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By C. Cheung, U. Erb

"Over the past few years, nano-processing of magnetic materials has received considerable attention, because many magnetic and other application-specific properties have been shown to be enhanced in materials with ultrafine grain size. This paper reviews recent advances in the production of nano-processed soft magnetic materials such as pure nickel and cobalt as well as binary nickel-iron and ternary nickel-iron-chromium alloys by electrodeposition. Magnetic, electrical and mechanical properties of these materials are presented and discussed in terms of their microstructural defects.IntroductionIn recent years, nano-processing of materials to enhance their magnetic properties has received considerable attention [1-23]. Thin films, compositionally modulated thin films, granular films and bulk materials have been produced by many different techniques. These include gascondensation [1-6], ball-milling [7,8], chemical processing [9,10], metal-organo complex routes, solution reduction and co-precipitation [11], sol-gel methods [12], sputtering [12-14], rapid solidification [15], devitrification of amorphous alloys [16-19] and electrodeposition [12,20,21]. The potential application of nano-engineered materials with enhanced magnetic properties has been specifically discussed for soft magnets [18,19,22,23], hard permanent magnets [15] as well as for layered materials showing giant magnetoresistance effects [13,14] and nano-composites for magnetic refrigeration [11,12].The purpose of the present paper is to review recent advances in the development of nanocrystalline soft magnetic materials by electrodeposition methods. These materials could find applications in areas such as magnetic recording heads, high efficiency electric motors, transformer cores, etc."

Jan 1, 1994

Present value maximisation studies are a useful aid in enhancing the economic performance of open pit mining operations. Maximising present value helps to reduce the risk of financial failure. Maximisation of present value also means that the capital invested is being used most efficiently. A characteristic step in determining the present value of an open pit mining operation is to set out the sequence in which increments of material (ore of various grades and waste rock) are mined. Traditionally, present value maximisation has been performed by selecting a cut-off grade for each increment so as to maximise the present value of the total operation, by an iterative process using computers. Kenneth F Lane has developed a method and applied it to many mining operations. An alternative method for determining the maximum present value of an open pit mining operation is given. In this method the maximum present value is determined by working backwards from the end of the operation life, progressively asking the question of each increment `what cut-off grade maximises the the present value at the start of mining of that increment?' The method allows calculations to be performed by a `spreadsheet' package. Present value determinations are characteristically performed under constant conditions (eg prices, costs) throughout the operation life. Unfortunately real life circumstances are rarely constant, with the costs of mining inputs rising at variable rates. The prices received for mineral products have been shown to broadly trend downwards with time in real terms. Treatment of such changes in the determination of the maximum present value of an operation is discussed.

Jan 1, 1994

By Debra A. Griffith

The U.S. Bureau of Mines currently is researching the relationship between the level of back strength and the probability of low-back injury. This report is a review of the literature and statistics on over-exertion injuries. Overexertion continues to be a significant source of injury in metal and nonmetal mining, accounting for approximately 24 pct of all injuries yearly. These injuries, particularly to the lower back, can be very expensive in human and monetary terms. An examination of the accident data on overexertion injuries is necessary to provide a background for research into prevention and/or amelioration of those in-juries. The job categories outlined in the Accident Data Analysis data base most affected are "Mechanic/Electrician" and "Mill/Plant Worker." The age group most affected is "30-39" years, and the experience group most affected is "0-.99" years. The most prevalent type of overexertion injury is "Strain/Sprain," and the trunk is the body part most often involved in an overexertion injury.

Jan 1, 1994

By H. H. Murray

In the past thirty years, there have been a large number of ownership changes in the industrial minerals arena and many medium to large companies have made industrial mineral acquisitions. Industrial minerals are exceedingly important to the achievement and maintenance of a high standard of living in the United States and in other developed countries. In the developed countries of the world the value of industrial minerals exceeds the values of the metallic minerals. In the U.S., the value of our industrial minerals is some 2 112 times that of the value of our metallic minerals. Almost every single thing we use or touch in our daily lives can be related to an industrial mineral. Examples are the construction industry, agriculture, ceramics, paper, paint, plastics, electronics, glass, petroleum, and many more in which an industrial mineral or minerals playa functional role. Industrial minerals are exceedingly diverse in their values, properties, and applications. Sand and gravel is an example of an essential industrial mineral commodity which has a low price but moves in very high volumes. Geographic location of this commodity is critical because of transportation costs. High calcium limestone or marble has a moderately high price particularly if it is white enough for use as a pigment or extender. This moves in moderately high tonnages and location is not as critical be-cause it can be shipped for considerable distances and still be competitive. Some specialty industrial minerals such as a white tale or white bentonite sells at a high price at low volumes and geographic location is not a major factor in marketing. Prices of industrial minerals do not tend to be cyclic and generally keep up with inflationary increases. Because of the diversity of industrial minerals very careful analyses of acquisitions or divestitures must be undertaken by buyers and/or sellers in order to prevent serious mistakes.

Jan 1, 1994

By E. L. Bohnet

The purpose of this paper is to translate a mining company's "Corporate Objectives" into usable and practical guidelines for long term mine design and production scheduling. These guidelines are required to ensure that both operating and development properties are designed and economically ranked on the same basis, and with the "current" Corporate Objectives in mind. Secondly, if both management and mining engineers have a better understanding of the cause and effect of corporate policies, then penalties and risks associated with various Corporate Objectives can be put into better perspective for management. Corporate Objectives, relative to usable guidelines for either short and/or long term mine planning, could be defined as one or more of the following four objectives: 1) Maximize the recovery of the economic portion of the defined geologic resources, and hence, maximize total non-discounted project cash flows and profits (most common approach in mine design), 2) Maximize the Net Present Value (NPV) of the after-tax cash flows from each existing or proposed project, either on an individual basis or in concert with other projects, including downstream processing facilities (primary method used to judge relative investment merit of a proposed development or operating concept), 3) Limit short and long term capital expenditures to a defined ceiling, 4) Maximize product output for the existing facilities in the short term, or conversely, keep commodity production at a constant level for a series of years.

Jan 1, 1994

By Richard L. Unger

The Crewstation Analysis Programs (CAP) is a package of computer programs that can be used to analyze some human engineering aspects of crewstation design (such as visibility and illumination) that have particular significance in underground mining. It was developed under the U. S. Bureau of Mines (USBM) Health, Safety and Mining Technology program at the Pittsburgh Research Center, Pittsburgh, PA. This manual describes the steps necessary to collect data in the laboratory to develop luminaire profiles for the CAP illumination analysis. It also describes how the CAP Illumination Model calculates illumination. 1.1 How CAP Calculates Illumination 1.1.1 Background -CAP currently includes assessments of visibility and illumination in the surrounding work area. The advantage of using computers for these types of analyses is that many design iterations can be tested quickly and efficiently to learn the effects of changes. This reduces the need for expensive testing using physical mockups. Another advantage is that design ideas can be tested in situations where it would not normally be possible. For instance, the effects of modifications to a lighting system or canopy design on visibility could be tested while the machine remains in service.

Jan 1, 1994

By Thomas S. Jones

This report discusses processing and use of the principal forms of manganese. The focus is on trends in the United States in the 20th century and specifics of domestic manganese material flows as of about 1990. To protect proprietary data, quantitative assessments are limited to the iron and steel industry, which accounts for about 90% of consumption. Nonmetallurgical uses are considered qualitatively. Approximate disposition of a U.S. cumulative consumption during 1901-90 of an estimated 69 million st of manganese is estimated to be iron and steel slag, 69%; nonmetallurgical uses of a dissipative na¬ture, 10%; iron and steel scrap, 9%; National Defense Stockpile, 3%; unidentified and/or including items in service, 10%. In slag from iron blast furnaces and steelmaking, manganese is present as a minor, relatively im¬mobile component, which so far has been uneconomical to recover. Construction and road building are main applications for these slags. Steel slag contains the greater amount of manganese. Studies by others of global manganese fluxes and the effect of human activities on them also are discussed. One source concludes that the main effect of human activities, via deforestation and agricultural activities, has been to increase the rate of transport of manganese to the oceans.

Jan 1, 1994

By F. Kassabji

This publication presents the main experimental and theoretical results on the recovery of aluminum scrap (dross and Used Beverage Can) without use of any addition of fluxing salts. Dross and UBC's processing experiments have been conducted in a rotary plasma furnace operating in the transferred and non-transferred mode, using different plasma gases. The investigation involved the treatment of more than 100 kg of dross and other aluminum residues using plasma torches with less than 100 kW power. The experimental work showed that this process is .far more economical and kind to the environment than the conventional route using a salt flux. An equilibrium thermodynamic calculation at elevated temperature makes possible the prediction of by-products at various temperatures for different plasma gases.

Jan 1, 1994

By T. H. Courtney, B. R. Murphy

"Nominal room temperature mechanical alloying (MA) has been used to synthesize the high melting temperature NbC and Cu-NbC composites. Elemental powders of Cu and Nb were alloyed in the presence of either graphite or hexane to form nanocrystalline NbC or a Cu-NbC composite. Through control of hot-isostatic-pressing (H/Ping) parameters, we have been able to minimize microstructural coarsening during densijication, and have processed fully dense bulk compacts of both single phase NbC and two-phase Cu-NbC while maintaining a nanocrystalline or near-nanocrystalline structure. These materials generally exhibit high strength and low fracture toughness. However, mechanical properties vary significantly depending upon the Cu content and the method of NbC synthesis (graphite or hexane).INTRODUCTIONMechanical alloying (MA) has been recently used to synthesize a variety of inorganic solids; sulfides (1-2), nitrides (3), borides (4), and carbides (3, 5-8). One advantage of this processing route is that synthesis of fairly high melting temperature materials takes place at what is nominally room temperature. Another advantage is that the structures generated are often nanocrystalline in scale, with attendant interesting properties. The consolidation of these fine structures into near fully dense or fully dense materials while limiting microstructural coarsening is a challenge that has just recently seen limited success (5, 9). We report here on some recent studies of ours dealing with crystallite size and structural analysis of NbC and CuNbC composites consolidated to full density from mechanically alloyed powders. Bulk mechanical properties and their dependence on milling parameters are also presented."

Jan 1, 1994

By M. L. Smith

The U.S. Bureau of Mines Cost Estimating System (CES) has been used for prefeasibility analysis and mine cost engineering since 1978. In the past, prefeasibility analysis with CES has involved the solution of regression equations. The new generation of CES uses an object-oriented expert system in a Windows? environment. Knowledge bases are structured around generic mine models which access shared knowledge bases for system design.

Jan 1, 1994

By C. L. Schaidle

Computers and communications technology have revolutionized many industries. In earthmoving, this revolution has just begun. The major changes are still to come, but they are just around the corner. This paper presents a vision of this up-coming revolution in our industry. This vision is comprehensive. It includes basic communication, machine monitoring and diagnostics, job and business management, planning and operations, and machine control. For our industry to realize maximum benefits from the information age, we must have a vision of the future that is shared by technologists, machinery producers, and miners.

Jan 1, 1994

By J. G. Pippenger

The Coteau Properties Company's Freedom Mine is a surface lignite mining operation utilizing large draglines, trucks and shovels, tractor-scrapers, and bulldozers to uncover a single coal seam. In 1989, a work order system was instituted to record data by equipment type, cost, productivity, and distance, and to provide historical information for planning the most efficient and economic use of each equipment type in the mining operation. This report explains how the work order system was initiated, what data is tracked, and how the data is utilized for equipment and project scheduling.

Jan 1, 1994

By G. J. Hartman

A presentation of this project was given previously at the SHE Annual Meeting, Denver Colorado February 23-27, 1987. The project concerns the development of in situ recovery of borate products from a deep-seated colemanite deposit in California. The deposit contains some 147 million tons of borate ore containing 6.4% boron oxide (B2O3). This paper involves the numerous changes in the process that has taken place since that first presentation. This paper further explains the reasons for these changes which are primarily environmentally based and secondarily capital requirements related.

Jan 1, 1994

By Patricia O. Milley

Two years ago, AlliedSignal embarked on a journey to improve QUALITY. However, the focus of this endeavor was on the CUSTOMER and not the traditional product focus. It wasn't that a focus to improve product quality wasn't fruitful in the past. We've practiced it in the chemical industry for many years with significant results. But our industry today is in a survival mode and yesterday's way of doing business is simply not good enough. In the mining industry, we have to make lug strides in how we do business or face losing our customer base. As you are well aware, other parts of the world are importing our technology at a rapid rate. We must work smarter to stay ahead of our customers ever more demanding need for higher quality at lower prices. With this as a driver, throughout the Corporation we reviewed in depth how we support our customers to keep them competitive and sought to eliminate work which did not help them reach this goal. Our first year of emphasis was on tools: how to hold meetings, gather data, and how to make decisions. This sounds very basic, I know, but you can't begin to imagine how productive meetings can become when you start with an agenda and prework delivered days in advance, and agree at the start of the meeting what should get accomplished. In the second year, we applied these tools to our work processes. We mapped how we do our work, scrutinized each step for value to the customer, and then set to work on how we could do things better. The areas we concentrated on were customer linked commercialization of new products, manufacturing and materials management. Our discussion today will focus on the commercialization of new products.

Jan 1, 1994

By R. S. Krarner

Fly ash, a by-product of coal burning power plants, poses a major problem for the utility industry since most fly ash must be landfilled. These quantities may represent as much as 20% of the total material going into landfills. A major problem with fly ash utilization is that although the ash consists of useable components, ash composition can vary depending on the types of coal burned and plant operating conditions. Ash is first characterized using SEM, image analysis, and chemical methods. Processing techniques were developed to separate ash into various components including cenospheres, magnetic spheres, carbon, and clean ash. These products are again evaluated for various utilizations before being used to produce valuable products such as mullite, activated carbon, fillers in plastics, and concrete.

Jan 1, 1994

By P. A. Hendricks

This U.S. Bureau of Mines (USBM) report identifies and evaluates factors responsible for metal/nonmetal (M/NM) underground mining accidents involving mobile equipment. Information regarding the occurrence and severity of the accidents, the type of equipment involved, the primary and contributing causes, and preventive measures is included. The goal of this report is to provide information that will aid mine operators and safety managers in the recognition of hazards associated with operating mobile mining equipment in an underground mining environment.

Jan 1, 1994

The accurate estimation of ore reserves along with capital and operating costs are two key components to the successful outcome of any feasibility study. In recent years, there have been many project failures caused by improper estimation of ore reserves. The accurate estimation of ore reserves for any deposit relies heavily on understanding its geology and underlying assumptions unique to the estimation techniques being used. The assumptions unique to commonly used traditional and geostatistical reserve estimation technique will be reviewed. The shortcomings of the estimation techniques and their possible impact on a given project's economic outcome will be discussed. The latest developments in geostatistics in overcoming existing reserve estimation problems will be presented.

Jan 1, 1994

By H. Kamarudin

The behaviour of cassiterite-sulphosuccinamate flotation system was examined in the light of zeta potentials measured by micro-electrophoresis method. It was observed that sulphosuccinamate substantially affects the zeta potentials of cassiterite, lowering its i.e.p. to pH 2.5 and indicating a specific adsorption and/or chemical interaction. The optimum concentration for flotation, as seen in micro-flotation tests, was found to be associated with the most effective lowering of the zeta potentials, the optimum pH being 3.0. The effect of cations in the pulp was examined for the presence of ferrous, ferric, aluminium and lead ions. The ions ferric and aluminium were observed to create an intense effect of increasing the potentials to positive side, possibly due to adsorption of cation hydroxy complexes, as indicated by their respective species distribution diagrams.

Jan 1, 1994

By G. Ahuja

Tests were conducted to investigate the effects of cyclone geometry, operating conditions, and particle size on magnetite classification. The effects of these parameters on the partition curve for narrow size fractions were studied using a 25mm diameter cyclone cleaning -150 µ m coal. Additional tests were run to investigate the effects of geometry and operating conditions on the slurry, solid, and water splits. The relationship between the relative density of the underflow stream and the relative density of separation was also investigated. This paper presents the results from this study.

Jan 1, 1994

By D. R. Spears

The U.S. Bureau of Mines has had an ongoing interest in developing new reagent schemes for floating Stillwater, MT, chromite ore. Previous reagent schemes have been unsuccessful in achieving complete separation, primarily because little is known about the surface chemistry of the minerals in this ore. In order to design a rational reagent scheme, a study of the binding of various functional groups (R = -H, -OH, -CO2H, -NH2) on the two components (chromite and forsterite) of the Stillwater chromite was undertaken. Electron Paramagnetic Resonance (EPR) Spectroscopy was used to determine the adsorption isotherm, from a cyclohexane solution, of spin-probes which contained the functional group of interest. This was complemented by studies of the saturation surface coverage of the spin probe on the two minerals. In each case, more sites existed on chromite than forsterite; however, the forsterite sites were more strongly binding for each functional group. The results are discussed in terms of their implications for flotation.

Jan 1, 1994