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By Charles A. Sorrell

This Bureau of Mines publication reviews the structural characteristics of crystalline phases and phase equilibria data for the system NaC1-KC1-AlC13-NaF-KF-AlF3, which encompasses a large number of molten salt fluxes currently used in aluminum recycling. Its purpose is to provide guidelines for research into the relationships between molten salt compositions and their physical properties, notably vapor pressures, densities, surface tensions, and viscosities, knowledge of which is essential to maximizing fluxing efficiencies and metal recovery and minimizing hazardous emissions and disposal problems. In addition, this report describes experimental determinations of sub-solidus compatibility relationships in the system, which is of the quaternary reciprocal type, containing 12 different stable 4-phase assemblages in the solid state. The compatibility diagram serves to define the important compositional planes across which important changes in properties are likely to occur.

Jan 1, 1986

By Craig M. Sams

Phosphate mines in Florida are continuing to encounter higher dolomitic content host rock with the phosphate pebbles(1) necessitating a change in grinding conditions and/or circuits, One of these changes is to install hydrocyclones and close circuit the mill as opposed to the traditional open circuit grinding plant. Close circuiting of the grinding mill with hydrocyclones allows one to take advantage of reduced process mill power requirements by circulating the coarse mill discharge back into the mill for multiple chances of particle breakage. Additionally, as in this case, the hydrocyclones de-slime the pebbles, allowing for more efficient use of grinding power by reducing the amount of dolomitic material recycled to the mill.

Jan 1, 1986

By C. W. Huggins

The primary objective of this Bureau of Mines research was to measure the size distribution of respirable quartz collected at metal mines, nonmetal mines, and processing plants to select the best reference standard for use in quantifying quartz in mine and plant dust samples. The secondary objective was to size all the nonquartz particles collected at the same sites. Particle size measurements were made on 29 samples using a scanning electron microscope in the backscatter mode of operation, interfaced with an image analysis system. The Mine Safety and Health Administration, Denver, CO, provided the 29 samples, which were collected at mines and processing plants in 19 states. The accumulated particle size measurements indicate that NBS 1878, minus 5-f.lm Hin-U-Sil, and minus 5-f.lm Supersil would be preferred over Silver Bond B as reference standards for most quantitative determinations by X-ray diffraction and infrared spectrometry. The respirable dust samples collected at sand plants, however, would be better served by a new reference standard having a quartz particle size distribution of approximately 2.2 um, as none of the four existing reference standards matched closely with them. Commercially available NBS 1878 and minus 5-um Hin-U-Sil CQuid be used as reference standards for 28 of the 29 samples studied in this investigation.

Jan 1, 1986

By Terry R. Neumann

During 1984, at the request of the U. S. Bureau of Land Management, U.S. Bureau of Mines personnel conducted a mineral survey of the 28,600-acre South Pahroc Range Wilderness Study Area (NV-050-0132). The Wit derness Study Area is located in Lincoln County, NV, about 900 miles north of Las Vegas. Five mineral properties and two mineralized zones were examined during this study; of these, one mineralized zone, two small prospect pits, and part of two claims are within Wilderness Study Area boundaries. Perlite resources were identified in the study area; however, no significant metallic mineral values were noted at any of the sites. The Wilderness Study Area is dominated by a Tertiary volcanic sequence consisting of an interlayered series of tuffs containing thin beds of volcanic pebble gravel, sandstone, and perlite. At the base of the exposed volcanic section, perlite occurs along a 2.4-mile-long zone that parallel s the study area's northeastern boundary. The perlite is suitable for filtration, insulation, and soil conditioning purposes, Because of prohibitive operation and transportation costs, the estimated 6 million tons of perlite occurring inside the South Pahroc Range Wilderness Study Area are classified as an indicated subeconomic resource.

Jan 1, 1986

By K. Taniguchi, Y. Inada

When underground openings are excavated in rock mass for storage of Liquefied Natural Gas, hereinafter referred to as L.N.G., as its temperature is -162o C, steep temperature gradients and thermal stress occur around the openings. That is, the plastic zone and cracks around openings will expand with time. In this paper, the range of cracks which were obtained by the Crack Analysis Method and the range of the plastic zone which was obtained by the No Tension Analysis Method were investigated and compared.

Jan 1, 1986

By Dae S. Young, Steven F. Hoerger

The geostatistical method of indicator kriging (IK) was extended to analyze two-dimensional distributions of rock joint orientations. The IK method provides a non-parametric approach for spatial analysis of local probability distribu- tions. By taking into account the spatial correlation of rock joint outcomes and the relative geometry between estimation unit and samples, the IK method provides optimum, spatially conditioned estimates. The estimation method was tested by comparing distributions of actual mapped rock joint orientations with their corresponding kriged estimates. The comparisons show the unbiasedness and accuracy of the non-parametric approach for estimating local probability distributions.

Jan 1, 1986

By Ralph W. Barbaro

This paper presents a cyclic queueing model which evaluates the productivity of a shovel-truck materials haulage system. For a cyclic queueing problem with exponentially distributed service times, a cyclic queueing model provides exact solutions in a fraction of the time that simulation takes to produce an approximate solution. The model is applied to an example problem, and the results are validated with simulation. Simulation is used to show that the assumptions of exponentially distributed service times and steady-state are not serious problems. A cyclic queueing model can be used to quickly obtain an accurate assessment of the productivity of a shovel-truck system.

Jan 1, 1986

By R. C. Jr. Babcock, V. S. Znamensky

The Pyke asbestos deposits were discovered by Kennecott Explorations (Australia) Pty. Ltd. in 1969 during the course of base metal exploration on the South Island of New Zealand. Extensive occurrences of chrysotile asbestos were found associated with the Red Mountain ultramafics in the headwaters of the Pyke River, and to the north and south along the ultramafic belt for a distance of 70 km. Surface evaluation and drilling by Kennecott in 1970 and 1971 identified numerous small deposits of good grade fiber in the Little Red Hills between the Pyke and Barrier Rivers. Additional drilling and three adits have been completed by other companies since that time. The property is presently held by Lime and Marble, Ltd., of Nelson, New Zealand, and Kennecott Explorations (Australia) Pty. Ltd. This chapter presents the regional and local setting of the asbestos deposits, including the geology and nature of mineralization. In addition, the exploration methods used by Kennecott in the discovery and evaluation of these deposits are outlined. Subsequent work by other companies is mentioned, but not de- scribed in detail. This subsequent work did not alter Kennecott's conclusions or produce any serious changes in the interpretation of geology and mineralization. The author acknowledges the contribution of the many employees of Kennecott Explorations (Australia) Pty. Ltd. who have been involved in the project. In particular, thanks go to Ramon Farmer, N.G. Corner, and A.W. McConie, who were responsible for completion of field work and reporting on the project. The responsibility for the conclusions and interpretations of this chapter are solely that of the author and result from his involvement in the discovery of the deposits and management of the exploration program. REGIONAL SETTING Ultramafic rocks on the South Island of New Zealand are thought to be Permian in age and occur between crystaIline and metamorphic continental rocks of Precambrian through Cretaceous age in the west, are thought to have once been part of the Antarctic subcontinent, and the extensive geosynclinal graywacke deposits of the Mesozoic New Zealand geosyncline in the east. They consist of the Dun Mountain ultramafics, a 130 km long segment of ultramafic rocks located at the north end of the South Island, and the Red Mountain ul- tramafics that occur in a zone 200 km long in the south half of the South Island as shown in Fig. 1. These two belts, once contiguous, have been offset a distance of 560 km by the still active Al- pine fault, which is analogous in character and offset to the San Andreas fault of the United States. The ultramafic rocks occur within a sequence of Permotriassic volcanic and sedimentary rocks that probably formed at the eastern margin of the continental plate. The ultramafics appear to be tectonically emplaced between Permian lithologies in the Dun Mountain belt (Coleman, 1966), and at the base of or between Permian volcanics and sediments in the Red Mountain belt. The Permotriassic ultramafic volcanic sequence of the Red Mountain ultramafic belt appears to be a typical ophiolite sequence. Ultramafic rocks, mixed mafic intrusive rocks and volcanics, volcanic rocks, and volcanoclastic sediments occur in apparent superposition from east to west in the area of Red Mountain. Farther south, ultramafic rocks are associated with basaltic volcanic rocks and some sediments, and still farther south are emplaced entirely in sediments. These structural compIications of the normal ophiolite sequence have resulted from the coincidence of Permian subduction, early Mesozoic extension and sedimentation, and Cretaceous subduction along the same plate margin (Landis and Bishop, 1972). The general geology in the area of the Red

Jan 1, 1986

By Robert B. Hoekzema

The Bureau of Mines and U.S. Geological Survey completed a 4-yr (1979-82) mineral appraisal of the Chugach National Forest (CNF), AK. This report summarizes the Bureau's placer gold studies in the CNF. Placer mining from the mid-1890's through 1982 produced an estimated 133,800 oz of gold, of which two-thirds was produced prior to 1920. As much as 6,800 oz of placer gold was produced from 1979 to 1982. Most production came from Crow, Canyon, and Resurrection Creeks. Five types of placer gold deposits were identified in the CNF: (1) alluvial placers, (2) bench placers, (3) eluvial placers, (4) glacial placers, and (5) marine placers. Placer sampling indicated a potential for gold production from alluvial and bench placers associated with historically mined drainages such as Crow, Canyon, Resurrection, Sixmile, and Mills Creeks and from unmined drainages including the Avery, Kings, Snow, Copper, and Tasnuna Rivers and several smaller streams throughout the CNF. Results of fineness tests indicated that gold from the CNF ranges from 455 to over 950 fine. Subsequent investigations in drainages with anomalous placer sample values also identified previously unknown lode mineralization.

Jan 1, 1986

By Leon E. Esparza

The Bureau of Mines studied 780 acres of the 24,130-acre Sheldon Contiguous Wilderness Study Area (CA-020-1012) in 1985. The study was done at the request of the Bureau of Land Management and authorized under the Federal Land Policy and Management Act (Public Law 94-579, October 21, 1 976) in order to evaluate the mineral resources. The study area is located in Washoe County, NV, about 35 miles northeast of Cedarville, CA. A search of county courthouse records and an examination by foot traverses through and adjacent to the study area did not reveal evidence of any mining or mining exploration activity past or present. In addition, evidence of any form of rock alteration was not observed. Evidence of mineral resources is not apparent. Although basalt, the only rock-type present in the study area, can have some limited industrial applications, sources closer to potential markets probably would preclude rock from this area being economically competitive. INTRODUCTION This report describes the USBM (U.S. Bureau of Mines) portion of a cooperative study with the USGS (U.S. Geological Survey) to evaluate mineral resources and potential of the Sheldon Contiguous study area at the request of the BLM (U.S. Bureau of Land Management). The USBM examines individual mines, prospects, claims, and mineralized zones, and evaluates identified mineral and energy resources. The USGS evaluates potential for undiscovered resources based on areal geological, geochemical, and geophysical surveys. Results of the investigations will be used to help determine the suitability of the study area for inclusion into the National Wilderness Preservation System. Although the immediate goal of this and other USBM mineral surveys ;s to provide data for President, Congress, government agencies, and the public for land-use decisions, the long-term objective is to ensure the Nation has an adequate and dependable supply of minerals at a reasonable cost.

Jan 1, 1986

By Donald D. Born

Mine No. 95 is located in Harrison County about 5 miles west of Shinnston, WV, with coal properties covering the northwest corner of Harrison County and the southwest corner of Marion County and with adequate Pittsburgh seam reserves to support the mine for many years. The mine was opened in 1967 and was planned, projected and operated as a room and pillar mine. It is located on a spur branch of the Baltimore and Ohio Railroad, has rail loading facilities and shipped by rail during its development stage. In 1972 it was converted to a mine mouth power station supplier and now transports coal by conveyor belt directly to the Harrison Power Station of Allegheny Power System. In 1971 the first longwall unit was installed in a selected area of the mine and immediately an orderly system of planning was developed to overcome the restrictions associated with longwall mining. The first was the development of the technique necessary for the plugging of abandoned oil and gas wells that existed in the area. With the assistance of the Morgan- town Energy Research Center of the Bureau of Mines, this restriction was overcome and thus opened a great potential for longwall mining in northern West Virginia. Other restrictions that had to be considered for longwall planning were dwellings and other improvements, snap top zones, water courses, and adequate bleeder systems, and the handling and treatment of mine drainage. In 1975 the second longwall unit was installed and soon therefore became a total longwall mine.

Jan 1, 1986

By H. G. Fleshman

Thousands of years ago, Chinese water well drillers developed a technique for punching holes in the ground by lifting massive metal bits and letting them fall against the rock. With diligence, they could pound away about 2 feet a day. The Chinese drillers pounded holes in the ground this way for almost 2000 years. In the 1860's, French water well drillers developed a perforated bit moistened by fluids pumped into the hole through a hollow rod. The fluids carried the cuttings from the hole and spared the Frenchmen the task of bailing them out by hand.

Jan 1, 1986

By Mark S. Sanders

The purpose of this work was to develop and field test improved knee protection for underground coal miners working in low seam mines. In a previous phase of this contract (Sanders, 1982), experimental knee pads were developed and field tested. The field test revealed several design deficiencies with the knee pads, and suggestions for improving the design were made. The work summarized in this report, therefore, consists of modifying the design and method of fabrication of the knee pads originally describes by Sanders (1982), and of field testing the improved design. The new prototype was shorter and wider than the original design, and used a neoprene pass-through strap design rather than a cloth strap molded into the pad itself. The new prototype was constructed by slush molding a hollow bladder that was then filled with foam. Initial reactions to the pads in the field test were very positive. However, after two months, the opinions about the new prototype became less positive. They were judged, generally, to be no better or worse than the pads usually worn by the field-test participants. Problems were encountered in the field with respect to durability. Water seeped into the inner cavity of many of the pads and caused the foam to deteriorate. It was concluded that it would not be cost-effective or feasible to significantly improve upon current commercially available knee pad designs.

Jan 1, 1986

By Je M. Oh

The Bureau of Mines is conducting research to determine the high temperature oxidation resistance of substitute stainless steels (SS) containing two less strategic elements, Al and Si, instead of Cr. Chromium is considered to be a critical and strategic metal. Although the Cr content was reduced to 8 wt pct, the alloys showed better oxidation resistance than did 304 SS containing 18 wt pct Cr. Specifically, the alloys that contained Fe-8Cr-16Ni with combinations of Al and Si showed excellent oxidation resistance even at temperatures up to 1,000° C. In this study, the effects of the alloying elements on oxidation kinetics and morphology of oxides were investigated using a Cahn Rg electrobalance, scanning electron microscopy, an energy-dispersive X-ray analyzer, X-ray diffraction, and an electron microprobe. Aluminum and silicon additions in combinatin were more effective in providing oxidation resistance than either element was alone.

Jan 1, 1986

By J. -C. Roegiers, M. Thiercelin

Accurate toughness determinations are difficult to achieve in the case of soft or heterogeneous rocks. The existence of a large process zone ahead of the crack tip makes the determination of the apparent toughness crack length dependent, in the case of subsized specimens. In order to use practical size specimens, the authors propose a new toughness test, the Modified Ring Test, which pre- vents a largely developed process zone to form ahead of the crack tip. This test has also the advantage that its geometry is core-based. Numerical and experimental results are discussed.

Jan 1, 1986

By Manfred K. Walther

"Tests were conducted on instrumented plates cast in the Abex Experimental Foundry to compare recorded solidification histories with results computed for corresponding models simulated with the C.A.S.T. program. The first plate was cast of low alloy steel and the second of carbon steel with a graphite chill at one end. Both were cast in molds of bonded silica sand. Temperature histories were recorded in the castings, molds and chill. Exceptionally good agreement was achieved between computed and experimental data. Other investigators will find the results useful as a benchmark against which they can compare the results of their own calculations.IntroductionSince the early 1970's our foundry engineers have used both two- and three-dimensional versions of the G.A.S.T. program to gain knowledge of the solidification process [1,2,3]. Study of the computed data gave insight as to how the rigging and risering of specific castings might be changed or adjusted to improve quality and yield. New schemes based on such analyses were then recommended for implementation on the foundry floor. The degree of success of the new practice was subsequently evaluated after the part had been poured, shaken out and examined. Similar conditions were noted in the sectioned castings whenever porosity and voids had been predicted by the computations. Appropriate modifications, when found successful in the model, were applied to the process. This led to a reduction, if not complete elimination, of the defects. Such results gave credence to the use of these programs as an aid in the production of better castings.Earlier investigations on simple shapes revealed excellent correlation between output derived with the G.A.S.T. program and exact solutions. Results also compared favorably with data calculated using other codes as reported in the literature [4] and summarized in the Appendix. However, since the computer program had not been verified by direct experiment, it was decided to run instrumented tests to check the theoretical predictions with actual measurements."

Jan 1, 1986

Titanium dioxide (TiG ) is produced 2 commercially by two methods generally referred to as the "sulfate" route and the "chloride" route. The SCM Corporation, in supplying 15% of the world's demand for TiO 2, uses both of these processes. Of the two processes the sulfate route is generally regarded as the older and more established technology. Worldwide the sulfate route accounts for some 70% of total Ti02 production. However, in the U.S.A. the chloride process accounts for 80% of production. The processes vary in chemistry and raw material requirements. In the "sulfate" process finely ground ilmenite or titanium slag is digested with sulfuric acid to produce a porous "cake" vrnich is extracted with water and recovered liquor. The solution is treated with scrap iron to reduce any ferric ions to the ferrous state which is then crystallised and removed as ferrous sulfate heptahydrate. The liquor is concentrated by evaporation and hydrolysed to form the insoluble hydroxide which is filtered and washed free of impurities. This is converted to the dioxide by calcination at 800 - 1000¦C and milled to break up any aggregates. The "chloride" process uses a higher quality feedstock of natural or synthetic rutile and/or high grade titania slag. The feedstock is mixed with ground high-purity coke and chlorinated at 950¦C in a fluidised bed. The resulting crude titanium tetrachloride is purified by distillation and chemical treatment. The purified titanium tetrachloride is burned with oxygen or oxygen enriched air to give titanium dioxide and chlorine, which is recovered and recycled to chlorination. Titanium dioxide pigment from both processing routes undergoes similar finishing techniques. It is subjected to further stages of wet and dry milling, then coated with layers of inorganic oxides in order to enhance its properties for specialist applications.

Jan 1, 1986

By P. Bartel

Coal cleaning can be effected by the bacterium Sulfolobus acidocaldarius, which in oxidizing sulfur and dissolving mineral matter requires carbon dioxide and oxygen; carbon dioxide as a carbon source and oxygen as an electron acceptor. The desulfurization of coal by thermophilic bacteria under elevated partial pressures of carbon dioxide and oxygen was studied at a total pressure of 1 atm. The partial pressure of carbon dioxide was varied over the range 0.00032 to 0.33 atm (0.00032, 0.007, 0.10, 0.33 atm), and the partial pressure of oxygen was varied over the range 0.14 to 0.40 atm (0.14, 0.21, 0.30, 0.40 atm). The maximum rate of coal desulfurization increased by 32%, from 9.0 to 11.9 mg S/1 hr, as air was enriched in carbon dioxide from its atmospheric level of 0.00032 atm to 0.10 atm. Enrichment with carbon dioxide up to 0.10 atm, at constant oxygen partial pressures, increased the desulfurization rate, but enrichment to 0.33 atm caused the rate to decrease. At constant carbon dioxide partial pressures, the desulfurization rate was maximum at oxygen partial pressures of 0.21 and 0.30 atm. At higher (0.40 atm) and lower (0.14 atm) oxygen partial pressures the rate decreaed by 9 to 20%. The desulfurization rate decreased by 58X, from 9.0 to 3.8 mg S/1 hr, when the air pressure was increased from 1 atm to 3 atm. The effects justify an economic analysis during design and operation of a commercial air feed in a process to desulfurize coal by microbial action.

Jan 1, 1986

By Charles D. Litton

Introduction The successful performance of a mine-wide fire detection system depends upon its ability to detect the presence of a fire rapidly and reliably. It should be sufficiently rapid so that there remains enough time to either safely evacuate a mine or successfully extinguish and control the fire or both. It should be reliable so that false alarms are minimized without sacrificing sensitivity or time response. Systems should also be durable enough to withstand the mine environment over long periods of time while maintaining a high degree of re1iability. Maintenance and calibration of the system should be simp1 e and not require the expenditure of excessive time and manpower to keep it operational. Sensitivity, reliability, and durability of mine fire sensors and their electronic support systems have been the subject of significant Bureau research within recent years. The bulk of this type of information, along with the reports from which the remainder of this paper is derived, can be found in the Bibliography. It suffices to say that there exist commercially available systems for use in mines. This paper addresses a strategy for the use of such sensors and systems. Many factors influence the design of a mine-wide fire detection system, such as the potential sources and modes of ignition, the types of combustibles involved and the quantities avai1able for fire growth and flame spread. Mine air ventilation influences the growth and spread of a fire and also serves to transport the products-of-combustion to other areas of a mine remote from the fire. Fire sensor alarm thresholds place limits on the sizes of fires that can be detected. The time to respond to a detected fire, either in terms of evacuation or control and extinguishment, place additional time constraints on the design of fire detection systems. These factors interact with each other, often in complex ways, and it is the definition and understanding of these factors and their interactions that hold the key to the design of adequate and re1iable fire detection systems. Our level of understanding of the problem has increased dramatically within recent years and it is the intent of this paper to discuss the progress that has been made and how the information can best be used to improve the level of fire detection in underground mines.

Jan 1, 1986

By Lilly PA, Kavetsky AP

An empirical, kinematic model is developed which calculates the trajectory of individual blocks of rock in a blast, their point of impact in the muckpile and the final shape of the muckpile. The method is based on the determination of initial block velocity and requires input on stemming length, bench height, subdrill, burden, spacing, energy of explosive per unit length of blasthole, energy attenuation rate and resistance to movement. The model, which will form part of a comprehensive blast simulation package, has application in open cut mining in predicting muckpile geometry and the movement of grade blocks during blasting, which in turn impact on shovel productivity and grade control.

Jan 1, 1986