Search Documents

By Sung Jin Han

Magnesia-based refractory is generally used in an electric arc furnace (EAF) due to its relatively high corrosion resistance and strength at high temperatures. However, the magnesia refractory is attacked by EAF slag and thus the lining life continuously decreases. Thus, it is significant to identify the interfacial reaction between magnesia refractory and FeO-rich EAF slags. In the present study, the influence of FeO-rich slag on the corrosion behavior of MgO refractory was evaluated. The (Fe,Mg)Oss layer was observed at the slag-refractory interface and its thickness increased with increasing content of FeO in the slag. The specific reaction phenomena and formation behavior of (Fe,Mg)Oss layer were evaluated by thermochemical computing program, FactsageTM7.0.

The compliance sampling method for coal mine dust in the United States has not changed appreciably in the last 30 years. A call for more frequent sampling with immediately available results is leading to new instruments that may supplement or replace the existing sampler. This report discusses two such instruments that provide immediate results of dust levels. The first, called the Respirable Dust Dosimeter (RDD), is designed to supplement the existing U. S. cyclone compliance sampling method. It uses the pressure drop across a filter to provide an inexpensive screening type of measurement. The RDD has been tested in the laboratory and a limited number of coal mines. Side by side testing has compared the RDD performance with personal coal mine samplers in triplicate area sample measurements. Results show that the differential pressure of specific filtration media can be an effective surrogate for respirable mass. Data show that there is a dependence on coal type and an effect of relative humidity. There also appear to be two distinct responses related to coal type. For specific coals the coefficients of determination, R2, are better than 0.9. For general use the detector tube, using laboratory generated calibration curves, can be used to estimate respirable dust levels. However, a calibration to a specific coal type may substantially improve the accuracy. Another sampler in development is called the Personal Dust Monitor (PDM). Designed to give compliance quality accuracy, the PDM uses the frequency change of a vibrating element to measure dust and give immediate feedback of results. Results of laboratory comparison of the prototype PDM sampler to personal gravimetric samplers indicate R2 values of better than 0.99 for three different coal types. Work is in progress to package the components into a person-wearable unit combined with a cap lamp system with a total projected weight of less than 1.4 kg (3 lbs).

By D. M. Beeson, G. D. Ortloff

Water-propelled banks of carbon dioxide recovered both high- and low-viscosity crude oil substantially in excess of that recovered by water flood in linear flow model experiments. The increase in oil recovery is explained by oil swelling and viscosity reduction. Additional oil was recovered by solution gas drive at the end of the carbon dioxide floods when the model systems were depres-sured. This study was an investigation of the use of a water-driven carbon dioxide bank to recover crude oil. Techniques involving the injection of carbon dioxide have aroused con-siderable interest in recent years among methods considered for increasing oil recoveries. A number of investigators have studied the process in the laboratory1-' and in the field.7,5 Laboratory studies referenced indicate that carbon dioxide in conjunction with water flooding recovers more oil than does water flooding alone. These re- ports diverge widely, however, in stating magnitude of improvement. We believed that a water-driven carbon dioxide bank would increase recovery of crude oils by two mechanisms: viscosity reduction and oil swelling. Due to reduction in the oil viscosity caused by solution of carbon dioxide, displacement efficiency should be improved. In addition, the residual oil should be highly swollen by the carbon dioxide held in solution. Thus, the final residual oil saturation, in terms of stock-tank oil, would be lower than in the absence of carbon dioxide. To test this hypothesis, experi-

By C. P. Lazzara, R. A. Franks, G. F. Friel, J. C. Edwards, J. J. Opferman

A series of four coal combustion experiments was conducted at the National Institute for Occupational Safety and Health's (NIOSH) Pittsburgh Research Laboratory (PRL) in the Safety Research Coal Mine (SRCM) to evaluate the response of fire sensors to a small 0.61 m square smoldering coal fire which transitions to flaming combustion in the presence of diesel emissions. An optical path smoke sensor alarmed earlier than a point type diffusion mode ionization smoke sensor which alarmed prior to a CO alert value of 5 PPM above ambient. The presence of steady state diesel emissions resulted in a decrease in the optical smoke sensor analog output voltage signal by less than 1.4 pct for the three coal fire experiments in which a diesel engine was operating, whereas the ionization smoke sensor output decreased between 10.8 and 26.7 pct after the initial surge of the diesel engine. A commercial diesel discriminating fire sensor did not alarm for a fire in the one experiment for which it was used. The results of the experiments demonstrated that an optical path smoke sensor might be used to detect a coal fire under the experimental conditions considered of starting a diesel engine followed by a slowly developing coal fire.

By F. H. Deily, D. S. Rowley, R. J. Howe

By T. Gupta, T. Ghosh

Rare earth elements (REEs) and their compounds are essential in a multitude of mundane and sophisticated applications such as renewable energy technologies, catalysts, medicine, and defense applications. The global supply deficit could be attributed to the destabilization of REE market that has, as a result, incentivized indigenous production of REEs. Cost-effective and environmentally benign opportunities are being explored for the production of REEs from non-conventional mineral sources including coal and coal by-products to stabilize the supply chain. Coal from Healy coal mine and Wishbone Hill deposits in Alaska have been quantified for REEs and were found to possess elevated total REE concentrations as compared to world average levels (60– 70 ppm). The objective of the study was to concentrate the REEs in the froth phase by froth-flotation of the fine size fraction (< 75 μm). A Box-Behnken design of experiment was employed to ascertain the main and interaction effects of operational parameters on response variable by analyzing 3D response surfaces. Experiments were carried out to maximize REE recovery and concentration by modeling and optimization of three operating variables (frother dosage, pulp density (% solids), and collector dosage). Based on the results, the optimum flotation conditions for maximum recovery at an elevated concentration of REEs in the froth fraction was obtained at 4.2% solids and 32.7 ppm of frother dosage for Healy sample and 10% solids and 37.9 ppm of frother dosage for Wishbone Hill coal sample. The quadratic relationship between the input and response variable was found to be independent of collector dosage suggesting good surface hydrophobicity and floatability of the two coal samples.

By A. T. Iannacchione

Designing coal pillars to provide resistance against overburden and gob loads has long been an aim of rock mechanics engineers. This requirement has become more imperative as greater overburdens are encountered and when mining in stiff coal-bearing strata. Current design procedures rely on theories of coal pillar behavior that take into consideration a common hypothesis. This hypothesis states that the elastic core is surrounded by an inelastic yield zone. The distribution of stress at low-to-moderate pillar loads has been effectively defined by this hypothesis. However, it suffers greatly when applied to large width-to-height (w/h >lo) coal pillars under considerable overburden (>500 m) . In these situations, the hypothesis says the elastic core can achieve unrealistic stress states giving the pillars extremely high calculated strength. A growing body of field studies has shown this is not the case. It has become clear that same other mechanism must be involved. It is the purpose of this paper to discuss the importance of an interface slip mechanism between the coal- bed and the surrounding strata in controlling the extent and pattern of stresses and deformations in a coal pillar.

By Emery Chilton, Charles Taylor, Mark Senk, Linda McWilliams

Three-axis ultrasonic anemometers are used to study airflow in the NIOSH ventilation gallery where ventilation in an underground mine is simulated. In this study, performance characteristics of this anemometer are evaluated and the effects of sensor orientation and sampler location on flow readings are examined. The study results provide guidelines for more effective use of the ultrasonic anemometers in the ventilation gallery.

By Steven J. Schatzel, Robert B. Krog

Frictional ignitions are defined as the ignition of a flammable mixture of methane and air that is initiated by frictional heating. Ignitions created through the addition of energy from open flames and exposed electrical circuits are not included in this analysis. Energy released in a roof fall that creates a spark and ignites a methane mixture would be considered a frictional ignition. Frictional ignitions represent the majority of all ignitions in underground coal mines. Over the study period of 1983 to 2005, a total of 1993 ignitions were reported in underground bituminous coal mines in the United States, of which 1589 were frictional ignitions. Reportable ignitions to the Mine Safety and Health Administration (MSHA) are any unintentional occurrences of flame underground regardless of duration. Frictional ignitions were reported in 155 mines and 13 states. Continuous miners represented the largest source for frictional ignitions with 1090 (68.6% of all frictional ignitions). Longwall mining operations represented the highest concentration of frictional ignitions during this study period with 1365 frictional ignitions (85.9% of all frictional ignitions). The 17 mines with the most frictional ignitions were all longwall mining operations and had 1130 frictional ignitions (307 from the shearer) that represented 71.1% of the total. In 1983, mines with frictional ignitions represented 6.9% of operating underground mines and 36.6% of total underground coal production. The percentage of operating underground mines with frictional ignitions and their total production has increased steadily and in 2005 represented 9.8% of active mines and 46.2% of underground coal production. The three coalbeds with the highest number of frictional ignitions (Blue Creek, Pittsburgh No 8, and Pocahontas No 3) had 1049 ignitions that represented 66.0% of all frictional ignitions. The three states with the highest number of frictional ignitions were Alabama (710), Virginia (247), and Pennsylvania (242) that represented 75.5% of the total. Frictional ignitions peaked in 1991 with a high of 114. In 2005, only 34 frictional ignitions were reported. If only frictional ignitions that occur at the face are considered, there have been no fatalities since 1983. Since this time, there were 33 ignitions that caused 53 workers to lose a total of 2912 working days. When including ground falls, then there have been four frictional ignitions with one incident causing two fatalities and injuring eight workers. From 1983-1991, underground productivity and the number of frictional ignitions increased. However, productivity continued to increase from 1991-2000 while total frictional ignitions fell, thereby disproving this connection between productivity and frequency of frictional ignitions. Ninety percent of all frictional ignitions occurred in underground coal mines that liberated more than 393 L/s (1.2 MMcfd million cubic feet per day) of methane through the main ventilation system. Although methane production is not the determining factor for the occurrence of frictional ignitions, it is a good indicator of the anticipated frequency.

By Eric J. Foell, Hjalmar Thiel, Gerd Schriever

Environmental studies for the mining of polymetallic nodules (PN) from the deep sea may be traced back for some 35 years.

By L. Xia

Sodium silicate(s), also known as “water glass”, are one of the oldest and most widely used industrial chemicals. Its first use in Canadian operations can be traced back to around 1925, which coincided with early use of xanthates in mineral flotation. Silicate functions as a sulphide and non-sulphide gangue mineral dispersant, depressant and modifying reagent in grinding and flotation operations. It is believed that soluble sodium silicate promotes selectivity of value added sulphides against gangue minerals, resulting in both grade and recovery improvement. This paper seeks to link improved grade/recovery to the interaction characteristics of minerals and the sodium silicate. A systematic study was performed with individual mineral species, an artificially designed model ore and the feed ore from a copper flotation operation. The function of sodium silicate was evaluated in the context of colloidal chemistry and linked to mineral surface chemistry. Measurement of pulp rheology and mineral zeta potential identified that sodium silicate works as a dispersant. The dispersion is accomplished by increasing a mineral’s net surface charge, resulting in a change in slurry viscosity. Bench scale laboratory flotation tests suggest that better dispersion leads to a diminished interaction of chalcopyrite with gangue. The improved Cu grade and recovery then are likely in response to an increased accessibility to collector along with a linked increase in particle bubble attachment resulting in better separation efficiency. ToF-SIMS surface chemical analysis of the flotation samples found a higher proportion of sodium silicate on minerals from the flotation tailings relative to the concentrates. Moreover, attachment of sodium silicate appears to be mineral specific; the data indicates that sodium silicate favours the surface of gangue phases over the value sulphides.

By Krishna Parameswaran

This paper illustrates sustainability considerations in copper hydrometallurgy using examples of practices at ASARCO LLC, an integrated U.S. primary copper producer. Using the classic Brundtland Commission development of sustainable development, i.e., “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper discusses how copper hydrometallurgical processes can be sustainable. The examples used to illustrate sustainable development and related concepts include: water conservation opportunities in milling and leaching operations; implementing green chemistry and promoting product stewardship in the electrorefining of copper.

The February General Meeting of the Branch was held at the St. Helena Club on Wednesday, 19th February, 1969. Present were: Twelve members: Mr J. G. Kirchner (Chairman of the O.F.S. Branch), Messrs J. N. Saunders, N. A. Honnet, L. O. W. Leimer (Committee Members), Messrs R. C. Espley-Jones, J. W. Wilson, A. T. Lewis, A. von Holdt, L. J. Thorne, C. Mostert, V. O. Steed, H. H. Schellhorn. Nine Associate Members: Messrs E. R. Penny, G. T. C. Emere, M. Forster, K. Pearce, R. B. Sutherland, D. E. Couperthwaite,A. H. Edwards, M. D. de Lange, G. ,R. Still. Four Graduates: Messrs M. H. Smith, N. Mayer, T. R. Stromsoe, T. A. Ward. Four Affiliates: Messrs D. S. Robinson, L. D. Hulley, R. B. Smith, R. L. Soll11s.One Student: D. R. Fleming. Twenty-three Visitors. Total present: 53. Apologies were received from Messrs C. R. Netscher, A. Leger and V. C. Barnes. MINUTES OF PREVIOUS GENERAL MEETING The minutes of the General Meeting held on 15th November, 1968 and which were published in the February Journal, were taken as read and their adoption moved by Messrs J. N. Saunders and N. A. Honnet. There were no matters arising from the minutes. GENERAL BUSINESS The Chairman reminded members of the forthcoming visit by the Branch to the Dudfield Works of the Anglo-Alpha Cement Company, to take place on Wednesday 16th April. TALK ON ROCK MECHANICS The Chairman called upon Mr J. W. Wilson to address the meeting on the subject of the practical applications of rock mechanics to mining. Mr Wilson used a slide projector to present his subject in a most interesting and instructive manner which eventually resulted in much useful discussion taking place. The Chairman then called upon Mr A. von Holdt to thank the speaker. CLOSURE After thanking the speakers, the Chairman thanked members and visitors for their attendance and closed the meeting at about 10 p.m., after which refreshments were served.

By Dr. Calvin J. Konya, Anthony Konya

Blast violence has always been a criteria that has been analyzed without a quantitative approach relying on opinions of those viewing the blast and oftentimes does not transfer between open-pit mines, quarries, and construction projects. Added to this confusion is that on many regulate projects, such as U.S. Army Corp of Engineers construction projects, the definition of "flyrock" or violence can vary, and contractors must be able to meet this requirement. This project analyzed hundreds of blasts from various construction projects to develop a new metric to determine blast violence - the Violence Factor. If a blast is fired using 1.25" (32 mm) diameter product and a 10-foot (3 m) bench, vertical uplift of 60 feet (18.3 m) would be considered extreme and violent by any professional in the industry. However, a 100-foot-high (30.5 m) bench using 12" (305 mm) bulk product, having a vertical displacement of 60 feet(18.3 m)might be considered typical or non-worrisome. This is where violence factor is beneficial as itprovides a system of scaling the violence of a blast based on the bench height to give manager a keyperformance indicator (KPI) which is easy to monitor and can provide a large amount of information onsite-specific design variables for their performance on blasting and the end-results of the blast. The Violence Factor of a blast is an integer which is scaled to determine how high vertical uplift of a blast is compared to the bench height. This project analyzed numerous blasts to determine what blast design variables contribute to violence. This violence has also been shown to occur when a non-optimal breakage mechanism, cratering, occurs and the design criteria that lead to this cratering. Finally, this paper will present typical results of various levels of violence including backbreak, fragmentation, and muckpile configuration.

By Josh Savit

Corporate responsibility already encompasses safety and compliance. No longer will companies be able to use differing standards of care to miners based on the country in which they are working. This is not only an issue of social license, but one of global risk management.

By Wen Tao Liu, Tong Tian, Fu Sheng Niu, Xiu Man Liang

In order to address the difficulty of accurate segmentation of froth images of different sizes, a method of froth image segmentation based on highlight correction and parameter adaptation is proposed. First, a machine vision system on a single-cell flotation machine is built to collect froth images. Homomorphic filtering is used to improve the uneven brightness and shadow of the images. Fuzzy c-means (FCM) clustering is then utilized to classify similar highlights that belong to the same froth. After Otsu threshold segmentation, a parameter-adaptive morphological operation is used to extract the marker points and edge bands and correct the froth edges in the original image. Finally, the modified image is filtered by morphological reconstruction, and the highlight mark is used as the local minimum point for watershed segmentation. Three sizes of froth images are segmented in comparative experiments. The results show that the proposed method is suitable for the segmentation of froth images of different sizes. The position of the extracted segmentation line is close to reality, with average over-segmentation and under-segmentation rates for froth images of 2.6% and 6.8%, respectively. The froth image segmentation performance is stronger than that of the other methods examined.

By D. A. Flanagan, P. B. Crawford

A study has been made of the feasibility of storing liquid meihane at low pressures in undergrohd caverns. Methane liquefies at — 258°F at atmospheric pressure. It is shown that the methane evaporation rates will rapidly decrease and cool the surrounding rock so that at the end of one month they would be between 50 Mcf/hr for a cavern of 25-ft radius and 700 Mcf/hr for a cavern of 100-ft radius. At the end of 10 years, the evaporation rates would be 18 and 100 Mcf/hr, respectively, for caverns of the same radii. The evaporation rates may be reduced by a factor of 2 to 10 by the application of insulation. The cost for mining the caverns is estimated to be $.75 to $1.25/Mcf of storage. This is substantially less than surface storage; it is believed to be safer and to result in lower maintenance, savings in space and savings in strategic materials. INTRODUCTION During the past few years, there has been an increasing interest in the economic feasibility of liquefying methane. Methane liquefaction is being considered for tanker transport; in addition, liquefaction is being reconsidered for shaving peak gas demands. Several articles have described natural gas liquefaction and the progress of the tanker in making trial runs from the United States to Great Britain to determine the feasibility of tanker transport. At the present time, pipelines are not designed to supply peak gas loads during extremely cold periods such as are oiten encountered in the North and Northeast. Gas is being stored in underground reservoirs en-route to its destination, but in many instances satisfactory storage in porous reservoirs has not been practical, especially along the Eastern seaboard where few petroleum reservoirs have been found. In England and other foreign countries, it is unlikely that satisfactory porous structures could be found, and it may be desirable to mine or excavate the rock to obtain storage. By storing the methane near the consumption point, product availability can be increased during periods of need. Methane liquefies at - 258OF at atmospheric pressure, and 1 cu ft of liquid methane will make about 600 cu ft of gaseous methane. Methane liquefaction for shaving peak gas demands was conducted in Cleveland, Ohio in the early 1940&apos;s. The Cleveland plant was designed to liquefy 4 MMcf/D of natural gas.&apos; Development of several low-temperature processes has resulted in some improvements in the design of low-temperature storage vessels. Liquefied-methane storage vessels can be designed for various evaporation rates. The desired rate will depend on the reason for liquefaction. For shaving peak gas demands, the desired evaporation rates would be low, possibly between 0.2 and 1.5 per cent/day. For methane tanker transport and supply, the evaporation rates must be high and must equal the total daily rate of supply. It is apparent that the cost of storage facilities will depend on the objective and will vary appreciably. Surface storage of methane may cost between $3,000 and $20,000/MMscf, depending on the size and design. The failure of the surface storage vessels at Cleveland, with the resulting injury and loss of many lives, has caused considerable emphasis to be placed upon developing new, safer and improved methods of storing liquid methane. Storage of liquefied propane and butane in underground salt domes has been very satisfactory. The per-barrel cost of underground storage for any sizeable capacity is very small compared to the cost of surface storage for LPG mixtures. The larger the capacity of the underground storage, the less is the per-barrel cost. Numerous advantages appear to exist if liquefied methane could be satisfactorily stored underground, the principal advantages being increased safety, lower initial cost, lower maintenance cost, savings in space and savings in strategic materials. The purpose of this paper is to determine the feasibility of storing liquid methane underground in mined caverns. If a large spherical cavern is dug underground and is filled instantaneously with liquid methane, the surface of the sphere may approach the liquid methane temperature almost instantaneously. The temperature distribution for a sphere of radius r. in an infinite medium, initially at one temperature with spherical surface kept at T, from time t = 0, is given by Eq. 1.&apos;

By Bryan Buchholz, N. Kumar Kittusamy

Previous studies indicate that operators of heavy construction equipment are afflicted by musculoskeletal injuries of the arms, shoulders, neck, and lower back. These injuries appear to be due to excessive periods of sitting (static posture), work intensity, whole-body vibration, high resistance levers, repetitive motions, and awkward postures. (2-5) Although numerous studies have shown an association between operation of heavy construction equipment and symptoms of musculoskeletal disorders, very little research has been performed that systematically characterizes operating engineers&apos; exposure to ergonomic hazards. The objective of this study was to systematically characterize the ergonomic hazards associated with excavating operations. As such, the following were performed: (1) vibrations were measured at the operator/seat interface (X, Y, and Z axes), and at the floor of the cab (Z axis); (2) psychophysical ratings of whole-body vibration (WBV) level and overall seat design were obtained; and (3) postural assessments of the job were made. Methodology This study evaluated an inexperienced female operator performing excavation, utilizing two different pieces of equipment. The operator was 37 years old, 162 cm tall, and weighed 80 kg. She had approximately 15 hours of operation time (experience) on the equipment evaluated. The two pieces of equipment used were: a Case Super 580E (1986) backhoe/loader, and an Insley H-2000 excavator (1975) (see Figures 1 and 2). More evaluations were performed on the backhoe/loader than on the excavator. The following evaluations were performed on the Case equipment: 1) vibration levels at the seat and floor; 2) psychophysical ratings of the overall seat design and vibration levels (for the task duration, and for an 8 hour duration); and 3) postural assessments. For the Insley equipment, all of the evaluations were performed except vibration measurements. When the evaluations were conducted, the following environmental conditions were noted: the temperature was 31°F, and soil and terrain conditions were rough and frozen.

By Eben E. Olcott

The Mine.—For some years attention has been drawn to the copper deposits of the Appalachian range of mountains, and especially to those in that portion crossing the corners of Virginia, North Carolina, and Tennessee. Certain it is that in many places in this locality available deposits of copper await the miner, and one after another are being opened and worked. The parts of these three States alluded to are but sparsely settled, and communications are insufficient to meet the demand for transportation. Railroads are wanted, as the existing wagon roads are unfitted for heavy hauling; these circumstances increase very much the difficulties in the way of mining enterprises. Notwithstanding this, the success of some of the mines of this section is an established fact, and Ducktown has for some years held a high rank among the copper-producing localities of the United States. of all these deposits, however, none is more interesting or more deserving of attention than the one now under consideration. The works of the Ore Knob Copper Company have been energetically pushed forward, since the reopening of the mine, in the spring of 1873, by Mr. J. E. Clayt,on, the superintendent and one of the chief owners of the property, and if one thing more than another can insure success it is the combination in this gentleman of rare business capabilities with the deepest personal interest in the prosperity of the undertaking. The copper vein at Ore Knob* is a clearly defined fissure traversing the gneissic rocks of Pre-silurian age in a direction 61&apos; east of north.