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By M. Downing

This paper gives a brief overview of impacts of coal blending on coal-fired power plants performance and discuses the preliminary results of an on-going study aimed at evaluating the effect of coal properties on the effectiveness, compatibility and thermal reactivity of coal blends. Plant survey studies reported no significant impacts on an existing plant designed for a high rank coal when switched to a blend of low-and high-rank coal. However, slight modification of some aspects (handling, fuel storage/stockpile, transportation, preparation, and general housekeeping) of plant design and operation may be necessary. The preliminary results of an on-going study at the Mineral Industry Research Laboratory shows that more compatible and better blends could be made from coals where ranks are closer than from those where ranks are far apart.

Jan 1, 1997

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the LaJoya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein(BPV) type, with a signi?cant amount of the gold reserves contained in the oxide cap.Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997

By G. H. Schnakenberg

In 1986, the US Bureau of Mines (USBM) embarked on a major research effort to develop technology that could substantially reduce worker exposure to face hazards by simply relocating the equipment operators to an area of relative safety. This reduced-exposure mining system (REMS) research effort enhances the USBM's ongoing health and safety efforts aimed at reducing and controlling dust and noise and reducing accidents through training and better mining practices. This paper reports on the progress made on the developing research and demonstrates the technologies required for the computer-assisted teleremote operation of continuous mining machines, haulage systems and roof bolting machines.

Jan 1, 1997

By S. Agatzini-Leonardou

The objective of this work was to prove repeated loading capacities and investigate the selectivity of physically stabilized algal biomass from Spirulina platensis and Chlorella sp. for the removal and recovery of cobalt, nickel and chromium from laterite heap leach liquors. The testwork was carried out on a bench scale in small glass columns and proved that it was possible to immobilize the biomass on the highly porous surface of pumice stone (kissiris). Nickel and cobalt could be removed from pure aqueous solutions of each metal by the immobilized cyanobacterial biomass. Nickel and also cobalt biosorption was sensitive to the initial solution pH. Cobalt recoveries up to 80% were achieved after 5 loading cycles, from low concentration solutions, at pH 6.0. Nickel removal was complete under the same conditions, whereas chromium sorption was ineffective. Desorption of the metal loaded columns was effected by dilute sulfuric acid. The algal species giving the best adsorption capacities for the metals under consideration was selected for further experimental work with real laterite heap leach solution produced by column leaching. A statistical analysis of all obtained results was conducted using the fraction of metal removed as response. The ratio "mass of metal removed to mass of protein contained in the immobilized cells" was determined as well. The described method might be applicable for recovery of cobalt and nickel from diluted laterite heap leach solutions, such as heap wash waters, or for their removal from waste streams of a hydrometallurgical extraction process.

Jan 1, 1997

By S. K. Bhoumik, D. K. Sengupta, B. P. Singh

This paper deals with experimental work to improve the settling and filtration characteristics of an industrial sludge from an iron-ore mine using synthetic polymeric flocculants. The experimental work consisted of the characterization and evaluation of suitable flocculants to enhance settling and filtration rates. The optimum dosage of the flocculants were determined. The experimental results revealed that the settling rate can be increased many times, compared to untreated sludge, by using a suitable combination of flocculants. Compared to cationic and nonionic flocculants, anionic flocculants were found to be more efficient in sludge flocculation. The synergistic effect of two anionic flocculants produced the best settling conditions. Filtration test results also reveal that suitable flocculants can improve the dewatering characteristics of the slurry.

Jan 1, 1997

Mine design and selection of ore processing capacity depend upon a correct estimate of the grade-tonnage distribution. The estimate must reflect what can be recovered and processed. The McCoy/Cove operation in central Nevada, USA, is a gold and silver mine. Case studies of recoverable reserve estimation for gold and silver were made using multiple indicator kriging and the log-affine variance correction. From this model, the grade-tonnage distribution was constructed. Optimal pits were generated by utilizing the distribution, and the results were compared with the pit generated by ordinary kriging. Studies indicate that the proposed method for multi-metal recoverable reserve estimation is more accurate than ordinary kriging in terms of both tons and the grade. Using recoverable reserves for mine design will maximize global recovery of mineral resources.

Jan 1, 1997

By Michael S. Wieland

Delay detonators that are damaged by cross-hole wave interactions degrade blasting work and raise the risk of incidents. Damaged detonators impose risk, because they can retain sensitive explosives that respond to stray energy during recovery, inspection or disposal. Laboratory techniques were developed to rank the ruggedness of delay detonators under replicated field-shooting conditions. The hazards are tremendously magnified if trial detonators are installed directly in secondary explosives to rank initiation strength. Therefore indirect ranking techniques were sought that mitigate the risks without compromising the worthiness of the method. Four types of hardware fixtures, referred to as simulators, were developed to yield distinct forms of transient compression. The shock and rift versions generate compression pulses representative of in situ waveform components. The waiting time, until the trial detonator functions, duplicates typical delay periods. The trial detonator is mounted within water, which has a density and inertial resistance comparable to most blasting explosives. The work output from the trial detonator explosion is registered as fixture wall-expansion. This work output determines malfunction results, regardless of which type of simulator is used.

Jan 1, 1997

By Miskelly N

In Australia and New Zealand, the 'Australasian Code for Reporting of Identified Mineral Resources and Ore Reserves', which was released by industry in 1989, is operating successfully in a co-operative approach between industry and regulatory authorities. Similar codes or guidelines exist or are under development in the United States of America, Canada, the United Kingdom and South Africa, although the regulatory backing given to the Australasian Code is unique. International standard definitions for Mineral Resources and Reserves, and for categories of Resources and Reserves, have been under development by the Council of Mining and Metallurgical Institutions since 1994 and have already stimulated considerable convergence of definitions and reporting standards in participating countries. It is hoped that agreement on this international standard for public reporting by mining companies will be reached within the next two years, and it is expected that adoption of the standard will result in a higher and more uniform quality of reporting worldwide, with a consequently greater interest on the part of the general public and financiers in investing in the mining industry.

Jan 1, 1997

By Mark J. Schultz, William J. Francart, Michael P. Snyder

The Pittsburgh Safety and Health Technology Center surveyed MSHA Coal Mine Safety and Health Districts to monitor the implementation of computer based atmospheric monitoring systems (AMS) in underground coal mines. This survey was first completed in 1984, and has been periodically updated with the latest update completed in 1995. The utilization of computer based monitoring systems has steadily increased over the past 12 years, with over 16 percent of all producing underground coal mines using this technology in 1995. This paper discusses the results of the MSHA 1995 AMS Survey.

Jan 1, 1997

By J. T. Crawford

A comprehensive strategic planning model has been developed for the phosphate strip mining and chemical operations at White Springs, Florida. The computerized model covers ore body modeling, production simulation and financial analysis. Several innovative features in the model include using NPV techniques in ore body block economics, adapting the floating cone method to a floating template for generating dragline mining units automatically, using interactive graphics for designing mining units, and a dragline move economics algorithm for automatic scheduling of mining unit assignments and moves. Simulation of chemical plant production uses linear programming and concentrate inventory levels control mine operating schedules.

Jan 1, 1997

By Albert W. Spitz

Profitably recovering copper and precious metals from copper bearing scrap is a demanding and frustrating combination of art, science and economics. With fluctuating markets, varying raw materials and increasingly stringent environmental regulations requiring process revisions, practically everything is changing. The volatile copper market constantly shifts the percentage of copper in the scrap that can be economically processed. Scrap that has value one day may incur a disposal cost the following day. Also with less copper in the scrap, more residuals, slag, fume, etc. are generated which frequently present disposal problems and infrequently generate income. The ever increasing amounts of electronic scrap add value to the copper produced by virtue of the precious metals present. Printed circuit board materials create more slag and organic off gases which must be treated. Finally, the emphasis on reducing emissions of organics and other metals, especially lead, is a continuing challenge. Stack gases, fugitive emissions and ambient air quality all demand constant surveillance.

Jan 1, 1997

By Alexander A. Knminskii

Polymorphism of BaR2F8 compounds is analyzed, and some peculiarities of obtaining monoclinic low-temperature (3-BaR2F8 crystals (R=Y, Ho-Yb) and orthorhombic high¬temperature a-ßaR2F8 crystals (R=Yb, Lu) by the Bridgman-Stockbarger growth technique are discussed. We pay a special attention to BaYb2F8:Er3+ crystals, which are able to generate both 2:µm SE using the new four-level operating scheme (4F9/2?4I11/2 laser channel) and 2- and 3-µm SE by means of the cascade scheme (4F92?+4I11/2?+4I31/2). This 2-µm generation of Er3+ ions has an advantage over similar SE of Ho3+ and Tm3+ ions (especially under diode laser pumping), that is important in designing the medicine and ecology laser. We report on orthorhombic BaR2F8 crystals with the ordered structure, a new crystalline materials for generating Ln3+ ions. The growth conditions are determined and orthorhombic BaLu2F8 crystals of several cm3 in volume doped with Ce3+, Nd3+, Ho3+, Er3+, and Tm3+ ions are obtained for the first time. Spectroscopic and laser characteristics of these crystals are discussed for Nd3+-and Era+-doped samples serving as representative examples. In particular, low-threshold stimulated emission was excited in 4F3/2?+4I11/2 channel of Nd3+ ions in the BaLu2F8. Room-temperature generation was obtained also at -1.317 µm wavelength for Nd3+ and at ~2.8 µm (several lines) for Era+ ions in this new laser crystalline host with a threshold of about 20 J.

Jan 1, 1997

By J. N. Adamson

The Alcan Smelter project at Lynemouth on the Northumbrian coast draws cooling water for the power station through shafts and tunnels from the North Sea. The sea at this part of the coast is frequently very rough and even in calm weather the coastal currents are strong. The adjacent coal mine makes use of these currents to disperse colliery waste and discharges into the sea some thirty thousand tons each week. In consequence the sea bed is continuously shifting and the sea is black and turbid. Construction of sea shafts under these conditions presents difficulties as drilling from a floating vessel is hazardous and sea bed activity of divers is greatly hindered by the entire absence of visibility. After considering several alternatives a method of construction was agreed with the Consultants in which the drilling and also the lining of the shaft would be completed in sequence from an eight legged work barge (GEM 126). Each shaft would be drilled to full depth and a steel cylinder, with its ends closed temporarily, would be lowered into the hole and grouted into the formation to form a full-length permanent lining. The bell mouth for each shaft would be constructed in advance to form part of the cylindrical casing. On interception of the shaft by its appropriate tunnel the lower end of the cylindrical casing would be cut away and the internal walling of the shaft installed from below. After completion of construction the shafts and tunnels would be flooded and the bell mouth sealing covers removed by divers.

Jan 1, 1997

By M. J. Laurila

On-line analyzers have made possible the use of fuzzy logic control (FLC) for local control applications in coal preparation plants. This includes FLC of heavy media vessels, cyclones and froth flotation. These circuits can be controlled in real time in a feedback control loop with an on-line analyzer. Control strategies can be developed using statistical process control (SPC) techniques that are first applied offline in manual mode through the use of control charts. This process is then brought on line using FLC in conjunction with an on-line analyzer to automate the circuit. The advent of programmable logic controllers into preparation plants has enabled the implementation of regulatory control. As shown in Fig. 1, regulatory control is the first level of process control as applied in a processing facility. This involves: ? The logic sequences for start-up and shutdown procedures and all the necessary interlocks for safety purposes. ? The systems to control individual parameters and individual units. Various sensors provide information that is useful to plant operators, while some can be used as signals to simple control loops (Couch, 1996). This is the foundation of process control. It must be performed well if there is to be any success in supervisory control (level 2). Supervisory control involves overseeing and directing the operation of unit operations, or of the whole plant. This includes more complex loops with cascade control. And it may involve feed forward and feedback systems. There have been some applications of this kind of control to thickeners and flotation circuits in coal preparation plants. In addition, there are supervisory controls on some dense medium circuits and, in a few cases, on jigs. These are implemented with proportional integral- derivative (PID) controllers that are available in the PLC or distributed control system (DCS) operating soft ware. In a coal preparation plant, there might exist 200 to 400 PID loops. In a coal-pro¬cessing plant, this number is increased to 2,000 loops or more. It is important to use the correct algorithm or function to control a process variable to the point where automatic control shows a markedly decreased variability over manual mode. This is where fuzzy logic and neural networks have an advantage over traditional model-based expert systems. Because dynamic models of coal preparation unit operations do not exist, model-based expert systems that are prevalent in minerals processing cannot work. Not enough is known about the dynamics of the gravity separation processes employed in coal preparation. Therefore, an artificial intelligence (AI) system consisting of a subset of fuzzy logic, genetic algorithms and neural networks must be applied in coal preparation plants if a supervisory control system is to be successful across a range of feed characteristics and variable set points.

Jan 1, 1997

By L. Bloom

In 1996, lack of confidence in assaying methods and sample handling affected companies as diverse as Bre-X and Timbuktu. Both share prices and the ability to raise financing are impacted when the quality of assay data is suspect. Overseas projects are subject to enhanced scrutiny when local facilities are used that are unfamiliar to brokers, financing agencies and banks. Quality control systems can be -implemented but there are associated costs. These costs should reflect the risk to the mining company, investors and financiers and the size of the proposed investment. In this regard, assay control call is considered a form of insurance to enhance the value of an exploration or mining project.

Jan 1, 1997

By E. Daniel Baker

"The term ""oxide disseminated gold deposits"" refers to near surface, gold-bearing veins, faults, and shear zones that typically contain appreciable amounts of oxidized ore or gossanous material, resulting from oxidation of sulphides.The concept of oxide gold deposits underwent a dramatic change after the discovery of the Carlin gold mine in north-central Nevada in the early 1960's. Now the term implies large tonnage, low-grade bulk minable deposits that are processed by milling and/or heap leach methods.Oxide gold deposits may now be classified into two types: (1) primacy ores derived directly from the effects of hydrothermal alteration on host rocks, and (2) secondary oxide ores derived from the supergene oxidizing effects of circulating post-mineral meteoric waters on gold-bearing sulphides. Each type of deposit has unique diagnostic mineralogic and metallurgical characteristics that must be addressed to achieve successful exploration strategies and viable metallurgical exploitation.The author would like to thank the management of Newmont Metallurgical Services and Newmont Mining Company for allowing presentation of this paper. Thanks are due Sevkett Acar, Donald M. Hausen, Jerry R. Odekirk, and D. Erik Spiller for their critical review of the manuscript. Also, thanks are extended to all those cited and uncited whose hard work and dedication have led to the discovery and exploitation of near-surface oxide gold deposits. Our knowledge would be greatly limited without the dedication and research of many others."

Jan 1, 1997

By L. Bloom

In 1996, lack of confidence in assaying methods and sample handling affected companies as diverse as Bre-X and Timbuktu. Share prices and the ability to raise financing are impacted when the quality of assay data is suspect. Overseas projects are subject to enhanced scrutiny when local facilities are used that are unfamiliar to brokers, financing agencies and banks. Quality control systems can be implemented but there are associated costs. These costs should reflect the risk to the mining company, investors and financiers and the size of the proposed investment. In this regard, assay control can be considered a form of insurance to enhance the value of an exploration or mining project. Providing reliable assay data in a production laboratory is challenging. Pressures such as time constraints and profitability affect data integrity. In Australia and North America, reliable assaying services have been provided by several laboratories. Mistakes are primarily due to human error but systems are available that monitor results and identify these types of errors. As the mining industry expands globally, mining companies encounter difficulties in some of these areas due to lack of infrastructure, poor communications, bureaucracy and political risk. These challenges also apply to the operation of laboratories, enhancing the risk of compromised data.

Jan 1, 1997

By D. G. Tisdale, W. Curlook, J. M. Toguri

"In this study, the vapour phase reduction of titanium tetrachloride conforms to the traditional Kroll chemistry, but employs argon as an inert carrier gas and requires a higher reaction temperature of 1150°C to 1250°C. A vapour phase reaction is advantageous because titanium is the only condensed phase present, and the metal can be collected free of magnesium or magnesium chloride, in marked contrast to the titanium sponge produced by the conventional Kroll process. The yield of metallic titanium from the reaction was determined as magnesium additions ranged from 36% to 168% of the stoichiometric requirement. Yields of over 99% were obtained when an excess of magnesium was present. Although the collection efficiency was low, metallic titanium was collected at the reaction site, where all other species were present as vapours. Magnesium and chlorine concentrations in the collected titanium were less than 0.3%.IntroductionA proposed method (Curlook, 1987) for titanium production has been investigated as an alternative to the conventional Kroll process (Kroll, 1940). The advantages of the new process include a simplified means of recovering the product metal, and a potential for lower overall energy consumption and greater product purity. A higher reaction temperature for the reduction of titanium tetrachloride results in a vapour phase reaction, rather than the conventional liquid phase reaction. This is the major conceptual difference between the proposed and the established (Kroll) processes.This study focussed on optimization of the process chemistry and briefly examined the issue of product deposition and collection. The reduction of titanium tetrachloride with magnesium, to produce metallic titanium and gaseous magnesium chloride:"

Jan 1, 1997

By Robert A. Haney, Scott G. Vail, Kenneth G. Fields

The Mine Safety and Health Administration, in cooperation with IMC Global Operations, Inc., conducted a joint study to determine the effectiveness of the technology currently in use at the mine to control diesel particulate exposures. IMC Global operates an underground potash mine using diesel-powered equipment to extract minerals. IMC uses a variety of technologies to control worker exposures to diesel particulate. These technologies include: ventilation, low sulfur fuel, oxidation catalytic converters (OCC), maintenance and work practices. The study was conducted over a two-week period, two shifts per day. During the first week (six shifts), baseline data on exposures and diesel particulate emissions were obtained. New OCC's were installed over the weekend on all equipment on the test section. During the second week (six shifts), data were collected to assess the effectiveness of the new OCC devices. In addition to exposure and diesel particulate emissions data, mine ventilation, engine exhaust temperatures and mine operational data were obtained. The primary means of determining diesel particulate concentrations was the respirable combustible dust (RCD) method. Gas concentrations carbon monoxide (CO), carbon dioxide (CO,), and nitrogen dioxide (NO,) were measured using passive dosimeter badges and gas bottles. Results of measurements of diesel particulate, gases, and air- flows were analyzed to determine the effectiveness of airflow and oxidation catalytic converters for controlling diesel particulate exposures. The use of oxidation catalytic converters resulted in reductions of both workers' exposures and diesel emissions.

Jan 1, 1997

By C De La Cruz

The use of a thin-film piezoelectric stress gauge to determine the pressure profile in a detonating explosive has been demonstrated. These PVDF gauges have measured, in the borehole, the Chapman-Jouget pressure and the release adiabat of the detonation products for several explosives including ANFO and ANFO/emulsion mixtures. The technique can provide: (1) a direct measure of the blasting stimulus, (2) a sensitive QA tool for the blaster, and (3) a means to examine the magnitude and effects of preshock from adjacent bore holes. The PVDF pressure gauge is self powered, can measure pressure from a few bars to 400 kbars, has high time resolution (0.05 µsec), and is easy and economical to use.

Jan 1, 1997