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By R. M. Rowe, A. K. Bhasin, D. Malhotra

Introduction Most primary molybdenite producers use a selective flotation process in which molybdenite is floated from the ore while other sulfide and nonsulfide gangue minerals are depressed in the same step. The process was developed at the Climax mill. Reagents used in the rougher flotation stage include vapor oil (collector), syntex (surfactant), pine oil (frother), and occasionally sodium cyanide and Nokes reagent (depressant). Rougher concentrate is upgraded by cleaner flotation to produce market-grade molybdenite concentrates. Reagents used in the cleaner flotation stage are Dowfroth 250, vapor oil, sodium cyanide, and Nokes reagent. The development of the flotation reagent scheme at Climax and the role of the reagents have been well described by Born et al. (1976) and Malhotra et al. (1976, 1977a, 1977b, 1977c, 1980). The hydrocarbon collector, vapor oil, accounts for approximately 50% of the total molybdenite flotation reagent cost. Because vapor oil sources are limited, and the cost of vapor oil has increased significantly over the last decade, several studies have been done to evaluate alternate oil-based collectors and/or blends of collectors that would produce similar metallurgical results at a reduced cost, or increase the overall molybdenite recovery at the same cost (Smit and Bhasin, 1983; Hahn, 1969; Smith and Bhappu, 1971). The approach taken in the present study was to evaluate alternate nonoil-based collectors and collector systems that are less expensive than vapor oil. A series of potential nonoil-based collector classes were identified and evaluated in the laboratory against the current collector system. The metallurgical performance of these collector classes was related to their chemical structures. The results of this study are discussed. Collector classes A survey of sulfide mineral collectors was performed with the objective of identifying and selecting potential collectors for molybdenite flotation. The available reagents were categorized into 10 general classes. Table 1 summarizes these collector classes, their chemical formulas, the manufacturers, and selected commercial collectors in each class that were evaluated in the present study. Experimental procedure A Climax ore sample, assaying 0.3% MoS2, 2.2% FeS2, 0.007% Cu, 0.003% Pb, and 0.03 oz per ton Ag, was used for this study. Standard laboratory rougher flotation test procedure involved grinding a 2-kg ore charge in a rod mill at 60% solids. Reagents were added to the rod mill including a collector, syntex (0.005 kg/t), pine oil (0.03 kg/t), lime (to adjust pH to 8), and sodium silicate (0.15 kg/t). The ground pulp was transferred to a 1000-g cell, and flotation was performed at 35% solids and 1800 rpm using a Denver D-1 flotation machine. Concentrate was collected for a flotation time of six minutes. The general approach used in the present study was to substitute the nonoil-based collectors at two to three different dosage levels (0.01 to 0.15 kg/t) for vapor oil in the bench-scale, open-circuit rougher flotation tests

Jan 1, 1987

By Sunil Jain, Jan M. Mutmansky

As coal mining evolves in this country, underground coal is being mined at greater depth and under more difficult conditions than in the past. At the same time, economic conditions make it necessary to mine more efficiently and economically. As a result, pressures on mining companies arise on two fronts and make the job of mining coal underground very difficult. Recent improvements that have been made in health, safety and productivity have come about primarily due to improvements in existing technology and better management of all the production resources. However, this trend can continue only so far and thus innovation will be needed to continue the improvement. This paper deals with a concept that, on the surface, appears to be more efficient in terms of the costs to provide ventilation. The resulting design is oriented toward increasing the ventilation efficiency through use of a unidirectional ventilation plan but it also promises to increase recovery and decrease the requirements for development entries. To analyze this ventilation concept, two mine layouts with a similar production schedule were planned in a hypothetical 1.83 m (6 ft) coal seam. The first alternative analyzed uses a traditional approach to ventilation with centrally located shafts and a bidirectional ventilation pattern. Using this system, it is necessary to use large-diameter shafts and a large number of main entries. Using the same assumptions on ventilation requirements, the second alternative utilizes unidirectional ventilation whenever possible, a smaller number of main entries and small-diameter blind-bored shafts in the bleeder areas. The comparative analysis is performed using PSU/TDMVS, a computer network analysis program that is capable of determining the ventilation power requirements at any time in the mine life and converting the costs to a present value. The economic analysis is then completed by including the shaft-sinking and entry-driving costs and the costs associated with the recovery of coal that are directly related to the change in the ventilation system. The results are summarized on a present-value basis.

Jan 1, 1987

By Thomas W. Martin

This chapter includes tables from 1984 that were not available in time for publication of the 1984 Minerals Yearbook, but does not include corresponding tables for 1985. The value of raw nonfuel minerals produced in the United States during 1985 was estimated at $23.2 billion, an increase of $0.07 billion over the value for 1984. This is the third consecutive year that the value has increased, and except for a decrease in 1982, the value for each year has increased since 1971, or 13 out of 14 years. However. while the value of industrial minerals production continued to grow, reflecting the growth of the domestic economy, the value of metal mine production decreased in 1985 by 6%. This drop was more than offset by a 3% increase in the value of industrial minerals production because the value of industrial minerals produced was more than three times larger than the value of metals. The decrease makes 1986 the third year in the past 5 years in which a drop in the value of metal mining production occurred in the United States where production continued to lag behind growing world production. Domestic production of such major commodities 88 aluminum, copper, iron ore, phosphate rock, and zinc continued to decline owing to a number of international and domestic factors. Gold continued to be the most active commodity in the domestic metal mining industry. Despite lower prices, gold output increased to 2.5 million troy ounces, a 19% increase over that of 1984. The estimated annual production capacity of new gold mines beginning production exceeded 1 million ounces.

Jan 1, 1987

By J. A. C. Diering

All underground openings are three-dimensional, and in many cases it is not valid to analyse two-dimensional sections. This has been a problem in the past owing to the magnitude and complexity of three-dimensional stress analysis. In this paper a three-dimensional boundary element approach, using non-conforming quadratic elements, which is specifically applicable to underground excavations, is described. In addition, the philosophy of application of stress analyses is discussed. Three case histories are presented to demonstrate the practical nature of the approach as a tool in solving mining problems.

Jan 1, 1987

By Benson CD

Increasing numbers of Australian gold companies are active in the United States, due to the great untapped gold potential, which is currently undervalued by traditional U.S. companies. The differences in technical, cultural and financial character between the two mining industries provide the Australian companies with a relatively unique blend of strengths (and weaknesses) that can be used to advantage in the U.S.

Jan 1, 1987

By Subhash Sethi

The WIPP (Waste Isolation Pilot Plant) Project near Carlsbad, New Mexico. is a research and development project sponsored by the U.S. Department of Energy, designed to demonstrate the safe disposal of radioactive waste. A mine (repository) is being developed 2150 feet below the surface in a thick salt bed, which will serve as the disposal medium. The underground ventilation system for the WIPP project was originally designed based on a fixed project scope. The design criteria and ventilation requirements were developed for the performance of various activities as then envisioned towards the achievement of this goal. However, in light of new information and actual site-specific experience at WIPP leading to a clearer definition of the scope-related programs and activities, it was realized that the existing ventilation system may need to be modified. A re-assessment of the ventilation requirements--based on the current status of the facility and a clearer definition of the scope of the experimental programs, waste storage methodology, mine developmental activities. and current equipment list--indicates a two- fold increase in underground airflows from 210,000 cubic feet per minute (cfm) to 425,000 cfm. Various options to provide the increased airflow to the underground facility were considered and analyzed. Based on the techno-economic analysis, safety and environ- mental considerations, and other conditions unique to a facility like WIPP, it was decided to construct a new shaft to serve as the primary fresh air intake, along with the installation of additional fans in parallel with the existing set up. Low cost and the ease with which the new design could be implemented and integrated into the existing ventilation system with minimum impact on current activities and projected schedules were the guiding factors in designing the shaft and related ventilation modifications.

Jan 1, 1987

By Manzoori AR

From a detailed combustion testing program and earlier experience with Leigh Creek coal, the Electricity Trust of South Australia (ETSA) gained a wide insight into the use of low rank coal fired boiler plant. This work is fundamental for the selection of boiler design parameters and other details which in turn determine the correct coal deposit selection for future power station development. In addition it gives boiler designers a good indication of the measures required to give reliable plant operation. Extrapolation from experience with existing plant, the designers main source of information, was not considered appropriate because of the lack of experience with similar coals. Brown coal beneficiation is also being assessed by ETSA in an attempt to improve the coal quality by the pretreatment of the raw coal prior to combustion in future coal.fired boilers. ETSA is also involved in the development of circulating fluid bed and gasification processes to determine whether these alternative processes are a more viable method of utilising the South Australian coals than pulverised fuel firing.

Jan 1, 1987

By Muir D

A review of the various methods of degrad- ing cyanide either from gold processing liquors or electroplating baths is presented with some discussion on their relative merits or problems. Whilst alkaline chlorination is common practice in many U.S. and Canadian plants it poses particular problems for certain plants. Alter- native methods include electrolysis, hydrolysis and air oxidation with activated carbon as catalyst which are also integral steps in the carbon-in-pulp process. A basic study of the degradation of cyanide ion has been carried out therefore to determine the effect of temperature, oxygen and carbon. It is shown that carbon is an excellent catalyst for degradation by air and likely to lead to higher losses of cyanide in a C.I.L. circuit. Degradation by hydrolysis is important at high temperatures and high pH such as employed in the Pressure Zadra or Anglo elution processes. Carbon catalysed degradation of cyanide by oxygen in effluent streams may be an environmentally acceptable alternative to conventional chlorine degradation.

Jan 1, 1987

By K. L. Riemer

The West Wits Line first began yielding gold in the mid-1930s and is among South Africa's leading gold-producing areas. Gold mining operations are carried out amidst the occurrence of seismic events which cause both damage to underground excavations and injury and loss of life to production personnel. The feasibility of establishing a system to minotor the seismicity on all the Gold Fields mines was investigated during the early 1980s. This led to the establishment of a centralized seismic network in 1981. The system was structured around three major objectives. It uses Perkin Elmer (now Concurrent Computer Corporation) 16 and 32 bit mini-computers. The hardware in use at both the central and remote sites is outlined, giving a good insight into the role of computers in the system. The system software reveals the fast flow of data through the network; it can be divided into three categories: (1) data logging and transmission - remote sites, (2) data capture and communications - central site, (3) applications and research - central site. Several examples are given which show how the system is measuring up to its objectives. These case studies also indicate how the computers are effective in representing the seismic data collected. It is concluded that the use of computers enables the pin-pointing of seismic events on the West Wits Line within about 3 -4 minutes of their occurrence. The choice of hardware is largely dependent on the objectives of system, and the Gold Fields Network has chosen mini-computers because of the speed of communication and the large amount of data and storage required for research applications.

Jan 1, 1987

By Sakai S, Suga S, Bisque RE

Soil gases were collected on activated charcoal, analyzed by computerized mass spectrometry and treated with multivariate statistical pattern recognition to determine the diagnostic geochemical signature associated with the Okuaizu Geothermal Field in Japan. From this a geothermal model was developed and compare to 175 "unknown" samples in a 250 m spaced grid over 30 1Qn2 mapping the areas with a matching geochemical character. Faults and fractures were generally located by the presence of high molecular weight components. Following the initial survey, the faults in two specific areas were precisely located by a second survey with samples at 10-30m spacing. Where earlier geochemical surveys had placed anomalies 1-2 Km northeast of the geothermal center, the fingerprint survey accurately mapped the system and detected several faulted zones. It was not misled by hot springs located away from the geothermal System.

Jan 1, 1987

An extensive railway construction prog- ram in the People's Republic of China has required the excavation of many tunnels in difficult ground, particularly in mountainous regions. Conclusions drawn from case histories permit guidelines to be formulated as to the optimum location of tunnel alignments in faulted and folded terrains, and also in karst regions. Geological factors adversely affecting durability of tunnel linings can be minimised by adoption of appropriate construc- tion practices.

Jan 1, 1987

By Edward L. McHugh

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 5-acre Zwagg Island Wilderness Study Area (OR-12-14) in order to evaluate its identified mineral resources. The study area is located in Curry County, OR, immediately west of Brookings. There is no evidence of mining activity on or near Zwagg Island, and no mineral resources were identified. The steep-sided, flat-topped island is normally accessible from the mainland by way of a sandy beach. The island consists mainly of marine sandstone, mudstone, and conglomerate of the Jurassic Dothan Formation. Dothan Formation sandstone has been used locally as construction material. Rock along the coast has also been used for construction of jetties to improve harbor access; additional work has been proposed at the port of Brookings. Although suitable for other construction uses, stone from Zwagg Island would probably not meet physical requirements for jetty stone. Development of a stone resource on the island is unlikely.

Jan 1, 1987

By Sterling J. Anderson

Through the use of nondestructive testing techniques, the Bureau of Mines is pursuing a goal of improving the efficiency of the rock excava-tion process. Toward this end, 44 laboratory tests were conducted to identify a practical method of monitoring fracture development in rock, as caused by an excavation tool. An acoustic emission CAE) transducer was used to monitor the test samples as they were loaded. The signal from this instrument was recorded in real time along with the radial and axial loads generated by the fracturing device. Through the review of these signals on a common-time base, it was possible to see the relationship between the developing fracture and the loading conditions. As a part of the posttesting investigations, samples that were pletely fractured were sawn and ground to expose the fractures. examination of these samples allowed approximations to be made incom-Visual of the total surface created. Surface area approximations were also made for the completely fractured samples. Quantitative analyses· of the AE signals were conducted for comparisons with the calculated surface areas.

Jan 1, 1987

By C. D. Thompson

Pile load test programs were carried out in 1984 and 1985 at Stelco's and Dofasco's Steel Making Plants in the Hamilton Bayfront area. 323.9 mm outside diameter by 9.5 mm wall thickness Grade 3 steel closed-end pipe piles were driven to practical refusal at depths of 21 to 30 m in very dense silt till with Delmag D30 open-end diesel hammers. Ultimate bearing capacities of up to 5330 kN were proved by dynamic monitoring and static load tests. Allowable bearing capacities of 1780 kN were achievable on production piles without undue difficulty. It was found that the impact stress at the top of the pile was controlled by the yield strength of the steel rather than a useable upper limit based on the modulus of elasticity. A bearing to impact stress ratio of 1.2 at practical refusal was observed to be reasonable but conservative at this site, and is felt to be generally applicable for piles driven to practical refusal elsewhere. Dynamic monitoring during production pile driving was able to show that apparent relaxation was caused by pre-ignition of the hammer when visual observations indicated that pile driving was proceeding satisfactorily.

Jan 1, 1987

By Walter E. Dean

Twenty six samples of carbonaceous gold ores and associated rocks from outcrop and mine localities in northcentral Nevada were analyzed for concentrations of major. minor, and trace elements, total sulfur, and organic carbon. Q-mode factor analysis was used to define six distinctive carbonate, organic, and detrital associations of elements, and to group samples based on these associations. The trace metals that have clearly enriched the organic-carbon-rich samples are V, Zn, Ni, Cu, Cr, and Mo, although few of the samples could be considered "metal-rich" when compared to other organic-carbon-rich black shales. Rock-Eval pyrolysis was used to evaluate thermal maturity and hydrocarbon yield of the samples. Unfortunately, most samples were too thermally altered to be suitable for routine organic geochemical characterization of organic matter. The 813C values of organic carbon in rocks from different deposits have a trimodal distribution, but there is no clear distinction between the three groups of deposits that can be related to age, thermal history, or depositional environment.

Jan 1, 1987

By Malcolm Scoble, Jean-Marc Robert, Luciano Piciacchia

"An approach to the in situ testing of mine backfills is outlined. It has been developed to provide a measure of the effective strength and stiffness of such materials after placement in stopes. This paper is based upon recent field studies undertaken at five Quebec mines. Details of the selected instrumentation, supporting equipment and testing procedures are reviewed. The mechanical behaviour of the backfills is reported and related to their physical properties. This approach represents an economical, simple and reliable means to assess the mechanical characteristics of backfill materials as an aid to both mine design and placement quality control. IntroductionDevelopments in backfill and mining method technology are creating a pressing need to develop effective techniques for characterizing the physical and mechanical properties of backfill in situ, rather than relying on traditional laboratory testing. The development of bulk mining methods is creating the requirement to more fully understand the nature of exposed fill faces to design for stability in pillar recovery operations. Other backfill technological developments currently receiving widespread attention are high density placement and the use of alternative additives to Portland cement. In Canada, U.S.A. and South Africa attention is also being placed on employing backfill to alleviate rockburst hazards(1,2.3l. In situ testing offers the potential to measure the geomechanical properties of backfill once placed in stopes , in order to assess its actual role in pillar recovery and ground support. Similarly, it offers the ability to provide some quality control during backfill placement. This role is seen as becoming increasingly important with the growing recognition of the need to pay greater attention to the mode of placement, which governs segregation and variation in the properties actually achieved by the backfill after placement."

Jan 1, 1987

By Gary E. Sherman

The Bureau of Mines estimated the remaining lode gold endowment of eight mining districts in Alaska using historic production data. A log-arithmic model of cumulative tonnage of ore processed versus cumulative grade was applied to the following districts: Chichagof, Fairbanks, Homer, Hope-Seward, Juneau, Ketchikan, Prince William Sound, and Willow Creek. To assess the remaining endowment, a computerized production data base was compiled from Bureau records. These data were aggregated in 5-yr intervals for each district. Data were sorted in order of declining grade, and log cumulative grade was plotted against log cumulative tonnage. Linear regression was performed on the data for each district. The linear equation for each curve was used to predict remaining endowment at a limiting mining grade. Based on conservative extrapolation of the grade-tonnage curves, a substantial total endowment of 8,415,100 tr oz of gold remains in the eight districts. The districts with the greatest remaining endowment are the Juneau, Chichagof, Fairbanks, and Willow Creek Districts.

Jan 1, 1987

By P. A. K. Wilkinson

This paper is concerned with the development of an in situ recovery of boric acid from a deep-seated colemanite deposit in California. The deposit contains 147 million tons of borate ore containing 6.4% boron oxide (B203). It is the largest undeveloped colemanite deposit in the United States and because of its unique occurrence and grade, in situ extraction appears to be the most economic viable process. The paper covers the geological, mineralogical, hydrological, well-field development, and extraction considerations leading to the initial pilot plant and subsequent demonstration plant phases of the project. Market potential aspects and preliminary economics of the project are also covered.

Jan 1, 1987

By D. S. Barr

Mineralogical, lithological, and metallurgical studies were conducted on various gold ore deposits currently controlled by Freeport-McMoRan Gold Company. Ore samples were first lithologically and mineralogically categorized, then subjected to chlorination, roasting, and autoclaving pretreatments to determine their effects on gold recovery in a subsequent alkaline cyanide carbon-in-leach extraction. The studies indicate that, while organic carbon and sulfide sulfur are the primary refractory components, their effect on process response must be interpreted with respect to the deposit's geology and mineralogy. This approach has proven to be an effective method for evaluating metallurgical alternatives and fore-casting future mill performance.

Jan 1, 1987

By K. Knuutila

The behaviour of thiourea, animal glue and chloride ions in the electro¬lysis of copper has been investigated by various different electrochemical experiments, i.e. polarization curves with stationary copper electrodes, long-time galvanostatic electrolyses and Hull cell experiments. Polarization curves with stationary copper electrodes show that animal glue has a polarizative effect on the deposition potential. Small thiourea contents affect depolarizatively when high concentrations retard the copper deposition. The microstructures of the deposited copper after the long-time electrolyses show that animal glue favours a basis oriented deposition structure. With thiourea the field orientated structure was evident. It was also observed that the deposited structure depended much on the grain structure of the starter sheet. The chloride ion concentration has a drastic effect on. the crystal size of the deposited copper as it was found out in Hull cell tests. Chloride ions flattened the the crystals and the deposition became smoother when the chloride ions were added. The cathode copper quality is discussed according to the literature. Special attention is paid on the codeposition of thiourea and the origin of sulphur impurities in copper cathodes.

Jan 1, 1987