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By D. R. Nagaraj

The practice of nonsulfide minerals flotation can be best characterized as an evolutionary blend of scientific theory and art. Although extensive fundamental studies have been carried out in the past several decades, and significant theoretical aspects have been developed, plant practice has developed the art form, often ahead of the theory, which is somewhat in contrast to sulfide minerals flotation. Several excellent review articles have been published in the past highlighting both the theoretical aspects and plant practice. An overview of nonsulfide flotation is presented here. Major differences in sulfide and nonsulfide flotation are highlighted. An assessment of the state of nonsulfide flotation, recent advances made in flotation processing, and industry needs are also given.

Jan 1, 1999

By K Orth

The volcanic successions that host massive sulphide deposits are diverse in composition, facies types and facies relationships. They also show a variety of spatial and temporal relationships to mineralisation. In many examples, such as the Koongie Park Formation in Western Australia, the host succession includes more or less conformable syn-volcanic sills with peperitic contacts. Such sills can be an important source of heat for fluid circulation, influencing patterns of hydrothermal alteration and the location of co-eval and later mineralisation. The impact of syn-volcanic sills on the host succession depends in part on the initial porosity and permeability of the enclosing facies. The special properties of glassy pumice û being highly porous, permeable, and reactive û allow pumice-rich facies to preferentially focus hydrothermal fluid flow. However, the same properties promote early alteration and porosity reduction. Hence, the diagenetic and compaction history of pumiceous facies strongly influences their potential to host massive sulphide mineralisation. In contrast to pumice, dense glass has relatively low porosity, at least initially, and does not compact. Non-vesicular glass is a major component of submarine lavas, syn-volcanic intrusions and some volcaniclastic facies. However, especially in submarine settings, dense glass is commonly intensely perlitically fractured soon after eruption. The fractures greatly increase the porosity and permeability, locally accelerating diagenetic and hydrothermal alteration. In addition to false pyroclastic textures, altered perlite may exhibit false porphyritic textures. Silica- or feldspar-altered perlite kernels surrounded by intensely altered phyllosilicate domains can resemble phenocrysts in a fine grained groundmass.

Jan 1, 1999

By Kenneth S. Johnson

Oklahoma is a region of complex geology where a mobile belt of Paleozoic geosynclines and uplifts on the south abuts against the margin of the North American craton to the north. The state contains many classic areas where fundamental concepts of sedimentation, stratigraphy, structural geology, historical geology, mineral investigation, and petroleum exploration have been formulated through the years. In the southern Oklahoma mountain belts, there are exposed a great variety of igneous and sedimentary rock units seen at few other places in the Midcontinent area. Major geologic provinces of Oklahoma (Fig. 1) include: (1) the cratonic and relatively stable northern shelf areas, including the Ozark uplift; (2) the Ouachita geosyncline (now the Ouachita Mountain belt) and associated Arkoma basin in the southeast; and (3) the southern Oklahoma aulacogen (geosyncline), comprising the area of Anadarko, Ardmore, Marietta, and Hollis basins, as well as the Arbuckle and Wichita Mountain uplifts. The three principal fold belts, the Ouachitas, Arbuckles, and Wichitas, all originated from a series of Pennsylvanian orogenies (about 300 million years ago) in the two Paleozoic geosynclines.

Jan 1, 1999

By P. M. Pincheira Brown

The widely accepted inverse relationship between copper prices ail stocks, has been commonly used by analysts to explain the behavior of the copper market and to forecast film copper pries. However, empirical data have not shown such a clear relationship between copper prices and stacks. Existing evidence only indicates a weak tong-nut relationship that vanishes in some periods. In this paper a simple comprehensive model is provided which explains both parallel and opposite direction movements between prices and stocks. Former are explained mainly by stocks demand expansions-contractions while the latter are in essence due to increases in the supply curve. Furthermore, econometric estimations are provided, thus giving a powerful tool to forecast and explain price developments of the copper market.

Jan 1, 1999

By James E. Simpson, Suresh V. Garimella, III de Groh

"An experimental and numerical study of the horizontal Bridgman growth of pure succinonitrile (SCN) and of a succinonitrile-1.0 mol. % acetone alloy (SCN-1.0 mol. % ACE) has been performed. Experiments at growth rates of 0, 2 and 40 µmis were investigated. The solid/liquid interface was stable (non-dendritic and non-cellular); however, it was not flat. Rather, it was significantly distorted by the influence of convection in the melt and, for the growth cases, by the moving temperature boundary conditions along the ampoule. For the alloy, the interface was determined to be unstable at growth rates greater than 2.8 µmis, but stable for the no-growth and 2 µmis growth cases. When compared to the pure SCN interface, the alloy interface forms closer to the cold zone,· indicating that the melting temperature has been suppressed by the addition of the alloying element. Two-dimensional computer simulations were performed for the no-growth case for both the pure and alloy materials. These simulations indicate that a primary longitudinal convective cell is formed in the melt. The maximum magnitude of velocity was calculated to be 1.515 mmls for pure SCN and 1. 724 mm/s for the alloy. The interface shape predicted by the computer simulation agrees well with the experimentally determined shape for the pure SCN case. In ongoing work, numerical simulations of the process during growth conditions are being performed.IntroductionIncreasingly, advanced materials used in the aerospace, automotive, optics and electronics fields require low levels of defects and high levels of solute uniformity. Directional solidification by the Bridgman process is widely used for synthesis of these high-quality materials. During Bridgman crystal growth, heat and mass transfer by both thermal and solutal gradient-driven convection and diffusion influence the shape of the solid/liquid interface and dopant segregation levels, and hence, directly determine the final crystal quality. Key process parameters include the applied furnace temperature distribution and rate of translation, ampoule properties and furnace orientation."

Jan 1, 1999

By B. Unver

Effective strata control is a prerequisite for maintaining an efficient mining operation. If the strata in the vicinity of an opening are not controlled effectively, it is impossible to perform a safe, efficient and economical operation. In this paper, the reasons and outcome of instability problems observed in roadways opened in clay and marl at the Bolu Colliery of Yeni Çeltek Establishment are investigated. Roadways under examination were located in a syncline causing high residual tectonic stresses. Factors affecting the instability have been studied thoroughly by examining geology and tectonics of the area, establishing convergence measuring stations to understand in situ behaviour of supports and laboratory tests to determine engineering properties of samples taken from nearby convergence measurement stations. As a conclusion, a new production strategy and a new support system are recommended to maintain stability.

Jan 1, 1999

By Yushiro Hirai

Saganoseki smelter & refinery had operated two flash smelting furnaces from 1973, attaining 330,000 mtpy of copper production in 1989. In 1996, however, it carried out a "integration of two flash furnaces". That is, it doubled the feeding capacity to one flash furnace to shut down another furnace while maintaining the same production. Single flash furnace operation has successfully started in March 1996 accomplishing a great reduction of the total production cost. The production had reached to 350,000 mtpy in 1997, and further increased to 450,000 mtpy by executing the expansion program with single flash furnace in 1998. This paper introduces results of the single flash furnace operation and describes about an outline of the expansion.

Jan 1, 1999

By John Stankus

Regional high horizontal stress has long been recognized as an important factor affecting roof stability However, localized high horizontal stress, although causing many ground control problems, has not received due attention, Through many ground control studies and underground experiences, it has been round that localized horizontal stress can be created by abrupt changes of overburden and stream valleys. The magnitude of localized horizontal stress depends on the valley configuration and overburden depth. Utilizing the Jennmar Finite Element Analysis System (JFEA), this paper analyzes the mechanism of the localized horizontal stress concentration based on two cast studies.

Jan 1, 1999

By R. C. Berry

The Environmental Impact Statement (EIS) has become a routine requirement for mining operations on federal lands. A similar document is being required in developing countries. Baseline studies are needed prior to writing an EIS and these studies involve surface water, groundwater, air quality, and wildlife/ native plant evaluations. The required baseline hydrology and geochemical studies are often the most expensive and lengthy evaluations. This paper summarizes the hydrology and geochemical baseline studies required for .An EIS and presents suggested methods to expedite these studies and to shorten the time and the cost to complete the studies and the EIS.

Jan 1, 1999

Conditional simulation provides a model of the ore body that represents variability in the data. This can be used to determine the impact of various grade control and mining strategies. A number of transfer functions are discussed that assist in optimizing grade control sampling. The cost effectiveness of various drilling and trenching techniques are discussed. Modelling of the expected performance of a mill head grade sampler is investigated. Conclusions are drawn about the likely impact of various sampling techniques on the economic performance of an operation and about applying sampling theory to grade control sampling.

Jan 1, 1999

By Munetaka Iwasaki

Nitrogen strongly affects mechanical properties of steel and therefore we may sometimes modify the various processes for its content. Numerous studies based on the results of chemical analysis of quenched samples were reported with a few exceptions of Hot Sievert method. The technique always poses a risk of uncertainty whether the true content of nitrogen in liquid metal is measured or not. In this study vacuum remelting under relatively low pressure was done to enhance gas phase mass transfer. Total pressure of the melt chamber was about 10-3 pa and electron beam heating was used. Mass spectroscopy was used for the direct observation of the rate of denitrization. Nitrogen molecules or atoms were detected by a mass spectrometer set above the melt. Continuous monitoring of the intensity of the fixed mass number may reflect the transfer of nitrogen from the melt to the vacuum. The results of the new and conventional techniques agree, both technique can be verified.

Jan 1, 1999

By G. E. S. Valadao

Filtration is an important solid liquid separation technology employed widely in the mineral processing industries. The effectiveness of the filtration operation can be influenced by numerous variables, related to the particulate phase, the slurry rheology and the equipment. The classical approach for analysis is based on Darcy's law. Knowledge of the cake pore microstructure and its correlation to macroscopic cake properties is required to model the filtration operation from a fundamental point of view. Since cake formation seems to occur randomly, a 3D Monte Carlo method was used to simulate cake formation. The configuration for simulation was a space with width of 500 µm, length of 500 µm and height of 4000 µm. Size distributions of five different industrial products whose particle size distributions follow the Rosin Rammler distribution function were used. The particle shape was assumed to be spherical. The simulated cake structures were described in terms of volume porosity (volume of pore space per unit volume of cake) and surface porosity (area of pore space per unit area of a cross section). The results indicate: I) it is possible to simulate 3D packing, which mimics cake structure, using the Monte Carlo method, 2) segregation phenomena occurs during simulated cake formation, 3) the values of calculated porosity for simulated samples B, C, D, and E were lower than those determined for corresponding industrial products Br, Cr, Dr, and Er, and 4) some structures of simulated samples seem to correlate with laboratory leaf test data obtained for different products from plant operations.

Jan 1, 1999

By S A. Johnson, J Cassidy, J L. Mauk

Geophysical anomalies at Puhipuhi reflect both diverse lithologies and different degrees of hydrothermal alteration. Most significant is a strong negative gravity anomaly (up to 50 g.u.), encompassing but extending beyond areas of known alteration, which is modelled as a deep zone (up to 3 km) of reduced density in the host greywacke basement. This zone, interpreted as being due to alteration (at least in part), closely correlates with the extent of overlying basalt flows. The gravity data indicate that the most intense alteration occurs below the basalts and correlates with the location of previously inferred hydrothermal upflow zones. These observations suggest that the basalt may have acted as a cap rock to a mineralising geothermal system. Aeromagnetic data identify highly variable but typically low magnetisations in the basalts which suggests that alteration may have been contemporaneous with volcanism. These geophysical data at Puhipuhi confirm the locations of centres of known alteration and suggest potential exploration targets below the basalt cap where there is no surface manifestation of alteration. Further implications of these results are discussed in Locke et al. (1999).

Jan 1, 1999

By M. E. Ramos Rada

Mexicana de Cobre, which is part of Grupo Mexico, carried out studies for the construction of a copper refinery in the La Caridad Metallurgical Complex located in Nacozari, in the state of Sonora, Mexico. After the studies were concluded, the decision was made to construct a 180,000 t/y refinery using the state of the art permanent cathode Kidd Process. The basic engineering was developed by Fluor Daniel and the detail engineering and the construction were carried out in record time by the Mexican company Bufete Industrial. During the construction phase, Grupo Mexico decided to expand the refinery, and actions were taken to increase its capacity by an additional 120,000 t/y; the final result was a refinery capable of producing 300,000 tonnes of grade A cathode per year. Construction began in January 1996, and the operation of the first stage began on July 1, 1997. The operation of the second stage commenced on January 7, 1998. The capacity of the first stage was reached in November, 1997 and the total capacity of the refinery was achieved in May, 1998. This presentation describes the process and equipment installed in the refinery, the steps leading to the start-up, the operation and the results obtained during the first two years, the handling of anodes with high impurity contents, and the problems confronted and the way they have been solved. It also includes personnel productivity, the control parameters and the most relevant data on the operation of the process.

Jan 1, 1999

By Godwin M. Beene

Large scale mining operations started in Zambia in 1913 and rapidly expanded during the post 1930 period with the opening of several mining and processing plants on the present Zambian Copperbelt. As a consequence of poor tailings dumps design methods at the start of the mines, and in view of stringent Government Legislation pertaining to environment in the recent years, Nkana Mine has developed a unique method of dump construction at its current tailings depository, Tailings Dam 15A. This method has enabled the revegetation of the dump retaining walls while construction is still in progress, a situation which was not possible on the older dumps. Cowdung has proved to be a superior fertilizer for providing plant nutrients on the tailings. The new method of dump walls construction and walls rainwater runoff drainage system has almost eliminated tendency of gully formation which is common on older dumps, as rainfall on the Zambian Copperbelt comes in intense thunderstorms. The decanted water from the dump is discharged to the natural environment in a controlled fashion after ensuring that it meets the Zambian Government Statutory requirements.

Jan 1, 1999

By A. A. Shook

For relatively little capital outlay, the metal delivery control system in the BHP Copper Rod Plant at San Manuel' was significantly upgraded using the UNAC process simulation and control system (CICS Automation, Newcastle, Australia). An accurate simulation of the metal delivery process was developed with UNAC, which was then used to design a robust controller capable of dealing with plant complexities such as noise, time delays, and nonlinearities. This controller was implemented online using UNAC. Thanks to the extensive preparatory simulation, the controller worked immediately and required no additional online "tuning". Operator response has been favorable, and the UNAC control system has become part of the standard operation of the plant.

Jan 1, 1999

By Jackson Jenkins

The second survey of world copper SXEW plants has been completed. Solvent extraction and electrowinning data published in 1996 has been updated and leach data from seventeen plants is now included. The following pages list the results of the thirty- two plants that responded to the survey. Selected information is summarized in graphical form.

Jan 1, 1999

The key elements required to maintain final wall integrity and hence slope reliability are discussed. Failure modes and mechanisms in highly structured rock slopes are then reviewed. The impact of blast disturbance on rock masses in general is discussed and the relationships between the slope failure mode and blast disturbance is then explored. The question of how designers can incorporate such impacts into the slope design process is then addressed. This necessarily involves rock mass strength consideration and two case studies are used to demonstrate a recent dilemma in this regard. Some progress regarding this dilemma has also been reported for the second case study. The major conclusions are that: Slope reliability can be severely compromised if the slopes are damaged by blasting and this impact is not often incorporated into the slope design process. The location and extent of the blast damage will impact some slope failure geometries and failure mechanisms more than others. The concept of failure mechanism specific vulnerability needs to be further developed. The evidence indicates that this aspect is even more extreme for weak ground conditions. The quantification of the reduction in rock mass strength due to blast damage is not well understood and limitations exist with some recent guidelines. The use of the Hoek-Brown criterion for slopes in blocky rock masses requires considerable judgement. Further applied developments in this regard would be very beneficial to the industry. Some promising methods to incorporate blast damage estimates into the slope design process are emerging. It is good business to minimise final wall blast damage otherwise a whole range of issues relating to reduced slope reliability emerge.

Jan 1, 1999

By R. Hiebert, M. Foote, S. Nordwick, M. Canty

An innovative biological treatment system designed to detoxify cyanide and nitrate and immobilize metals from cyanide leach operations is described. A pilot-plant demonstration was conducted to detoxify cyanide and immobilize several metals from a process stream at the McCoy/Cove Mine. Testing was performed under the EPA’s Mine Waste Technology and Superfund Innovative Technology Evaluation Demonstration Programs. This technology was successful in detoxifying cyanide and effective in removing metals. The pH was consistently neutralized and nitrates were successfully removed. Results show that biological treatment can offer an innovative, cost-effective alternative for the treatment of mining wastewaters.

Jan 1, 1999

By Gao Zhinzhong, Gu Zhengxing

China abounds with phosphate resources, but most of them are of old geological age, have high dolomite and other impurities, and are fine grained. Prior to beneficiation, fine grinding is usually required for liberating impurity minerals from phosphate. These deposits are perhaps the most difficult to treat phosphate ores in the world. In its 30-year campaign for efficient utilization of indigenous phosphate resources in China, the Lianyungang Design and Research Institute (CLDRI) has developed fine-particle flotation technology for beneficiation of such low-quality phosphate ores. The processes of direct flotation using L or S series depressants and carbonate flotation have been successfully applied on industrial scale with very satisfactory results. This paper introduces three phosphate beneficiation practices in China: the Jinping plant of Jiangsu province, the Dayukou plant of Hubei, and the Wengfu plant of Guizhou.

Jan 1, 1999