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By Joseph F. Shirley

Introduction Inorganic depressants are chemicals added to the froth flotation process to maintain or produce hydrophylic surfaces on one or more minerals so they will remain in the pulp rather than attach to the air bubbles. Whether a depressant will be effective in depressing a given mineral depends on how it is used and the environment in which it is used. Some depressants must be added and conditioned into the pulp before the collector is added. Other depressants can be added in the presence of previously added collectors and effectively depress the desired minerals. Often the concentration of depressant relative to the collector concentration is critical to making an economic separation. It should be noted that some depressants will only work when specific collectors have been used. Some reagents such as sulfuric acid and hydrogen peroxide essentially act as depressants by altering the previously added collectors so that they are no longer effective. Some depressants such as sodium ferrocyanide are only effective in a very limited pH range and an essentially collector free environment. Major Depressants CaO Milk of Lime is by far the most used depressant both in tonnage and dollar value. Although it is most commonly listed as a pH modifier, it is also an important depressant for pyrite in copper and copper molybdenite flotation plants. Although a simple pH adjustment will often depress pyrite, there are times when grinding with fresh milk of lime is required to obtain optimum depression. Lime is also a molybdenite and gold depressant. NaSH Sodium hydrosulfide is by far the most commonly used reagent to depress copper and iron sulfide minerals in by-product molybdenite flotation plants. NaSH also depresses gold, silver sulfides and silver chloride. ZnSO4 Zinc sulfate is commonly used to depress sphalerite in lead-zinc and copper-lead- zinc flotation plants. It has also been used to effectively depress talc in by-product molybdenite circuits at a pH of 6.5.

Jan 1, 1986

By S. C. Sethi

The WIPP (Waste Isolation Pilot Plant) Project near Carlsbad, New Mexico, is a research and development project sponsored by U.S. Department of Energy, designed to demonstrate the safe containment for disposal of radioactive waste. A mine (repository) is currently being developed 2150 feet below the surface, in a thick salt bed which will serve as the disposal medium. Provision of a proper ventilation system at the WIPP Project is a major priority of those responsible for its design, management, and operations. As an ongoing effort towards this goal, it was decided to simulate the mine's ventilation system using Dravo's MINEVENT computer program. Specifically, the work included the development of the following simulation models: 1. Simulation of the current ventilation system 2. Simulation of the designed ventilation system for the following modes: o Mine Construction mode/shift o Waste storage mode/shift o Fire or exhaust filtration mode These computer models are useful in solving complex ventilation problems likely to be encountered in an R&D project, like WIPP. They are particularly helpful for the development of contingency plans to incorporate during emergency situations, such as fires, fan stop- pages, radiation leaks, etc. Also, they can be utilized when considering expanding certain underground areas to ensure the availability of adequate ventilation.

Jan 1, 1986

This case study reviews the Charters Towers vein systems for potential open-pittable bulk tonnage resources in' stockworks, horsetails or multiple vein systems. The review summarises district evaluation undertaken over the last 18. months before specific drill evaluations.Historical mining from Charters Towers includes in excess of six million ounces at head grades of one ounce per ton. A review and structural studies show most veins as simple, tight systems without significant horsetails or multiple sheeted systems. In addition the normal gold content of the pyritic selvages ('formation') is low and disseminated gold is virtually absent. Shoots are structurally controlled on vein/vein and vein/contact intersections. Historically high production vein systems are hosted by .,.t o of the younger granodiorite phases.Geometrically most veins dip shallowly (from 45¦ to as low as 200) in a north or easterly quadrant. Flat dips permit open cut exposure of considerable vein area at a favourable stripping ratio.

Jan 1, 1986

By Andrew M. Leszcykowski

In 1984, personnel from the U.S. Bureau of Mines examined 41,550 acres of the North Fork Owyhee River Wilderness Study Area for mineral resources. This study area, in southwestern Idaho, is underlain by tuffs and basalt of Tertiary age. There are no known mines, claims, or prospects in or near the area. The northeast and southwest corners of the area are covered by oil and gas leases or lease applications, but no known exploration has been conducted. On Nickel Creek and Pleasant Valley Tables, in the southern part of the area, thin flows of vesicular, moss-covered basalt occur that are suitable for use as decorative building stone. The stone available for exploitation crops out over several square miles. However, more suitable material, outside the study area, is closer to potential markets.

Jan 1, 1986

By Richard D. Lang

Introduction Argyle is located in the Kimberley region in northwest Australia (Fig. 1). It is a significant diamond discovery by world standards and is the first major diamond find in Australia. The deposit consists of a pipe and associated alluvial deposits. Before the 1970s, diamonds were known to exist only sporadically in Australia. They have been found occasionally in association with gold deposits in Western Australia. There is a small deposit near Copeton in New South Wales. Some alluvial occurrences have also been found in Victoria, South Australia, and New South Wales. The first indicator minerals in the Kimberley region of Western Australia were discovered in January 1973. Production from the alluvial deposits at Argyle began in 1983. A $430-million construction program to develop a mine and treatment plant capable of producing 25 million carats per year was completed in December (1 carat = 0.2 grams). Ownership and management Participants in the project are known as the Argyle Diamond Mines Joint Venture. The group consists of CRA Ltd., 56.8%; Ashton Mining Ltd., 38.2%; and the Western Australian Diamond Trust (formerly Northern Mining Corp.), 5%. The project is managed by Argyle Diamond Mines Pty. Ltd., a wholly-owned subsidiary of CRA. Marketing is undertaken separately by the Western Australian Diamond Trust and by Argyle Diamond Sales Ltd. (for CRA and Ashton Mining groups). History Ownership of the Exploration Joint Venture has changed over the last 12 years as various parties changed their shareholdings. The original Kalumburu Joint Venture was formed in 1972 with five participants, each holding a 20% interest. By 1983, a number of ownership changes had occurred. The end result is that two original participants have sold out. CRA now holds a 56.8% share and the Ashton Mining Group holds 38.2%. CRA also assumed project management in January 1977. Table 1 demonstrates the long lead times involved in developing a project.

Jan 1, 1986

By Hardy J. Smith

The rock mass parameters which need be evaluated to estimate the rippability of rock are briefly outlined and their significance is discussed. Several methods used for estimating rippability are compared, and the advantages of taking into account a wide spectrum of rock mass parameters are emphasized. A systematic means of numerically weighing six rock mass parameters to produce a Rippability Rating (RR) is recommended, and a method of correlating this rating with the refraction seismograph method and with tractor horsepower is shown. Although the overall method demonstrated is systematic and yields specific numerical results, an integrated approach is recommended to its application, taking into account: the Rippability Rating; seismic velocity and geologic material; and other engineering judgment factors.

Jan 1, 1986

By W. Z. Choi

A model describing size reduction and mineral liberation during grinding has been extended to include multiple classes of composite particles. The majority of the model parameters have been directly determined using computerized image processing equipment to analyze the products from batch grinding tests. A coarse-grained sphalerite ore from Tennessee, representing a nearly ideal binary mixture of sphalerite and dolomite, has been used to experimentally validate the model for the case of dry, batch grinding. In all cases, excellent agreement has been observed between the model predictions and the experimental results.

Jan 1, 1986

By W. W. Roepke, B. D. Hanson

A major problem facing the coal mining industry today is the need to meet more stringent dust standards due to quartz. When secondary suppress ion is not adequate, the time-consuming and costly cut-and-try method of modifying the mining machine is used in the hope that it will reduce dust generation. The Coal Cutting Technology Group, at the Bureau of Mines' Twin Cities Research Center, has developed an inter-active computer program for drum- type cutting systems to help identify, in advance, modifications that offer the best potential for reducing dust. The program, Relative Dustiness Indicator (REDI), evaluates machine dimensions, seam characteristics, and operator-controllable variables for dust generaton, energy, forces, and product ion.

Jan 1, 1986

In 1985 BMR assessed Australia's economic demonstrated resources of mineral sands as follows: rutile 8.0 Mt, ilmenite 41.4 Mt, zircon 11.5 Mt, and monazite 229 000 tonnes. These resources are located along the east coast of Australia, in the southwest corner of Western Australia, and in the Eneabba region, north of Perth, WA. However, over 40% of Australia's rutile and zircon resources, particularly those on the east coast, are presently not available for mining because of environmental considerations. As well, east coast ilmenite has been considered unsuitable for use by sulphate route pigment producers because of its relatively high chrome content. World demonstrated resources of rutile and zircon are estimated by BMR as 29 Mt and 38 Mt respectively. Demonstrated resources of ilmenite amount to about 1 billion tonnes. These occur predominantly in hard rock deposits in Norway, Canada, USSR and China, as well as alluvial deposits in Australia, South Africa and India. Quantitative data for world monazite resources is sparse. However, world production of rare earth oxides is now mainly from bastnaesite, a hard rock resource. Australia is presently the world's principal producer of rutile and zircon, and also provides a major share of the world's ilmenite. With the expected increase in Australia's rate of output of these commodities, combined with restrictions on mining along parts of the east coast, its position could diminish substantially over the next 25 years.

Jan 1, 1986

By William J. Gregg

Mechanical testing results on oriented Devonian gas shale core throughout the Appalachian basin show a preferred fracture direction perpendicular to bedding. The preferred direction is generally parallel to the Allegheny Front, but is only coincidentally parallel with in-situ stresses in some areas of the basin. The strength of the preferred orientation of induced fractures decreases with distance from the Front. It is suggested that strain related to Paleozoic deformation is responsible for this mechanical fabric and thus the direction of induced fractures in laboratory tests may not be of use as indicators of in-situ stress orientations as previously suggested.

Jan 1, 1986

By M. Ghoreychi, M. Fauueau, P. Lebitou, P. Berest

A brief study of the history of gas caverns in salt formations enables us to consider creep mechanism in a cavity as a phenomenon of dissymmetrical deformation. Among different parameters affecting such a phenomenon, gravity forces, especially in large caverns, seem to be responsible for important bottom heaves as compared to roof releases. This fact is demonstrated here by means of certain theoretical considerations concerning elasto-viscoplastic constitutive laws relevant to rocksalt rheological behavior.

Jan 1, 1986

By B. K. Parekh, W. M. Goldberger

Silicon carbide (Sic), produced by heating rice hulls to elevated temperatures, contains a mixture of beta crystalline silicon carbide whiskers, particles, and unreacted carbon. The silicon carbide whiskers are 0.5 micron in diameter and 50 to 100 microns in length and have been found useful for reinforcing metal and other composite materials. The carbon can be removed by combustion, but this makes separation of the silicon carbide whiskers from particles difficult and a high grade whisker product cannot be made. However, a clean, high grade SiC whisker product can be obtained from the pre-burned converted rice hulls using physical separation processes that are based on differential wetting. Recovery of Sic whiskers from the pre-burned material was found to exceed 90%. A modification of the froth flotation process developed during this study is now being used commercially to separate silicon carbide whiskers and particles and to recover a high grade whisker product.

Jan 1, 1986

By H. L. O. Huyck

A microcomputer equipped with spreadsheet, data management, and FOR- TRAN programming software is used to update and quantify a model for ranking seventeen economically important metal commodities in terms of market potential (Huyck, 1982). Weighted factors are used for the ranking: (1) demand growth trends, (2) end-use substitution vulnerability, (3) recycling trends, (4) price trends, and (5) cumulative demand versus world reserves factor. Price trends are defined using (1) price-vs.-year slopes (with prices in 1967 constant dollars) and (2) standard deviations of slopes (to indicate price volatility). Substitution vulnerability is defined as the percent of end-use which is replace- able by other commodities, and a factor indicating the likelihood of such substitution. Factors are normalized and linearly combined to produce a ranking of the seventeen metals. Microcomputer software is essential for organizing data and calculating statistical parameters and linear combinations of factors.

Jan 1, 1986

Coal slurry pumping was introduced into the U.K. in 1973. Gateside packs were prepared in areas of containment using R.O.M. coal and a special fast setting cement. The packs restricted roadway convergence and moderated spontaneous combustion risks, but costs were high and alternptives were sought. A similar system using OPC and an accelerator had limited success. Much more successful was the Aquapack process which used dilute slurries of a special OPC based cement and an accelerator based on sodium carbonate and bentonite pumped simultaneously into la fabric packbag. The Tekpak system using HAC and a much modified calcium sulphate mixture superceded Aquapack on the grounds of improved cement pumping life lower alkalinity and lower costs. A further modification of this system gave a cement with a 24 hour pumping life thus obviating flushing out pipe ranges except at the week-ends, improved packbags also increased the efficiency of the process. The hazard of spontaneous combustion can be inhibited if air supply channels across the waste can be located and plugged. Using gas samples from pack pipes to locate the heating and injecting a special grout, formulated from bentonite, sodium silicate and thixotroping agents. into the waste on the intake road has proved a successful method of controlling heatings. Mine' roadway and face cavities are being safely and successfully filled with cementitious foams produced in a novel placer machine. The foams are based on fast setting cements with specialised foaming agents. Up to 13 cu. metres per hour of fast setting thixotropic foams can be produced and their use is now widespread throughout U.K. coal mines.

Jan 1, 1986

By Laxman S. Sundae

The Bureau of Mines designed, fabricated, and is using an in-seam tester (1ST) for in situ determination of coal cutting forces. This re-port describes the results of field tests conducted in the Pocahontas No. 3 and Upper Freeport seams to obtain peak and mean cutting forces during coal cutting with several bit geometries, including radial and point attack bits currently used on drum-type machines. Comparisons were also made between new and worn bits, and using data obtained from a Bureau-modified chisel bit. The test results show that longwall plough cutting (horizontal cuts) in bony coal bands (shale) requires >3 times the cutting force for the same cuts in a vertical direction. When no bony coal is present, the cutting forces required to make horizontal and vertical cuts are equal. Worn bits require 4 to 5 times more cutting and normal force than new or undamaged bits. Normal force increased drastically for the worn chisel bit. Peak force encountered in making independent cuts was found to be ~3 times higher than that required to make interactive cuts using a spacing-to-depth-of-cut ratio of 2. Both rake and clearance angles were found to have a significant effect on normal and cutting force.

Jan 1, 1986

By Kenneth P. Michalek, James E. Kelly, Jonathan A. Dantzig

"Many investigations have been reported regarding the simulation of continuous casting with emphasis on in-mold heat transfer. These analyses have been limited, however, because they require either estimation or measurement of the characteristic heat transfer between the ingot and the mold. In this paper, a self-consistent model 'is presented for calculating the heat transfer between a solidifying continuous casting and the mold, in the context of the continuous casting of steel. Using both thermal and stress analyses, the air gap formed during continuous casting is calculated and used to compute the heat transfer coefficients. Iteration between the thermal and stress analyses is used to determine a self-consistent solution. IntroductionThe continuous casting process for steel is illustrated schematically in Fig. 1. Molten steel is tapped into a tundish from which it flows at a controlled rate into the continuous casting mold. The initial shell of the casting forms in the mold by transfer of heat from the metal through the mold wall to the cooling water. The remainder of the casting is solidified by application of water sprays, and/or radiation cooling below the mold.Heat transfer in the mold portion of the process is important because it controls the formation of various defects which are deleterious to subsequent processing. Examples of defects formed in this region are surface irregularities, such as cold folding and oscillation marks, and more serious defects, such as longitudinal or transverse cracks. A more catastrophic problem which may occur is a breakout, in which the shell ruptures and molten steel is discharged in an uncontrolled way."

Jan 1, 1986

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, - (G° - H°298)/T, ?RC, ?Gf°, and log Kf as functions of temperature are given in tabular form. Thermodynamic data were compiled for Ag2SO4, A12(504)3, A12(S04)3?6H20, BaSO4, BeSO4, BeSO4?2H2O, BeSO4?4H20, CaSO4, CaSO4?1/2H20, CaSO4?2H2O, CdSO4, CdSO4?H20, CdS04?8/3H20, 2CdO?CdSO4, Cs2SO4, In2(S04)3, K2504, KA1(S04)2, KA1(S04)2?12H20, Li2SO4, L12SO4?H20, MgSO4, MgSO4?H2O, MgSO4?2H20, MgS04?4H20, MgS04?6H2O, MgS04?7H2O, Na2SO4, Na2S04?7H20, Na2SO4?10H20, (NH4)2SO4, NH4A1(S04)2, NH4A1(S04)2?12H20, PbSO4, Rb2SO4, T12SO4, and Zr(S04)2.

Jan 1, 1986

By Z. R. Llanos

The petroleum refining industry makes extensive use of catalysts for the conversion of crude oils into more usable products such as gasoline, fuel oil and gas, aromatics, and others. Catalysts used for hydraprocessing contain cobalt-molybdenum or nickel -molybdenum, although there are catalysts that also contain tungsten. During hydroprocessing, nickel and vanadium are deposited on the catalysts, eventually rendering them inactive. The refiners are then confronted with the problem of disposing the spent catalysts. In the past, landfilling was a common method of disposal and it is still practiced in some countries. Other refiners prefer to stockpile the spent catalysts at the refineries until the price of metals warrants their sale to metal reclaimers. This practice, however, poses environmental problems to the refineries for storage and disposal of spent catalysts. Other types of catalysts are amenable to regeneration. The purpose of this paper is to focus attention on the recovery of nickel, cobalt, molybdenum, vanadium, and alumina from spent hydroprocessing catalysts by Gulf Chemical and Metallurgical Corporation and to review the use of sodium hydroxide and sodium carbonate for pressure leaching of spent catalysts.

Jan 1, 1986

By Erdal Unal

In order to define the support parameters, by use of empirical approaches, it is particularly important to analyze the rock-load height that should be controlled by supports. The controlling mechanism however, depends on the type of support used there- fore, the rock loads should be treated differently. In this paper, an empirical equation is introduced which relates the rock-load height (ht) to a quantitative rock quality index (REIR), and roof span (B) as fallows:

Jan 1, 1986

By Baafi EY, Chatterjee PK

The quality of mine planning decisions ultimately depends on reliable estimates of the characteristics of the orebody. The quant- ifiable factors such as grades or thickness can be estimated from field data gathered from outcrops or exploratory drillholes. Since outcrop data is necessarily limited to the periphery of a deposit, extensive drilling generally is required. This paper outlines a method for selecting the number and location of additional exploratory boreholes using an iterative procedure based on a mathematical optimization concept called fixed point theory. The method is illustrated through its application to an exploratory drilling program for a coal mine where optimized locations gave a lower estimate of regional and block variances than a manual Choice.

Jan 1, 1986