Search Documents

By N. Krishna

The utilization of Electrochemical Impedance Spectroscopy (EIS) in conjunction with Atomic Force Microscopy (AFM) is a powerful surface characterization technique to study the role of sulfur formation during acidic oxidation of chalcopyrite. It has been established that the chalcopyrite dissolution kinetics is controlled by the formation of passive sulfur layer during leaching. The objective of the study was to characterize the intermediate sulfur layer formation at different oxidation conditions in acidic solution. The chalcopyrite samples were subjected to anodic oxidation and the oxidation process was analyzed using impedance spectroscopy. The sulfur growth on the chalcopyrite surface during oxidation was further analyzed using Atomic Force Microscope for sulfur roughness and grain size, peak height and sulfur growth.

Jan 1, 1999

By Osarnu Inoue

In Mitsubishi Continuous Copper Smelting and Converting Process, smelting, slag-matte separation and matte converting are continuously carried out in series in three furnaces connected by launders. As a result of this operational configuration of the furnaces, influence of the change in operating condition in upper stream, such as variation of feeds in the smelting furnace, propagates to down stream with some delay. In order to achieve stabler operation, process control algorithm based on the dynamic characteristics of each furnace would be very effective. In this study, the dynamic process simulation model was developed for the smelting furnace. The model consists of two mathematical modules, i.e. the thermodynamic module and the mixing module. The calculation results using operating data obtained at Naoshima Smelter showed good agreement with the actually observed change in temperature, composition and flow rate of matte and slag at the outlet of the furnace. In addition, operation parameters such as reaction efficiency of oxygen and coal, dead volume of melts were estimated.

Jan 1, 1999

By Sarma S. Kanchibotla

In overburden cast blasting the explosive energy is used to move a significant percentage of overburden from the high wall to the spoil pile thus reducing the amount of material to be handled by machinery. However, the obvious trade-off between the extra explosive energy in the cast blast versus reduced dragline effort is complicated by an increased risk of damage to the underlying coal. This damage may not be obvious but inevitably leads to reduced coal recovery and may negate much of the benefit sought from cast blasting.

Jan 1, 1999

By S. Motoiu

Data acquisition is widely used for controlling flash smelting furnaces. A Romanian smelter from which a large amount of data can be collected uses such a technique. A computer program was developed for interpretation of the data. Inputs to the program are the process data files. Abnormal data are identified using standard statistical techniques; they can be edited if necessary. The following methods can be used for the analysis: linear correlation (single or multiple), polynomial correlation or comparison of two average values. Time variation graphs and histograms can be displayed. The random balance method was used for determination of significant parameters influencing the process performance. Not all process parameters are recorded, and some of them are not even measured. The software can compute some of these parameters such as: air flow rate required and the oxygen content of the gas: exiting the reaction tower. The software was used for the interpretation of a large amount of process data. The analysis showed that the process did not operate properly at some times.

Jan 1, 1999

The Managalase area is remote and little visited by geologists or prospectors. Yet it holds the key to the tectonics and petrology of this part of Papua. The eastern Managalase plateau (M, Figure 1) lies between the Hydrographers andesite volcano (H) and Sesara shoshonite volcano (S) to the south of Popondetta on the Papua Peninsular. It contains over 30 small volcanic centres in an area of only 400 km2 . To the south and west lies the basic-utrabasic belt (B-UB) of the Morobe arc. This is the leading edge of oceanic plate obducted over the Owen Stanley Metamorphics during the lower Eocene time. To the east and southeast lies the Cape Vogel geosyncline where the western end of the Woodlark basin spreading centre enters mainland Papua. The extension of the spreading centre as a suture might pass as far as the southern margin of the Musa Coastal plain. A new pattern of plate tectonic motions has been determined by the global positioning system and the southern margin of the Woodlark plate has been redefined (Tregoning et al, 1998; Taylor, Goodliffe and Martinez, et al, 1999). The Managalase plateau is margined by two inferred faults. These outline a cusp protruding from the main basic-ultrabasic belt where these rocks are near the surface. The westerly arm of the cusp passes through the centres of the Hydrographers and Mount Lamington andesitic volcanoes. Mount Lamington overlies Quaternary alluvium and underlying Tertiary sediments (Arculus et al, 1983) but members of the basic-ultrabasic belt crop out on the southern flanks. The easterly arm of the cusp is an inferred shear zone (and ? fault) connecting up with the terminus of the suture on the Musa coastal plain. Movements on the two faults forming the cusp are thought to have produced the conjugate N-S, E-W faults on the plateau (Ruxton, 1966). To the east, and isolated, are the two large andesitic stratovolcanoes of Mounts Victory (V) and Trafalgar (T) which together form Cape Nelson. Mount Victory was last active in the 1890s. The Waiowa shoshonitic volcano explosion centres (W), last active in 1943 - 1944, lie near the suture adjacent to the actively rising Goropu mountains. Extension in these mountains is clearly demonstrated by the soil profiles being skeletal along a bounding fault and ageing uphill. The incision of small parallel ravines also dig deeper further upslope from the fault. To the south-east of Mount Suckling (K) the Dayman Dome is also an expanding mass. The Owen Stanley fault is parallel, and located to the south of the suture. The Mesozoic metamorphics form the backbone of the Papuan Peninsula. The intramontane Musa Trough is thought to date from the mid-Tertiary. At the eastern end of the trough Pleistocene and Recent ultrabasic breccias and alkali basalt crop out (Green, 1961).

Jan 1, 1999

By R. J. Pruett, J. Yuan

Kaolin clays from five different commercial deposits in Georgia were studied to understand the variations of zeta potential and related fundamental properties. The results suggest that higher negative zeta potential is related to exchangeable or soluble calcium ions in the clays.

Jan 1, 1999

Our modern cities are almost incapable of sustaining themselves without subsurface infrastructure, which is not identifiable at first glance. This very soon becomes evident when the chaotic conditions prevailing in some cases in the multi-million cities on the African, Asian and South American continents are taken into consideration. This does not simply apply to the hopelessly congested streets in the downtown areas. If anything, it is shown here too that a subsurface infrastructure represents an important prerequisite for public health right up to banishing the danger of disease. Even during the 1990s, this has been clearly underlined through examples of cholera and plague epidemics in parts of Central and South America as well as on the Indian subcontinent. The overriding significance of an inner urban subsurface infrastructure in order to create decent conditions in the major built-up areas was once again emphasised not all that long ago at the United Nations HABITAT-II Conference in Istanbul, Turkey, in June 1996. More than 15 000 delegates from all over the world mulled over and discussed the prerequisites for humane living conditions in human settlements taking the varying climatic, topographical and cultural marginal conditions in different regions of the globe into account. Apart from the built-up areas themselves, the utilisation of underground space is experiencing high and ever increasing significance in less densely populated regions. Attractive and fast transport links between industrial centres call for high- performance transport arteries for the economic, speedy and unhampered carriage of people and goods. Important impulses for the economic power of a region or nation are provided by transport development and links. As a consequence, tunnels for roads and railways are being built or planned to a great degree for crossing mountain ranges, rivers and straits.

Jan 1, 1999

By L. A. Barta

A new process for the leaching of chalcopyrite concentrates has been developed and tested in miniplant campaigns and locked cycle testwork carried out between 1996 and 1999. The process involves pressure leaching in a sulphuric acid solution, e.g. raffinate from copper solvent extraction. Iron in the feeds is precipitated predominantly as hematite in the autoclave, simultaneously with copper extraction. Gold and silver in the pressure leach residue are recoverable by conventional cyanidation, following flotation to remove elemental sulphur by-product. The results of recent miniplant tests and batch locked cycle tests are provided.

Jan 1, 1999

As discussed previously, total cost is the sum of the direct materials, direct labor, and production overhead costs. The assignment of direct materials and direct labor costs to individual activities is generally straightforward. The assignment of overhead often is not. Overhead costs frequently contain allocations that only approximate the demand the activity has made o; the overhead resources. The inaccuracy of the overhead calculation can create erroneous production cost information and lead to suboptimal management of the operation. This problem is particularly acute when determining the production cost of individual products in multiproduct firms. Pricing, process management, and product mix decisions are especially susceptible to errors in product costing. The problem of properly determining production cost is complicated by the fact that few if any alternative methods exist to identify the inaccuracies in overhead allocation. To avoid errors, some firms simply ignore overhead costs in their product cost calculations, particularly those resulting from marketing and distribution of the final product.

Jan 1, 1999

By S. S. Peng, V. Z. Sun

One of the major concerns of ground control in a coal mine is the prevention of roof, pillar and floor failures of the mine entry. To better design and evaluate the stability of a mine entry within a certain level of confidence, a reliability approach is introduced. The advantage of using the reliability approach, rather than the conventional safety-factor (SF) method, is that it not only takes variability of both rock/coal properties and stress into consideration but also assesses the stability of each component and the mine entry as a whole. Therefore, it is anticipated that by using this approach the current ground-control technology in a coal mine will convey a better sense of confidence. The results of a case study show that there is a significant difference in mine entry stability between the current design method and the reliability approach.

Jan 1, 1999

By M. K. LeBegue

Water sprays located behind the bits of cutter drums have been shown to reduce the incidence of face ignitions. This paper details the design approach to successfully incorporating water seals into a drum miner cutter head.

Jan 1, 1999

By Jonathan M. Berkoe

Design engineers and metallurgists have long recognized the need for better methods to calculate a wide range of fluid dynamic effects in smelters and hydro- metallurgical facilities. Examples can range from the capture of fume in the secondary hoods of a copper converter, to controlling the thermal effects of heat transfer resulting from metal and slag flows within a furnace. With the advent of relatively low-cost, high- speed computers and user-friendly, commercially available computerized fluid dynamic (CFD) programs, these calculations can now be made. Use of CFD increased the understanding of both hot gas and molten flows in smelter facilities and has already led to design improvements in converter fume control hoods as well as improved management of heat transfer in electric furnaces. This paper will present two representative CFD applications to metals industry facilities. To date, Bechtel has implemented CFD results on four continents.

Jan 1, 1999

By Rodnei Graça, Jorge Silva Bettencourt, Lena Virgínia Soares Monteiro, Baruch Spiro, Tolentino Flávio De Oliveira

Abstract - The Vazante Mine is located in the Vazante District, the largest zinc district in Brazil. The Vazante deposit consists dominantly of an unusual willemitic ore. Small sulfide bodies are tectonically imbricated with the willemitic ore, within the Vazante shear zone. Structural styles of deformation and petrographic and isotopic evidence indicate that willemitic mineralization and deformation occurred synchronously during the Neo-Proterozoic. Various generations of hydrothermal veins and hydraulic breccias may pre-date, accompany and overprint the mineralization. Ore-formation temperatures are deduced from stable isotope geothermometry and mineral chemistry of both sulfide bodies and willemitic ore. Temperatures during the main stage of mineralization range from 206°C to 294°C (willemitic ore) and 317°C (sulfides), and reflect the prevailing metamorphic conditions within the shear zone. The fluid from which the gangue minerals of the sulfide bodies precipitated (at 250°C) had an oxygen isotopic average value of ?18O = +19.4‰. This value appears to reflect the interaction of metamorphic fluid with the carbonate rocks of the Vazante formation. At 250°C, the fluid in equilibrium with the vein mineral phases and willemitic ore assemblage exhibits a uniform oxygen isotopic composition, with an average value of ?18O = +11.5‰. The positive linear covariance of ?18O and ?13C ratios of the carbonates is most likely due to the mixing of metamorphic and meteoric fluids. The ?34S values of sulfides indicate a direct crustal origin for the sulfur. It is suggested that the sulfur is largely derived from pre-existing sulfide bodies and has been transported by metamorphic fluids. The willemitic ore may have originated from the precipitation of metal in sulfur- poor fluids under oxidized conditions, within the Vazante shear zone.

Jan 1, 1999

The spatial and temporal evolution from the porphyry to high-sulphidation epithermal environment can be assessed by integrating new results on such deposits (Arribas et al, 1995; Hedenquist et al, 1998) with past studies of plutonic and porphyry systems (Dilles and Proffett, 1995; Cline, 1995; Shinohara and Hedenquist, 1997; Hedenquist and Richards, 1998). Some time ago, Sillitoe (1973) argued for the nature of the tops and bottoms of porphyry deposits. He concluded that epithermal deposits may form over the tops of some porphyry systems. We can now conclude more confidently what the tops and bottoms of many high-sulphidation ore deposits appeared like while active (Arribas, 1995; Hedenquist, 1995). In addition, we better understand the nature of the zonation of high-sulphidation epithermal systems from the intrusive to surficial environment (Sillitoe, 1999), and how these two styles of ore deposit are related. Geological and geochemical evidence clearly indicates a continuum between these two ore environments. This improved understanding of genesis allows more efficient exploration for these deposits. There are many examples of spatially associated porphyry and epithermal ore deposits. A genetic connection has been suggested by some, and argued against by others. Nowhere is this spatial association better seen than in northern Luzon, Philippines, where the Lepanto high-sulphidation epithermal Cu-Au deposit overlies the Far Southeast (FSE) porphyry Cu-Au resource (Figure 1). Together these mineralised bodies contain a resource of >3.8 M tonnes Cu and >550 tonnes Au. Lepanto was largely mined out in early-1997. Post-war production until 1995 was 0.73 Mt Cu, 115 t Au and 393 t Ag at an average grade of 2.2 per cent Cu, 3.5 g/t Au and 11 g/t Ag. The recent discovery of the adjacent Victoria low-sulphidation quartz-Au-base metal vein deposit, with a resource of >68 tonnes Au (Cuison et al, 1998), illustrates the variety and abundance of mineralisation in the Mankayan district. This district also hosts the Guinaoang porphyry Cu-Au deposit (Sillitoe and Angeles, 1985) and other epithermal vein occurrences (Figure 1). This brief summary reviews the results recently published on the Lepanto-FSE deposits (Arribas et al, 1995; Mancano and Campbell, 1995; Claveria, 1998; Hedenquist et al, 1998), and stresses the evidence for coupling of mineralisation between the porphyry and high-sulphidation epithermal environments.

Jan 1, 1999

By Bert S. Hall

"The purpose of this paper is to review the evidence at hand concerning the earliest centuries of cast iron in Europe, from roughly 1400 A.D. until the second half of the sixteenth century. For the most part it is concerned with the relationship between two technologies which emerged first in China and then later appear in Western lands, gunpowder weapons and iron founding. We should not assume, as I hope to show later in this discussion, that weapons constituted the only product for which the iron founder had any market, but it is clearly true that attempts to produce weapons constituted the most severe technical challenge for the early founder. Firearms appear for the first time in Europe in the 1320s and develop into significant weapons on the field of battle by the end of the century. Theirs is a complex history, subject neither to easy summary treatment nor to simplified models of development. I hope to be able, through the analysis of the evidence concerning cast iron, to show that one important strand in the fabric of gunpowder's history concerns the materials from which cannon could be made. This question is subject to a number of shades of meaning, because ""cannon"" can be made for many purposes under a profusion of different names, and under sharply varying conditions of use. As a result, the question of materials is frequently really a question of competing materials, and involves a complex set of factors, of which production costs and the ultimate safety of the user seem the most important. Judged in this manner cast iron was an important but unsatisfactory metal for weapons purposes until 1543, at which time English founders learned to make iron muzzle-loading cannon which could rival bronze ordnance in most important performance criteria, but which cost much less to produce. With that event, the history of cast iron and the history of weapons entered into the close relationship that persisted until the advent of rifled artillery made of steel in the middle of the nineteenth century."

Jan 1, 1999

By C Ausa, Nyunt Htay, A, L Deiparine

The main tectonic elements in Myanmar are a late Mesozoic and Cenozoic magmatic arc system in the west, repeated in northern Myanmar by more than 300 km of dextral movement on the Sagaing Fault, and the back-arc continental region affected by early and late Mesozoic orogenies, in the east. Historically most lode gold production has been from latest Cretaceous high-grade mesothermal veins and derived placers in the Wuntho and Tagaung-Myitkyina segments of the magmatic arc. Placer deposits in the Ayerwaddy River north of Myitkyina are currently worked by more than 100-bucket dredges. South of Wuntho, the magmatic arc and Pegu Yoma fold belt host epithermal gold with associated As, Sb and Zn in mid-Tertiary marine sediments. MyanmarÆs most productive lode gold deposit, the Kyaukpahto mine, lies within a north-trending district east of the magmatic arc and north of Mandalay. Here mineralisation and associated jasperoidal silica occur in Eocene sandstones and Permian and Triassic carbonates. Possibly this district continues southeastwards, across the Sagaing Fault, as sediment-hosted Sb Au and locally skarn Au mineralisation within a 1100 km long fold-thrust belt. Also present in the back-arc region are sandstone-hosted Au Cu in a Palaeozoic slate belt, and gold and stratabound gold-base metal mineralisation in the medial metamorphic belt. While untested targets remain in the magmatic arc, particularly for high sulphidation Au, the best potential is clearly within the back-arc slate and fold-thrust belts in the western part of the Shan Plateau and in northeastern-most Myanmar.

Jan 1, 1999

By J. B. Nanor, J. Lorengo, M. Misra, C. B. Bucknam

The dissolution of mercury during the gold cyanidation process is the cause of many environmental, health and processing problems. The removal of mercury-cyanide complexes from synthetic solutions and process water were investigated using sodium and potassium dimethyl dithiocarhamates and sodium sulfide as precipitating reagents. The results have shown that efficient mercury removal can he achieved by the formation of stable mercury compounds with the addition of potassium dimethyl dithioearhamate. The mercury dimethyl dithioearhamate precipitates are stable under plant operating conditions, and they do not have any deleterious effect on gold adsorption by activated carbon. Furthermore, it is possible to stabilize mercury in the heap during cyanidation by adding dimethyl dithioearhomate.

Jan 1, 1999

By M. M. Salari Rad

An investigation of gold distribution in the mill products of Sar Cheshmeh beneficiation plant demonstrates that on average 44% of the gold is routinely recovered as a by-product in the copper concentrate, and the remaining is lost to the tailing. In order to evaluate the causes of gold losses, the distribution and mode of gold occurrence in the Sar Cheshmeh ore and mill products were studied. Searching for gold within samples and within individual grains of sulphide minerals was carried out by SEM in the backscattered electron mode and SIMS, respectively. The mineralogical distribution of gold revealed by microbeam techniques were combined with the results of relevant metallurgical experiments including, sizing, heavy liquid separation, and diagnostic leaching tests, and the nature and location of gold in the ore and mill products were determined. The combined results of the experimental approaches pursued suggest that while there are some gold in solid solution and/or -colloidal size within sulphides of the Sar Cheshmeh ores, "visible" gold is the principal form of gold occurrence at Sar Cheshmeh.

Jan 1, 1999

Traditionally, production volume has been considered the major determinant of cost. As volume increases, total cost increases but unit cost decreases. This concept has been so widespread in industry that many of the tools used to analyze costs are based on production volume as the sole measure of activity and driver of unit cost-fixed and variable costs, cost-volume-price and breakeven analysis, contribution margin, flexible budgets, and others. Clearly, volume is a driver of cost. It is important in both a tactical sense (to the manager at an operating mine) and a strategic sense (as one determinant to the firm's overall cost position). However, many other factors influence costs as well, even though they have not been studied to the same extent. For example, production managers know that their costs will be reduced if the workforce does not have accidents. Safety costs are to a large extent independent of volume. Other cost components increase as volume increases, such as some environmental charges. Some costs may or may not reflect volume changes. Maintenance, for example, may appear as either a fixed or variable cost, as can operating labor in facilities that are highly automated. In the strategic sense, where the firm is selecting a strategy to pursue competitive advantage and increased profitability, all costs are variable. This reflects both the strategic intent and the long-term time frame associated with strategic positioning. Tactically, on a month-by-month basis, some costs are essentially fixed. Cost driver analysis must therefore consider the relevant time frame.

Jan 1, 1999

By Tracy Brettmann

A new method for estimating ground vibrations caused by pile driving was developed as a result of a vibration monitoring program performed for a large pile driving project. The method is accurate, rational and theoretically based starting with energy actually transmitted to the pile (not the rated or operating hammer energy). This energy is then assumed to be transmitted to the soil in the form of surface waves that attenuate from both geometric and material damping. The main input parameters for this method include the energy transmitted to the pile and the dynamic properties of the soil (wave velocity, material damping, and unit weight). In this study we concurrently measured both: (1) pile driving of 14-in.-square, 65-ft-long precast concrete piles with a Pile Driving Analyzer?, and (2) vibration levels at various distances away from the piles during driving. A geotechnical study for the site was also performed that included measurement of the dynamic soil properties using both crosshole and seismic cone testing. This paper presents the data obtained from the study and compares the results to the values estimated using this new method. Vibrations from pile driving is a serious matter that impacts virtually every pile driving project. It is important that accurate methods for estimating ground vibrations be available to engineers and contractors.

Jan 1, 1999