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By N. Edmonson

Apart from its role as an essential input to a wide array of agricultural chemicals and industrial processes, sulfur is interesting in that its supply involves competition between primary product and by-product. This general production structure is found repeatedly among markets for metals and other industrial minerals, and research results from the sulfur market potentially carry over to other markets with similar structures. The purpose of this paper is to present an analysis of the recent and prospective market for sulfur. The analysis will rely heavily on simulation using a comprehensive model of the North American sulfur market developed by the author. A brief description of the model is offered by way of introduction

Jan 1, 1993

By Patrick R. Taylor

Thermal plasma technology has a wide range of applications in extractive and process metallurgy. Beneficiation of complex ores, oxide reduction, melting/remelting of refractory metals and scrap, and the recovery of precious metals from waste products are some examples of potential uses for plasma technology. The highly concentrated enthalpy provided by plasma torches is a cleaner energy source and may give higher processing rates per reactor volume than conventional technologies. Some of the other advantages may be: controlled furnace atmosphere, ability to treat fine feed materials and rapid quenching. A review of some of the uses for plasma processing in non-ferrous process and extractive metallurgy is presented.

Jan 1, 1993

By P. Felix

A discussion on the need of visualization and animation tools in modelling solidification processes is made. An outline of an approach for the production of a video computer animation is provided. A number of examples including, 2 and 3 dimensional melting, filling, and macrosegregation are presented.

Jan 1, 1993

By Nielen van der Merwe

Mr Janisch' s comment' in the August issue on Dick Stacey's remarks about safety factors indeed requires wider debate. The example he quoted to illustrate the successful application of the safety factor concept in coal mining, namely the Salamon formula, is to my knowledge the only recognized application of that concept. Not only that, but that particular formula should be used only for what it was intended, namely to prevent major disasters. It was never intended to indicate long-term pillar stability, and it should not be used for that.

Jan 1, 1993

By C. Díaz

Roast-reduction smelting (RRS) of nickel concentrate, combined with flash smelting of copper concentrate, was one of the process options that Inco considered as a means of meeting its 1994 sulfur dioxide abatement target at its Copper Cliff operations. RRS involves deep roasting the nickel concentrate in fluid bed roasters. The roaster off-gas is heated in a sulfuric acid plant, and the low sulfur calcine is reduction smelted with coke in an electric furnace to yield a sulfur-deficient matte. The latter material is converted to Bessemer matte in Peirce-Smith converters, with minimal evolution of sulfur dioxide, and the converter slag is reverted to the electric furnace. Excellent nickel and cobalt recoveries are obtained. This paper discusses the development of RRS, including extensive commercial scale testing at Inco's Thompson Smelter, and its key operating parameters.

Jan 1, 1993

By M. W. Chanda

This paper presents the development of a rock-creep measuring apparatus using air as the initial pressure source. Servo-controlled machines can and have been used for time-dependent property tests. However, the long-term nature of some tests makes essential the complete independence of stress-maintaining equipment from main power sources or continuously running hydraulic pumps. The main objective of this paper is the development of a creep testing machine that is free from interference arising through power supply interruptions or mechanical maintenance normally associated with many compression testing machines. To achieve this, a compressed-air power source was used to drive a compression ram. A few trial results obtained and analyzed using the transient creep law are in reasonable agreement with the general creep law.

Jan 1, 1993

By D. A. Peterson

A research program is currently in progress at the University of British Columbia to determine the potential of composite cable bolt reinforcement in Canadian mines. Several prototypes of glass fibre cable bolts have been tested. Their evaluation consisted of lab testing at the University of British Columbia, United States Bureau of Mines (Spokane) and trial installations at Detour Lake, Winston Lake, and Myra Falls Mines. A market analysis of cable bolts within the Canadian mining industry has been completed. Fibre reinforced polymer composites have a high potential as cable bolt reinforcement in mining applications. They prove to be a viable alternative to steel cable bolting.

Jan 1, 1993

By P. E. Lenz

In Nevada, large deposits of diatomite were formed during the Miocene / Pliocene in deep, alkaline lakes. Associated sediments are predominately fine-grained lacustrine with varying fluvial-clastic layers. Tephra layers are common, and probably served as a source of soluble silica for the extensive diatom colonies. Four companies are currently producing diatomite from Nevada deposits. Nevada ranks second to California in annual domestic production. Nevada diatomite is used in filter aids, fillers, absorbents, catalyst supports, and many other products. Economics and mineral reserves indicate that diatomite production in Nevada will be significant well into the next century.

Jan 1, 1993

By Quast K. B

The effects of metal ion addition rates and contact time on the activation of synthetic sphalerite using copper, cadmium and silver ions were determined in order to investigate the exchange characteristics at the mineral surface. The stoichiometry of the adsorption indicated that the activation of sphalerite involved both a simple ion exchange and redox process in which the activating ion and oxygen were reduced, and the mixed-sulphide surface was oxidised to produce elemental sulphur and a metal-deficient sulphide surface. Unactivated sphalerite was shown to be relatively hydrophilic, with recoveries usually less than 20 per cent for a five-minute float. Activated sphalerite could be readily floated without the use of a conventional collector. This inherent flotability of the activated sphalerite had previously been associated with the formation of a metal-deficient sulphide layer; however, this study emphasizses the significance of the surface oxidation processes occurring.

Jan 1, 1993

By Fathi Habashi

In the past five years Cuba has been attempting to more than double its nickel production by constructing two new ammonia leaching plants. No metals are yet produced on commercial scale but a variety of oxides and sulfides. This report updates the Cuban nickel industry as a result of two visits : one at the invitation of the Cuban Ministry of Basic Industries in 1987 and the other as a consultant to the United Nations for the Cuban Laterite Project in 1989.

Jan 1, 1993

By Peter S. Schneidkraut

This paper will discuss the Final Tunnel Linings which were placed in 6700m of a 2.32m inside diameter precast concrete lined interceptor sewer tunnel in Staten Island, New York. Two methods were employed to install the final tunnel linings. One method involved forming and placing a polypropylene fiber reinforced concrete cunnette invert, followed by an arch pour. The second method involved the jacking of reinforced concrete pipe into the tunnel, followed by a low density cellular concrete backfill grout. These two methods will be described and compared.

Jan 1, 1993

By G. D. Hood

The U.S. Bureau of Mines investigated rapid froth flotation through more efficient bubble-particle collisions that improved the overall flotation kinetics. An in-line static mixer efficiently mixed the bubbles, water, and ore, selectively attaching these bubbles to the hydrophobic mineral's surface. As the mixture entered the flotation chamber, the hydrophobic mineral was already attached to the bubbles and was quickly floated away from the remaining ore pulp. The rapid flotation system was evaluated for beneficiation with a western porphyry copper ore containing 0.67 pct copper, and a phosphate-bearing amine flotation tailings sample containing 9.5 pct P2O5 in a quartz matrix. Over 88 pct of the copper was recovered from the ore in a rougher concentrate containing 5.9 pct copper at a rate 7 times faster than conventional flotation. Sixty percent of the quartz in the phosphate-bearing sample was floated at a rate 4 times faster than conventional flotation. The unfloated product retained 80 pct of the phosphate in a l6.9-pct P2O5 concentrate.

Jan 1, 1993

By Peter Cain

The Phalen Colliery in the Sydney Coalfield is extracting the 2.6 m thick Phalen Seam by the panel and pillar longwall retreat method. Abandoned workings occur in the Harbour Seam 140 m above and overlie the Phalen Colliery. Parts of these workings are flooded, and pose a number of questions relating to the safety of operations in the Phalen Colliery. In order to answer some of these questions, the Cape Breton Development Corporation re-entered an abandoned non-flooded roadway in the Harbour Seam directly above a retreat panel in the Phalen Seam to allow the deployment of instrumentation to monitor interaction effects. Fifteen monitoring sites, each 4.5 m apart, were installed in the 5 East Top Level after it had been re-entered and made safe. Each monitoring station included a vibrating wire strain gauge piezometer and a potentiometric extensometer. The piezometers were attached to rock bolts anchored into the floor and were connected by a flexible standpipe to a constant head apparatus. Variations in hydraulic head due to subsidence were monitored to determine subsidence. The extensometer units were mounted on rock bolts anchored into the floor of the roadway beneath the ribside and monitored ground strains. The instrumentation was capable of remote reading in the event that access to the site was restricted after installation. This paper describes the instrumentation, the installation programme, and some preliminary results.

Jan 1, 1993

By Best R. J, Poulos H. G

The method for design of primary roof support for the large todoidal cavern constructed to house the Sydney Opera House parking station is presented. The cavern was constructed with 5 m of rock cover beneath Sydney's Royal Botanic Gardens. Design of rock reinfonnent using a combination of fully grouted rock dowels and Macalloy bars was based on control of horizontal shear movement along bedding features in the roof. A combination of linear arch type analyses and non-linear jointed finite element analyses were used in the design study together with an analysis of the shear resistance offered by fully grouted bolts under shear deformation.

Jan 1, 1993

By Y. B. He

The effect of the stability and rheological properties of magnetite dense medium on the separation performance of a 6" dense medium cyclone (DMC) is studied with the use of fine density tracers. The tests in which different size fractions of magnetite are used to prepare the dense media reveal that at low medium densities (<1.5 s.g.), the best separation is achieved when using the magnetite with intermediate particle sizes (du3.2=18 11m). At medium densities above 1.5 s.g., however, it is beneficial to use coarser magnetite. With the fine magnetite dense medium, an increase in medium density results in a decrease in separation efficiency. With the coarse magnetite, an opposite trend is observed; the separation efficiency is improved with increasing medium density. An accurate cutpoint control is critical in gravity separation. The cutpoint shift for coarse feed particles is found to decrease with increasing medium stability (density). It assumes values close to zero in a highly stable fine dense medium. When the size of the treated particles is small (<0.5 mm), the cutpoint shift is mainly determined by medium rheology. With increasing medium density, a continuous increase in cutpoint shift is observed.

Jan 1, 1993

By P. K. Songfack

The transport of slurry within the ball mill depends on the peripheral velocity and porosity of the ball charge. Residence time distribution and mill hold up are of-ten used as indicators of the mode of transport. In this work, the transport problem is tackled via direct simulation of the three dimensional motion of the ball charge. In doing so, the following quantities are calculated: (i) ball size distribution as a function of the distance from the feed end of the mill (ii) mean peripheral and longitudinal velocity and longitudinal velocity of balls of different sizes, and (iii) the spatial distribution of porosity within the ball charge. Hence, the problem of transport is handled as a motion of part of the slurry with the ball charge and part as hydrodynamic flow through the porous structure.

Jan 1, 1993

By Y. Guan

The dissolution behavior of silver and copper from silver/copper alloys in ammoniacal solutions has been investigated using a rotating disc. Oxygen was used as an oxidant. The effect of composition of alloys, concentration of lixiviants, stirring speed and temperature on the overall dissolution kinetics has been studied. Silver / copper alloys of three compositions were used in this study. The atomic percents of silver in these alloys were 76.9, 46.9 and 24.1. The results on the rate of dissolution obtained for these alloys have been compared with that of pure silver and copper under the same testing conditions. A particular emphasis has been given to the galvanic effect on the overall dissolution rates.

Jan 1, 1993

By Xuanxue Mo, Kaihui Yang

"Abstract- The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Barly Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry . The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affinities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental rnicroplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820Jo Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 g/t) and recoverable amounts of Au, Tl, Gd, Ga, Ge, In. A massive sulflde zone, in which lenticular and stratiform orebodies are localized in a sulflde-carbonate-silica shale unit or sulfldic tufflte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulflde zone developed in a subvolcanic intrusion or volcanic sequence. The sulfide mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite- chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerais occur rarely in the massive ores. The massive ores are generally fine-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and dis­ placement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two dis­ tinctive alteration zones have been identified: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, trema­ lite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive mode! of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By Kerry Spickelmier

With the dissolution of the former USSR and a welcoming of foreign, minerals expertise by a host of developing countries, a "new," more international, world of minerals is open to the mining industry. However, even in the new frontier, the old laws of nature still apply. For those attendees of the 98th annual Northwest Mining convention, the adage "survival of the fittest" commanded particular attention. Miners, engineers, geologists and other unique species traveled to Spokane in December to learn of adaptations they can make to assure, or at least prolong, their place in the mineral industry&apos;s land of the living. You have heard the tales of the spotted owl and the desert tortoise, but add to this endangered list the North American mining industry. During a session on international investment criteria, D. Silver of Balfour Holdings (Littleton, CO) blamed excessive environmental regulation, 1872 Mining Law revision and the anti-mining-and-business attitude of our government for migrations from and extinctions within the domestic mining population. "We&apos;ve been on a death curve for some time," Silver said, "with a lower birth rate and a higher death rate. In the last four years, we&apos;ve lost 60% of the gold producers in North America, and we&apos;re down to 110 companies. The entire industry has lost about 400 companies and is now down to 2800." Unreasonable regulation founded on emotion rather than scientific fact has been the chief cause of death, according to many of the convention speakers. B.J. Kennedy, president and chief operating officer of FMC Gold (Reno, NV), emphasized, "We have accepted a regulatory environment - but we oppose being strangled to death by unreasonable regulations."

Jan 1, 1993

By Deno M. Pappas

The purpose of this U.S. Bureau of Mines study was to determine the material stiffness properties of the gob for use in numerical models of rock mass response to longwall mining. Photographs of actual mine gob were used to approximate particle size gradations of gob material. The gradation curve was shifted down to a laboratory scale, and 20 uniaxial compression tests were conducted on simulated gob material from 3 different rock types. The study found that the nonlinear stress-strain curves obtained from the three materials were similar, and could be represented in terms of moduli as follows: Es = 2.36s + 1,360 (1) Et = 0.00181s2 + 9.33s + 294 (2) where Es = secant modulus, psi Et = tangent modulus, psi and, s = stress level (due to overburden), psi. These curves correlated well with the theoretical solution curves developed by Salamon. Other effects on gob behavior were attributable to these studied factors including void ratio, thickness-to-width shape ratio, and rock compressive strength. The generated equations should provide numerical modelers with a practical means of estimating gob modulus as a function of stress level.

Jan 1, 1993