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By Luiz A. Teixeira

This paper reports the results of kinetic studies involving the precipitation of arsenic from aqueous solutions as FeAs041 Fe(OH)3' using FeS04 as source of Fe ions, and Air or H202 as oxidizing agents. Both systems lead to an efficient removal of arsenic. The differences in oxidants performances are in the precipitation reaction rate -much faster using hydrogen peroxide. Mechanisms of reactions were suggested based on the following main steps:

Jan 1, 1996

The dissolution kinetics of gold in iodide solutions with oxygen in an autoclave was investigated. The leaching process was described by a gas-liquid-solid heterogeneous reaction. The effect of stirring speed, temperature, partial pressure of oxygen, and concentration of lixiviants on the overall leaching rate was investigated. It was found that the dissolution of gold was limited by a heterogeneous chemical reaction. The apparent activation energy was measured to be 34.7-54.3 kJ/mol under the conditions studied. Experimental findings were in good agreement with the kinetic model proposed.

Jan 1, 1996

By James P. Cooney

What is required for the mining industry to grow and prosper in a politically challenging world? The answer to this can be summarized as “the industry’s three priorities.” The first priority is gaining access to the world’s mineralized jurisdictions. The second is establishing a measure of security and predictability in government treatment of mining. Confidence in the stability of the fiscal and legal framework within which mining operates is necessary to encourage the investment of large amounts of capital in mine development. The third priority is sustaining the industry’s welcome during the long term in those jurisdictions worthy of investment.

Jan 1, 1996

By Richard J. Mainiero, James Q. Wheeler, Lewis H. Kopera, Yael Miron, Solin S. W Kwak

The research reported here was part of an effort to evaluate the safety of a process to recover TNT from MK-9 depth bombs by the autoclave meltout process. In this process the depth bombs are heated to 121oC so that the TNT will melt and run into a vat. Unfortunately, asphalt lining the inside surface of the bomb also melts and flows out with the TNT. Prior to this study, it was not known what effect the asphalt contamination and the higher than normal process temperatures (121oC) would have on the sensitivity of the TNT.

Jan 1, 1996

By Donald R. Sadoway

Molten salt electrolysis is a proven technology for the extraction of metals -- all the world's primary aluminum is produced in this manner. The unique properties of molten salts, also make them excellent media in which to treat a variety of forms of waste. Of special .note in this regard is electrolysis in molten oxides, a .concept put forward by. the author, initially as a ."clean technology" for producing primary metal. However, in the context of waste treatment, electroly-sis in molten oxides is a process offering the prospect of changing the. valence of dissolved heavy metals while making pure oxygen gas as the main by-product .Laboratory tests conducted at a temperature of 1550°C on chromate sludge dissolved in an melt composed of Al2O3 and MgO have confirmed electrochemical production of oxygen on a carbon-free anode.

Jan 1, 1996

By Yves C. Lizotte

Although blasting remains the most inexpensive method of fragmentation in hardrock mining, the significance of the costs of blast-induced rockmass damage in terms of mining efficiency and safety is becoming increasingly recognized. There is no straightforward and systematic method of adequately measuring blast damage in on-going mining operations. This paper considers various techniques available to measure blast damage, making particular reference to recent underground hardrock mine studies. It concludes by proposing a damage audit procedure for integration into routine mine production control.

Jan 1, 1996

The U.S. economy and, consequently, the demand for minerals grew at more moderate rates in 1995 compared with stronger performances the previous year. Demand for metals such as steel and copper was relatively stable. For example, the decline in steel consumed in motor vehicle manufacturing (reflecting lower vehicle sales) for the first half of 1995 was offset by an increase in steel consumed in construction during the same period. More detailed information on events, trends, and issues in the mineral and material sector Is presented below and in the commodity sections that follow. Overall Performance The value of processed materials of mineral origin produced in the United States during 1995 was estimated to be $395 billion, an increase of almost 10% compared with 1994. The estimated value of U.S. raw nonfuel minerals production in 1995 was $38 billion, about 7% more than in 1994. The value of U.S. minerals production has increased in 30 of the last 35 years.

Jan 1, 1996

By Za-Chieh Moh

This paper presents a summary of the current pile foundation practice in Taiwan. Constructions of driven piles, drilled shafts, and barrette foundations are reviewed. This paper also briefly summarizes the pile works of four major construction projects in Taiwan, namely, Hsin-Ta Power Plant, Taichung Power Plant, Taipei Transit Systems, and Taiwan High Speed Rail.

Jan 1, 1996

By P. G. Semple

For the last four years, the Kilborn Group of Companies (Kilborn) has been involved in several major projects in the CIS. These projects include the Kumtor Project, the Kubaka Gold Project, the Kazgold Project, the Aginskoe Project and the Jerooy Project. These projects are all in various stages of detailed engineering and construction. In this paper, Kilborn will discuss our experience in the CIS and share some insight into project development in this geographic region.

Jan 1, 1996

By S. Seetharaman, Du Siehen

"In the processing of molten metals, it is extremely important to monitor continuously the concentration levels of various minor elements. In the production of common metals like copper, iron and aluminium electrochemical sensors involving solid as well as liquid electrolytes are being increasingly used to measure the concentrations of minor elements. The present paper deals with the electrochemical principles underlying these measurements and the possible errors involved. One of the major difficulties in the case of the solid electrolytes is to correct for the consequences of the electronic contribution to the conduction of the electrolyte.The application of the electrochemical sensors for molten metals processing involves designing of these probes to withstand the industrial operating conditions. In this respect, significant achievements have been made with respect to the design of oxygen probes for liquid metals in general and liquid copper in particular. Some of the salient design features are discussed in the paper. The application of auxiliary electrodes for impurities in molten metals like phosphorus in copper and silicon in iron are taken up. The development of oxygen sensors for slags is given special attention. Recent developments in the field of sensor technology, as applied to metals processing are highlighted.1. IntroductionThe rapid technological advancement today require precise control of the process parameters and the impurity levels. Most of the molten metals processing in industrialized countries are often steered by suitable computer models, either phenomenological or simulations based on theoretical principles. These models often require that the process parameters are continuously monitored so that the progress is followed and modified suitably as and when required. It is common practice to measure temperatures by incorporating temperature sensors at the various strategic points of the reactor. In the case of monitoring the composition changes in the various phases, the method of sampling followed by routine chemical analysis involves a time lag as well as uncertainties in sampling and analysis. In this respect, electrochemical sensors have the advantage of generating accurate data when properly applied and increasing attention is being paid in the development of electrochemical sensors for various common species in molten metals processing. In the present paper, the developments in this area over the years are outlined and typical process applications are discussed. A greater emphasis will be laid on sensors based on oxygen conducting electrolytes and their application to the production of common metals like iron and copper."

Jan 1, 1996

By James A. Voigt

"The efficient separation of metal species from aqueous streams by precipitation techniques requires a fundamental understanding of the various processes that occur during precipitation. These processes include particle nucleation, particle growth by solute deposition, agglomerate formation, and agglomerate break-up. The application of the population balance approach has been used to develop a kinetic model that accounts for these competing kinetic processes. The usefulness of the model is illustrated through its application to the precipitation of yttrium hydroxynitrate, YHN. The kinetic parameters calculated from the model equations and system specific solution chemistry are used to describe several aspects of the effect of pH on the precipitation of the YHN. Implications with respect to the simultaneous precipitation of more than one cation type are also discussed through use of example systems. The effects of solution chemistry, precipitator design, and solvent choice are considered.IntroductionThe application of precipitation technologies to the separation of metals from solution is widely used. Regardless of its application, be it in such diverse areas as the preparation of metal oxide powders for use in commercial products or as a unit operation in the removal of trace metals during wastewater clean up, the fundamental processes involved are the same. These processes include: nucleation from solution, either homogeneous or heterogeneous; growth from solution with chemical reaction either in solution or at the precipitate/solution interface; growth by particle agglomeration; and particle break-up by collisional or shear forces. The effectiveness of the operation and the properties of the precipitate formed, or ""quality"" of the product, are determined by the competing kinetics of the different processes. The kinetics of the processes, in tum, are determined by system-specific solution chemistries and the conditions used to carry out the precipitation operation. For example, generally, when system conditions are such that the supersaturation driving force for precipitation is very high, growth species normally do not have the time to organize themselves with a high degree of crystallographic order and the precipitate is amorphous. In this case nucleation rates are invariably extremely high and the primary mechanism for growth is the agglomeration of nuclei. Conversely, when the supersaturation levels for the same system are reduced, the kinetics of the nucleation and growth processes also are greatly reduced, and a crystalline precipitate can be formed, since the growth species have time to order on particle surfaces."

Jan 1, 1996

By R. G. B. Pickering

The Faculty of Engineering at the University of the Witwatersrand and the Mining Technology Division of the CSIR have co-operated to define the problems associated with deep level mining and in this paper they will identify what they consider to be the critical areas requiring technological solutions. This perspective will then be applied to work currently being carried out by both the organizations and gaps for additional developments will be identified. Finally the Co-operative Research Centre methodology operating in Australia is described. The purpose of this CRC is to provide a vehicle for R&D co-operation to develop and implement technologies which will increase the competitiveness of the mining industry. A further objective is to develop an appropriately skilled human resource base.

Jan 1, 1996

By I. E. Odom

A study was made of the physical and chemical nature of silica minerals found as natural impurities in bentonites and montmorillonitic Fuller&apos;s earth clay products as well as in <10 micron dust from eight processing plants. The results show that the silica minerals present in these clay materials are totally encapsulated or encased in clay. No "free" silica minerals could be observed in SEM images of either granular or powder products or in dust samples collected for MSHA crystalline silica analysis. Silica minerals, such as quartz, are identifiable by SEM and EDS analysis only after removing the clay coatings by vigorous washing. After washing it can be observed that all crystalline quartz grains also have diagenetic overgrowths of what is probably opaline silica. The clay and opaline silica encapsulation of quartz plus the strongly hydro scopic nature of montmorillonite are believed to be responsible for there not being a single confirmed case of silicosis among workers in the subject plants after more than 65 years of production.

Jan 1, 1996

By Miroslaw M. Hajdasinski

A project&apos;s rate of return (ROR) [The list of all the acronyms used in his text is provided at its end.], be it an internal or external one, usually needs to be approximated. The success and efficiency of an approximation procedure depend on the quality of the initiating parameters such as bounds or seed values (guesses). Current approximation procedures commonly use bounds and guesses dictated by intuition rather then by mathematical consideration. The paper presents three ROR-bounding and six ROR-guessing approaches and examines their suitability on the examples of the typical project cash flow patterns.

Jan 1, 1996

Between 1966 and 1976, Australia moved from being a non-producer to a position of meeting more than ten per cent of world nickel demand. New mine developments beginning the early-1990s have the promise of more than doubling the country&apos;s world market share - from around eight per cent to perhaps close to 20 per cent. This new surge in activity - the so-called `second nickel boom&apos; - has led to several developments which seem likely to have similar economic impacts to those of the late- 1960s and early-1970s. There are, however, some notable differences this time around. The impact of long distance commuting over the past 30 years has changed the regional development scenario. The gold industry is much stronger in Australia than it was in the late-1960s and this helps to place the importance of new nickel discoveries in a more realistic perspective. As potential players have jockeyed to complete feasibility studies and move into construction and production phases of new long-life mines, established suppliers clearly seem to be taking actions to discourage the newcomers. In what appears to be a classic oligipolistic market situation, the heightening of perceived entry barriers to the industry appears to be a particularly visible strategy undertaken. In the current scenario as well, greater vertical integration among producers appears a significant influence on market power.

Jan 1, 1996

Australia is presently the world&apos;s principal producer of rutile and zircon, and also provides a major share of the world&apos;s ilmenite. Since 1980, Australia&apos;s share of the world&apos;s output of these minerals has fallen. Exhaustion of known resources, together with the changing composition of new deposits, is expected to result in Australia&apos;s share of the rutile and zircon output continuing to decline. Its role as a major supplier of upgraded ilmenite, that is synthetic rutile, is expected to increase. In 1994, the Bureau of Resource Sciences assessed Australia&apos;s demonstrated resources of mineral sands as follows: rutile 14.4 Mt, ilmenite 132.5 Mt, and zircon 21.0 Mt. These resources are located along the coast of Queensland and New South Wales, in the Murray Basin of New South Wales and Victoria, in the southwest corner of Western Australia, and in the Eneabba region, north of Perth. However, some 45 per cent of rutile and zircon resources along the coast of Queensland and New South Wales are not available for mining because of environmental concerns. World demonstrated resources are estimated at 40 Mt (contained TiO2) for rutile, 50 Mt for zircon and approximately 312 Mt (contained T1O2) for ilmenite. Outside of Australia, the most important resources of rutile, ilmenite and zircon are in South Africa (rutile, zircon , and ilmenite in the form of titania slag), Sierra Leone (rutile), India (ilmenite, zircon and rutile), and Canada (hard rock ilmenite). Significant resources of ilmenite occur in Madagascar and Mozambique.

Jan 1, 1996

By Rick Coleman, Chelvan (Chevy) Veloo

"P.T. Freeport Indonesia's lrian Jaya Operation has been producing copper concentrate continuously since 1972. Numerous ore discoveries and five mill expansion programs have seen the initial milling rate of 7,200 MTPD escalate to the present rate of 125,000 MTPD, producing 2.5 million pounds of copper and 3,500 troy ounces of gold per day. The latest expansion, commissioned in February 1995, incorporates a 34 foot Semi- Autogenous Grinding (SAG) Mill, two 20'x30' Ball Mills, conventional roughing, cleaner column flotation, and attendant upgrades to the existing concentrate pumping and dewatering facilities. This paper will describe the SAG Plant flowsheet, and focus on the key training issues which contributed to a successful plant start-up.IntroductionP.T. Freeport Indonesia's operations in the Ertsberg mining district are located in the Jayawijaya Mountains of Irian Jaya, the easternmost province of the Republic of Indonesia. P.T. Freeport Indonesia (PTFI), the operator, is owned by Freeport MacMoRan Copper and Gold (81.3%), the Government of Indonesia (9.4%), and private Indonesian investors (9.4%). Geographical location, and sailing distances are provided on the attached location map.The operation stretches over 7 4 miles ( 114 km) from the dewatering and concentrate shipping facility at the Port of Amamapare on the Arafura Sea to the Grasberg open pit located at 3400m. The regional geology is covered in detail by Van Nort et al (1991 ), with current proven and probable reserves estimated at 1.13 billion metric tonnes grading 1.30% Copper, 1.42 ppm Gold, and 4.06 ppm Silver. The Grasberg open pit mining operation provides 92% of the mill feed, and is described in detail by Hickson (1991). The remainder of the mill feed is derived from several underground block caving operations. Current production rates provide a mine life in excess of 25 years. However, very favorable geology in the area leads to expectations that additional reserves will extend the life of the operation considerably."

Jan 1, 1996

By Daniel Hodouin, Bruno Girard, Claude Bazin

"Mineral processing and smelting operations have the reputation of being complex processes. Process operators of these unit operations have acquired from experience and basic training a superficial understanding of the relationships between process output and manipulated variables. This understanding, which is a very valuable know-how for process control and optimization as well as for operator training, is however difficult to extract. This paper describes a time series based approach that can be used to extract this know-how, which can subsequently be used for operator training. The method is illustrated with an example taken from a smelting process.IntroductionThe emergence of Total Quality Management and Statistical Process Control philosophies in the North American industry (Brown, 1991 ), as well as the increasing popularity of the IS0- 900x standard accreditation, provide a strong incentive to review the training procedures for plant operators. The importance of employees training is acknowledged in two of the 14 points of Deming's road to quality (Deming, 1982) as well as by control engineering consultants (Hendricks et al., 1994). However guidelines for the operation of industrial processes are often transferred from an operator to another one with allowance for flexible interpretation of many operating rules. Such transfer is typical of complex industrial processes to which particulate processes of ore dressing and extractive metallurgy belong.Capturing the knowledge of experienced operators is often a difficult task. Cognition engineers are able to extract this knowledge and transfer it into rules that ultimately are implemented into expert systems. Cognition engineers are however not always available and plant supervisors may prefer to keep training as an internal liability. Another difficulty through interviewing of the process operator is its lack of willingness to transfer what he has learned by hard working to other people, whose ultimate goals are to develop computerized applications that may replace him in a near future, or reduce its importance in the production line.This paper shows that time series can be advantageously used to capture the average process understanding of plant operators and to help reviewing training procedures. The method s illustrated with data collected during normal operation of electric arc furnaces and it is shown how the approach has led to a fruitful discussion between process engineers and operators that ultimately provided savings of more that $200,000 per year per furnace. There are 9 furnaces in the studied foundry. Such savings are not the results of application of advanced control strategies nor of ""miracle press button software», but of an improve awareness by engineers and operators of the importance of properly defining the operating procedures to control a process."

Jan 1, 1996

By James A. Bachmann, Christopher J. Gray

On December 26, 1994, at 1:00 am, Santa Fe Pacific Gold's Twin Creeks Mine experienced a major highwall failure involving over 2.5 million tons. The resulting effects of this slide were thousands of ounces of gold that were now deferred and an unstable wall above which made mining the slough material unsafe.

Jan 1, 1996

By Bjoern R. Petterson, Lars Haakon Siem

The world's longest highway-tunnel -- the Aurland Tunnel in western Norway -- is scheduled to be opened in the year 2000. A project to build a main highway between Oslo and Bergen with no ferry connections was approved by the Norwegian Parliament in January 1995. Construction of the five-year blasting project was started by the Norwegian Highway Authority in mid-March 1995, with an expected completion date of November-December 1999.

Jan 1, 1996