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By P. Maraboutis

Iron removal by precipitation as jarosite from Fe-Ni-Co sulfate solutions, (synthetic or real, resulting from laterites leaching) has been investigated. Precipitation was carried out at 95 C, and at an initial pH 1.6, which was either kept constant with CaCO3 or Li2CO3 additions, or left to drift with the evolution of the reaction to lower values. The precipitation of K-, NH4- and Na- jarosite was initially examined using synthetic solutions. In all cases, hydronium ions were incorporated into the precipitate as well. Residual iron in solution was lower (0.2-1 g/1) and equilibrium was achieved faster (within 4-8 h) when precipitating K¬jarosite at constant pH, using CaCO3 for neutralization. Nickel and cobalt losses were small. Na- jarosite precipitation was also studied from real solutions with high initial iron content, under constant pH=1.5, controlled with CaCO3 additions, and it was shown that low residual iron concentration in solution (0.3-0.5 g/1) can be achieved again, with relatively small nickel and cobalt losses. The thickening and filtration characteristics of the precipitates were excellent in all cases examined.

Jan 1, 1988

By Mark S. Stagg, Stephen A. Rholl

The Bureau of Mines is studying blast delay timing influences on rock fragmentation in a series of tests that started in 3-ft concrete blocks, progressed to 45in-bench reduced-scale tests in massive dolomite, and has now included 22-ft-bench full-scale tests in a thin-to-thick horizontally bedded dolomite. This paper discusses the full-scale test results and how they compared to the concrete block and reduced-scale studies.

Jan 1, 1988

Jan 1, 1988

By J. D. Lowell

The gold content of prophyry copper deposits ranges from less than .05 gmt (ppm) to more than 1.0 got, and most deposits contain on the order of 0.05 gmt Au. Perhaps the highest grade mineralization which has been found in close proximity to a porphyry copper is the Ok Tedi Gold Cap orebody whose grade falls in the 2-3 gmt Au range.

Jan 1, 1988

By A. Davaliev, K. Hrkovic, V. Pavlovic

On the territory of Macedonia in South Yugoslavia primary and dory gold occurences were known since ancient times. Remnants of numerous goafs and remainders of washaries on river terraces and alluviums date right back to the times of Phillip II and his son Alexander of Macedonia and from Roman times, as well as from the Middle Ages witness exploitation of primary and secondary gold. More recent explorations on primary and secondary gold occurrences date from the period between two World Wars. Over that period a number of private companies, each on their own jointly, carried out gold exploration, particularly of alluvial occurrences on rivers emptying into River Vardar, starting from Skopje to the Greek frontier. The latest gold explorations carried out In the alluvium of River Konjska date back in 1976, and in 1978 old terraces of River Konjska were explored. The Visibility Study was prepared on possibilities of exploitation of gold from River Konjska alluvium. In the paper are collected the basic date an all known primary and secondary occurrences of gold, the results of the latest explorations, and the study itself. To-date geological explorations and analyses show very interesting potentionality of River Konjska and River Vardar alluvium, which proves continuing of he further explorations. For the moment, it is necessary to re-explore more complete view of the deposit. After that it will be possible to make complete techno-economical estimation of the auriferious alluviums and the conditions of the evaluations of the alluvial gold. 1. REVIEW OF PRIMARY AND SECONDARY GOLD DEPOSITS IN MAOEDONIA,YUGOSLAVIA 1.1. Primary deposits Scarse data are available for primary gold deposits in Macedonia` being unadequate for clear

Jan 1, 1988

By J. C. Emerick

Preliminary investigations have shown that wetland-based treatment systems can be an effective and relatively inexpensive control strategy for mine drainage pollution in eastern coal mining regions. This strategy also has potential for western mining regions, although too few systems have been installed in the west to permit general evaluation of the concept for western climates. The construction of prototype systems is encouraged for some situations. Wet-land environments have the capability of removing metals by natural geochemical and biological processes, including precipitation, filtration, ion absorption, and biological uptake and accumulation. Data presented for natural wetlands receiving mine drainage show removal of iron and other metals, and high accumulation of metals in soils and plants.

Jan 1, 1988

By M. Guana

Island Creek Corporation is predominately an underground mine operator deploying room-and-pillar and retreat longwall mining methods for extracting coal. Wide variations are encountered in overburden depth, stratigraphy, and insitu stress fields. This requires major adjustments in mine design among mines and occasionally within a mine. Simple rock mechanics principles are utilized in mine design to optimize safety and productivity. Physical observations and micro deformation monitoring of roadways are the primary techniques employed. Pillars and artificial support systems are the primary design elements modified. The specific case histories reviewed in this paper include narrow panels with high extraction for conventionally mined rooms, pillar sizing for longwall gate entries at great depths, and bolt type selection for difficult ground conditions.

Jan 1, 1988

By Sinha DK

Coal Mining in India had been confined in the past primarily to two or three coalfields. Unscientific mining has led to huge degradation of land including massive subsidence of strata and disturbances of water tables to a wide extent. This has caused problems not only in flooding of mines from surface water but also in further planning of the surface drainage for current mining activities. Now, therefore, surface hydrology and land-use potentialities of the area have been endangered inflicting severe damage to the overall environment and ecology of the area. The paper Discusses certain investigative aspects of the problems highlighted as above in one of the coalfields, and encompasses mainly the following areas : 1) Quantitative estimation of the damage already done to the natural surface drainage system. For this purpose damage to topography and drainage for the last fifty years have been made out through the aerial photographs and topographic map sheets 2) Analysis and comparison of different states of such photographs are carried through to indicate the extent of damage to the hydrological conditions inducing undesirable changes in its land-use pattern. Based on the analysis, concrete suggestions are made to restore the water drainage system which will be most suitable for future mining in the area containing high grade coal. The design and planning of the drainage system is based on the total system approach including the cost benefit analysis as well as hydrological considerations.

Jan 1, 1988

By W. P. Tassie

"The location of Quintette Coal Limited's pit and geologic nature of the dedicated reserves combine to introduce a number of factors which can adversely affect waste dump stability. These factors include steep terrain, variable material type and particle size, and precipitation. This paper describes the solutions to related waste dump problems. A brief geotechnical review of the waste dumps is given and Quintette's operational strategies during periods of dump stability and instability are discussed. Despite best efforts, failures occasionally occur and discussion is included on Quintette's success at bringing failed dumps safely back into use. IntroductionQuintette Coal Limited (QCL) property is situated on the east slope of the Rocky Mountains near Tumbler Ridge, approximately 120 km southwest of Dawson Creek, British Columbia. This surface mine is located on mountainous terrain and is subject to climatic extremes of wind, precipitation and temperature.QCL has a current annual production of 4.75 million tonnes of metallurgical coal with a stripping ratio of 7: 1. This correctly implies the extraction of over 33 million bank cubic metres (BCM) of waste which is placed on numerous waste dumps at various locations adjacent to the pit.There are three active pits - Mesa, Wolverine, and Shikano (Fig. 1). Shikano is a newly developed pit located near the plant site. It is not subject to the unique dump management problems prevalent at the Mesa and Wolverine pits, therefore the Shikano waste dumps will not be discussed . The dumps for the Mesa and Wolverine pits, however, have been technically and operationally challenging since shortly after mining began in 1983. Their characteristics, associated site specifics and management, therefore, are the subject of this paper.Waste dump locations for the Mesa and Wolverine pits are shown in Figures 2 and 3 as is the relative waste distribution . Each sub-pit is connected to a principal waste dump in reasonable proximity and to an alternate dump should disposal of waste be necessary at that location. The waste dumps are constructed from the top elevations initially to coincide with subpit development. In the initial years (1-7) waste dump heights will be up to 250 m, then, as the mine matures (8-20 years), waste dump maximum heights will continuously decrease to coincide with lower bench elevations"

Jan 1, 1988

By Peter L. Sheehan, David A. Fawcett, Dennis C. Martin

"Smoky River Coal Limited has successfully completed a major program involving the pattern rock anchoring of a high, steeply dipping footwall slope. The slope dips at approximately 65 to 70 degrees to the north, is benched for the upper 200 feet, is supported with rock anchors for another 240feet, and is unsupported at the pit bottom. In addition to the height and steepness, several structural features including shears, rolls and stratigraphic pinch- outs complicate footwall stability.This paper presents an overview of the project with descriptions of the engineering geology and footwall design, anchor installation, instrumentation and monitoring and a cost summary.IntroductionSmoky River Coal's mines are located in the foothills of the Rocky Mountains near Grande Cache, Alberta, approximately 200 miles west of Edmonton. The Smoky River coal leases were initially developed in the late 1960s and, except for minor shutdowns, have been in continuous operation since 1969 producing a low volatile metallurgical coal, mainly for the export market. Initial coal production was from underground mines; sur face mining started in 1971, and a large surface mine, No.9 Mine, was opened in 1974. Since that time, a number of open pits have been mined within the No.9 Mine area. Surface mining is by conventional shovel-truck method s with the use of a backhoe for mining the narrow pit bottoms.Coal recovery is mainly from the No.4 seam, which has a typical unstructured thickness of 20 feet. The most attractive opportunities for open-pit mining exist in areas of over thickening of the coal seam in the hinge zones of synclines and anticlines and in dip-slope situations. The mining of the more structurally complex pits and steeply-dipping footwall slopes requires that consideration be given to footwall stability."

Jan 1, 1988

By Colin J. Douch

New Zealand has been a significant producer of gold for over a century. Total recorded production is over 850 tonnes. There were three major periods of production: the first and biggest was between 1860 and 1880, the second was between 1895 and 1920 and the third was between 1930 and 1945. After 1945 gold production fell continually until 1980 when the major upward adjustment in gold price led to renewed interest. There have been important new developments in each of the known gold-rich areas: Westland, Otago and Coromandel and exploration for gold in these areas and in previously unprospected regions has reached unprecedented levels. In Westland over 140 gold processing plants are each producing between two and six ounces a day from low-grade placers. A major gold dredging operation will soon be producing over a tonne of gold annually and other new dredges are proposed. There are still vast reserves of gold-bearing gravels in Westland and prospecting is continuing to reveal new resources. In the Reefton area there is renewed interest in gold-bearing quartz reefs which were the source of over a million ounces of gold between 1900 and 1951. New large opencast reserves are now defined.

Jan 1, 1988

By J. P. Sieverson

The Comprehensive Environmental Response, compensation, and Liability Act (CERCLA -commonly referred to as Superfund) was passed into law in December 1980 in the wake of such incidents as Love Canal and the Valley of the Drums. Superfund was originally perceived as a way of cleaning up spills of hazardous substances and/or cleaning up abandoned hazardous waste dumpsites. In February 1981, Michael Cook, EPA deputy assistant administrator for hazardous emergency response, called Superfund "a tremendously powerful law. It could revolutionize the way the environment is protected, but we certainly don't intend to realize the full potential of the law for some time." These words have proven prophetic for Asarco's East Helena Smelter.

Jan 1, 1988

By Donald R. Alvic

For electric utilities serving the aluminum smelter industry in the United States, sulfur oxide (SOx) abatement legislation could bring about increases in the costs of generating electricity. This paper documents the method and assumptions used in estimating these increases, and the contains the results of the estimation. 1.2 SMELTER INFORMATION The smelters used in this study were identified by the Bureau of Mines (BOM) and are listed in Table 1.1. Also included in Table 1.1 are the electric utilities that serve these smelters. Compliance costs were estimated for these utilities. Some of the utilities are unique in the way that the information is handled or in the way the utility is operated; these are discussed below. 1.2.1 Big Rivers and Associated Co-ops, Data for Big Rivers and Associated Co-ops were gathered by George Mason University (GMU) students for BON and are included in this study.

Jan 1, 1988

The crushing and concentration of ores, as Herbert Hoover commented in a footnote in De Re Metallica, stretches back at least 6000 years. During those years there have been continuing changes and improvements in mineral processing technology. It has expanded greatly in its ability to handle different types of minerals, and lower grade and more complex ores. Australia will be dependent on the mineral industry for the fore- seeable future and there will be continuing demands on the mill opera- tors to improve the technology with regard to efficiency, flexibility and costs. These demands will be met successfully in the future as they have been in the past. This Mill Operators' Conference is an important forum for assessing our present position and planning for the future.

Jan 1, 1988

By S. G. Axen

Design of wells for in-situ leaching is based on individual mining operation and ore deposit requirements. Major design considerations are well flowrate, depth, fluid composition, expected well life, mine operating plan and cost. A large variety of downhole equipment, materials of construction, contract services and methods of well completion and stimulation are available. A generalized design procedure which allows the engineer to optimize well design for a particular ISL application is described.

Jan 1, 1988

By X. Shi, V. Vallyathan, N. S. Dalai

"Using. ESR spin trapping methodology, evidence was obtained that fresh quartz dust in a cell-free aqueous medium generated hydroxyl - and possibly superoxide radicals. The hydroxyl radical generation potential decreases on storing of fresh quartz dust in ambient air and on the addition of either catalase, superoxide dismutase, desferoxamine, or DMSO. The role of quartz related radicals in the biochemical mechanism of acute silicosis is suggested from these findings.IntroductionThis report summarizes our electron spin resonance (ESR) detection of oxygenated radical formation by freshly crushed quartz particles in a cell-free aqueous medium, and its inihibition by radical scavengers. This study was undertaken with to elucidate the primary biochemical mechanism involved in the development of silicosis (Farber, 1983; Reiser and Last, 1979; Silicosis and Silicate Disease Committee, 1988). In particular the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still not well understood (Farber. 1983; Reiser and Last, 1979;). It is generally believed that the action of quartz particles on the cell membrane is the starting point of the silicotic process (Farber, 1983; Parazzi et al., 1968). Thus the surface characteristics of the quartz particles have been the subject of several recent studies (Bolls et al.. 1983; Dalai et al., 1986; Fubini et al., 1987). Recently, We reported that mechanical crushing of quartz under normal atmosphere generates free radicals which decay with time, and that these free radicals are associated with a higher cytotoxicity of fresh quartz dust as compared to aged dust from the same stock (Dalai et al., 1986; Vallyathan et al.. 1988). The formation of Si• and. SiO--type of radicals from quartz particles crushed under atmospheric conditions has also been reported by Fubini et al. (1987). In addition, Gulumian and van Wyk (1987) have reported that quartz particles react with hydrogen peroxide (H202) to generates hydroxyl radicals (•OH) and suggested that this process might contribute to quartz's pathogenicity. However, these authors did not report the effects of metal chelators, so it was not clear as to whether the detected -OH radicals simply resulted from the Fenton reaction involving exogenous metal ion contaminants. Earlier, Marasas and Harington (1960) reported that quartz particles could function as an oxidant in a number of in vitro oxidations, including the hydroxylation of proline and lysine. They postulated that silica dusts, on reacting with water, could release H2O2 which might have the potential to react with various biological constituents and thus cause tissue damage. In fact, Gabor and coworkers (Gabor and Anca, 1974; Gabor et al., 1975) suggested that the cytotoxicity of quartz particles might be associated with the generation of some 'factor or factors possessing the properties of a free radicals capable of promoting the peroxidative chain cleavage of polyunsaturated fatty acid moieties of the phospholipids in the cell membrane. More recently Weitzman and Graceffa (1984) reported that asbestos is able to catalyze the generation of • OH radicals from H2O2. Their later work indicated that lipid peroxidation may be one of the mechanism by which asbestos produces tissue injury (Weitzman and Weitberg, 1985). This is significant because • OH radicals are capable of causing peroxidation by abstracting hydrogen atoms from cell-membrane lipids and initiating lipid peroxidation in lysosomal membrane (Fong et al., 1973). In fact, the formation of oxygenated species in reactions involving quartz was suspected since Kolbanev et al. (1980) reported the detection of H2O2 in the reaction of fresh quartz particle with aqueous medium. The present work was thus undertaken to detect the anticipated formation of some oxygenated, radical species by reactions of quartz in a cell-free media and its inhibition by radical"

Jan 1, 1988

By U. M. Mutnti

In order to meet the stringent market requirements for high purity cobalt, ZCCM commissioned the VIR plant in December 1982. The plant comprises a 4.1 tonne/heat vacuum induction furnace with a rated annual capacity of 2,500 MT of barstock. In the VIR furnace, molten cobalt is held under vacuum at 1600°C resulting in the removal of more volatile impurity elements by distillation. Operations todate have demonstrated that Pb, Zn and Cd have good distillation rates in excess of 95%, leading to cobalt containing 1 ppm or less of the above elements. Removal of other impurities such as Se, Bi is about 65% with the finished product still assaying around 1 ppm of each of these elements. Vacuum refining of cobalt offers an economic route for producing higher grades of cobalt from the type of concentrates and treatment processes available within ZCCM. The consistency of VIR cobalt quality has been confirmed by ZCCM and some of its alloy customers.

Jan 1, 1988

By M. Rieber

In July 1985, as the U.S. copper industry contracted and the Mexican industry expanded, a trans border pollution agreement was signed which included smelter air pollution control in the "Gray Triangle": Cananea, Nacozari and Douglas. Since then the Douglas smelter has been closed, a year earlier than initially required; though its new smelter is operating, S02 collection and acid disposal at Nacozari is yet to come; and the Cananea smelter has been un-touched. Nacozari and Cananea copper mining have expanded while a reduced U.S. copper industry has rationalized to a point of fragile profitability. As a paradigm of U.S. copper competitiveness, this paper attempts to explain the differential fortunes of copper in the two countries, to project the future of the smelter agreement as a function of acid disposal, and to consider the consequences of the politicized application of smelter pollution control in Arizona.

Jan 1, 1988

By Trutwin W, Tracz J

The outbreak of open fires underground cause disturbances to the conditions of the mine ventilation process. Thermal and chemical effects due to fire create unsteady, transient states in airflow and the spread of combustion products in the mine ventilation network. Changes in airflow have an influence on the fire, constituting a sort of feed-back between the fire and the ventilation process. This paper deals with a numerical simulation method, which enables the determination of transients caused by fires. The mathematical model, of the simulation method considered, has been based upon a: simple model of combustion of fuel in the airway, unsteady exchange of heat between the fire, airflow and surrounding rocks, airflow in mine ventilation networks and the theory of heatflow in the rocks. Initial and boundary conditions allow the determination of a set of parameters describing the airflow, the propagation of combustion products, the tempera- ture of the fire and flow etc. due to the fire. The simulation method, facilitates a graphical presentation of the spread of combustion products throughout the network. The simulation method has been prepared for an IBM PC/AT Computer.

Jan 1, 1988

By G. J. Reid, D. H. Stewart

"A diversity of structures and rock types in the Aft on pit has resulted in the occurrence of several different types of wall failure. Delivery of ore to the mill has not been affected and safety has not been compromised thanks to effective remedial 1V0rk and to a system of structural mapping, back analyses of failures, groundwater monitoring, and simple movement monitoring. Remedial measures have included artificial support, dewatering (including vacuum-assisted drainage), flattening of slopes and temporary buttressing. This paper describes six different wall failures at Afton and highlights the features of each. Examples given include rates of movement, extent and direction of movement, and piezometric responses. The practical, low-cost monitoring system was sufficient in one case to allow the prediction of date of failure. IntroductionThe Afton copper deposit is located 13 km west of Karnloops, British Columbia and has been mined for nine years out o f an expected eleven-year life. Open pit mining has reached 700 feet below sur face and is designed to proceed to 970 feet below surface by the time the pit is completed. The excavation is in a structurally and lithologically complex environment. Inevitably, some wall failures have occurred but these have been limited to small, manageable failures which have not compromised production or safety. To handle the failures it has been necessary to understand their nature. Of prim e concern has been the rate s of movement, but displacement vectors and hydrology have been monitored as well. The monitoring system is based on EDM surveys and on wire extensometers and plates set across cracks. Water levels have been read in standpipe piezometers. At Afton the emphasis has been on simple, practical, and inexpensive monitoring and because rock type s and structures play such a major role in any failure, detailed geologic al mapping is carried out."

Jan 1, 1988