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By O. Kitamura, H. Kubota

The Harima Works started its ISP operation in 1966 and been expanding its production capacity from 3,000 tonne Zn/month and 1,500 tonne Pb/month to 7,500 tonne Zn/month and 2,500 tonne Pb/month. It is not only treating zinc, lead and bulk concentrates but also secondary materials like Waelz kiln oxide from the Shisaka Works of Sumitomo Metal Mining, waste treatment sludges, industrial wastes and others. Its final products cover Prime Western Grade (PWG) zinc, Special High Grade (SHG) zinc, continuous galvanizing grade zinc, electrolytic lead, cadmium, indium, thallium and sulfuric acid. This paper briefly describes the smelter's historical and present operations. The key data for the current impurity control management and for the distribution of impurities such as copper, iron and arsenic are presented.

Jan 1, 2000

By A Singleton, J Busfield

World coal producers have been under constant pressure in recent years because of falling export prices arising from oversupply and the Asian slowdown. This has resulted in a dynamic market place, a sharpening of focus on bottom line costs and some rationalisation of participants. Productivity has increased dramatically as many inefficiencies, typical of the coal industry, have been eroded through workplace reform. This is true for the both open cut and underground sectors of the industry. At the same time, the technology of underground mining is undergoing dynamic change. Mine operators are implementing better exploration and planning tools and are also starting to make gains against chronically low equipment availability and utilisation. æStep-changeÆ improvements in output are imminent. As the statutory environment shifts to a æduty of careÆ regime, it is hoped that mine safety performance will improve, particularly with regard to fatalities. The focus of the paper is on the Australian coal sector, although references to international benchmarks are made. Despite environmental threats to the future of coal, it is concluded that the next ten years will see impressive performance results from underground coal mines which will assist coal to maintain its position as the preferred fuel of lowest cost.

Jan 1, 2000

"IntroductionIn the 1970s, environmental concerns and associated liabilities were a new and unknown aspect of corporate risk. Today, social concerns and the associated conflicts that they can generate constitute a rapidly expanding aspect of risk. Although not a new phenomena — the Bougainville copper mine was forced into closure in 1988 — social risk has emerged as considerably more important, and increasingly visible, in the last few years. Social risk is now an aspect of all mining activities which needs to be calculated into project assessments, and to be managed throughout the life of a project. While social risk has a number of aspects at the corporate level, such as company image and shareholder relations, at the level of the individual project, its primary component is social acceptability, and the principal tool for managing it is the Social Licence to Operate.Social Risk in Latin AmericaThroughout Latin America there are newly modernized mineral codes and economic systems introduced over the last ten years which, together with new environmental legislation, look very much like regulations in developed countries. To the corporations, the existence of these instruments means that the risks from the environmental issues associated with the project are known; they are legislated, defined, quantifiable and hence manageable.It seems ironic that, just when comprehensive regulations for the environmental management of mining have been put in place throughout Latin America, there arise an increasing number of challenges to mining activities. For, in spite of the apparent guarantees provided by these new legislative reforms, communities in Latin America today are more frequently standing up and taking exception to the presence of mining companies, or the ways in which the companies are conducting themselves. The viability of projects becomes threatened because they are considered socially unacceptable, a phenomenon that we describe as social risk. These challenges are less about opposing mining activities than many people would think. Rather, they are based on an increasing desire on the part of the local population to have some measure of control over their own future, and to participate in the development process from the earliest stages."

Jan 1, 2000

By Sanjeev Malhotra

The American Petroleum Institute (API) method of predicting pile capacities in sands is reviewed. Factors that influence pile capacity such as soil parameters, pile parameters, loading effects and installation effects are listed. In addition, the simultaneous occurrence of physical phenomena such as grain crushing, pile shaking, stress-redistribution and plugging add to the uncertainty in the prediction model. To better understand the method of prediction, each parameter and the associated uncertainty is revisited. It is evident that these factors are inter­related and sometimes compensating. This discussion also draws attention to the influence that pile installation procedures can have on pile capacities and highlights the need for field experience with various pile installation procedures for designers. In summary, the strength of the method lies in its simplicity and ease of application, but the possible savings generated by an improved method are too substantial to ignore.

Jan 1, 2000

By P. Todd, K. Dever, P. S. Mills, A. A. Campoli

Resin bolt performance is dependent on the size of the resin annulus, the difference between the hole and bolt radii. The vast majority of the millions of resin roof bolts installed each year in the United States employ an annulus of 0.125 or 0.188 inches. Short encapsulation pull tests with resin annuluses of 0.125 and 0.095 inch resisted an average of 2.25tons per grouted inch, with no significant variation. Resin loses to simulated fractures increased as annulus size decreased, with a minimum loss of35% and a maximum loss of 60% associated with0.188 and 0.095 inch annuluses, respectively.

Jan 1, 2000

By R. M. Cox

Pneumatic coal loading and conveying systems provide alternative methods for the safe and efficient mining of the thin, high-grade coal seams found in the Southern Appalachians. Pneumatic systems eliminate most of the health and safety hazards associated with the operation of conventional mining and haulage equipment in small low-coal mines by removing powered mobile equipment from the mine. Ventilation is also improved by the coincidental removal of gas and respirable dust from the mine by the operation of the pneumatic loading and conveying system. Other significant advantages of pneumatic coal recovery systems are relative simplicity, operating flexibility, low capital cost, quiet operations, environmental benefits and ease of automation. The design considerations and field evaluations of experimental prototype pneumatic coal loading and conveying systems installed and operated in small thin-seam mines are presented in this paper. In addition, fundamental design criteria and recommendations for the installation and operation of a variety of pneumatic coal loading and conveying systems that offer alternative coal-recovery systems that alleviate the serious health and safety concerns of current small mine operations are proposed.

Jan 1, 2000

By M Scoble, E Rubio

The re-engineering of manufacturing production systems has demonstrated the benefits from using production information for optimising processes. This paper explores the techniques and issues in the acquisition and analysis of mine production data for tactical decision making in production control. The use of information and operations management tools is presented in the context of block caving studies, with particular focus on the relationship between secondary breaking and LHD production performance.

Jan 1, 2000

By William R. Yernberg

In October 1999, Liebherr-America, Liebherr Construction and Liebherr Mining Equipment held anopen house at its Newport News, VA, plant. The open house was held to celebrate the company’s50th anniversary and to demonstrate the new TI 272mining truck. Attending the open house members of the media, vendors and company representatives from all over the world. In his introductory comments, company president Peter Eller announced Liebherr’s dedication to expanding its presence in North America. Liebherr now has 30 dealers across the United States. As part of the open house, a brief history of Liebherr was presented, beginning with its creation in1949. Liebherr engineering and sales representatives were available to answer questions.

Jan 1, 2000

By D. A. Swanson, G. Danziger, G. Savci, C. Barnes

Hydrologic assessments of existing and proposed waste rock stockpiles are typically required for application of operating and closure permits at mine sites. A hydrologic assessment should include an evaluation of climatic data and prediction of the net infiltration rate through the waste rock stockpile surface. In addition, hydrologic factors such as the time required to deplete available moisture storage in the stockpiles and the time required for potential seepage to migrate to the underlying aquifer should also be predicted.

Jan 1, 2000

By Y Yang

This paper discusses various issues surrounding the metallurgical control for furnaces, especially focusing on processes with long time-constants and æmetallurgical memoriesÆ. Examples will focus on furnaces accepting particulate and sometimes ill-defined feeds, eg submerged-arc furnaces, blast furnaces, secondary scrap smelting operations, recycling operations, waste incinerators, etc. Generally, because of the usually higher metallurgical time constant of these furnaces, these reactors have to be controlled in a feed-forward manner by the use of a hybrid of æblack boxÆ or empirical and ægrey boxÆ semi-empirical first principles metallurgical modelling and simulation techniques in a supervisory metallurgical control capacity.

Jan 1, 2000

By U. K. Custred

Who We Are Farmland Hydro (FHLP) is a Limited Partnership formed by Farmland Industries, the largest U.S. farmers’ cooperative, located in Kansas City, MO, and Norsk Hydro, a large Norwegian company engaged in fertilizer, petroleum and the specialty metals industry. Both of our parent companies have a long history of commitment to the fertilizer industry. This year, Farmland Industry celebrates its 71st year in the business, and Norsk Hydro celebrates its 100th operating year! We employ approximately 300 associates in Central Florida. What We Do Farmland has been active in Hardee County, FL since the 1970’s as a large landowner and citrus grower. We plan to expand this activity into phosphate rock mining. The phosphate rock produced here will be shipped to our nearby chemical fertilizer complex in Polk County, where we produce quality phosphate products - liquid and granular fertilizers. Of the phosphate rock mined, 90% is used to make fertilizer. Other uses include animal feed, vitamins, medicine, light bulbs, soft drinks, film, flame resistant fabric, optical glass, toothpaste, bone china and other consumer products.

Jan 1, 2000

By Masahiro Yoshimura, Sergiy Korablov

"Hydi-othermal corrosion ofTiN, TlAlN and CrN PVD films (3 µm thick) deposited on SUS-304 substrate was studied in 100MPa water in 20-950°C temperature range up , to 750h. The beginning temperature of their reaction was determined as 200°c for TiN and TiAlN and 500°C for CrN films, which are quite low in comparison with that of air oxidation of those powders. Very thin oxide scales. of TinO; n-I homologous series phases were formed above 300°C. TiO2 anatare. is observed for TIN and TiAlN films at 400°C. The· feature of hydrothermal corrosion of CrN films seems to be CrNxOy phase formation.Distinguishable weight changes were observed at higher temperature than 700°C for TiN, 750°C for· TiAlN and 800°C for CrN respectively. Hydrothermal corrosion kinetics .was constructed to calculate the activation energy of hydrothermal corrosions. On the base of obtained data, hydrothermal corrosion resistance was as follows: TiN – TiAlN - CrN. Facetted oxide crystals were formed at higher temperature than 500°C for TiN, TiAlN and 850°C forCrN.IntroductionThe metallic nitride (TiN; TiAlN, CrN) PVD films have high hardness, strength and wear resistance. Therefore these films are widely used in industry for wear resistij.nce application such as cutting tools and die molds. Their performances depend on not only the mechanical properties but also corrosion resistance of coated films. High temperature oxidation of metalliq nitride and nitride films was well studied [1-5]. However there are no reliable data concerning the .corrosion resistance of coated nitride materials. In high-temperature and high-pressure water. There are a few reports on hydrothermal corrosion of nitride films [6,7]. The increase of corrosion resistance of CVD films was observed in following succession TiC - TiCNO - TiCN - TiN at 300-680°C temperature interval and I 00 MPa pressure water according to data of the first report. Kawana et al. [7] have reported about excellent corrosion resistance of CrN films under 290°C and 8, 6 MPa water during I 000 h in the circulating type experimental loop. The films thickness was about 7-10 µm in both cases. However it remains unclear the chemical state of the surface species and especially in-depth distribution, oxide scale thickness and its growth, and defects formation in the oxide film."

Jan 1, 2000

By T Akiyama, J A. de Castro, H Nogami

Blast furnace is a countercurrent moving bed reactor that produces pig iron from iron bearing materials like pellet, sinter or lump ore. The furnace has cylindrical shape and the lump solid materials are alternatively charged onto the top of the furnace. Hot air is introduced through tuyeres that are set on the lower furnace wall. Auxiliary fuels (pulverised coal, oil or natural gas) and raw materials (fine ore or fluxes) are injected into the furnace with blast air from the tuyeres. In front of the tuyeres, coke particles react with oxygen in the blast air and generate carbon monoxide. The hot reacting gas heats up the lump solids and reduces iron oxides in the upper furnace. In the middle height of the furnace, the reduced iron and slag are fused by the combustion heat and form the cohesive zone. The molten iron and slag that are generated in this region trickle down through the packed bed of coke particles and flow into the bottom of the furnace. Therefore, the flows of gas, lump solids and liquids exist at the same time in the lower part of the blast furnace.

Jan 1, 2000

By A. Anttila, S. Persson

The grinding mill is probably the most common unit operation in mineral processing. There is, however, much that can still be done in the way of optimization. This paper discusses the results of a well-controlled pilot-scale test in which the performance of a tumbling mill equipped with a conventional rubber lining and lifter bars was compared to a tumbling mill equipped with a smooth rubber lining of the magnetic type. The results indicate that the smooth lining is about 14% more effective with respect to energy consumption. By optimizing the size of the grinding media, the mill capacity can be increased in many grinding operations. In this specific case, grinding with a -20-mm ball charge required 26% less grinding energy than grinding with a -30-mm ball charge. The energy savings can, in most cases, be converted to an increase in capacity. The wear of the grinding media is difficult to assess over a short test period, but the results suggest that the wear is somewhat less when a smooth lining is used. A determination of the wear of the linings was not included in this study, but it is generally accepted that the use of magnetic linings reduces the lining costs dramatically. Computer simulation using the Millsoft code developed by Mishra et al. confirms and explains the increased effectiveness of comminution when a smooth lining and smaller grinding balls are used.

Jan 1, 2000

By Rick McGregor, David Blowes, Mike Choi, Ralph Ludwig

The oxidation of sulfide minerals at an ore transfer location in Western Canada has resulted in widespread contamination of underlying soil and groundwater. The oxidation of sulfide minerals has released sulfate [SO,] and heavy metals including cadmium [Cd], copper [Cu], nickel [Ni], lead [Pb], and zinc [Zn] into the groundwater. A compost-based sulfate-reducing reactive wall was installed in the path of the plume in an attempt to reduce the potential impact of the heavy metals on a down-gradient marine inlet. Monitoring of the reactive wall over a 21-month period has shown that Cu concentrations decrease from over 4000 ug/L to less than 5 ug/L. Cadmium, Ni, Pb, and Zn concentrations also show similar decreases with treated concentrations generally being observed near or below detection limits.

Jan 1, 2000

By K. Gie Tan, Frank Wright

"Misty Mountain Gold Limited (MGL - TSE VSE, MGLCF - NASDAQ) of Vancouver, owns the Harmony Gold Project located in the Queen Charlotte Islands of British Columbia. The deposit contains a mineable reserve of 2.3 million ounces of gold, at a 1.2 g/t cut-off and an average grade of 2.1 1 g/t Au.Discovered in 1970 and frequently investigated by previous owners, full-scale production has not yet occurred because of the complex metallurgy of the deposit. Recent process studies that were completed in six months at Process Research Associates Ltd. (PRA) of Vancouver resulted in significant improvements to the project viability. The work involved detailed mineral processing studies aimed at achieving a marketable concentrate. An option for bio-oxidation and cyanidation to allow on-site dor6 production was also investigated.The main findings at PRA followed the front-end recovery of finely divided free gold (Au) by gravity concentration. Approximately 20% of Au reported to less than 0.2% of the mass, resulting in a grade exceeding 500g/t Au. The resulting gravity tailing provided a uniform feed for flotation evaluation. The optimization of this step allowed for a reasonable primary grind size of 80% passing (&) 50pm. Efficient slime’s rejection was made possible by flotation at a reduced pulp density, and pre-oxidized sulphides were reactivated with Na,S. The regrinding of the bulk flotation concentrate followed by up to five stages of cleaning resulted in a combined gravity + flotation product of 50g/t Au with 82% recovery in less than 4% of the feed mass.Further studies indicated that the flotation concentrate was amenable also to tank bio-oxidation. At 65% sulphide oxidation the gold recovery improved from less than 70% to 90% by cyanide extraction using CIL (carbon in leach). This compares to less than 45% gold recovery from whole-ore cyanidation in several previous studies. Heap leaching may also be considered for lower grade material. PRA’s methodical approach and consistent results dispelled the uncertainty about predicting the material behavior for the Harmony Property."

Jan 1, 2000

By Daryl L. Gusey, John T. Neubert, Matthew A. Sares

The Colorado Geological Survey completed an inventory of environmental degradation associated with abandoned and inactive mines on National Forest System lands in Colorado. In the course of the inventory, areas with naturally occurring acid rock drainage were also noted. Approximately 18,000 abandoned mine- related features were inventoried, including about 900 features that are considered significant enough environmental problems to warrant further investigation. Water quality data, such as pH and conductivity were gathered at all features where water was present, such as draining adits, seepage at the toe of dumps and tailings, and standing water in shafts. Samples were taken where field tests indicated low pH andlor high conductivity, including several areas with naturally occurring acid rock drainage. Samples were analyzed for dissolved and total metals, and for selected anions. All mine locations and data collected by the field geologists were entered on field forms and, subsequently, into a computer database and GIS format. With the information provided by the inventory, the Forest Service, in cooperation with other agencies, has been able to prioritize abandoned mines for reclamation. In most cases, cleanup is approached on a watershed basis. Mines in priority watersheds have been selected for reclamation first. Watersheds where studies prerequisite to cleanup are occurring include the upper Anirnas River, Willow Creek (tributary to the upper Rio Grande), Chalk Creek (tributary to the upper Arkansas River), the Uncompahgre River, and the Alamosa River. During the inventory, evidence of naturally occurring water quality degradation was found in areas where little or no evidence of mining activity exists. These areas include the upper Alamosa River, the Middle Fork of Mineral Creek, Peekaboo Gulch, and Handcart Gulch. Water from these natural sources has been found to significantly exceed Colorado water quality standards for several metals.

Jan 1, 2000

By Hiroshi Ono

"By newly developed ICP method, trace amounts of As(III), As(V) .,Sb(III) and Sb(V) were precisely determined within accuracy of sub ng/ml. As(III) and Sb(III) were separated from As(V) and Sb(V) by extracting into ·xylene as diethyldithiocarbamate complexes using diethylammonium diethyldithiocarbamate (DDDC), and then back-extracted into nitric acid for a quantitative determiruition by ICP-AES equipped with hydridegeneration system The recoveries of As(III) and Sb(III) were satisfactory throughout the extraction with 0.04mol/l DDDC in xylene from lmol/l hydrochloric acid solution and the back-extraction with 7 mol/l nitric acid. As(V) and Sb(V) were reduced to As(III) and Sb(III) by ascorbic acid and potassium iodide, and their quantities were determined as mentioned above. The detection limits were found to be 0.58ng/ml for As(III), 0.63ng/ml for Sb(III) using 50ml of a sample. The proposed method was applied to analysis of the real sample.Introduction In drain, arsenic(AS) concentration is prescribed below 0.lmg/l, so As must be removed. As is existed at .the form of As(III) or As(V) in solution. For t1Jeir difference of chemic;µ property, it is not easy to remove As in solution. So it is an urgent necessity to develop for determining concentration of As(III) and As(V). Antimony( Sb) has resemblance .chemical property to As. So Sb was experimented the same as As.The separation and determination of As(III) and As(V) have been carried out using several methods, such as ICP after copreclpitating separation, HPLC, direct hydride generation atomic absorption. However these methods have some problems. One of main problems is that HPLC and direct hydride generation atomic absorption methods are influenced by coexisting elements."

Jan 1, 2000

By Mitsuhiro Ohtaki, Tetsuzo Arakawa, Fujio Murata

Refining of Zn from aluminum scrap melt by some vacuum distillation processes was studied to promote aluminum scrap recycling. Effects of distillation conditions, such as melt temperature, vacuum pressure and holding time, on Zn distillation behavior were investigated theoretically and experimentally by 0.3kg/ch scale vacuum resistance furnace. Three methods to increase the surface-area/volume ratio of liquid metal, such as gas atomizing, mechanical atomizing and mechanical stirring, were tested to increase the Zn distillation rate in 5kg/ch scale vacuum resistance-furnace. It was easy to lower the remaining Zn content to less than 0.1 wt% within one minute by mechanical stirring method. A water-model simulation experiment indicated that a significant agitation of the melt by stirring would be effective to increase the distillation rate. Continuous agitation vacuum distillation process (CA VP) has been designed and the pilot plant is now in construction.

Jan 1, 2000

By R. L. Grayson

In 1995, the United States Congress abolished the Bureau of Mines in the US Department of Interior. But Congress preserved the safety and health research functions being performed at the Pittsburgh and Spokane Research Centers. These functions were transitionally housed in the US Department of Energy before permanently merging with the National Institute for Occupational Safety and Health (NIOSH), Department of Health and Human Services, in October 1996. Since the rnerger of the former Bureau of Mines with NIOSH, there has been an active evaluation of ongoing research activities, significant interaction with stakeholders, and the development of a process leading to "data-informed" priority setting. This paper reviews the current surveillance information concerning the level of injury and disease from mining work and discusses how research priorities are evolving to improve the contribution of research to the prevention of injury and disease.

Jan 1, 2000