. Apparently I donÆt look too good in a bikini! However, I would love to have the opportunity to discuss the journey that I have taken so far û from my time as an environmental science graduate, then moving on to mining engineering, to now, being part of the Orica Mining Services Graduate Program. My suggestion is to use this paper as a resource. I have learnt during my time at university, as well as my time in the workforce, that the best people you can learn from are your peers. Take what you feel is relevant from the paper; hopefully it will help guide you in shaping your own career.

Jan 1, 2005

By R B. Venugopal, P Staples

The selection of the mode of transport for moving bulk materials is never a simple task as there are various concerns/considerations applied to the selection of the most practical and cost-effective mode of transport to be used to move bulk materials. This paper examines various alternatives for moving ore from a mine at the top of a mountain to a process plant below (some 5000 m apart and a vertical drop of 650 m). The terrain of the mountain section of the route has added its own specific requirements, resulting in the final selection of a pipe conveyor for this application. The paper further addresses the final selection of hardware used in the implementation of the solution.

Jan 1, 2005