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By Xiao Huang, Jean-Francois Thibault, Ali Merati, Prakash C. Patnaik

Single-crystal nickel-based superalloys are the current state-of-the-art technology for the manufacture of turbine blades. This technological improvement of the turbine blade has brought a considerable increase in its cost. Repair and overhaul of service stressed single crystal turbine components is an economic necessity for life cycle cost reduction of engines since the cost associated with replacement is significantly higher than its counterpart polycrystalline component. This paper will first review the recently reported research in developing repair technologies used for DS and SX components. These techniques repair the crack or defect while at the same time ensuring that the mechanical properties do not deteriorate and, more importantly, that the single-crystal microstructure is not jeopardized. It will then be followed by a brief overview of the research conducted and initiated by the authors with regards to the repair of single crystal alloys.

Jan 1, 2004

By A. More, J. Bullón

Metal casting is one of the most important operations in ferroalloys factories. After the tapping of the furnace and the depuration of the metal, the preparation for customers with cooling, crushing and sizing begins. In total production costs, this contains around 8 % of the total cost of the metal, depending on the value of the fines and other important parameters. From an investment point of view, this represents around 20% of the total capital for a new furnace. Casting onto a water-refrigerated copper plate is not new for molten metals. In steel, continuous casting machines are normal in every factory. Water granulation casting exists at some ferroalloys plants. However, the majority of plants and production technology still use the technology of lumping, crushing and sizing. This technology is time consuming, produces fines and requires a relatively large work force. In 2001, Ferroatlantica put into operation a new water-cooled copper casting-machine, which seems to be a very convenient solution to solve all these problems. It is in operation at a silicon factory; the same place where the new ELSA electrode was developed for silicon metal production. This paper describes our experiences using it.

Jan 1, 2004

By J. Björkvall, S. Ångström, L. Kallin

In this paper results from industrial trials of CaC2 injection during stainless steel production in an electric arc furnace at Sandvik Steel is presented. The main purpose of the investigation was to analyse the effect of the injection on slag foaming and final chromium oxide concentration in slag. The results show that both an increase in slag foaming and a decrease of the final chromium oxide could be obtained during the charges with CaC2injection. On the basis of the results, the economical requirements are also discussed. Both the technical and economical requirements could be achieved for steels alloyed with Mo. In order to secure the economical requirements for all steel grades of interest, the injection technology must be further developed. It would also be important to utilize the positive effect of the slag foaming on the electric energy consumption. The work has been performed as a part of MEFOS frame research programme with participants from Sandvik Steel, AKZO Nobel and Avesta Polarit. Keywords: stainless steel, EAF, slag foaming, injection, CaC2

Jan 1, 2004

By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By F. -Z. Ji, G. A. Irons, M. Barati, K. Coley

The use of oxygen in electric arc furnace steelmaking is tied to the use of fossil fuels, and slag foaming. The current work examines the kinetics of carbon injection into EAF slags especially the saturation injection rate and available reaction area in the slag foam. Based on individual rate data and experimental gasification rates of carbon in the slags, the available reaction surface area in the gas bubbles was found to be around 1900¬4700 cm2.kg-slg-1 for carbon injection into EAF like slags at appropriate injection rates and steel making temperatures. The ratio of number of bubbles to number of particles is 1 to 17 and the weights of carbon per unit reaction area are 0.001-0.008 gC-cm-2. Using the relationship between active reaction area and x supplied in this study, the gasification rates of carbon in slags can be estimated with gas-slag interfacial reaction rates.

Jan 1, 2004

By W. D. Gould, A. Kapoor

Acid mine drainage (AMD) is characterized by low pH and high concentrations of sulfate and dissolved metals such as iron, manganese, aluminum, zinc, and copper. Chemical treatment of AMD achieves pH neutralization and toxic metal removal but also produces large quantities of bulky sludge that requires long-term storage facilities and monitoring. Chemical treatment of AMD achieves only partial removal of sulfate (SO4) and total dissolved solids. Sulfate reducing bacteria (SRB) have been used for the removal of sulfate from industrial process wastewaters. The biological sulfate reduction process generates sulfide and alkalinity. The sulfide produced in the biological sulfate reduction process is used to precipitate metals present in AMD as their respective sulfides and the alkalinity generated is used to neutralize the AMD. This review article will present an overview of biological sulfate reduction processes using SRB, bioreactor configurations, AMD treatment studies, and full-scale systems in operation for the treatment of acid mine drainage.

Jan 1, 2004

By S. J. Frank

The development of feedforward semi-empirical control models for furnaces and the evaluation of mass balances are based on plant data. The models can only be as good as the data and it is therefore required to know the inherent uncertainty associated with the plant data. This uncertainty stems mainly from the fact that the slag, alloy or dust, have a distributed nature that depends on the degree of mixedness. It is commonly accepted that melts from open bath furnaces are well-mixed, and submerged arc furnaces less so. The impact of this assumption is significant, as a reasonably homogeneous melt could be represented by one sample only. As so much of metallurgical control depends on the assay information of the alloy and slag melts from furnaces, it was decided to characterise the possible variation in melt chemistry and temperature. Sampling campaigns and continuous temperature measurement of the melts were performed for different alloy and slag taps at a major ferrochrome producer. Both a submerged arc furnace and open arc furnace are evaluated in this way, by way of comparison. The slags of both open arc and submerged arc furnaces were found to be of similar degrees of homogeneity, with much spatial variance in the reducible iron and chromium oxides. However, it was found that the alloy melts deriving from open arc furnaces were significantly less homogeneous than the alloy derived from submerged arc furnace alloy production. The compositional variance could be related to the furnace operating conditions and it affects both metallurgical accounting and process control. In all cases it was found that the variance in melt solute components are larger than can be ascribed to analysis instrument error. It will be shown how this predetermined variance in melt composition could be included in process modelling and control.

Jan 1, 2004

By C. Anim-Sackey, R. K. Amankwah

Some large-scale mining companies in Ghana have adopted proactive management strategies in dealing with small-scale (galamsey) miners who have encroached on their concessions. This has been mainly achieved by ceding portions of the concessions held by the companies to the Minerals Commission of Ghana for licensing to the small-scale miners. This development has created an amicable relationship between the mining companies concerned and the galamsey miners in their host community. Ghana’s small-scale gold and diamond industry The small-scale gold and diamond mining industry in Ghana has existed for many centuries as an informal sector. Since the regularization of the activities of small-scale mining in 1989, two types of small-scale miners have emerged — legal and illegal.

Jan 1, 2004

By L C. Thompson

BioLix is the term for a new class of biologically-derived lixiviants for precious metals (gold and silver) recovery. BioLix can be used as an alternative to cyanide on virgin and spent ores. The BioLix process is based on inducing microbial enzymatic reactions that generate organo-lixiviant chemicals. The bioprocess involves a two-stage culture strategy. First, specialty microorganisms are cultured to generate a high biomass. Then, a food-grade quality amendment is introduced that forces the microorganisms to produce the organo-lixiviant. The second-stage culture is applied to the ore where the microbial/lixiviant system acts on mineral surfaces to extract precious metals. The process operates at ambient temperatures and near neutral pH. This paper will examine the BioLix process through an extensive laboratory development and demonstration project. Laboratory development consisted of identifying and isolating specialty microorganisms and inducing agents for the production of the organo-lixiviant solutions. A demonstration was performed on low-grade and high-grade oxidised ore from the Buffalo Valley mine in Nevada, USA. Results indicate that the BioLix process was comparable to cyanide in terms of gold recovery and operated at near neutral pH and ambient temperatures. Applications for the BioLix process will be discussed including spent-ore re-leaching, cyanide replacement for virgin ore, and in situ mining.

Jan 1, 2004

By W. M. Silva, PAP. Miotto, M. A. P. Silva, V. P. Ramos, L. R. M. Bittencourt

The major cause of breakdown of anode baking furnace fluewalls is chemical corrosion, which leads to deterioration of the properties of the bricks. Subsequent deformation of the fluewalls occurs, and also extensive cracking of the lining is observed. The present work studies the major changes of the brick during the operation of the furnace, after 22, 60 and 90 cycles of baking; in two different regions: upper and lower. Due to excellent cleaning conditions of the butts, negligible amounts of fluorine were found in the bricks. The major contaminants found were carbon, sulfur and alkali compounds, all of them present in the anode baked during the process.

Jan 1, 2004

By D. C. Van Aken, O. J. Rajtora

A research effort sponsored by the Department of Energy (DOE) and several steel producers, is investigating the benefits of coating steelcasting nozzles with various materials. Coatings were applied to casting simulation nozzles made from industrial tundish nozzles (primarily of magnesia) and industrial submerged entry nozzles (SEN's) (primarily of alumina-graphite) in order to extend casting time prior to nozzle clogging. Nozzles were coated by air plasma spray (APS) using a 9M series APS system from Sulzer-Metco. The ability of these coatings to provide protection from clogging was evaluated using a steel casting simulation. Substrate-coating compatibility was characterized using optical and SEM microscopy.

Jan 1, 2004

By A. J. Jager, D. P. Roberts

The stoping of platinum orebodies in the Bushveld has in the past been accomplished by using in-stope pillars to ensure stability of the workings. In the future, the use of continuous mining machines to mine the platinum orebodies is probable. It is not envisaged that such machines will cut in-stope pillars. This paper describes the alternative support systems that will replace the pillars and the stope geometries that will be required for this type of mining. The paper describes how the support resistance provided by in-stope pillars in current mining was determined and then evaluates support systems that can substitute for these pillars. Conceptual layouts based on existing breast mining layouts are presented. The layouts consist of panels of up to 100 m face length between rigid strike stabilizing pillars. A number of design charts are then proposed that allow for the design of appropriate support systems.

Jan 1, 2004

By I R. F MacCulloch, K Jones

Pintail Systems, Inc, a Colorado USA based company has developed and commercially applied bioremediation processes for biological detoxification of cyanide compounds in mine waste. Site-specific microorganisms are isolated from spent ore, tailings or process solutions and augmented in the laboratory for cyanide oxidation, denitrification and metal biomineralisation. Biological processes typically treat complex contaminants (cyanide compounds, soluble metals and nitrates) in a fraction of the time of conventional remediation processes. Cyanide is used in microbial metabolic processes as a carbon or a nitrogen source. Biological detoxification processes applied at the end of mine life can end long-term liability and perpetual monitoring and containment. Case studies from commercial application and demonstration programs for the US Environmental Protection Agency will be presented in this paper.

Jan 1, 2004

By J. P. Bennett, W. E. Lee, S. Zhnag, K. S. Kwong

An EAF slag properly saturated in MgO results in increased refractory service life and steelmaking efficiency. A computer model was developed using phase equilibrium data from the MgO-CaO-SiO2-FeO, MgO-CaO-Al2O3-SiO2 and SiO2-CaO-Al2O3-FeO systems to predict MgO saturated slag chemistry. This model has been successfully applied to a commercial EAF, although disciplined plant practices are required to achieve benefits from slag chemistry control.

Jan 1, 2004

By B. Samanta

A quality characteristic analysed through construction of the Shewhart control chart is required to be normally distributed. In mining applications, this assumption is often violated as many quality characteristics follow skewed or lognormal distribution. In this paper, two methods were investigated using a heuristic approach for setting up the control limits for a skewed population. Based on these approaches a Mode chart, and a Weighted Variance (WV) control charts were constructed. The performance of the proposed methods was compared with the normal based Shewhart method through a case study conducted in a surface mine supplying iron ore to a steel plant. A simulation study was also conducted to evaluate the effectiveness of the proposed methods over the Shewhart method. The study revealed that the Shewhart control charts generated more out of control alarms compared with the Mode and Weighted Variance control charts for a skewed population of Fe%. The simulation results also revealed that for extremely high skewed population, the WV control chart and Mode control chart provided higher probability of coverage than the Shewhart method; although the detection rate (probability of detection) of out of control condition for these methods was slightly reduced compared with Shewhart method.

Jan 1, 2004

By T. Takahashi, K. Oyamada, Y. Miyata, T. Isoo

The carbonation reaction of steelmaking slag has been known for many years. However, the size of blocks manufactured from this by-product material has been limited due to the difficulty of achieving a uniform reaction throughout the block. Using newly developed conditions, large porous slag blocks (1.0 x 1.0 x 0.5 m) were produced by car¬bonation of steelmaking slag with the optimum amount of water and supplying CO2 deep into slag powder compacted in molds. The development of these blocks has great poten-tial to solve the problem of slag utilization, for example, by recycling slag in large car¬bonated blocks for artificial fish reefs and seaweed cultivation beds. This paper de¬scribes the carbonation reaction, the new process for producing large slag blocks, and the utilization of blocks in past and recent years.

Jan 1, 2004

By J. H. Baek, S. Alexandrovskii, D. W. Lee, B. K. Kim

Nano-phase titanium carbide was synthesized by Mg-thermal reduction process using a novel route of Mg-thermal reduction. The processes are based on I) feeding of TiC14+CxC14 x = 1, 2 ) solution into liquid magnesium, 2) Mg-reduction of metal chlorides, 3) TiC formation by the reaction of released Ti and C atoms, and 4) vacuum separation of residual liquid phases of Mg and MgCl2. In this study, the process for titanium carbide production with composition close to stoichiometry and the minimum content of impurities was optimized with the various process parameters such as concentration of initial solution, its feeding rate and reaction temperature, as well as a kinetic study.

Jan 1, 2004

By J Liu

In situ coal gasification is a method of extracting a high proportion of the energy value from coal without the need for mining. In situ conversion of coal to combustible gases is achieved by drilling wells into the seam, injecting gasification agents and initiating combustion. The product gases are then extracted to surface using production wells. These gases are clean energy sources for power generation, heating or synthetic fuel production. In situ coal gasification is of particular interest with respect to its lower environmental impact, potential application to otherwise inaccessible energy resources (ie offshore, deep deposits or beneath protected lands) and low capital intensity. Practical application of this clean technology is restricted primarily by lack of satisfactory quantitative descriptions of the processes involved, in particular the hydromechanical processes.In this study, three characteristic physical zones of an in situ gasifier are identified as the rubble zone, combustion front and virgin coal zone. Coupled mechanical processes of coal consumption and overburden collapse are used to describe the permeability profile in the rubble zone. Additionally, the redistribution of overburden load associated with coal consumption is accounted for with the formulation of a stress (compressive) dependent permeability profile, which is applied to the virgin coal zone. The model was implemented into and solved by FEMLAB, an advanced computer simulation tool. The flow process, according to DarcyÆs Law, is subsequently described in terms of permeability dependent injectivity. Injectivity is an indicator of flow velocity, which has been identified as a crucial factor in determining the commercial value of product gases from in situ coal gasification. The stress alteration to coal permeability was found to have a dominating influence on the flow process. This finding implies that a greater understanding of the in situ coal burning induced deformation of surrounding rocks would be of significant value in assessing the economic viability of applying this clean technology to potential sites.

Jan 1, 2004

I report results of over 850 microprobe analyses of sulfides, sulfosalts and electrum from the Favona adularia-sericite epithermal deposit of the Waihi district in the southern Hauraki Goldfield of New Zealand. Pyrite and marcasite from altered wall rocks that enclose the veins are stoichiometric, with compositions of FeS2, and no significant trace elements. In contrast, pyrite in veins commonly contains appreciable As (up to 3.2 wt per cent), and locally contains several tenths of a percent of Cu, Zn, Co, Ag and Sb. Vein pyrite may contain up to 0.22 per cent Au, but Au contents do not show a positive correlation with As. Limited electrum data indicate that it ranges from Ag0.47 Au0.53 to Ag0.54Au0.41Cu0.01Zn0.04. Chalcopyrite is stoichiometric CuFeS2, and most galena is PbS, but some galena contains up to 4.4 wt per cent Se, which substitutes for S in its lattice. The galena is not argentiferous; the highest Ag content is 0.45 wt per cent Ag. Sphalerite averages 4 mol per cent FeS, but ranges up to 15 mol per cent. Tetrahedrites [(Cu,Ag)10(Zn,Fe)2(As,Sb)4S13] show variable substitution, but most are Cu- Zn- and Sb-rich. Veins also contain aguilarite (Ag4SeS), stromeyerite (CuAgS), naumannite (Ag2Se), and mckinstryite [(Ag,Cu)2S].

Jan 1, 2004

By J. Lux, B. Clermont

Magotteaux, with the co-operation of Anglo Platinum, has erected a fully instrumented pilot plant at Frank concentrator, which is being used to study the influence of a variety of grinding parameters. This paper will discuss only the influence of mill speed and pulp density on secondary stage grinding. A Ø0.82 x1 m open circuit mill was used with reclaimed Merensky tailings as feed. The conclusions apply to this pilot plant but further investigation needs to be done to verify whether the same trends will be applicable to a large industrial-scale mill.

Jan 1, 2004