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Semisoluble salt minerals are characterized by their ionic bonding and are distinguished from soluble salt minerals by their limited solubility in water. One group of semisoluble salt minerals being considered is the alkaline earth salt minerals, including fluorite (CaF2), calcite (CaCO3) and apatite (Ca5F (PO4)3), as well as celestite (SrSO4) and barite (BaSO4). Another group of semisoluble salt minerals being considered is the rare-earth salts, which include bastnaesite ((Ce, La) CO3F), monazite (CePO4) and xenotime (YPO4). Surface chemistry features of these selected semisoluble salt minerals are discussed with respect to flotation separations. First, the surface chemistry features of alkaline earth semisoluble salt minerals are reviewed, and then the surface chemistry features of rare-earth semisoluble salt minerals are examined. The discussion includes electrokinetic behavior, wetting characteristics and collector adsorption.

By M. A. Trevits, J. E. Urosek, A. C. Smith, M. P. Valoski

The National Institute for Occupational Safety and Health (NIOSH), in partnership with the Mine Safety and Health Administration (MSHA), is conducting research to test, evaluate, improve or modify coal mine fire-fighting strategies and methodologies through large-scale tests. Since wood is the second most abundant fuel available during a coal mine fire, it was decided that series of large-scale wood crib fire tests were needed to measure the products of combustion and to observe the capability of commonly available direct application fire suppression equipment, namely, fire extinguishers, water and gas-enhanced foam. This paper discusses the wood crib fire tests, provides insight into the products of combustion and describes observations made during the application of the fire suppression agents.

By J. L. Jernegan

In this paper I propose to give a short and, I must confess, a rather incomplete description, as regards many details, of the process used in Chicago, Ill., for smelting the argentiferous ores of the far West, and shall confine myself in this description, principally, to the process used at the Chicago Silver Smelting and Refining Company's Works, known as the Balbach process, as all the other smelting works in that city follow the same method, with the exception of one, which has the Cordurié process for the desilverization of argentiferous lead. In all, there are five silver smelting and refining works in and near the city of Chicago. The Chicago Silver Smelting and Refining Company's Works are situated at the little station of South Lynne, about seven miles south from Chicago. The plant at these works consists of one horizontal steam-engine, principally used for running the ore pulverizer, four reverberatory smelting-furnaces, connected by horizontal flues with a common chimney 85 feet high, three lead-softening furnaces, one so-called zinc or mixing furnace, one separating furnace or liquation hearth, one lead-refining furnace, three zinc distillation retorts, one English cupellation furnace, supplied with blast by a No. 3 Sturtevant blower, which is run by a small steam-engine having a vertical tubular boiler, and an assay office, in which there are two windfurnaces of the ordinary construction, and also a small muffle furnace. The assay office is supplied with all the necessary apparatus and reagents for fire assaying. There are also a superintendent's office, various store-rooms for coke and charcoal, and for the preparation of fire-clay, etc. Recently a small slag hearth (Krummofen) with one tuyere, has been put up for the purpose of working over such slags as assay too high in silver and lead to be thrown away, of which there are large amounts. The principal ore worked while I was in the employ of the company was that of the well known Emma mine in Utah, and also small quantities of Colorado ore. The character of the Emma ore is well known to most members of the Institute. In consists principally of ferruginous mixtures of carbonate and oxide of lead, oxide

By İbrahim Çınar, Hakan Özşen

Mine workers in heavy and dangerous work are under several physical risk factors, for example temperature, humidity, noise, vibration, lighting and air velocity. Thermal comfort includes parameters such as air temperature, air humidity, air flow rate, radiant heat, metabolic rate and garment insulation. In this study, thermal comfort conditions were evaluated using thermal comfort indices defined as predicted mean vote (PMV) and predicted percentage dissatisfied (PPD) which were determined by measurements taken from an underground coal mine for approximately 100 days. Although the metabolic rate (light work) was kept at 2 met, it was found that predicted mean vote ranged between − 2.58 and 1.68. The predicted percentage dissatisfied index was found to reach 95%. According to the results, it can be seen that thermal comfort may have negative effects on occupational health and safety. The change in thermal comfort index values in the Soma Underground Coal Mine was investigated in detail and the reasons for the changes were determined. Furthermore, determining the optimal working environment for the mine workers was also an aim of this study.

To be held from the 9th to 14th April, 1972, in Johannesburg, South Africa. GENERAL INFORMATION The first symposium in the series was staged by the University of Arizona in 1961. Since then Stanford University, Colorado School of Mines, Pennsylvania State University and the Society of Mining Engineers of the American Institute of Mining, Metallurgical and Petroleum Engineers have acted together with the University of Arizona as co-sponsors of the series. The 9th Symposium in 1970 was sponsored by the Canadian Institute of Mining and Metallurgy together with McGill University and Ecole Poly technique in Montreal. The 10th Symposium, the first to be held outside the North American continent, is being organised by the South African Institute of Mining and Metallurgy (with the Council for Scientific and Industrial Research and the South African Council for Automation and Computation) in close collaboration with the previous co-sponsors. OBJECTIVES Mineral ventures increase in scale and complexity. The planning and control of these projects requires more and more sophisticated techniques. The intention of the symposium is to pool and exchange experience and knowledge and also to discuss new and potential developments. The papers presented in the main sessions, which will extend over one week, will together indicate progress which has been made in the successful application of operations research, mathematical, statistical and computer methods in each of the various aspects of operation in the mineral industry. A coherent account will be developed by consideration, in consecutive sessions, of the stages through which mineral prospects evolve in the course of their life. Primary aims are thus to stimulate discussion in depth of previous applications, to highlight current trends and to provide guidelines for future developments. PARTICIPATION The intention is to bring together persons responsible for managing the various operations in the mineral industry and the workers engaged in the development of mathematical and computer methods relevant thereto. SYMPOSIUM TOPICS 1. Market Analysis-demand and supply trends, models of mineral markets, price prediction. 2. Exploration and ore reserve estimation--exploration strategies, choice of drilling and sampling patterns, quantification of geological information, geo-statistical analysis, ore reserve assessment. Storage and retrieval of associated data. 3. Project design and analysis-influence on viability and risk of capitalisation, scale and method of operation, processing, uncertainties in design premises. 4. Planning of operation-planning and scheduling of construction, of development and of depletion of ore reserves. Logistics, rock mechanics and ventilation. 5. Control of operations-financial, production, cost and quality control as applied to both mining and processing. Flow and processing of relevant information. CALL FOR PAPERS An invitation is extended to intending authors to submit a synopsis, in 200 to 300 words, of papers which would develop the themes outlined above. The Programme Sub-Committee will choose, on the basis of these synopses, some 20 to 30 authors who will be invited to submit papers. Selection will be aimed at the provision of a coherent structure. Other authors may be invited to submit short papers either as contributions to the primary papers or for brief discussion in ancillary sessions which will be scheduled to follow on the main sessions. The official language of the symposium will be English. DEADLINES Prospective authors must submit synopses of papers by ............end April, 1971 Authors will be informed of results of selection of papers by . . . . . . . end June, 1971 Manuscripts will have to be in the hands of the Editors by . . . . . . . . . end October, 1971 PRE-PRINTS Papers selected for presentation in the main sessions will all be pre-printed and distributed prior to the symposium. As many as possible of the shorter papers and prepared contributions will also be pre-printed. PROCEEDINGS All of the main and ancillary papers together with edited discussion will be published shortly after the symposium in a single volume. TOURS AND VISITS A choice of visits to relevant local undertakings on a day during the course of the symposium will be available to participants. These will include a deep level gold mine. A tour which will include mineral projects of interest and the Kruger National Game Park will be arranged in the week following the symposium. LADIES' PROGRAMME Arrangements will be made for the reception and entertainment of ladies. ACCOMMODATION Accommodation will be available at hotels convenient to the symposium venue. The cost of reasonable hotel accommodation in Johannesburg is in the range R5 to RIO (7 to 14 U.S. dollars) per person per night. All reservations and associated arrangements may be made through agents to be appointed by the organisers in due course. FEES AND COSTS Symposium fees will not exceed R70 (100 U.S. dollars). These will include registration, one copy of the published proceedings, a set of pre-prints of the main papers, teas and lunches during the course of the symposium, and the various official social events as well as the mid-week visits. Accommodation, travel and post-symposium tour charges are not included in this figure. FURTHER INFORMATION All communications should be addressed to: The Secretary, South African Institute of Mining and Metallurgy, Kelvin House, Hollard Street, Johannesburg, South Africa.

By Eric S. Weiss, Deno M. Pappas, Timothy M. Barton

During the past few years, the Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) has been evaluating developments with surface support liners which includes shotcrete and thin spray-on liners (also referred to as sealants, coatings and membranes) from a ground control perspective. The proper selection and use of a surface support material can significantly enhance ground control which may result in a decrease in worker related injuries due to ground falls. The purpose of this paper is to evaluate the preliminary findings of a long-term underground study of various types of surface support liners, and to examine installation practices that are critical for an effective liner material application. The underground study utilizes NIOSH’s Lake Lynn Laboratory Experimental Mine to evaluate the long-term performance of several types of shotcrete and thin spray-on liner materials. Liner material performance to date was evaluated on a regular basis over a three year period. Although the study is still ongoing, critical mining practices were identified that may seriously affect the bond of the liner material to the mine roof and rib.

By Don Dodds

Iron Mountain Mine Rehabilitation Project Brief History The Iron Mountain Mine is located in Northern California approximately 12 miles northwest of Redding. The ore body is a large, very dense pyritic intrusion, discovered in 1860, and initially minded for silver. The silver played out quickly and 34 years later the ore body was mined for copper. Copper mining was scheduled to cease in 1939, but WWII prolonged the closure. After WWII, the pyrite ore was mined to produce sulfuric acid. In 1949 when large amounts of cheaper sulfuric acid were being generated by the oil industry the underground mine shut down. Little was done with the site conditions until 1970 when the U.S. Bureau of Mines began monitoring the pH of the effluent. The initial pH readings were around 2.0. This was lower than anyone expected. Laboratory tests showed that when the ore from the mine was submerged in water, the pH of the water would stabilize above 4.0. However, the pH got steadily lower. In 1989 with the ph around 0.7, the U.S. Environmental Protection Agency (EPA) required the owner to build a capture and treatment facility. During this initial period, the majority of the effort was spent on the treatment plant. The relationship between the mine owner and the EPA was basically an adversarial relationship from the very beginning. In 2001, North Pacific Research was hired to upgrade the capture and control facility. The general layout of the Iron Mountain Mine is shown in Figure 1.

By J. C. Deppe

A method is presented for calculating approximate injection rates in secondary recovery operations. The method can be applied to cases of unequal fluid mobilities, irregular well patterns and boundary patterns. The steady-state pressure distributions for the four flood patterns reported by Muskat and for five additional patterns reveal that most of the difference in pressure between the injection and producing wells occurs in regions around the wells which can adequately be described as regions of radial flow. This leads to a method of calculating injectivity by approximating the flood pattern with radial flow elements (or a combination of radial- and linear-flow elements for some patterns such as the direct line drive). Irregular and boundary patterns can also be approximated by radial and linear elements. Each of these elements can be described by radial-and linear-flow equations and the results combined as series flow resistances to give an approximate equation for the initial injection rate. The mobility ratio does not affect the initial rate; therefore, if the well pattern is one of those regular patterns for which theoretical rate equations have been derived for unity mobility ratio, the approximate initial rate equation can be improved by adjusting it to match the theoretical equation. The available theoretical rate equations are listed, including five new cases. As the flood progresses, the injectivity changes because in general the flood front will divide the pattern into areas of different fluid mobilities. Simple shapes can be assumed for the flood front so that both areas can be divided into radial- and linear-flow elements. Radial- and linear-flow equations are applied to these elements to account for the change in flow resistance behind the front. To calculate injection rates after breakthrough, it is necessary to know the sweep efficiency at breakthrough. Areal sweep data are available in the literature for a number of patterns, and sufficiently accurate breakthrough sweep efficiency can be estimated from these data if it is not otherwise available. Again, simple shapes for the flood front can be assumed after breakthrough, and injection rates can be calculated for the remainder of the flood. When areal sweep data are available, these data can be used to cbeck. the calculated injection rates after breakthrough. Injection rates calculated by this approximate method compare favorably with available model data. INTRODUCTION When the fluid mobilities in the swept and un swept regions are equal, the injectivity will not change as the flood front advances; and for regular patterns it can be calculated by mathematical formu1as.l When the fluid mobilities in the swept and unswept regions are not equal, the injectivity will increase or decrease as the flood front advances. In this case, the injectivity has not been calculated by analytical means for any practical well pattern; and, furthermore, scale model and analog4,6 results have been published only for the five-spot pattern. The main object of this paper is to present an approximace method for calculating injectivity for the case of unequal mobilities. The method can be applied to regular, irregular and boundary patterns. Before the approximate method is discussed, the analytical formulas for equal mobilities will be summarized, and the analytical solution for radial flow with unequal mobilities will be used to show how the injectivity changes as the flood progresses. EQUAL MOBILITIES, REGULAR PATTERNS In a flooding operation the injectivity, the rate at which fluid can be injected per unit difference in pressure between injection and producing wells, depends on basic physical properties and, in addition, on three variables to be treated here—the area of the swept region, the fluid mobilities in the swept and unswept regions, and the well geometry (pattern,

By C. K. Eilerts, J. D. Ham

Laboratory research has been conducted to evaluate the characteristic effects of condensate saturation on the mobility of gas in typical reservoir rocks. A pump with two pistons provided phases in equilibrium at controlled flow rates and constant liquid-vapor volume ratios. Core samples were tested in a holder that permitted sealing steady-state phases in the pore spaces under flow test pressures for weighing with sufficient precision to give an accurate measure of the attained saturations. Parameters of the study were pressure, apparent velocity, flowing liquid-vapor volume ratio, fluid composition, core material and length-to-diameter ratio. Tests were conducted at 515 and 1,515 psia to determine the effect of pressure on the mobility-saturation relationship. Influence of the apparent velocities 0.30, 0.15 and 0.07 cm/sec and of five liquid-vapor volume ratios from 0.0001 to 0.01 was determined at 515 psia The principal fluid system was nitrogen and and separator liquid from a Gulf Coast condensate, but the effect of a condensate of different viscosity was also determined. The significance of a possible concentration of liquid near the outlet end of the test cores was investigated. Core materials included a consolidated sandstone and a low-permeability limestone. Relative mobility and liquid-vapor volume ratio relationships are concluded to be dependent on pressure, saturation and, to a lesser extent, on velocity. For each porous medium and fluid there is a minimum saturation essential to two-phase flow, and high velocities of flow have only limited effect on saturations in this range. INTRODUCTION It is now recognized that knowledge of the availability of a reservoir gas — the period that gas may be recovered from a reservoir at a given rate — is as important as the estimate of gas in place. When reservoir conditions are such that pressure decline owing to production will result in retrograde condensation, liquid saturation can increase in the structure around the production well in a way that may restrict flow capacity, and hence future availability. l Based on a numerical solution of transient radial flow of single-phase gas-condensate fluids, 2 a program for computing the accumulation of condensate in a reservoir and the effect of this condensate on deliverability has been developed. During this development a need evolved for data that described the influence of pressure, velocity of flow and condensed liquid on mobility as recovery progressed. This paper presents the results of experimental investigation to obtain insight into the mobility relationship at reservoir pressures of gas-condensate fluids. A core holder for flow tests at reservoir pressure was developed to weigh the core and its fluid contents under pressure to determine saturation. A specially constructed pump was used to drive a two-phase fluid through the core until a steady state prevailed. The core was used as a differential device, and properties measured were intensive rather than extensive. APPARATUS Fig. 1 shows a schematic representation of the major pieces of equipment used in the mobility determination. The weighable core holder is connected to a two-piston, constant-displacement pump. Attainment of steady-state flow is indicated by stability of the flow differential read from the high-pressure manometer. WEIGHABLE CORE HOLDER An important part of the data needed was the mobility-saturation relationship. This required that mobilities and saturations be measured at pressures, flow velocities and liquid-vapor volume ratios characteristic of condensate reservoirs.

By A. A. Oakes, P. M. C. Wilson

This paper describes some aspects of the planning of a new colliery which commenced production in the Middleburg district in 1966. An account is given of some of the problems encountered in the early years of operation and of what was done to solve them. The conclusion is reached that design of plant and machinery should be flexible to permit multiplication of units.

By Thomas C. Ruhe

The Pittsburgh Research Laboratory of NIOSH conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) conserves energy, reduces oil imports, and reduces mining costs. Since RO has a variable composition, there was concern that the additives/impurities it contains may cause ANFO made with RO to be unstable (as compared to regular ANFO) at high summer ambient storage temperatures. Reactivity of RO with zinc was also a concern. Thermal stability tests were conducted to help quantify and resolve these issues. ANFO mixtures (0.66 lb/300 g) were put into sample containers made of steel, stainless steel, and galvanized (zinc coated) steel pipe fittings, which were heated in isothermal ovens. The experimental parameters were temperature settings of 140° F (60° C) and 176° F (80° C), four sample container (pipe fitting) metal combinations, and nominal heating periods of one and three days. The ANFO samples contained 6% each of the following twelve different oils/oil mixtures: No. 1 was diesel fuel, Nos. 2 thru 6 were five candidate oils (2 thru 5 were used oils and 6 was a new synthetic oil), No. 7 was 5% diesel fuel + 1 % graphite, and Nos. 8 thru 12 were 3% diesel fuel + 3% each of the five candidate oils. All samples showed no reactivity when heated at 140° F (60°C). All samples (except No. 7) reacted at 176° F (80° C) in a steel pipe with galvanized caps as follows: No. I reacted most, Nos. 8-12 reacted moderately, and Nos. 2-6 reacted least. All ANFO samples were tested and found not to be cap sensitive.

By H. E. Sadler, Prof. Silliman

The research here recorded was undertaken early in the present year, and has been prosecuted steadily for about eight months. While the work has been under my constant supervision and advice, the labor has all been performed by Mr. Sadler, to whom is chiefly due the development of the successive steps which have led to the final result. The process is better than I dared to hope, and we are able to place at the command of chemists and engineers interested in the matter an apparatus of continuous and uninterrupted action, and methods of analysis by which the daily averages of the two variable and inconstant factors of illuminating gas, ammonia and sulphur, may be determined with all needful accuracy, even by those little skilled in chemical manipulation, and with very little loss of time. This research has been carried out in the laboratory of the New Haven Gaslight Company.

By M. H. Gaskell, D. M. Kehn, G. T. Pyndus

A correlation of the bubble point pressure for black oil systems is developed using the standard physical-chemical equations of soiutions. The correlation is based on 158 experimentally measured bubble point pressures of 137 independent systems and is expressed in terins of the usually measured field pnrameters— flash separation gm-oil ratio, rank oil gravity, total gas gravity, and reservoir temperature. The data were obtained on systems produced in Canada, Western and Mid-Continent01 United States, and South America. The average error (algebraic) in the representation is 3.8 per cent, and the maximum error encountered is 14.7 per cent. INTRODUCTION In the absence of experimentally measured properties of reservoir fluids, it is often necessary for the field engineer to make estimates regarding the fluid properties based on the usually measured producing parameters. To aid in these estimations, various correlations have appeared in the literature in recent years. Among the pertinent properties of interest is the bubble point pressure. A correlation for this parameter has been reported by Standing'. However, this correlation was based essentially on California produced crudes and this limitation was pointed out with its presentation. The correlation presented in this paper utilized data on crude oil systems from Canada, Wes- tern and Mid-Continental United States, and South America. CORRELATION DEVELOPMENT The basic assumption used in this development is the same as employed by Standing', There is a wide variety of ways to combine these parameters; however, in this instance the combination was made on the basis of Henry's law2. Accordingly, the relationship proposed is Although Eq. 2 defines an individual system, it is of limited value since H' is a function of gas-phase composition and the system temperature. It was observed that for the systems where the bubble point was measured at several temperatures that the ratio of the bubble point pressures and the ratio of the corresponding absolute temperatures (R) were practically identical. Thus, for correlation purposes the bubble point pressure may be taken as a direct function of the absolute temperature. This relation is valid only for those systems that are not near the critical point. Accordingly, this correlation will be inadequate for systems in the region of the critical point. The solubility of the various hydrocarbons found in the gas phase increases with the molecular weight. Thus, the saturation pressure should be inversely related to the gas gravity. Applying these principles to Eq. 2 and rearranging terms gives: The variables 02 the left side of Eq. 3 were designated as the "hubble point pressure factor". The number of mols of tank oil per barrel is a function of the "mclecular weight" of the tank oil. Although the tank oil is a complex mixture, it was assumed for the purposes of this correlation that a unique molecular weight could be assigned to a given oil. This was designated as the "effective molecular weight", and was related to the oil gravity, This empirical relationship was developed simultaneously with the correlation by assuming values of M,. and working to obtain a smooth curve for both the correlation and the effective molecular weight. The relationship between the oil gravity and the effective molecular weight used in this correlation is shown in Fig. 1. The effective molecular weight is somewhat higher than the molecular weight of the C fraction. The difference between these values is largest for the low-gravity systems. It is noted that this effective molecular

By William Gates, Gabe McClain, Thomas Pallua, Joe Schrank

The Tennessee Capitol Corridor connects the Cordell Hull Building (CHB) to the State Capitol, which isa 232-foot-by-124-foot (71 x 38 m) structure in Nashville that includes porticoes built from local massive limestone. This connection was affected by the Capitol Connector Pedestrian Tunnel (CCPT) project, which is part of the overall Cordell Hull State Office Building and Central Services Demolition, New Construction and Renovation Project (Cordell Hull Renovation Project). To construct this connection, the two existing elevator shafts and a new emergency stairwell in the State Capitol were extended down to anew lobby area—the elevators by about 50 feet (15.2 m) and the stairwell by about 60 feet (18.3 m). This lobby was connected to the CHB by a 435-foot-long (133 m) pedestrian tunnel. It was predicted that most of the tunnel would be excavated in a relatively strong limestone; therefore, considering the project features and constraints, drill-and-blast techniques were selected as the primary excavation method. Because of restrictions on blasting in urban areas and, more importantly, the proximity of this construction to national historic landmarks, blasting operations were extensively monitored to measure and correlate ground vibrations as peak particle velocity (PPV), frequency, and strain—these being the major factors that would impact the surrounding buildings. As a result, copious amounts of data were gathered and interpreted within a short time to estimate blasting parameters and optimize the subsequent blast rounds. To calculate the ground response factor, the scaled distance of each shot was compared to the ground vibration as PPV, generating a subsequent regression curve with an R2value of about 0.7. Using the best fit curve equation, the estimated ground response factor was about 150 for the best fit line. Other than some cases with relatively high (> 2 in./sec [51 mm/sec]) recorded PPV values, the blasting operation was successfully conducted as planned and the observed strain on the monitored buildings was very low, mainly within ±2 με (0.0002% elongation). (In general, the recorded PPV was lower than 2 in./sec at frequencies of more than 50 Hz.). The strain gauges at key locations (cold joints and old fractures) in the Capitol and on other critical structures demonstrated strain was insignificant in relationship to ground vibrations from the blasting operations. The apparently small vibration-induced strains were related to the massive limestone construction of the Capitol and ancillary buildings, as the induced strain plus the existing strain did not exceed the critical strain of the massive structures.

By W. Reed

During the 20th century, the increased emphasis on worker health and safety and the advent of new mining equipment and methods led to many changes in mine face ventilation practices. Efforts by government and private industry to improve and modify ventilation practices resulted in better health and safety conditions for workers. This paper examines factors that had a significant influence on mine face ventilation design during the past century. Several “milestone” events are discussed along with the impact they had on worker health and safety. Significant ventilation research efforts by government and private industry are presented. This brief ventilation history highlights innovative ventilation designs and a consistent commitment to mining health and safety.

By T. Egleston

IF we may characterize the aim of metallurgists twenty years ago by any one point towards which their efforts were especially directed, we should say it was the idea of adapting '' waste products" to some useful purpose, while the energy of to-day seems rather to take the direction of so arranging processes as to have no "waste products." The iron-master of this decade no longer speaks of the waste gases

By Hoda Emami

In this study, a combined pyrometallurgical and hydrometallurgical technique has been designed and used to recover rare earth mixture elements (REE) and cobalt from a NdFeB magnetic waste. while addressing the cost of reagent and process facility. This process can be adjusted to different magnetic wastes regardless of their compositions. Prior to the leaching, the magnet scrap was pretreated by two rounds of roasting (750°C in air) and a mechanical grinding in between, to convert iron metal to ferric oxide. Subsequent leaching was performed using optimized conditions (pH, temperature and retention time) where the extraction ratio of REE to Fe III is the highest. After removing iron content from the leachate (pH ≈ 3), REE was precipitated selectively and purified further. The produced REE concentrate reaches 99% purity with 85% recovery in a single run. The cobalt oxide was isolated from the PLS as a by-product with 99.8% purity.

By H. J. Ramey

A general solution is presented for the transient temperature distribution caused by radial movement of a cylindrical heat source through a homogeneous medium of infinite extent. This problem represents a highly simplified model of the movement of a combustion front during the thermal recovery of oil. Numerical solutions are presented for a heat source moving at a constant velocity, and a velocity inversely proportional to the radial location of the heat source. Numerical solutions are presented for both finite and infinite vertical thickness of the heat source, i.e., with and without vertical heat losses. The numerical solutions are used to estimate the fuel concentration needed to maintain a combustion front during the thermal recovery of oil. The sensible heat carried to the combustion front by the injected gas stream is discussed in regard to the fuel concentration. Numerical solutions for a heat source (combustion front) of finite vertical thickness indicate the field conditions that may be necessary to sustain the temperature of a combustion front above the ignition temperature of the fuel over considerable distances from an injection well. The results also have implications in regard to the quantity of heat required during ignition. The results of this computation apply to a highly idealized model of a thermal recovery process. But the results may be used as a guide in engineering consideration of the thermal recovery process. INTRODUCTIO N The thermal recovery of crude oil has received considerable attention since the publication by Kuhn and Kochl of laboratory and field tests of this method of oil recovery. Other publications2,3,4,5,6, since that time have dealt with various features of the thermal recovery of oil and have illustrated the extremely complex nature of this process. Vogel and Krueger7 described an electric analog computer designed to solve a moving heat source problem which was analogous to movement of a combustion front during the thermal recovery of oil. The heat source was maintained at constant temperature and was a cylindrical source of infinite height (no vertical heat loss) moving radially at either constant velocity, or at a velocity inversely proportional to the radial location of the heat source. Jenkins and Ramey2 presented analytical solutions to a similar heat conduction problem and pointed out the possible importance of vertical heat losses. The following presents a general solution to the transient heat conduction problem introduced by Jenkins and Ramey4 as well as numerical solutions for a wide range of conditions possibly similar to those that might exist during field operation of the analogous thermal recovery process. DESCRIPTION OF PROBLEM The problem considered in this paper is determination of transient temperature distribution caused by a cylindrical heat source of infinite or finite vertical height, moving radially through an isotropic medium of infinite extent. It is further assumed that the heat flux generated at the surface of the moving heat source may be a function of time such that the fuel concentration required may be constant, or permitted to vary, and that heat is generated at the surface of the heat source only. In regard to the thermal recovery of oil the assumption that heat is generated at the surface of the front is equivalent to assuming that the thickness of the combustion zone is infinitely small, or that the reaction rate between fuel and oxidant gas is infinite. The last assumption does not appear stringent. See laboratory information published by Martin, et al3 Under these assumptions the temperature distribution throughout an infinite medium caused by a heat source moving radially with an arbitrary velocity may be described by The heat generation function or heat flux at the surface of the source, +(t), is Note that the fuel concentration may be defined as a function of time. Eq. 1 is derived in the Appendix.