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By Ryan CG, Ramsden AR, Sie SH, French DH, Griffin WL

Proton microprobe and electron microprobe analysis are being used in combination for in situ determination of the trace element contents of oxide, sulphide and silicate minerals in a sample of the Merensky Reef. Initial results indicate that chromites contain only Ni, Zn, Ga, Zr ar d Nb. Platinum-group elements, if present, are at concentrations less than 2 to 6ppm. Ru, Rh and Pd are the only platinum group elements to be consistently detected in the sulphides. PentLindite is the most important host for these elements with the concentration of these elements being dependant upon the mineral association in which it occurs

Jan 1, 1989

By David R. Quigley, Patrick R. Dugan

First reports of microbial coal solubilization appeared in the early 1980's (Fakoussa, 1981; Fakoussa and Truper, 1983; Cohen and Gabriele, 1982). These degradations, which occurred at ambient temperature and pressure, resulted in a dark brown to black viscous liquid and required days to weeks to occur. Rates and degrees of coal biodegradation varied from coal to coal. Hard coals were not extensively degraded (5-7%) while low-rank coals such as Leonardite, a sublignite, were completely solubilized. A correlation between degree of weathering or oxidation of coal and the coals susceptibility to biological attack was observed. This led to oxidative pretreatments as a method to enhance microbial degradation of coal (Strandberg and Lewis, 1986). Products of microbial degradation of coal are water soluble solids that do not have significant solubilities in organic solvents (Wilson, et. al., 1987; Quigley, et. al., 1987; Quigley, et. al., 1988a). Solutions of solubilized coal did not separate or form precipitates which suggested that they were true solutions and not colloidal suspensions. Biosolubilized coal contained more oxygen than starting material suggesting that microbial attack of coals involved oxidative cleavage of carbon-carbon bonds. This small change in oxygen content was the only change observed in coal structure during the biosolubilization process. Many coal solubilizing microorganisms have been isolated. Some are lignin degrading organisms such as Phanerochaete chrysosporium and various Streptomyces species (Gupta, et. al., 1988; Wilson, et. al., 1987). This was not unexpected since the structures of lignin and low-rank coals are similar. These organisms produce an enzyme complex, ligninase, that utilizes hydrogen peroxide to oxidatively cleave the bond between a and ß carbons of an aliphatic chain bound to an aromatic nucleus. Another important organism is Trametes versacolor (syn. Coriolus versacolor, Polyporus versacolor). Even though this organism produces a ligninase (Dodson, et.al., 1987), coal solubilization has been attributed to the enzyme laccase (Pyne, et. al., 1987). Laccase utilizes molecular oxygen to oxidatively cleave a - ß bonds using a mechanism similar to that observed for ligninases (Kawai, et. al., 1988). Other coal solubilizing microorganisms have been isolated from coal outcrops (Ward, 1985; Ward, 1988), but enzyme activities responsible for coal solubilization have not been identified. Research at the Idaho National Engineering Laboratory has focused on those mechanisms involved in coal biosolubilization. An

Jan 1, 1989

By Collins D. N

The Olympic Dam Copper Smelter Acid Plant is a hybrid plant capable of producing sulphuric acid from either sulphur burning, metallurgical gases or a combination of both. Commissioning of the Acid Plant on sulphur burning commenced in early April 1988 and commissioning on combined sulphur burning and metallurgical gas commenced in August 1988. During commissioning on sulphur burning a number of acid spills occurred due to balancing of tower flows and control of acid dilution. A number of other significant problems were encountered including failure of boiler gaskets, failure of strong acid pumps seals, the fracture of the teflon dilution water injector and the subsequent failing of the acid circulation pump, tank steel failures and various instrumentation problems. The Commissioning of the Acid Plant on metallurgical gases commenced in August and with the exception of the production of oleum in the boiler economizer was relatively trouble free. Oxygen Plant commissioning commenced in May 1988 and was without significant incident. An outline of the basic equipment for the Acid Plant and Oxygen Plant is presented together with aspects associated with the commisisoning of both plants.

Jan 1, 1989

By R. C. Freas

Imported products and materials have been in the news over the last several years in a wide variety of industries. Certainly the mining and industrial minerals industry has not been exempt from this. Cement imports have received considerable attention in the press and a number of written articles. We are also seeing imported aggregates particularly along the gulf coast and east coast of the United states. We are now hearing increasing talk of bringing high brightness calcium carbonate from offshore sources into the U.s. domestic markets. This paper takes a look at the location of these sources, factors affecting their acceptance by U.S. industry and presents a general cost comparison of offshore and domestic calcium carbonate. In addition, the market response of U.S. suppliers and the impact of imports is also discussed.

Jan 1, 1989

Answers to the questions "which rocks contain diamonds?" and "which indicator minerals should diamond explorers look for?" are no longer so easily obtained, now that diamonds are known to occur in lamproites and various types of lamprophyres, as well as their traditional source of kimberlites. One way of isolating those factors (host-rock"geochemistry, geographical or tectonic location, xenolith minerals, etc.) which are most critical in determining the diamond potential of a given pipe, is a detailed and critical re-examination of the huge volumes of accumulated data on kimberlites, lamproites and related rocks. A large analytical database to this end has been set up on an Apple Macintosh II microcomputer using the quasi-relational database management system 4th Dimension. Currently, it contains data for up to 90 major and trace elements, isotopic ratios and contained mineral compositions for some 4,000 rock specimens from all over the world. Many experiences in setting up this database are probably relevant to other geologists setting up their own systems: they include determining the relationships between data items; the advantages of codes over free text in representing categorical variables such as rock types; the need for rigorous error trapping and data validation; and the problem of missing data values and ambiguities thereof. The working system is now being used in a rigorous statistical assessment of the criteria which distinguish diamondiferous from non-diamondiferous rocks.

Jan 1, 1989

By Eric Johnson

"IntroductionHistoricalCyanidation is a leaching process, in world-wide use, to extract gold (and silver) from ores and concentrates. The process has many inherent advantages on account of its adaptability:a. to any scale of operation;b. to a wide range of ore types and mineral associations;c. to a wide range of physical characteristics of the gold particle size, alloy (electrum) or mineral (telluride);d. to relatively simple plant controls and operating procedures;e. to simple marketing procedures and quick cash return.The basic idea for cyanidation was first described and patented by a German chemist, L. Elsner, in 1846. Some forty years later, J.S. McArthur, a metallurgical chemist and R.W. and W. Forrest, medical doctors, all of Glasgow, Scotland, came to realize the import of the discovery and accordingly, registered patents in Great Britain in 1887 and in the United States in 1889. The keystone of the McArthur-Forrest patent registration was the use of weak (0.05o/o) instead of strong (1.0%) solution.The years 1890-1910 saw much progress in equipment design and the advance from batch to continuous processing to increase efficiency and reduce operating costs.In later years, technological progress followed advances in materials of construction and control systems. Current innovations include large-scale equipment, high-capacity thickeners, belt type filters and Steller, candle-type filters for plants using zinc dust precipitation. As well, environmental protection is increasingly a major concern.The technology of gold adsorption from cyanide solution onto activated carbon has made rapid strides in recent years. This has followed the initial efforts of Potter, Salisbury, Zadra and their colleagues of the U.S. Bureau of Mines Research Station in Salt Lake City, Utah, and the field work of Homestake Mining Company personnel, in Lead, South Dakota."

Jan 1, 1989

By Davies S. G, Mackey L. C

The oxidation of iron and nickel sulphide concentrates, and the dominant sulphide minerals which comprise them, has been studied under ignition conditions using thermogravimetry (fG). The concentrates were derived from various minesites and they showed differing tendencies to ignite. Ignition temperatures ranged from 416 to 488°C and the extents of reaction, measured at 500°C, varied from 64 to 88 percent. The reactivity of the least reactivematerial was improved significantly by grinding. Particles <63/lm showed 85 percent oxidation compared with 55 - 65 percent for particles >63/lm.Examination of the individual sulphide minerals revealed that these materials also have significantly different degrees ofreactivity and are subject to particle size effects. For particles <45/lm, the ignition temperatures were as follows:ò pyrite and violarite 380 - 385°C; pentlandite 425 - 430°C; and pyrrhotite 470 - 475°;ò for particles >90 /lm, the ignition values were: pyrite 395 - 400°C;ò violarite 430 - 435°C; pyrrhotite 540 - 545°C; and pentlandite 560 - 565°C.Using the data on the individual minerals it was possible to rationalise the differing degrees of reactivity of the concentrates. The role of the most reactive constituent in initiating the ignition reaction has also been discussed.Finally, the results of this work were found to compare. favourably with the behaviour ofthe concentrates in industrial and pilot-scale flash smelters.

Jan 1, 1989

By Giuseppe Bonifazi

This study examines the problems involved with the control of characteristics of the products resulting from comminution operations. A methodology of investigation based on texture analysis procedures by image processing techniques of the comminution product is proposed. Some examples of applications are considered with particular reference to comminution products of different textural, structural and mechanical characteristics. The advantages and the limites of this method of approach are, indicated, both as regards performance of the investigations and subsequent processing of results.

Jan 1, 1989

By Frederik P. Agterberg

Mineral exploration consists of the acquisition of data and their interpretation to ascertain the presence or absence of uncertain events. In general, the amount of uncertainty decreases during exploration when targets become increasingly well defined. Decisions on further exploration and whether or not mining should be commenced are based on new information using both objective facts and subjective reasoning. Computers play an important role during all stages of exploration. Three recent books (References 1-3) on decision-making in exploration and mineral-resources evaluation provide additional background supplementing the papers in this volume and articles in scientific journals or other conference proceedings (e.g., References 4 and 5) dealing with the subject. Other new developments to be considered are that microcomputers are becoming increasingly important in the earth sciences (Reference 6), and so are applications of artificial intelligence (Reference 7). Microcomputer- based technology allows rapid communication between field parties and main office. Expert systems are becoming increasingly sophisticated aids for mineral exploration an can now contain objective rules based on statistical theory (Reference 8).

Jan 1, 1989

Since the ecrly 1970's several factcrs have changed. In the East the larger tracts of coal mined with large eauipment are being dePleted, The cost of moving the larger equipment from small tract to small tract becomes eccnomicallv unattractive, Conseauently, the tracts are being mined with smal!er draglines or with loader/truck haulage combination, This has resulted in a major increase in the cost of moving a cubic yard of overburden,

Jan 1, 1989

The nature of the specialty glass and ceramic business magnifies the dependency of the ultimate product on the unique properties of their raw materials used to make them. This dependency has implications in the management of risk in the supply process which requires a special procurement organization and program commitment to be successful. The Coming system of managing critical materials and factors in development of alternate new suppliers and products is discussed.

Jan 1, 1989

By T. S. Golosinski

"This paper reviews the types of selective continuous miners (SCMs) available at present, and compares their main features. Furthermore, operating practices and mine planning aspects of the SCMs applications are reviewed and conditions for efficient application of this equipment are defined. Finally, the potential applications of the SCMs in surf ace mining of oil sands are discussed INTRODUCTIONIn the 1970s the United States Bureau of Mines (USBM) conducted a program of investigations, design and demonstration of various continuous surface mining concepts, This included continuous mining equipment which was an adaptation of several civil engineering and/or underground mining machinery concepts to surface mining. Upon termination of this program, the related development was continued by a number of equipment manufacturers, leading to development of several types of SCMs. This new type of surface mining equipment is able to mine selectively hard and thin multi-layered formations at high, sustained, and economically viable production rates.While used mostly in coal mining at present, the characteristic features of this equipment permit conclusion that it may prove to be an efficient tool for surface mining of oil sand, and/or related overburden stripping. Of particular interest here may be the ability to mine thin layers of hard material, without a need for its earlier fragmentation, and the ability of the SCMs to load a variety of haulage equipment, including belt conveyors."

Jan 1, 1989

By Kotaro Ohga, Kiyoshi Higuchi, Zhang Xun Tao

In Japanese coal mines, drivage works of in-seam gate roads are mainly carried out by blasting methods. Changes of methane concentration in gate roads are recorded by centralized monitoring systems in general. To obtain useful information from the recorded data, authors analyzed changes of methane concentration for 3 hours after blastings. As a result, the changes of methane concentration with time can be divided into five distinct patterns. It is thought that appearance of the each pattern depends upon the geological conditions of the surrounding of the headings. Therefore, we attempted to confirm such observations by simulations using mathematical models.

Jan 1, 1989

The South African Institute for Mining and Metallurgy celebrated its 95th anniversary with a banquet at The Carlton on Friday, 2nd June, 1989. This event was attended by 600 people, including the Presidents of AS&TS, constituent societies, and other kindred bodies, together with members and their guests. The guest speaker was Mr Muray Hofmeyr, Chairman of the Johannesburg Consolidated Investment Company Limited, who gave an interesting and thought-provoking talk entitled 'Will we still be the best in the year 2001'

Jan 1, 1989

By A Tinnelly

Land disturbed by alluvial gold mining should be restored to a capability or productivity as good as that which existed prior to disturbance.   Effective rehabilitation requires detailed planning prior to mining and must also be closely integrated with the mining operations.   The main constituents of a rehabilitation plan: description of existing site conditions, choice of final land use, establishment of final landform, water management and erosion control, soil reconstruction, revegetation and management of rehabilitated land are briefly described.

Jan 1, 1989

By Surendra K. Mishra

Metallic and oily components are the major contaminants of industrial wastes. Underground burial and incineration have been the commonly practiced methods of waste management. To provide a relatively more permanent solution, different processes have been developed. In addition to reviewing these processes, potential of using flotation as a process to treat hazardous metal and oil contaminated wastes is discussed in this paper.

Jan 1, 1989

By P. Tsang

The mechanisms and functions of yield pillar are analyzed by employing finite element method that takes time dependent and plastic failure of rock into consideration. The design criteria for different geological conditions are discussed. The results provide further evidences that yield pillar design will improve floor or roof condition, especially when the floor and/or roof strata are weaker than the coal. Based on this study, the yield pillar size is determined for one cod1 mine located in southern West Virginia.

Jan 1, 1989

By James R. Craig

Petroleum coke is becoming an increasingly important source of light hydrocarbon products as product crudes become heavier and of poorer quality. The use of petroleum coke to generate synthesis gas results in the formation of residual slags that are enriched in silica, alumina, sulfides, oxides, and free metals. The characterization of these slags and their con? stituent phases is an essential step in considering the ultimate use or disposal of such slags and in understanding how to alter the properties of the slags to optimize the efficiency of gasifiers. Depending upon temperatures and bulk compositions, quenched slags typically consist of silicate glasses, calcium silicates, iron-nickel oxide-sulfide masses, aluminate spinels and free metals. Whereas the glasses contain relatively uniformly dispersed metals and sulfur, the iron-nickel oxide-sulfide masses highly concentrate nickel and sulfur. The aluminate spinels very effectively concentrate vanadium and chromium, thus depleting glasses or other adjacent phases. The abundance as well as the make up of the slags strongly affects the physical behavior of the slags within the gasifiers

Jan 1, 1989

By Jim Avraamides

The properties of activated carbon which are important for gold recovery applications include activity, capacity, wear resistance, particle size distribution and bulk density. There are experimental difficulties in attempting to simulate the plant environment in the laboratory in order to measure the above properties. However, standard tests can be set up to compare the characteristics of different carbons and to assist in monitoring the performance of carbon in CIP operations. These laboratory tests are critically evaluated and data are presented on the performance of carbon from a number of CIP plants.

Jan 1, 1989

By N. M. Cheimanoff

GEOCAD is an ambitious research program aimed at the development of a computer based system assisting the geologist and the production or planning engineer. BONANZA, its mining part, is a computer production scheduling tool (short to medium term) of particular relevance to complex orebodies. The principle is to simultaneously use a powerful information management system (CAD potentialities) and small expert modules integrating the exploitation context and the engineer's knowledge (Artificial Intelligence tecniques). As an illustration, a module of mineable block determination for underground exploitation is discussed.

Jan 1, 1989