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By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting, lime roasting, is being tested fro retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04), oldhamite (CaS), calcium sulfite (CaS03), hematite (FenOs), magnetite (Fe304), and minor amoupts of pyrrhotite (Fel.,S) and pyrite. At 600°C, 650°C and 700°C the main constituents are anhydrite, oldhamite, and hematite. At 750°C, 800°C, and 850°C anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides, calcium sulfite, hematite, and minor oldhamite, magnetite, and pyrrhotite. At 650°C 700°C 750°C and 800°C, anhydrite, oldhamite, arsenic sulfides, and hematite are present. At 850°C, the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CLM) in the determination of the calcium-sulfur- oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RLM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1993

The Boddington Gold Mine orebody is a large tonnage, low grade gold deposit located within the Archaean Saddleback greenstone belt within the south-western region of Western Australia. The orebody consists of laterite caprock (30 per cent) and clays (70 per cent) produced by lateritisation of felsic volcanics and intrusives. The caprock comprises gravel, hardcap and B-zone which have a specific gravity of 1.8, 2.4 and 1.8 respectively. The clay has a specific gravity of 1.5.

Jan 1, 1993

By Mario Coderre, Andre Pinsonnault, Francois Lefebvre, Pierre Groleau, Yves Newman, Christian Pouliot

"This paper describes the blasting methods used to excavate the tailrace channel at theLaforge hydroelectric plant. It also shows the importance and versatility of the dopedemulsion explosives used in this project."

Jan 1, 1993

By B. M. McKay

The Walnut Creek Mine was developed in 1989 to supply lignite to the Texas-New Mexico Power TNP-ONE power plant. Being new, we had the opportunity to start from scratch and rethink many of the traditional methods of managing a mine operation. We had the opportunity to create a team environment, encouraging people to get involved and make decisions. The founding philosophy of the mine, "A Quality Product by Quality People", acknowledged that the key to a productive, quality operation was the people. This paper will explore methods employed by Walnut Creek in selection of team members, building the team and the relative success of these methods.

Jan 1, 1993

By G. E. Agar

"The distribution of gold in the grinding-classification circuit of an operating gold plant was determined by assaying the size fractions of samples from each of the streams. This analysis identified the streams with the maximum potential for gravity recovery of gold and revealed that there was up 110 seventy-five times as much gold in the primary cyclone underflow as in the concentrator feed.Laboratory jigging and tabling tests were done on samples from two of the streams to determine what the recovery might be with a gravity circuit and to show that a high grade concentrate could be produced. A numerical simulation procedure was used to calculate a material balance for a circuit that included gravity separation on the primary cyclone underflow. The numerical simulation optimistically indicated that as much as 84% of the gold might be recovered in a reasonable grade of concentrate even though the recovery in batch bench scale tests was only 14%.Incorporation of a gravity separation device would reduce the inventory of gold in the grinding-classification circuit.INTRODUCTIONMany gold concentrating plants include a gravity concentration operation while others do not and the reasons that some do and some do not is not clear. Some of the advantages and disadvantages of gravity circuits are discussed by Penman (Penman 1987) without clear cut resolution. Penman's comments elicited an interesting response from Lloyd (1989) who produced a simple way to determine if the addition of a gravity concentration circuit would enhance the recovery of gold. Lloyd's method does not consider the cost of running the circuit so it only partially answers the question. There are reports in the literature (Wells and Patel 1991, Matwijenko 1988) that as much as 60% of the entire production comes from a gravity circuit when it is used, and that the grade of the concentrate produced often exceeds 65% gold, an assay that far exceeds most Merrill-Crowe precipitates that are sent to refining. In at least one instance (Hood 1984) a range of recovery from 40-50% was indicated from laboratory test work and the plant subsequently realized recoveries in the range of 26-40%. Despite these favorable numbers other plants use gravity separation when as little as 20% of the gold is recovered in the gravity concentrate (Carter 1992)."

Jan 1, 1993

By F. Shaw, E. C. Chemaly, A. F. S. Schoukens

Steel-plant dusts are hazardous waste materials, containing toxic constituents such as lead, cadmium, and hexavalent chromium. These dusts can be treated by a number of thermal processes, which are described as used in Western Europe and the USA. A detailed description is then given of the thermal Enviroplas process, which as developed at Mintek and produces disposable slag and valuable byproducts such as ferroalloys containing chromium and nickel, and fumes high in zinc oxide.

Jan 1, 1993

By Charles L. Karr

Grinding is a necessary component in the processing of a number of minerals, and improvements in this area could provide substantial cost savings for the minerals industry. Optimizing the process of grinding, however, is a difficult task because there are multiple objectives; i.e., several aspects of the process are important including the fineness of the ground product, the energy consumed in the process, and the viscosity characteristics of the final slurry. Genetic algorithms (GAs) are search algorithms based on the mechanics of natural genetics and have been proven capable of solving multiple objective optimization problems. These robust search techniques are able to rapidly locate near-optimum solutions across a broad spectrum of very difficult optimization problems. In this paper, two varieties of GA are used to optimize a grinding process as it is described by a computer model: (1) a simple genetic algorithm (SGA) and (2) a micro genetic algorithm (MGA). The performance of these techniques is compared to the performance of a more conventional search technique, a simplex algorithm. Results indicate that the GAs are efficient, versatile, quite capable of improving the grinding process, and easily incorporated into the toolbox of today's process engineer.

Jan 1, 1993

By S. Rajendran

Much advance has been made in offshore hydrocarbon exploration and exploitation in India. But the same amount of success could not be achieved in the case of other offshore minerals which are amenable for mining. However, employing present technology, there should not be any difficulty in successful exploitation with minimum environmental hazards. A demonstration is provided by considering the conditions prevailing in the Kerala offshore (southwest coast of India) scenario of monazite, ilmenite, phosphatic mud and calcareous deposits. Mud banks are unique phenomenon of the Kerala coast during monsoon season. Acting as barriers to waves, mud banks protect portions of the beaches from being eroded and trap sediments from either side facilitating growth of adjacent beach. The easy minable possibilities of the phosphatic mud during non-monsoon season with less pollution hazards and dumping back the waste material after processing for phosphate at the breaker zones to reduce the erosional effects on the coast make the exploitation economic and ecofriendly unlike the benefication of the lowgrade phosphate ores on land on a comparatively larger area and subsequent crushing, transport and resulting pollution.

Jan 1, 1993

By Daniel Hodouin, Claude Bazin, Sami Makni

Computer systems, installed in mineral processing, are designed to accumulate massive amounts of real-time data. Frequently these data are only partially processed because of the lack of adequate methods and the limited accuracy of mineral processing sensors. Methods are proposed to estimate missing data and reconciliate sensor data on a real-time basis. They are based on dynamic extension of steady-state techniques such as the node imbalance minimization or the least-squares mass balance adjustment techniques. The methods are illustrated for simulated and actual flotation data. Their data upgrading ability could be used to improve process monitoring, control and optimization.

Jan 1, 1993

By D. A. Smith

The successful integration of overburden casting techniques into the mine production cycle can be an extremely cost effective use of explosives. The entire mining cycle revolves around the cast blasting and to be successful requires a great deal of planning and cooperation. Several operations of Cyprus Coal Company in the Appalachian coal fields have successfully integrated blast casting into their mine plan. This paper will detail the parameters and necessary controls to integrate an overburden casting program into a surface coal operation.

Jan 1, 1993

By G. A. Kosick, L. Kuehn

The design of an information management system (IMS) for a mineral processing plant requires prior consideration of many factors, which can be broadly categorized into two domains, process plant considerations and IMS considerations. The process plant considerations include: plant characteristics, management and personnel issues, existing organizational standards and policies, and the level of existing hardware and software systems. The IMS considerations include: system functionality, system sizing and desired performance, hardware components, software components, and system support issues. All of these aspects must be addressed in order to achieve a functionally successful and cost effective system. The purpose of this paper is to lay out these design issues and, in doing so, to provide process engineers with a guideline with which to tailor a system that is best suited to their specific application. The paper is completed by presenting an approach that has been used in two Canadian concentrators. Both of these plants have incorporated MillEX, a software system designed specifically as the central component of a mineral processing IMS.

Jan 1, 1993

By R. H. Sergent

The interest in using halogens for extracting precious metals from ores has increased due to changes In ore characteristics, environmental concerns and regulations. The rediscovery of halogen leaching capability has been the topic of these and other writers1-30. Much work has been done on the performance of bromine, chlorine and iodine5-29. Of these, bromine and chlorine look most promising. Iodine is quite expensive and sometimes forms an Insoluble film on a precious metal surface22,23. Little experimental work has been published on the relative performance of bromine versus chlorine. The Pourbaix diagrams for the halide leach system (see Fig. 1-4) Indicates a significant stability advantage for bromine In forming complex ions with gold. This should result In greater extraction of gold under similar leach conditions and Is evaluated In this work. The regeneration of halogen from a spent leech solution is a critical requirement for an environmentally acceptable halogen leach process. Bromide can be oxidized In-situ to bromine ~ adding chlorine or ozone2,31. Bromide like chloride can be oxidized In an electrochemical cell to produce halogen on demand 13,15,17. Bromine clearly offers a number of possible regeneration pathways. This work strives to compare the relative ability of chlorine and bromine to extract gold from partially and fully oxidized ores. A commercially pressure oxidized sample was evaluated under a number of experimental conditions. The autoclave feed ore from the same mill was also evaluated after complete oxidation In a laboratory autoclave.

Jan 1, 1993

Plenary Address Zinc is a trace element in all igneous rocks and its background geological occurrence roughly follows iron but at much lower concentration. Living matter reflects this abundance and zinc is an essential trace element for complex life forms. Thus, environmental issues include zinc deficiency in soils and/or water - and thus in local diets - and zinc toxicity evident in natural or modified ecosystems. Increased knowledge of the role of zinc in plant and animal metabolism emphasises the need to manage, within guidelines based on naturally occurring abundances, the concentrations of zinc in water, spils and in the food chain. Although recognition of the natural variability of zinc concentration provides some basis against which environmental protection standards might be set, the measure of environmental `pollution' is more commonly taken as the degree of change to natural, background levels, attributed to the particular land or water use activity. Environmental constraints on mining, processing and usages of zinc may have less to do with actual

Jan 1, 1993

By Charles L. Kimbell

For a study such as this, which summarizes and amalgamates much information collected, compiled, and utilized by the numerous U.S. Bureau of Mines country specialists and branch chiefs for inclusion in their country and regional reports that comprise the five other volumes of the international studies of the Minerals Yearbook, it is clearly impossible to cite all sources of information used in its presentation, but some recognition seems due. Generally speaking, this study and its related detailed studies on countries and areas would be much more difficult, if not impossible, without the efforts of the personnel of our counterpart agencies throughout the world. Information they collect, compile, and then publish, either in their own volumes or those of central statistical agencies in their countries, are the foundations on which this work rests. Thus, we must begin by expressing our appreciation to the multitude of persons employed by these agencies for their contributions.

Jan 1, 1993

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-9 (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 160' C for 1 h in a pressure vessel dissolved over 95 pct of the PGM from virgin catalysts and over 90 pct from used pellet catalysts. Over 85 pct of the PGM was dissolved from used monolith catalysts when a third leaching step was added. PGM concentrates as metallic powder containing over 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 250' C and used catalyst to 275" C for 1 h. The solution after heating contained primarily sodium carbonate from cyanide decomposition and less than 0.2 ppm total cyanide.

Jan 1, 1993

By Edita Vircíková, J. B. Hiskey, Ludovít Molnár, Peter Lech, B. J. Scheiner

This paper describes the results of a study of hydrometallurgical methods of producing sodium arsenate for the glass industry from arsenic oxide wastes occurring in carbon dioxide washing. This paper addresses the following aspects: theoretical assumptions for leaching arsenic and its oxides, experimental results of As(III) oxidation to As(V) in aqueous solutions, sodium arsenate crystallization (the system As2O5-Na2O-H2O), characteristics of the crystalline product, and pilot-plant tests using sodium arsenate in the glass industry.

Jan 1, 1993

By C. K. Skokan

Various geophysical tools have been tested over the last eight years to evaluate their usefulness in defining damaged rock zones in an underground facility at the WIPP site in New Mexico. These tools include direct current and frequency domain electrical methods and seismic tomography. The electrical measurements show a "drying rind" to exist around older excavations. Seismic tomography confirms that a rind of lower velocity has developed along walls. In combining these tools, a monitoring program has been proposed to observe long-term changes in bedded salt. Results from the monitoring of electrical data over a 2-year time period illustrate the applicability of the technique in an underground environment.

Jan 1, 1993

By T. Shibaraki

A new larger, more efficient and economical Mitsubishi furnace line at Naoshima was put into operation in May 1991. Naoshima Smelter had produced previously about 230,000 mtpy anode copper with two smelter lines, i.e., a conventional reverberatory furnace line and Mitsubishi furnace line, which had been shutdown at the same time of the start up of the new smelter. At the beginning of the operation, there were several initial problems at the area of off gas trains and feeding system. By overcoming them now the process has been continuing satisfactory operation at the design rate. The paper describes about the design concepts and the actual operation of the new smelter.

Jan 1, 1993

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

Abstract -The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the F1avrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has yielded 2.75 M tonnes of ore grading 30Jo Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of F1avrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993

By Darrell E. Young

This presentation will define what talc is, how it is mined and processed, and how talc is used in the paper industry. It will also give you some idea about who Luzenac America is and from where it came. Luzenac America was formed in July, 1992 as a result of the acquisition of the talc assets of Cyprus Minerals by RTZ of the United Kingdom. Cyprus Industrial Minerals was then merged with the other RTZ talc interests under the Luzenac name. Luzenac is a town in the Pyrenees of Southern France -and the home of Talc de Luzenac, RTZ's first talc acquisition. The Luzenac Group is the largest talc producer in the world.

Jan 1, 1993