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By Gareth Barnes

Traditional approach to improvement is driven by good ideas from good people, but whilst the business case may sound good, when the project is complete, we often have not delivered on expectations.  Why not? The best way to successfully predict the outcomes of an improvement effort in a complex process is through using statistical modelling, which considers the impact of uncertainty within interacting processes.  Applying Theory of Constraints in a model helps leaders to quickly determine: Where the constraining process(es) is/are Where improvements will add the most value How much improvement should be targeted - before the next constraint takes over The confidence level of achieving a given target, which gives us a clear pathway to improvement. This paper presents an analysis of statistical modelling applications at Vale’s Manitoba Operations to achieve the 2025 targets. Using statistical modelling of the Business Structure, the team identified a series of process improvements through a Theory of Constraints Analysis. Value Stream Maps (VSMs) were used to define the required data, apply statistical modelling, and conduct training sessions enabling the Manitoba team to identify the constraining influences. Scenario testing in the Statistical models helped identify the Hierarchy of Constraints and specify the pathway to improvement. How to Improve a Business Video link https://vimeo.com/344418155

May 4, 2025

By Dr. Rory Cameron, Dr. Terry Cheng, Dr. Nadia Mykytczuk, Ian Bedard, Kristie Tarr, Ruth Joseph

Pyrrhotite-rich tailings from Sudbury, Ontario mining activities are known to contain significant amounts of EV metals, such as nickel and cobalt.  CanmetMINING has developed a novel bioleaching process for recovering the nickel and cobalt (both critical for vehicle electrification) from tailings that incorporates partial neutralization and iron removal in the bioleaching circuit; bench- and pilot-scale tests have resulted in excellent nickel and cobalt recovery over a range of temperatures.  However, this process generates a new bioleach residue, which is heavier and more voluminous than the original tailings due to pyrrhotite oxidation and jarosite formation during the bioleaching process. This residue can be problematic for long-term disposal. A possible solution being studied for this issue is using mine backfill as a disposal mechanism.  Underground backfilling allows for effective re-purposing of mine waste, however the backfill must also be able to withstand a certain load, since in most cases it is used as an underground construction material, such as in cut-and-fill mining methods.  Therefore, the composition of the mill tailings must be such that when combined with a binding agent and pumped underground, the slurry or paste is then able to withstand a certain load within a certain period of time.  Unfortunately, high-pyrrhotite content tailings, commonly found on mine sites in Ontario and Quebec, are reactive and can easily oxidize and produce acidity and/or metal-laden drainage under some disposal conditions. This means that the pyrrhotite in the tailings can lead to acid mine drainage if stored on surface, however, it can also cause strength degradation if re-purposed in too high a concentration in underground mine backfill.  The research being done at CanmetMINING related to the bioleaching process is aimed not only at recovering nickel and cobalt from mine tailings, it is also being used in an attempt to neutralize the tailings to reduce acid mine drainage and backfill strength degradation. This paper reports on research designed to evaluate different options for transforming the bioleaching process residue into iron oxide phases, for better environmental footprints if stored on surface, as well as increased disposal possible, if re-purposed as underground mine backfill material.  

May 4, 2025

By Joel Lööw, Johan Larsson, Stig Vinberg, Malin Mattson Molnar, Mats Jakobsson, Jan Johansson

The mining industry is undergoing rapid transformation, driven by technological advancements, sustainability concerns and demographic shifts. This transformation will put more younger people in management positions. This study provides valuable insights into the leadership behaviors of younger and older managers within a large Swedish mining company, highlighting the importance of managerial experience and targeted training programs to foster effective leadership, particularly in the context of change management. The findings emphasize the need to create work environments that support managers to develop their leadership, contributing to improved employee well-being, operational efficiency, and adaptation to the changing demands of the modern mining sector.

May 1, 2025

By Ashma Singh, Nichole Maistry

Due to declining iron ore grades, low-grade ores with complex mineralogy — namely, banded iron formation (BIF) — are being explored to maximize iron ore resources and increase the life of mine. Flotation is the standard global process used for the beneficiation of BIF ores, as it is a complex ore reserve, and liberation is typically achieved below 1 mm. This study focuses on the flotation of a South African BIF, evaluating its response to different collectors, as well as effect of grind. As flotation is an expensive process and South Africa ranks high on the production cost curve, preconcentration by gravity or magnetic separation is performed prior to flotation. Thus, flotation was also performed on a gravity concentrate to determine if a grade suitable for steelmaking (approximately 63 percent) is achievable. The results indicate that the use of an alkyl ether amine-based collector partially neutralized with acetic acid is suitable for separation of hematite from illite and quartz at high pH values. Further optimization tests are being pursued to improve overall recovery and grade.

May 1, 2025

By Katherine Hynard, Colin Eustace

Suboptimal decisions introduced during the mine planning process are generally a consequence of both a myopic view of planning objectives as well as time and resources available to convert longer-term plans into execution plans. Erosion of strategic mine plan value in conversion to execution plans is likely to amount to billions of dollars each year. When integrated with operations data feeds, simulation and optimization tools can be used to preserve the value in the strategic mine plan. Optimization models are capable of both automating production of execution plans and improving performance. This reduces the manual burden of revising plans while improving alignment with long-term production objectives. Simulation models can also support the process of developing effective execution plans by providing forward visibility of mine operations performance. They can also be used to test the robustness of optimized execution plans and response to operational variability and disturbances.

May 1, 2025

By Jonathan K. Hrica, CASSANDRA L. HOEBBEL, Jennica L. Bellanca

Accidents involving powered haulage and mobile equipment like haul trucks are a major safety concern in the U.S. mining industry. They account for more than 50 percent of surface mine fatalities each year [1]. A recent National Institute for Occupational Safety and Health (NIOSH) analysis of 91 fatal incidents identified loss of vehicle control and situational awareness as key contributors [2]. However, the first-hand perspectives of operators are often missing, emphasizing the need for deeper insights into operators’ decisionmaking, lessons learned, sensory cues and mental strategies used during near-miss events. The findings in this analysis will help inform the development of training and safety solutions to prevent or reduce haul truck accidents.

May 1, 2025

By Carter Brown, Kate Brown Requist, Eric Lutz, Moe Momayez, Athira Satheesh

New mining health and safety training modalities are becoming increasingly prevalent in the underground mining industry. Various digital training tools have been developed over the past several years, but the extent of their use remains unclear. Advances in gamified training by way of computerbased video games and virtual reality (VR) have opened a new avenue for mine rescue and self-escape training, but these methods have not been widely adopted across the mining industry. Mine rescue and self-escape situations require a mix of in-classroom training as well as live drills, but it is important to assess the extent of and effectiveness of new training modalities. The Mine Rescue and Self-Escape Survey (MRSES) was distributed to underground mining operations to collect perceptions of current training effectiveness as well as willingness to adopt new training methods as a complement to live rescue drills. Responses from the MRSES indicate that adoption of digital training technologies has been slow-going despite an interest in their use. Further, there appears to be no meaningful connection between more frequent escape and rescue training and feelings of emergency preparedness. With relatively little use of already developed digital training tools but an interest in their adoption, it may be time to reassess current emergency preparedness training philosophies.

May 1, 2025

By David Graham

Dedicated by President Franklin Roosevelt in 1940, Chickamauga Lock and Dam is located just upstream of Chattanooga, Tennessee, at Tennessee River Mile 471. The Tennessee Valley Authority (TVA) owns the structure, and the U.S. Army Corps of Engineers (USACE), Nashville District, operates and maintains the navigation lock. Constructed under the direction of the TVA as part of the New Deal, Chicka- mauga Lock and Dam serves the TVA's mandates of flood control, improved navigation and hydroelectric power generation along the Tennessee River and its tributaries. Chickamauga is one of the busiest navigation locks in the country, handling nearly 10 million tons of freight each year. As a critical link in the transportation of goods, particularly bulk commodities like coal, grain and chemicals, its efficiency directly im- pacts the economy. The Chickamauga Lock was designed by the USACE and was based on the design of Guntersville Dam downstream. The Chickamauga Lock is 60 ft (18 m) wide by 360 ft (110m) long. However, the dam was designed to allow a larger 110 by 600 ft (34 by 183 m) lock to be added if needed in the future. That future is now, and the USACE is leading a project to construct a new, larger lock to increase the flow of river freight and address structural issues. Extensive concrete surface cracking was observed soon after the lock and dam was completed in 1940. The cracking is a result of alkali-silica reaction (ASR) and alkali-carbonate reaction (ACR), which cause the concrete to expand. The existing lock suffers from structural deficiencies resulting from ASC and ACR concrete expansion, making a new lock that much more critical. The overall cost of the lock replace- ment project is estimated at $954 million with operational completion estimated in 2028 and final completion estimated in 2031. As part of the project, C.J. Mahan Construction Company was awarded a $61 million contract to con- struct the upstream approach walls that will guide vessels into the new lock. The approach walls were planned to be sup- ported on 28 drilled shafts of 6.5 ft (2 m) diameter. The contract also included a nonproduction technique shaft with a bidirectional load test. The baseline design included four piers, each sup- ported on four drilled shafts, and two nose piers, each supported on six drilled shafts. The drilled shafts included 6 ft (1.8 m) diameter rock sockets ranging in length from 25-45 ft (8-14 m).

May 1, 2025

By Robert Tonning

Boston's Landmark Center, a historic site in the Fenway neighborhood, is undergoing a major transformation. Originally built in 1928 by Sears, Roebuck & Company, the building is being repurposed into a mixed-use development that will breathe new life into the structure while preserving its historical significance. A key aspect of Historic photo of Bo this project is the deep foundation system, which employs drilled micropiles. While these have been commonly used on construction projects for the past several decades, these truly "super piles" pushed con- ventional limits of both drill depths and working capacity in order to meet the project's requirements. The installation of these micropiles presented several challenges, from extreme depths and high capacities to tight timelines and complex site conditions. This article explores the engineering feats, challenges faced and innovative solutions that were developed and implemented throughout the process. Thanks to creative problem-solving and collaboration with the wider pro- ject team, Phoenix completed its work as a geostructural subcontractor ahead of schedule. The Landmark Center has a rich history in Boston's Fenway neighborhood. Before the present building was constructed almost 100 years ago by Sears, the site had been home to a number of factories, warehouses and other industrial buildings dating back to the late 1800s. The location was also near the former Fenway Railroad Yard, a modest transportation hub that served the surrounding area at the turn of the 20th century.

May 1, 2025

By Matthew Conte

Overgrown vegetation. Little to no effective drainage. Three or four different construction methods over the years. Live loads from above. Property line to navigate. Buildings on either side. I drove by this site for years wondering when someone was going to have to deal with it. That day came, and it turned out to be us. This particular project had typical attributes: limited space and restrictive conditions. This retaining wall system supported the neighbor's parking lot above, roughly 14 ft (4 m) in elevation change. At a length of 92 ft (28 m), both ends of the wall abut an active building in the lower property. Only a small parking area of roughly 50 ft (15 m) in depth lies before the heavily traveled state route in Westport, Connecticut. Roughly two-thirds of the existing wall was tiered, and the other third was taller, with a concrete masonry unit (CMU) wall that appeared to be part of a former structure. The existing wall was failing and leaning over the parking spaces. The drainage system showed signs of failure, and the vegetation was clearly retaining moisture and frost was heaving the walls a little more each year. During the initial kick-off of the project, it was decided we would immediately shore up this taller portion of the existing wall. That shoring would stay in place through construction. With active tenants and neighbors, the property owner needed a solution that would allow businesses to stay open and limit any disturbance to the above property. Very little documentation existed showing the construction of the walls or the soil conditions. Above, the neighboring property had added a small retaining wall when its parking lot was constructed. Soil borings were found, but nothing showing details on that newer retaining wall. The borings indicated structural fill was compacted in lifts beneath the lot, but nothing indicating any geotechnical measures beneath the wall, at the property line. We were forced to design a new wall considering the 'worst case' conditions. This new wall also required construction methods that would allow all aspects of the surrounding area to remain intact.

May 1, 2025

By Keshab Sharma, Jibendra Misra

Caissons and piles are mostly used as foundation types in bridges. Caissons are particularly suitable for bridges with expansive spans, locations with deep alluvial deposits, soil prone to lique- faction and when there's a notable risk of vessel collisions. However, they face challenges related to sinking and limited resistance against earthquakes. On the other hand, pile foundations are not well suited for deep-water scenarios due to their excessive length, diminished rigidity, susceptibility to vessel col- lisions and complications associated with construction. A potential solution to the issues mentioned above could be the adoption of CCPF. These foundations can also be applied to enhance existing caisson. foundations through retrofitting techniques in wind turbines, trans- mission lines and bridge foundations, demonstrating their adaptability and potential for improving the perfor- mance of foundation systems. There has been successful implementation in China, as evidenced by projects like the Qiongzhou Straits Bridge and the Longna Highway Yangtze River Bridge. Moreover, this foundation approach has been adopted for numerous cross- sea bridges globally, including ex- amples like the Benicia Martinez Bridge (U.S.) and the Hitsuichi-Jima Bridge (Japan). Research from 2016 has shown CCPF systems can be potentially used for offshore wind turbine foundations and retrofitting existing caisson foundations. The construction sequences of CCPF systems involve the sinking of caissons followed by driving the pile beneath the caisson. There are two possible options for connecting the pile with the caisson. The first option can be provided by ending the pile at the bottom plug level of the caisson, in which the pile is threaded into the caisson bottom to achieve a connection joint between the caisson base and the pile tops. This methodology enhances the flexibility of the foundation. The second method is to continue the pile up to the cap level of the caisson. The pile up to the cap level of the caisson provides better integrity than the first option between caisson

May 1, 2025

By S. Mudau, P. Mohasoa, M. J. Cole

Derelict and ownerless (D&O) mines in South Africa have been an ongoing concern for over a decade. While some progress has been made to rehabilitate D&O asbestos sites, significant work remains, exacerbated by the growth in illegal mining. There are concerns regarding the accuracy and transparency of the D&O database, lack of oversight, and constrained funding, and the government is increasingly looking to the private sector to fund rehabilitation. Given these challenges, a new, sustainable approach to D&O sites in South Africa is needed to bring clarity and transparency to the process, recognise responsibilities and promote partnerships, and explore economic opportunities at D&O sites to reduce the financial liability and respond to the growing demand for critical minerals. This article has three components: i) reviews of international D&O good practices; ii) it analyses South Africa’s current approach and the D&O sites; and iii) proposes a D&O framework that addresses data, risk ratings, responsibilities and rehabilitation, economic opportunities, and stakeholder engagement. The study finds that the majority of the 6,100 so-called abandoned D&O mines are quarries and mine site features, 16% are operational, at least 11% have owners, and only 752 (12%) require rehabilitation. The framework aims to bring clarity and fairness to decision-making and to assign risk and responsibility for rehabilitation and seeks to incorporate economic opportunities to reduce the financial burden of rehabilitation, create jobs for local communities, and respond to the growing demand for critical minerals for the clean energy transition.

Apr 25, 2025

By S. J. van Wyk, A. S. H. Haagner, A. Abraha

Opencast coal mining is responsible for the greatest area of land disturbance across all of the commodity types in South Africa. Many thousands of hectares have been rehabilitated to date and, although rehabilitation performance is not always measured or reported, a significant database, spanning 24 years, has now been analysed to identify the main shortcomings holding back rehabilitation sustainability across the industry. Data from 48 different collieries with rehabilitation performance scores measured from 2000-2024 were analysed. A standardised assessment framework was implemented at all 48 collieries, focusing on aspects of land capability, soil fertility, landscape form and drainage, vegetation species composition and basal cover, implementation of maintenance programmes, and prevalence of invasive alien plants. The findings show that, although invasive species management, plant species composition, and plant basal cover are often adequate, the implementation of aftercare and maintenance programmes (influencing soil fertility) and deficiencies in overall landform design and drainage systems are most significant in preventing overall rehabilitation progression and self-sustainability. Integrating these during design and rehabilitation execution, followed by intensive maintenance (especially in the first five years post-topsoiling and seeding) will be key for the overall industry performance to improve to acceptable levels. The database is biased towards collieries that actually do undertake rehabilitation and that do measure it, hence the actual industry performance is likely worse than what is presented. Due to the substantial hectarages involved and the main post-mining land uses being grazing and crop production, the industry cannot afford to keep perpetuating deficiencies in achieving the foundational aspects of rehabilitation that would pave the way for sustained economic future use.

Apr 25, 2025

By S. J. van Wyk, A. S. H. Haagner

Land rehabilitation transcends the mere establishment of vegetation across disturbed landscapes; it should be conceptualised as a specialised ecological reconstruction process. This process necessitates a long-term perspective on the success of land repurposing. It requires a continuum of inputs specified and managed by a dedicated and qualified custodian to ensure the sustained economic viability and ecological sustainability of the land. Based on the authors’ combined experience and field observations over more than five decades, they advocate for an urgent shift away from traditional land rehabilitation practices toward a paradigm centred on land capability reconstruction and active stewardship. The prevailing rehabilitation culture has overly simplified the process to a mere revegetation exercise, which is fundamentally incompatible with the comprehensive requirements for sustainable land capability. While the regulatory framework provides valuable guidance for obtaining a mine’s social license to operate, a paradigm reset is essential. Mining companies must prioritise rehabilitation quality, set achievable sustainability goals, and establish clear pathways and milestones to meet relinquishment criteria. Currently, the status quo view—a model reliant on outsourced contracting and agricultural approaches—is that mine rehabilitation is a one-time intervention rather than a complex, systemic, and long-term process. This perspective presents significant challenges, as the success of ecological interventions can only be accurately assessed over extended timeframes, often spanning decades. Shortsighted rehabilitation specifications, coupled with practitioners operating within agricultural decision frameworks, frequently overlook the necessity for integrated rehabilitation expertise and the scientific foundation essential for designing and implementing effective ecological outcomes. A lack of long-term monitoring information impedes the required adaptive management of rehabilitated systems and, therefore, delays the transition towards final land use. This short approach costs the mining industry millions annually, often without recognising the inadequacies in long-term liability mitigation and the substandard ecological success achieved. The disconnect between procurement processes, the qualifications of service providers, and the unclear pathways to relinquishment can impede successful rehabilitation outcomes, frequently undermining progress toward sustainability milestones. Unless there is a fundamental reset of the land rehabilitation culture, pursuing sustainability will remain an elusive and perhaps impossible objective. Consequently, mining companies may hesitate to fully commit to sustainable land rehabilitation practices, as the prospects for relinquishment and final closure remain uncertain at best.

Apr 25, 2025

By O. Koatlhai

Mine closures have traditionally prioritised environmental rehabilitation, often overlooking the deep socio-economic disruptions that follow, particularly in mining-dependent communities. This paper argues that mine closure should not mark the end of prosperity but rather the beginning of a sustainable transition. The coproduction model, which integrates community participation, governance, and economic planning, offers a transformative approach to closure planning. Drawing on case studies from Ghana, Zambia, and Indonesia, this research examines the successes and failures of past closures, highlighting the critical role of stakeholder engagement, skills development, and economic diversification. By incorporating emerging technologies such as AI-driven economic forecasting, blockchain for governance transparency, and decentralised finance (DeFi) models, mining companies can ensure a just and sustainable post-mining future. This study challenges outdated closure models and presents a forward-looking strategy that sees mine closure not as an endpoint, but as a catalyst for social resilience and economic transformation. It underscores the need for policy reforms, stronger governance, and investment in alternative industries to prevent mining towns from becoming economic wastelands. By shifting the paradigm from remediation to regeneration, this research calls for a new era of mine closure planning that puts people and prosperity at its core.

Apr 25, 2025

By L. Marais

The development of a post-mining economy is generally framed as accessible and desirable and something that mining companies, consultants, and the government can, and should, plan for. It is indeed possible. Yet, most mining regions, other than the big metropolitan municipalities, find economic diversification after mining challenging, despite their grand plans, consultant reports, and company intentions. Their efforts blind them to other ideas that are often prerequisites to diversification. This paper highlights some economic and social misconceptions about economic diversification and explains where planning goes wrong. Mistakes typically stem from ignorance and misunderstandings. Planners and policy makers fail to grasp the essential requirements for economic diversification. They underestimate the structural constraints created by mining. They do not see how mine rehabilitation is linked to economic diversification. They generally do not understand the South African space economy or the nature of new economies. The paper also proposes a more careful consideration of those economic aspects that mining cities have control over, such as land use management and infrastructure. The paper further explains how understanding long-term dependencies can help prevent governance failures. The social disruption that accompanies mine decline and closure must be recognised and dealt with. The mines must plan for decline as a way to resuscitate the economy. It concludes with a framework for assessing and developing a post-mining economy.

Apr 25, 2025

By Yi-Hsuan Chen, Jürgen Brune, Candace S. J. Tsai, Alejandro Munoz, Connor Krause

This study highlights the significant presence of submicrometer- sized airborne particles in underground coal mines, especially around the belt conveyor drift areas. Using realtime instruments and gravimetric samplers, the assessment revealed that particle concentrations were notably higher in the belt entry compared to other locations, with a strong presence of submicrometer- and nanoparticle-sized dust. The study’s findings emphasize the importance of addressing small particle exposure, as these particles, composed of harmful substances like calcium, copper and iron, can pose serious health risks to miners. This research emphasizes the importance of improving air exposure estimation through more effective monitoring and characterization techniques to better understand and reduce workers’ exposure to hazardous airborne particles in the mining environments.

Apr 1, 2025

By Adrianus Halim, Jenni Hooli, Bartłomiej Skawina, Fredrik Sundqvist

Transitioning from diesel-powered loading and hauling machinery to battery-electric vehicles (BEVs) responds to the need for deepening underground mines as regulations become tighter. When using BEVs, exhaust gases and diesel particulate matter (DPM) emissions can be eliminated, and the energy required for the machines is used more effectively. Unlike their diesel counterparts, which are refueled, BEV loading and hauling machines — specifically, load haul dump (LHD) machines — can use battery swapping. This brings additional aspects to the operation that need to be considered, which have not yet been studied extensively. This study used discrete event simulation (DES) to analyze how the different numbers of BEV LHDs affect queueing and productivity when using different numbers of batteries and different swapping times in an underground block cave mine. The results identified the formation of working groups, where the machines swapped their batteries concurrently within each group, and their relation to the queueing time. Additionally, the minimum number of batteries per machine was identified to maximize productivity while minimizing queueing time. This study demonstrates DES as a powerful tool to assess and analyze conceptual systems and identify their underlying structures, which can enhance the deployment of BEV LHDs in underground block cave mine operations.

Apr 1, 2025

By Georgios Bartzas, Vasiliki Karmali, Konstantinos Komnitsas, Anna Kritikaki, Dimitra Vathi, Stylianos Tampouris, Arne Peys

Large volumes of slags, with varying mineralogical and geochemical characteristics, are produced annually by the ferrous and nonferrous metallurgical industry. Most of them are considered as potential secondary resources and may be valorized, following the principles of circular economy, for the recovery of critical elements, including energy transition metals. Apart from the economic benefits, valorization of slags may contribute to the competitiveness of the metal industry and the conservation of natural resources. Valorization also results in minimization of environmental impacts on soils and waters in slag disposal areas, due to the prevention of solubilization and subsequent migration of potentially hazardous elements. The present study utilizes ferronickel (FeNi) slag for the production of alkali-activated materials. The effects of the main experimental parameters, including sodium hydroxide (NaOH) molarity, silica/sodium oxide (SiO2 /Na2O) molar ratio in the activating solution, precuring and curing time, curing temperature and aging period on several properties of the final products, are assessed.

Apr 1, 2025

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

This study investigated the performance of citric acid as lixiviant for cathode material from end-of-life lithium-ion batteries (LIBs). Black mass containing 84.2 weight percent MNC (LiNi0.45Mn0.4Co0.15O2) and 15.8 weight percent LCO (LiCoO2) material was leached at solid-to-liquid ratios of 20, 50 and 100 g/L. Leaching with 1.5 M citric acid, 2 volume percent H2O2 and a solid-to-liquid ratio of 20 g/L at 95 °C extracted 90 percent Co, 95 percent Li, 94 percent Mn and 94 percent Ni within 20 min. At the highest solid-to-liquid ratio of 100 g/L with 1.5 M citric acid, 10 volume percent H2O2 and 95 °C, 84 percent Al, 84 percent Co, 87 percent Li, 86 percent Mn and 96 percent Ni were leached after 40 min, producing a leach solution containing 0.68 g/L Al, 20.0 g/L Co, 6.0 g/L Li, 13.6 g/L Mn and 19.3 g/L Ni. Using stepwise addition of H2O2, instead of initial bulk addition, did not significantly improve the leaching efficiency but did reduce the required leaching time. Temperature control of the reactor was also more manageable with stepwise addition of H2O2, and evolution of gas was less vigorous. It was observed that the leaching efficiencies of Co, Li and Mn decreased slightly at solid-to-liquid ratios of 50 and 100 g/L, while the leaching of Ni increased slightly. The solution leached at 20 g/L could be stored for six weeks without any spontaneous precipitation. However, solutions leached at 50 and 100 g/L showed changes in concentration after one month of storage, suggesting that processes that have a large material throughput and use high solid-to-liquid ratios around 100 g/L must ensure that the solutions are not stored for extended periods of time.

Apr 1, 2025