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By Z. H. Xie, D. S. He, W. M. Xie

China has rich phosphate rock resources, but with their continuous depletion, the rich ore resources have become increasingly scarce, which makes the exploration of collophane more important. Medium- and low-grade phosphate rock cannot be utilized until their impurities have been removed through mineral processing. However, due to the similar physical and chemical properties of dolomite and phosphorus minerals, the separation of dolomite from phosphate

By Walid M. Abdellah, Soliman Abu Elatta A. Mahmoud, Hanaa A. Abu Khoziem

The high-grade Th-U-Y zone is one of the numerous mineralized zones found in the El Garra El Hamra hydrothermally altered syenites in southwestern Egypt. It is characterized by the thorium minerals thorite and thorogummite, which are closely associated with xenotime-(Y). This zone of mineralization is localized in the eastern part of the El Garra El Hamra hydrothermally altered syenites. This zone does not relate to the first phase of syenites that appeared on the surface but is linked to the other, hidden phase of the syenitic body. Additionally, the fluids responsible for the mineralization of this zone belong to the late-stage hydrothermal event as well as the fault action due to the fact that it had continued reactivations for a long period of time. The studied mineralized zone also contains ceriopyrochlore-(Ce),(Ce,Ca,)2 (Nb,Ta)2O6 (OH), fluorite (CaF2) and barite (BaSO4), which are found in considerable amounts, whereas apatite (Ca5(PO4)3F) and chromite (FeCr2O4) are rarely found together with Fe-oxi-hydroxides (hematite and goethite) with a minor amount of jarosite (KFe33+(OH)6(SO4)2). Finally, the main constituent mineral in the zone is the pseudomorph perthite in addition to quartz, which is found as deformed crystals. A technological sample was collected from this zone and was found to assay 4.62 weight percent thorium (Th), 0.37 weight percent uranium (U) and 3.12 weight percent rare earth elements (REEs). From the chemical and mineralogical composition of the studied technological sample, the leachabilities of Th, U and REEs were investigated using sulfuric acid (H2SO4) agitation leaching and pug leaching methods. The latter was found to be preferred under the conditions of 0.54 ton H2SO4 per ton of altered syenite at 110 °C for two hours.

By V. Srivastava, T. Ghosh

The modeling and simulation of semiautogenous (SAG) mills have been widely used in the design and optimization of mill performance in terms of its power draw, processing capacity and product size distribution. However, these models are solved under steady approximation and do not provide any information on mill charge distribution in real time. 7KLVSDSHUDWWHPSWVWRFKDUDFWHUL]HPLOOFRQWHQWVE\VROYLQJ:KLWHQ¶V¿UVW RUGHUFRQWHQW EDVHGPRGHOLQWKH0$7/$% Simulink environment. The parameters in the model, such as breakage rate constant, discharge rate and appearance function, were estimated using process and design data collected from a gold mine operating in Alaska coupled with a nonlinear parameter estimation scheme. This model was then used to predict the dynamic responses of other key operational variables, such as mill power, bearing pressure, charge level and product size distribution. The transient response of mill behavior with respect to changes in feed size distribution, tonnage and mill feed water is also presented. This dynamic simulation approach can be used for practicing different control strategy and training purposes. The observed response of mentioned variables was validated using dynamic response data from the plant to encompass operational characteristics of SAG mill behavior.

By S. M. S. Azghdi, K. Barani

The effect of microwave treatment on the surface roughness and wettability of chalcopyrite (CuFeS2 ) and on the chemical composition of its surface was studied. The microwave source was a conventional multimodal oven with frequency of 2.45 GHz and maximum power of 900 W. Pure chalcopyrite specimens and purified chalcopyrite concentrate were used in this study. Analysis using atomic force microscopy showed a decrease in the surface roughness of the chalcopyrite after microwave radiation. This decrease may be due to oxidation of the surface and formation of iron oxide. Moreover, the surface wettability of the chalcopyrite mineral increased with increasing duration of microwave radiation, which was in good agreement with the micro-flotation mass recovery results. The increased wettability of the surface may be attributed to the decreased surface roughness by microwave radiation. Analysis using scanning electron microscope/energy-dispersive X-ray spectroscopy indicate that after microwave radiation, the contents of sulfur and iron increased whereas that of copper decreased on the surface of the chalcopyrite, significantly changing the average atomic number of the chalcopyrite surface.

By X. Cai, L. Jiang, G. Fu

A process for recovering manganese from low-grade manganese oxide ore through a reduction acidolysis-selective leaching method is investigated. Two types of biomass, sawdust and straw, were used as reductants. Reduction acidolysis, using concentrated sulfuric acid, was used to disrupt the structure of the biomass, allowing the biomass to be hydrolyzed into monosaccharides. Analysis by X-ray diffraction revealed that Mn2O3 was reduced to MnSO4. Then, in the selective leaching process, iron was removed through the formation of goethite. The optimized experimental parameters are as follows: reductant to ore mass ratio of 0.4, sulfuric acid to ore mass ratio of 0.9, water to ore ratio of 0.5, aging time of 18 h, leaching temperature of 95 °C, leaching time of 90 min, and solution pH of 2.5 to 2.8. Under these conditions and using sawdust as the reductant, the manganese leaching efficiency and iron removal efficiency were 91.8 and 99.2 percent, respectively.

By J. Casado

This paper presents the results of an analysis and summary of relevant literature on the mechanism of cementation of metals in acidic aqueous media, with the aim of reconsidering the conventional assumptions. The simplicity of the process as a mere galvanic metal displacement is discussed, and the real effects of pH and hydrogen pressure in different cases assessed. Finally, an alternative mechanism scheme with respect to the role of hydrogen species, in agreement with reported data, is proposed.

By E. D. Gálvez, L. A. Cisternas, R. Acosta-Flores, F. A. Lucay

Froth flotation processes are carried out in flotation cells that are grouped into banks, and these banks are interconnected, forming a flotation circuit. A literature review shows the existence of papers related to flotation circuit design based on mathematical programming. However, due to the complexity of solving the mathematical model in most of the work, it is considered that a small number of species is present in the feed to the circuit, which differs from practice. In addition, simple bank models are generally used. This paper presents a methodology for designing mineral concentration circuits that overcomes the problems mentioned. It allows the use of more suitable cell or bank models and the inclusion of several species. The methodology is based on two phases. The first phase identifies the set of optimal structures using discrete values of stage recoveries, solving several mixed integer linear programming (MILP) problems. In the second phase, the optimal design for each of the structures obtained in the previous phase is determined using a suitable model for the recovery at each cell or bank, which results in a mixed integer nonlinear programming (MINLP) model. The design of a copper concentration plant with eight species and the design of a zinc concentration plant with three species and five size fractions by species are used to validate the proposed methodology. The structure of the cells in the rougher and cleaner banks deliver structures that are novel.

By J. D. Miller, C. L. Lin

From mine to mill, the 3D characterization of particles ranging in size from meters to micrometers is now possible. A brief review of X-ray tomography for mineral processing is given with recent advances considered, such as high-speed scanning and image analysis procedures to describe important particle properties, including size, shape and composition. Considering these new 3D characterization tools, applications in mineral processing are discussed for high-resolution X-ray microtomography (HRXMT) laboratory analysis of particles ranging from 20 mm to 5 μm, with a voxel resolution of about 1 μm, including (1) multiphase particle characterization by HRXMT and comparison with scanning electron microscopy (SEM), (2) particle damage state as a result of blasting/comminution, (3) liberation characterization to describe expected separation efficiency, (4) exposed grain surface area analysis to explain the flotation of locked particles, and (5) floc size, shape and water content for polymer-induced flocculation. Finally, applications in mineral processing for plant-site analysis using high-speed X-ray computed tomography (HSXCT) are examined, including, for example, coal washability analysis, the analysis of crusher plant products, and the analysis of pebble phosphate products from central Florida. Scanning rates on the order of 1 kg/min for particle sizes ranging from 150 mm to 1 mm are possible, with a voxel resolution of about 100 μm. For coarse particles smaller than 5 to 10 mm, high scanning rates of more than 300 t/h may be possible at a voxel resolution of about 1 mm.

By L. Rintala, P. Latostenmaa, T. Kalliomäki, O. Forsén, I. Lehtiniemi, M. Lundström, J. Aromaa

Conductivity is a typical physico-chemical property that has a substantial effect on electrical energy consumption in the electrorefining process. The objective of this study was to examine the validity of regression models predicting the conductivity of industrial copper electrorefining electrolytes. The models were based on data measured with synthetic solutions on a laboratory scale. The variables included in the models were temperature and the concentrations of copper, nickel, arsenic and sulfuric acid. Both first-order and combined effects of the variables were investigated. The measured data were analyzed using MODDE 8.0 modeling and design software. The validity of the models was investigated by comparing the predicted values with tankhouse conductivity measurements taken at the Boliden Harjavalta Copper Refinery in Pori in Finland. During the tankhouse tests, the conductivity and temperature of the industrial electrolyte were measured, and the composition of the electrolyte was analyzed. The measured conductivity values were compared with the predicted conductivities calculated using the developed models. The conductivity model developed in this paper was shown to be more accurate than previous models and suitable for industrial use.

By H. Y. Yang, L. L. Tong

Semicontinuous-flow, multistage biooxidation experiments of a Chinese refractory, high-sulfur gold concentrate were conducted with different pulp densities for gold recovery. The maximum iron, sulfur and arsenic oxidation rates of 90.0, 88.8 and 96.4 percent, respectively, were obtained in the experiments with 5 percent pulp density. The highest gold and silver recoveries of 96.1 and 68.9 percent, respectively, were achieved by cyanidation. The negative effect of high pulp density on biooxidation was related to the decrease of free and adsorbed cell concentrations with increasing pulp density. The data of iron oxidation from the semicontinuous biooxidation experiments were best fitted by a shrinking core model in which the chemical reaction controlled the rate. The dissolution kinetics of sulfur and arsenic were therefore analyzed by a shrinking core model in which the internal diffusion controlled the bioleaching rates. For the quantitative description of biooxidation efficiency, two parameters — mass dissolution rate and volume dissolution rate — were proposed. In the first stage, the mass dissolution rates of minerals were negatively correlated while the volume dissolution rates were positively correlated with the actual pulp density. The iron and sulfur mass dissolution rates decreased with increasing actual pulp densities in the third and fourth stage, while linear increasing relationships between the volume dissolution rates of minerals and the actual pulp density were observed from the second to fourth stage. The highest mass dissolution rates of minerals were obtained in the first stage with 5 percent pulp density. The highest volume dissolution rates of minerals were obtained in the first stage with 15 percent pulp density. Compared to the volume dissolution rate, the mass dissolution rate was more intuitive to reflect the negative effect of high pulp density on biooxidation efficiency.

By J. D. Miller, C. L. Lin, J. Dong

Nano clay mineral particles such as kaolinite — with primary particles typically smaller than 2 μm in size — can cause significant problems in flotation processes and tailings disposal, including the processing of Florida phosphate rock and Canadian oil sands. In this study, the consolidated state of flocculated kaolinite sediment was examined, and high-resolution X-ray microtomography (HRXMT) was applied to describe the structure of the consolidated sediment. Using this tomographic information, the complex geometry of the channel network structure for the consolidated flocs was established for the first time. With the establishment of the experimental channel network structure, permeabilities were estimated by flow simulation using the Lattice Boltzmann method. Results for kaolinite sediment with and without polymer are compared and discussed. Results for flocculated kaolinite sediment in a gravitational field are also presented and discussed. The results show that as polymer dosage increases, the permeability of flocculated kaolinite sediment increases, and as suspension pH increases, the permeability of flocculated kaolinite sediment decreases.

By Charles W. Robinson

Si bien, durante un breve periodo la industria internacional del hierro ha experimentado diversos problemas dado el exceso de oferta en relación con la demanda. En este sentido, el objetivo del texto radica en estimular los grandes inversiones que se requieren para satisfacer la demanda futura del mineral de hierro. Para ello, se describe la historia de la comercialización internacional del hierro, las fases de desarrollo, las tendencias en el precio del mineral, el desarrollo industrial del hierro en Australia y las características especiales de la industria como: ausencia de normas para el producto, estrecho enlace entre técnico entre comprador y vendedor, falta de flexibilidad de la demanda mineral de hierro, dependencia de transporte de costo y la fórmulas de organización entre propietarios y administradores. Asimismo se revisan los avances en la industria mineral del hierro, como las factores que influyen en su producción

Nov 20, 1969

By Kenneth C. G. Heath

The paper point out the economics importance of the Torco process as lubricant and fuels of the motor in the mining. It is possible to envisage an arrangement in which TORCO would be used to treat a sulphide ore, the acid used to dissolve the metallic ccoper in the concentrate and the copper produced in cathode form by electrowinning. However, there are studies point out that it would be as profitable as conventional flotation, smelting and refining. To carry out full testing of the TORCO process on anyore would be expensive, involving sending several hundred tons to one of the pilot plants located in Johann esburg or Milan. Such pilot plant testing should & be considered as confirmatory rather than exploratory, and a good economic case for using theTORCO process would have to be made out based of mallet scale testing before in curring the larger expense.

Nov 20, 1969

By M. I. Freeman

This paper point put if the companies will considerate large- scale mining in South Américan in the future. In this sense, the philosophy of an international mining company means that the company and the country working in the partnership and they can convince the outside world of the creditworthiness of the project. The mining company would be considering the account metal requirement in the future, the code of behaviour, the obligations and the rights among the employees, the shareholders, the customers, and to the State in wich its work. However, is not specially tailored philosophy for South America. The most important is the satisfactory agreement can be reached even with governments whose domestic laws preclude equity participation by the mining company.

Nov 20, 1969

By Sacha Gueronik

El presente trabajo señala la repercusión del CIPEC sobre el precio del cobre en los demás países y en un futuro inmediato, así como describe las relaciones entre la política minera y la política de desarrollo referidos a los países en vías de desarrollo. Para conocer la importancia de dicha institución, es necesario señalar sus funciones y las características básicas entre los cuatro países miembros: Perú, Chile, Congo y Zambia. Posteriormente, se analiza la política de estos países participantes para definir dos objetivos importantes. El primero, señala el aumento de la producción mineral -en tanto haya posibilidad de crecimiento del mercado de cobre- y así crear condiciones favorables para el crecimiento a largo plazo de consumo. Mientras que el segundo, refiere cómo el CIPEC debe afontar el desequilibrio de los países entre las tasas de crecimiento de las exportaciones y de las importaciones a través de cambios rápidos en sus estructuras económicas para facilitar al mismo tiempo la industrialización y el desarrollo de la producción agrícola .

Nov 20, 1969

By John F. O'Leary

The paper review the process the minerals industry and the materials revolution. For a long time, Latin América attemps at industrialization have been attempts in part, by need to important some of the many raw materials that industrial nations must have. However, the industrial sistem may be in for some of the many raw materials that drastic changes would increase the mineral self sufficiency of countries that are industrialized. In this way, the materials revolution would be a boom to Latin America, it would reduce some of the serious obstacles to the goals which all Americans seem to share.

Nov 20, 1969

By Alejandro Hales

Para comprender la necesidad del cobre en Chile, es necesario conocer el significado del mineral en la formación socio-política de dicho país. Por ello, el presente trabajo refiere la importancia de producción cuprífera en la economía del país sureño a través de la implementación de un programa basado no solo en el aumento de producción del mineral, sino en la participación del Estado y de la integración de la industria. Asimismo, se realizaron tres programas que complementen esta política de desarrollo. El primero, buscó la expansión del mineral y su inversión, el segundo, se basaba en la implicancia del Estado en la propiedad de las empresas productora y el tercero estriba en la integración de la industria del cobre a la minería nacional y así generar una mejor calidad del mineral mismo. Paralelamente a estos programas se desarrollaron programas de expansión de la pequeña y gran minería, asi como reforzar los patrones de chilenización a la nacionalización en la minería.

Nov 20, 1969

By Simón D. Strauss

El presente texto señala los factores que han influenciado el comportamiento de los precios de los metales no ferrosos desde el fin de la Segunda Guerra Mundial. Tras la finalización de este periodo bélico, se dio una inflación que afectó los niveles de precios de todos los productos, alterándose los costos de cuatro de los ocho metales no-ferrosos en la industria minera peruana. Para ello, se realiza un estudio comparativo de los precios estipulados durante la Segunda Guerra Mundial con los precios vigentes al 31 de octubre de 1969. Asimismo se analiza los problemas básicos de oferta y de demanda, encontrándose que la demanda es mayor a la oferta, pese al descubrimiento de nuevas reservas del mineral. En consecuencia, tanto el avance científico y tecnológico como el desarrollo de la competencia son factores de importancia en la tasa de mercado actual que necesitan evaluarse constantemente.

Nov 20, 1969

By R. C. Head

The investigation describe the history of copper in the seventties, as well as indicates the forecast the probable trend of the Copper Industry over the coming decade, and second, to stimulate some discussion on what is a somewhat controversial subject. At the same point, the period of surplus production from about 1972 to 1976-1977, during part of which some voluntary restriction on output maybe necessary. In consecuence, its a necessity for forward planning so that, by 1973-1974, new mines maybe developing to preserve the continuity of supply .

Nov 20, 1969

By José Claro

El texto revisa el proceso de financiamiento de las inversiones en el mineral de hierro. Para ello, se evalúan las condiciones económicas para la producción del hierro, a través de tres términos: la primera, refiere los préstamos otorgados por los gobiernos de países desarrolllados y sus agencias financieras a los países en desarrollo para nuevas producciones mineras. El segundo término señala los préstamos de futuros compradores y el tercer término, están los bancos comerciales, cuyos préstamos agilizan su utilización en una producción minera. Paralelamente a estas condiciones, se desarrolla la modalidad más común de financiamiento, donde la misma empresa minera o sus accionistas intervienen en la capitalización de la empresa. Esta modalidad permite recuperar la inversión a través del pago de préstamos e intereses, en lugar de recibir las utilidades en forma de dividendos sujetos a impuestos. Como consecuencia de ello, el flujo financiero puede utilizarse para recuperar la inversión, afectando la estructura del precio del cobre ya que hace necesario que la venta del producto genere recursos financieros suficientes para cumplir los compromisos.

Nov 20, 1969