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By F. Mucciardi

With the increasing trend to continuous smelting and converting, granulation of copper matte is gaining prominence as a means of decoupling the smelting and converting operations. Moreover, granulation is also being seen as a possible avenue to using higher grade oxygen in converters. By feeding cold solid matte, the oxygen concentration can be increased to compensate for the lower enthalpy feed. This leads to a higher grade of SO2 in the off gas and a lower total flow rate. Current granulation technology relies on the cooling of a falling matte film by water jets. This technology while effective has several drawbacks including those related to safety. Noranda and McGill University have developed a new process (patent pending) for solidifying copper matte (or slag). It overcomes many of the negatives of current technology. The system is based on an air cooled twin roll caster. This: new system uses no water and instead incorporates heat pipe technology to transfer the heat from the solidifying matte to the cooling air to produce a thin strip of 1 to 2 mm in thickness. Testing of a prototype unit demonstrated its viability. This paper describes this newly developed, twin roll casting system that is completely waterless. The advantages of this process as well as the findings from several tests are also detailed.

Jan 1, 1999

By W. G. K. Fleming

The general history of piling is traced up to the present time with regard to the evolution of methods and materials. The processes have been strongly influenced by developments in basic equipment and industrial change. It is noticeable that in the twentieth century more progress has taken place than in the many previous centuries. It has been strongly influenced by the general development of Soil Mechanics. Test loading is probably the most effective way to assess the success of designs and many empirical relationships have been challenged through it. As we approach a new century it appears that it will be an age of rapid equipment development, with much enhancement of understanding of what has been done. Processes of automatic construction and testing will becoming commonplace. These changes will narrow the limits of conventional scatter that have come to be accepted and to a large extent will be driven by political efforts to curtail energy consumption, to raise standards of quality and reliability, and to conserve the environment. 1. Ancient history. Piling is an ancient art. Its first mention in history is from Herodotus, the first person to commit an account of his times to the written word in the years 557 to 479 BC. He evidently had a strong interest in engineering matters because he wrote of building, brick making, reinforced brickwork, river training, canal building, bridge construction, tunnelling and its acoustic detection and piling. The piling reference comes from Book 5 at paragraph 16.

Jan 1, 1999

By F. Leuzzi

Asbestos is a natural mineral fibre which has been known and utilized commercially for about a century. From the forties, it was employed on an ever-increasing scale throughout the mechanical engineering, building, paper-making and plastics sectors, to name but a few. There are essentially five minerals which provide fibres for industrial applications, namely, the chrysotile variety of serpentine and the amphiboles such as riebeckite, anthophyllite, cummingtonite-grunerite (amosite) and tremolite. About a fifth of the world's asbestos output was once taken by Europe for the manufacture of asbestos-cement products, reinforced plastics, paper and cardboard, panels, soft insulation and spray-on powders. However, in the sixties and seventies the hypothesis regarding the pathogenic nature of asbestos fibres started to gain ground. Moreover, between the sixties and eighties the EU issued a series of regulations designed to bring about a steady decrease in asbestos consumption. This line of action has culminated in recent years in a whole set of directives banning the use of asbestos in all products. This created a major problem, namely, how to clean-up the several million tons of various types of asbestos products in various states of conservation existing in Western Europe. CORDIAM (Pat. RM95 A 000269 and Pat. RM96 A 000782 in the name of ECOTEC S.r.1.) is one of the thermal inertization techniques recently proposed for this purpose. The process provides for the low-temperature ceramization of the toxic-harmful material. Of course, with such a great variety of waste materials and the volumes to be treated, as well as the need to ensure the correct dimensional design of the thermal sections of the treatment plant, it is necessary to know as much as possible about the thermal behaviour of the wastes concerned. This paper details the steps taken firstly to ascertain the thermal behaviour of such materials as may be encountered in day-to-day practice and secondly to examine the influence of the main process parameters on the preliminary design of gas- or fuel-oil-fired rotary kilns of the kind used for waste treatment.

Jan 1, 1999

By S. Michael Feroz, Paul Gribbon, Jan Rosholt

Approximately six billion gallons of combined sewage are discharged annually into Willamette River and Columbia Slough through Portland’s combined sewer system. The Columbia Slough Consolidation Conduit (CSCC) is an important element of mandated Combined Sewer Overflow (CSO) abatement. It includes2,548m (8,361 ft.) of 3.7 m. (12 ft.) internal diameter tunnel. The CSCC alignment traverses the UP railroad, Columbia Boulevard and parallels an old sewer. Geologic conditions include river alluvium and fine to coarse-grained flood deposits containing cobbles and boulders. This paper describes design and construction of a tunnel in soft-ground, with shallow cover and close to an old concrete sewer.

Jan 1, 1999

By David R. Baughman, John C. Gathje, K. C. Oberg, Gary L. Simmons

Santa Fe Pacific Gold Corp. conducted pressure-oxidation pilot plant studies on refractory carbonaceous gold ores from the Twin Creeks Mine in Nevada. The tests were conducted at Hazen Research Inc., Golden, CO, during 1993 and 1994. Laboratory investigations using CIL cyanidation after batch pressure oxidation demonstrated gold recoveries of 90% to 95%. However, pilot plant testing showed that several of the same ore types responded very poorly, with gold extractions of only 45% to 75%. Plant testing was suspended for approximately four months while extensive research was conducted to determine why these ores responded poorly and to identify potential solutions. This paper describes the batch and pilot plant test results, the extensive research activities that eventually identified the cause of the gold recovery problem and the final semicontinuous and continuous pilot plant operations that confirmed possible solutions. Final pilot plant results showed gold recoveries that were consistently greater than 90%.

Jan 1, 1999

By J. Etay, S. Daugan, Y. Fautrelle

"New type of electromagnetic parametric instabilities arising at the free surface of liquid metal in the presence of a low frequency magnetic field are presented. First, the mechanism of the instability is analysed in an idealised case. Then, the experimental device working with mercury is described. Various shapes, both regular and irregular, of free surface are found. A experimental stability diagram is obtained. Measurements of the deformation performed on photographs are compared with physical orders of magnitude.IntroductionWhen a liquid metal pool of electroconductivity a is submitted to an A.C. magnetic field B = B0 cos mt, electrical currents j are induced in the liquid metal and interact with the applied magnetic field to create electromagnetic body forces F = j x B. Those Lorentz forces comprise both a mean value (time average) and an oscillating part. Those forces are widely used in many metallurgical processes to stirr a liquid metal or to control its free surface, e. g., in aluminium continuous casting or electromagnetic levitation problems (1-3). When liquid metal free surfaces are submitted to AC. magnetic fields, the shape of those interfaces may interact with the applied field and leads to a various instabilities. A review of these instabilities may be found in Fautrelle (4). That instabilities may be a problem for the control of processing as electromagnetic levitation or quasi-levitation."

Jan 1, 1999

By David Ellis

The next generation of Reusable Launch Vehicle (RLV) will utilize regeneratively cooled combustion chamber liners in the engines. The current design calls for using a new Cu-8 at. % Cr-4 at. % Nb (Cu-8 Cr-4 Nb) alloy for the liners. Work is ongoing to characterize the thermophysical and mechanical properties of the alloy from - 253 to 800°C, the temperature range to which the alloy will be subjected during service. The alloy has been commercially produced in quantity for NASA. The powder size has been characterized and the microstructure examined. The powder was extruded into bar using a commercial extrusion press. In addition, samples have been hot isostatically pressed (HIPed) at NASA Glenn Research Center. Both processing methods produced fully consolidated material. Transmission electron microscopy (TEM) revealed highly faulted Cr2Nb and some elemental precipitates. Cryogenic tensile testing showed the extruded specimens had significantly higher strengths than NARloy-Z (Cu-3 wt % Ag-0.5 wt % Zr) even after being subjected to a simulated braze cycle. The Young's moduli (Cu-8 Cr-4 Nb) were lower than NARloy-Z. The lower moduli is highly beneficial for reducing thermally induced stresses in rocket engine combustion chamber liners and similar applications.

Jan 1, 1999

By Charles Schmidt

Phalabonva (Figure 1) is situated in the northern province of South Africa adjacent to Kruger National Park, about 500 km from Johannesburg. The nearest South African port to Phalaborwa is Richards Bay about 700 km distant by rail.

Jan 1, 1999

By Pieter Berendsen

Lamproite occurs in two locations in southeastern Kansas that are in close proximity to each other. In both locations, the lamproite is restricted to north- east-elongated, ellipsoidal depressions measuring about 3 mi by 1.5 mi. At the surface and in the shallow subsurface, lamproite occurs as sills that were intruded into Middle and Upper Pennsylvanian rocks consisting of shale, limestone, and minor sandstone. Isotopic age determinations by Zartman and others (1967) indicate that the lamproite was intruded during the Late Cretaceous (88-91 my). Drillholes for hydrocarbon exploration down to a depth of about 1,400 ft (top of the Mississippian) and numerous shallow drillholes (mostly 200-300 ft) by the Kansas Geological Survey in the northern portion of Silver City dome helped to understand the structural complexity and extent of the near-surface sills. Numerous radial faults showing small apparent vertical offsets limit the lateral continuation of individual sills. Concentric faults are believed to mark the edge of the depression. Wagner (1954) mapped the geology of Silver City dome in considerable detail and recognized a northward dipping, 120-ft-thick, lamproite sill exposed at the surface along the northeastern edge of the dome. The upper 40-50 ft of the sill weathers olive-brown and has a soft, clayey consistency in which only the phlogopite mica is recognizable. The weathered material has been mined by Micro-Lite LLC since 1982 from the exposed sill in an open-pit that measures about half a mile extending in an east- west direction. The bulk of the material, about 98%, is used as an additive in mineral supplements for cattle feed.

Jan 1, 1999

By V. Jiricny

The novel spouted-bed electrode (SBE) is a cathode system where copper is deposited at a high current density in a moving bed of copper particles. Preliminary results on the deposition of copper from acidic sulfate electrolytes using this novel cathode system were described during Copper '95 conference. Despite a high current density, the electrical energy consumption was equal to or lower than that in the conventional electrowinning. The present paper describes more investigations on SBE. The SBE consists of copper particles with approximately 1 mm diameter onto which copper is deposited from acidic sulfate electrolyte whose composition is similar to conventional electrowinning. Three types of anodes were used in conjunction with the spouted-bed cathode, namely, DSA anode for oxygen evolution, and two novel anodes. One anode is less expensive than DSA; however it showed much promise in energy consumption. At a superficial current density of 2200 A/m2, the energy consumption was around 1.0 kWh/kg copper. The research activities described in this paper were supported by BHP Copper.

Jan 1, 1999

By K. Osseo-Asare

Third phase formation, the separation of a solvent extraction organic phase into two liquids, is generally attributed to the limited solubility of the extracted complexes in the hydrocarbon diluents. Much of the research on third phase fomiation, therefore, emphasizes experiments designed to establish the stoichiometry of the species responsible for the limited solubility. This work offers a different approach, based on the recognition that the solvent extraction third phase, in fact, corresponds to the middle phase in a microemulsion fluid system. Using the tri-n-butylphosphate (TBP)-diluent-water-electrolyte system as a model system, current concepts of microemulsion phase behavior are utilized to develop a general framework for interpreting and predicting the patterns of phase behavior in solvent extraction systems.

Jan 1, 1999

By H. J. Thevik, A. K. Dahle

"A mathematical model that calculates the stress development in a coherent and stationary dendritic network due to interdendritic flow is proposed. The fluid flow is assumed to be related to the solidification shrinkage, and under the assumption of no porosity formation and unidirectional solidification, the shrinkage-induced flow within the mushy zone is calculated analytically. The interdendritic melt flow exerts a force on the solid network and an analytical expression for the stress build-up in the network is developed. Parameter studies illustrating the influence of cooling conditions, mushy zone length, dendrite coherency, fraction solid, volume fraction of eutectic, and solidification shrinkage upon the stress development within the solid network are presented. Comparing the magnitude of the calculated stresses to measurements of the strength in equiaxed mushy zones shows that it is possible for the stresses to exceed the strength, thereby resulting in reorientation or collapse of the dendritic network.IntroductionInterdendritic fluid flow is at present regarded as a very important mechanism for feeding of shrinkage during solidification of metal alloys. Solidification of many alloys is often characterised by heterogeneous nucleation of the primary phase on substrates in the melt with subsequent evolution of equiaxed dendrites. These equiaxed dendrites can initially grow freely, but impinge on each other and form a continuous dendritic network, ie. dendrite coherency, quite early in the solidification process. Measurements of the dendrite coherency point have shown that the dendritic network is established at solid fractions ranging between 0.1 and 0.5, and most often around about 0.2 [l]. Depending on the alloy composition this means that as much as 70 to 80% of the volumetric shrinkage has to be compensated by flow of liquid through the interdendritic network. Interdendritic flow occurs with a much larger resistance compared to free flow of the liquid and flow of a liquid with dispersed crystals. The pressure drop associated with the interdendritic flow increases rapidly with decreasing fraction ofliquid."

Jan 1, 1999

By R. Q. Honaker

Although the fundamental principles of hindered bed classifiers are relatively simple, the complex interactions between the operating parameters provide a degree of difficulty that hinders the ability for on-line plant optimization. Thus, a dynamic population balance model was developed for determining the hindered settling velocity of particles varying in density and size. The steady-state results of the model include partition curves as a function of particle size and density as well as metallurgical data. A statistical comparison of the simulation results with those obtained from industrial units reveal a high level of accuracy with adjusted R2 values greater than 0.95.

Jan 1, 1999

By Stephen Chryssoulis, Stamen Dimov

Detection and quantification of precious metals (Au, Pd, Pt, and Rh) in spinels and silicate minerals is important for establishing the maximum attainable recovery by sulphide flotation. To achieve this goal subpart per billion (ppb) detection limits are required plus the ability to quantify results. Existing quantitative microbeam techniques (EPMA, PIXE, SIMS, TOFLIMS) have limits of detection in the O. l-200ppm range. Time-of-flight resonance ionization mass spectrometry (TOF-RIMS) is a microbeam analytical technique that allows for the identification and quantification of atomic species in very small quantities. It utilizes a tunable laser source for resonant excitation and ionization of a particular element of interest and has some unique features: elemental selectivity, linear response over a large dynamic range and very high sensitivity. The analysis consist of three steps: (i) the solid sample is vaporized by laser ablation to form a plume containing neutral atoms, (ii) the neutral atoms of a specific atomic element in the plume are resonantly excited and ionized by another tunable laser, and finally (iii) the ions created are mass analyzed in a time-of-flight mass spectrometer. A TOF-RIMS mass spectrometer was developed at AMTEL for trace element analysis of Au, Pd, and Rh in minerals. The spectrometer was calibrated using homogeneous CANMET and NIST reference samples covering three orders of magnitude in concentration. Attained minimum detection limits (MDL=2cr of the background) are in the low ppb range.

Jan 1, 1999

By Yang Ruilin

Bulk gassing technology is a growing trend in the commercial explosive industry. The gassed bulk products produced differ from microballooned bulk products or cartridged products. It is easy to know the loaded or in-hole density for microballooned bulk products or cartridged products, whereas it is not as straight forward to know the m-hole density for gassed bulk emulsions. The loaded density is one of the key parameters affecting explosive performance and therefore it is important to have a field technique to monitor the in-hole properties of gassed bulk products in order to accurately predict the blast performance and to ensure efficient use of the products.

Jan 1, 1999

By M J. Bourassa

In addition to the geologic risk of a particular project, the criteria that an international exploration company (æIECÆ) utilises when making an investment decision in a particular country should also include a critical analysis of the political, judicial and fiscal regime of the host country. A key investment criteria of an IEC is mineral tenure and the security and continuity of that mineral tenure under the host countryÆs existing legal system as well as the host countryÆs overall legal, political and fiscal framework, the latter of which can affect the projectÆs overall economic viability in a number of ways. The authors, Steve Vaughan and Michael Bourassa of Aird & Berlis, Toronto, Canada, have taken the position that developing an understanding of a countryÆs legal tradition is a crucial first step in analysing the mineral regulatory regime of a particular country. This paper continues their efforts to overview the most recent legal trends affecting the worldÆs mineral industry and attempts to analyse, categorise, compare and contrast differing legal systems, cultural backgrounds and economic philosophies relating to the development of mineral rights in Pacrim countries and the resulting commercial, legal, and political framework which ultimately drives the relevant mineral legislation. For the convenience of organisation of this analysis, the authors have divided the Pacrim countries into four smaller groups, firstly, on the basis of their legal tradition and, secondly, by their geographic location:Common Law Countries: USA, Canada, Australia and New Zealand; Spanish Civil Code Countries: Mexico, Central America (Panama, Nicaragua, El Salvador, Guatemala), South America (Chile, Peru, Ecuador, Colombia). Communist or Former Communist Countries: Mongolia, China, Russia. Countries of the Pacific Southwest: Phillippines, Indonesia, Malaysia, Indo-China (Vietnam, Laos, Cambodia, Thailand), Papua New Guinea. The discussion starts with an analysis of the various types of legal regimes, attempts to classify or categorise them, reiterates the necessity for the rule of law and those factors which encourage mineral exploration and development and discusses and recommends the expansion of a practical country competitiveness rating system developed by the Fraser Institute. In addition to the fundamental issue of mineral tenure û what it is and how secure it is û the paper discusses how different legal systems have shaped different approaches taken by individual nations to attract foreign mineral investment. The paper analyses the best practices and experiences accumulated in different Pacrim countries with varying legal traditions and identifies a practical country competitiveness rating system which the authors believe should be expanded to cover all minerally endowed countries. This rating system will permit countries to identify their mineral regime weaknesses and adjust their legal systems to better attract mineral investment and will also permit exploration and mining companies to compare their jurisdictional choices with those selected by their competitors.

Jan 1, 1999

By Gaston Giuliani, Jérome Massot, Didier Bourlès, Lionel Siame

"Abstract - We present a new approach for the evaluation of the potential of emerald reserves in gem projects using beryllium (Be) mobility. The distribution of Be in the different phases of hydrothermally altered (albitized) black shale hosting Colombian emerald deposits indicates that Be mobility is associated with the breakdown of Fe-Mn oxyhydroxide phases. The amount of Be that can be mobilized (~0.7 x 10-6 g/g; i.e., 0.7 ppm) may represent up to 18 wt% of the total Be contained in the black shale. A mass balance calculation applied to a well-constrained alteration zone of the Chivor mines, and based on the quantification of Be that can be mobilized under hydrothermal conditions, gives an estimate of the total gem reserves of these mines. Resumé - Une nouvelle approche, basée sur la mobilité du béryllium (Be) pour l’évaluation des réserves d’émeraude dans des projets d’exploitation de gemmes est présentée. La distribution du Be dans les différentes phases minérales de schistes noirs hydrothermalisés (albitisés) qui contiennent les gisements d’émeraude colombiens, indique que le Be mobilisable se trouve dans les oxyhydroxydes de fer et de manganèse. La quantité de Be potentiellement mobilisable (~0,7 x 10-6 g/g; soit 0,7 ppm) constitue jusqu’à 18% poids du Be global contenu dans le schiste noir. Un bilan de masse appliqué à la zone d’altération hydrothermale des mines de Chivor et basé sur la quantification du Be mobilisable, donne une première estimation des réserves à émeraude de ces mines. rieur."

Jan 1, 1999

By M. Cornelius

Drilled shaft construction through caving soils has historically been an uncertain, risky and costly operation. Uncertain, because the zone of caving may or may not be known, risky because the loss of a shaft is disastrous, and costly because the Contractor, who faces these risks, must include large sums of money in his bid for shaft wall stabilization techniques. This case study will discuss the stabilization techniques that are typically used within the United States, and then present new technologies, born in Europe, that are being utilized in the States by Malcolm Drilling Company today.

Jan 1, 1999

By Yuan Zeping

The distributions of impurities in the copper melt, the slag and the gas phase in copper flash smelting process were under study in the Guixi smelter, particularly during operating conditions of high oxygen enrichment with production of high grade matte. Several methods for the removal of impurities such as As, Sb and Bi in the copper smelting process were developed and implemented at the Guixi smelter. This paper described the effects of high oxygen enrichment, elevated matte grade, high temperature and high production rate on the distribution of impurities, methods adopted at the smelter for the removal of impurities, and the associated benefits in the utilization of these removal techniques which include the mathematical model for material blending, high thermal intensity operation at the flash furnace, extended converter blowing, and injection of slag modifiers consisting of Na2CO3 and CaO powder mixture to the converters and anode furnaces.

Jan 1, 1999

By Jean-Guy Levaque, Robert Ethier, Ron J. Elliot

This paper presents data gathered during a comprehensive study on the impact of improvements to fragmentation in a major Limestone quarrying operation. The full impacts of gains in fragmentation are tracked through the mucking, crushing, and grinding phases of the operation.

Jan 1, 1999