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By Paul T. Allsman

1.1-1. Current Status. The history of surface mining is essentially that of mining coal, copper, and iron ores, and the nonmetallic minerals--clays, gypsum, phosphate rock, sand, gravel, and stone. Table 1.1-1 is a comparison of the estimated world production of crude metallic and nonmetallic ores and coal with that of the United States for 1964, in short tons. It includes an estimate of the quantity produced by surface mining methods. Two-thirds of the 8.8 billion tons are mined from surface, ranging from a third of the coal, half the metallic ores, and nearly all clays, stone, sand, and gravel. In the United States, production by surface methods parallels that of the world with two major exceptions: 74% of copper ore and 90% of usable iron ore are mined from the surface, whereas outside the country less than 40% of copper ore and only 50% of usable iron ore are mined from the surface. In surface mining of both metallic ores and coal, much waste is stripped, but in mining nonmetallics the ratio between waste and ore is small. Assuming that the stripping ratio for surface mining in the United States will apply equally to world production, it is estimated on a weighted basis that over 21 billion tons of waste, or a total of nearly 27 billion short tons of material, are mined annually in the world by surface methods. Data are not available to confirm the assumption for waste stripping outside the U.S., but the estimate expresses an order of magnitude that is worth noting. Table 1.1-2 shows the materials-crude ore, coal, and waste-mined by surface methods and the relation to total mined by both surface and under- ground methods in the United States during 1964. Eighty-two percent of all crude metallic and nonmetallic ores and coal was mined from the sur- face, including 82% of metallic, 96% of nonmetallic ores, and 35% of coal. Copper and iron ore comprise 83% of the metallic ores mined from the surface, and clays, gypsum, phosphate rock, sand, gravel, and stone

Jan 1, 1968

By Charles F. Park

Mining in the Pacific Coastal Region has passed through three stages of development. First came the gold rush days, a period when gold and silver were the objects of intensive search. Second was the development of the high-grade base-metal deposits and of the smaller and more refractory precious metal deposits. And third was the modern period that covers the discovery and development of the rarer metals, of large low-grade deposits, and of the industrial and nonmetallic minerals. Brief discussions of the salient geologic features of the region and of a few of the better known mineral deposits are given. The regional geology is favorable for continued exploration and discovery of new deposits and districts.

Jan 1, 1968

By W. S. Sanner

Grinding experiments were conducted to determine the finest anthracite particles that could be produced in a ball mill. Continuous and batch tests were run in a dry-grinding ball mill. Batch grinding produced the finest coal particles. They averaged 2.2 microns in diameter and were 99.0 percent smaller than 37 microns. Continuous grinding yielded a product 6.1 microns in diameter, with 96 percent smaller than 37 microns.

Jan 1, 1968

By W. L. Acherman

The Bureau of Mines found the chemical and galvanic corrosion behavior of the TZM and molybdenum-30 tungsten alloys to be generally equal or superior to that of unalloyed molybdenum in many aqueous solutions of acids, bases, and salts. Notable exceptions occurred in 1 [N] nitric acid, where both alloys corroded appreciably faster than molybdenum. In mercuric chloride solutions, the TZM alloy was susceptible to a type of crevice corrosion which was not due to differential aeration. The alloys were usually not adversely affected by con-tact with dissimilar metals in galvanic couple experiments, but the dissimilar metals sometimes corroded galvanically. Both alloys were resistant to substitute ocean water spray at 60° C.

Jan 1, 1968

By P. Shibley, P. R. Clarke

Since this was an interim report of the initial operation of a long term project it is not available for publication. It is expected when the project is completed a full report of the work will be published.

Jan 1, 1968

By Gordon. I. M., J. Blackshaw

"The wet part of the Hollinger mill is housed in two buildings, the grinding plant and the treatment plant. In the grinding plant there are four 7xl5 ball mills which grind the ore to 60 per cent through 200 mesh. There is also one 7xl5 ball mill which grinds table concentrate to 9 5 per cent through 200 mesh.The primary classifier overflow is pumped to the treatment plant where it passes over shaking tables, producing a concentrate and a tail. The concentrate pulp is pumped to the grinding plant for secondary grinding. The secondary classifier overflow is pumped back to the treatment plant where it is thickened in two 40xl 5 tray thickeners and agitated in four 20x24 mechanical agitators arranged in series of two (with 2 spares).The table tail pulp is thickened in nine primary 40xl5 tray thickeners (with 2 spares). The thickened table tail pulp and the concentrate agitator discharge pulp are mixed and pumped to four rows of 15x45 pachuca agitators, arranged in series of five tanks.The pachuca discharge pulp is divided. The smaller part goes to two rows of 3-step decantation using 40xl5 tray thickeners (with 2 spare rows). The larger part goes to six 14xl6 drum filters. The repulped primary filter cake and the thickened pulp discharged from the decantation rows are fed to eight 14xl6 drum filters. The secondary filter cake is mixed with water and pumped to the tailing line."

Jan 1, 1968

By M. C. Fuerstenau, J. D. Miller

The response of calcite to flotation with saturated fatty acids and alkyl sulfonates of various chain lengths is presented. The amount of collector re-quired for flotation is shown to decrease systemati-cally with increasing carbon content from 8 to 12-carbon atoms per molecule. This systematic flotation response is correlated with the solubilities of the calcium-collector salts, which were established with a nephelometer. The 14-carbon collectors deviate from this systematic behavior, and no flotation is possible with the 16-carbon homologs. As determined by infrared analysis, the mechanism of collector adsorption involves a specific chemical reaction be-tween the collector and the surface. A reaction of the form CaCO3(s)+ 2 RCOO"=*=Ca(RCOO)2(s) + C03= is suggested. The pH of the system is also shown to be a most important parameter as it controls the carbonate, calcium, and collector ion concentrations in solution and thus controls flotation response. The importance of hydrocarbon chain length of collectors was recognized early, and various studies have been made on this aspect of flotation. Wilkinson, ' for example, noted that as the chain length of alkyl xanthates is increased, the amount of collector required for flotation of sphalerite is decreased. The same effect has been shown in the flotation of galena.2 Similar results were obtained when malachite3 and calcite4 were floated with various fatty acids. DeBruyn5 has shown that a similar phenomenon occurs when quartz is floated with amines at constant pH. Recently, Fuerstenau, Healy, and Somasundaran6 correlated this phenomenon with the van der Waals cohesive free energy of association of the hydrocarbon chains. It seems unlikely, however, that chain association could be involved in the sulfide and carbonate systems with the collector additions employed, especially with the short-chain xanthates. Rather, it would seem that the decrease in collector concentration with increase in chain length noted for flotation is related to the solubility of the metal-collector salt. The purpose of this investigation is to verify this premise and also quantify this phenomenon if possible. Calcite was selected for study with both alkyl sulfonates and saturated fatty acids as collectors. EXPERIMENTAL MATERIALS AND METHODS The collectors used in this investigation ranged from 8 through 14 carbon atoms per molecule. The fatty acids had a reported purity of greater than 99%. The sodium alkyl sulfonates were provided by the Marathon Oil Cot, Littleton, Colorado, and had the

Jan 1, 1968

By R. Kossowsky

USING etch-pit techniques, Johnston and Gilman' have shown that the stress dependence of dislocation velocity can be represented by the expression where r, is the dislocation velocity, a is the applied stress, and oa, is the stress to produce a unit velocity. Noble and Hul12 showed that the exponent m is strain-dependent and increases rapidly in the work-hardening region. This was explained by arguing that in the work-hardened material the applied stress required for any given velocity will be greater than in the annealed material by an amount equal to a back stress due to work hardening. schadler3 has stressed the importance of substructure as a possible source of error in dislocation velocity measurements, and took care to make velocity measurements in which dislocations moved such short distances that interactions with boundaries were avoided. schadler3 also pointed out that, if standard testing equipment is used, measurements of m from flow stress data could be seriously in error in materials with a high initial work-hardening rate. Noble and Hu112 have further argued that, due to the strain dependence of m , the extrapolation to zero strain4 to obtain the true value of m can be justified only in the preyield region. Microstrain experiments in high-purity iron5,6 have led to the conclusion that aiA (Ref. 5) (defined as the stress to first produce a permanent set of 10-6 in. per in.) and oflow are not controlled by the same deformation mechanism. It has been proposed5,6 that aA is governed by the lattice resistance to the motion of screw dislocations in a given slip plane and that oflow is controlled by the lattice resistance to a full-scale cross slip. The purpose of this note is to extend Noble and Hull's argument further and to show that measurements of m from flow stress data can be in error due to the rapid increase in stress in the microstrain region6 when stress is increased beyond aA. Double z-one-refined single crystals of molybdenum (with the (101)[ 111] slip system operating and a Schmidt factor of 0.475) were used in an experimen-

Jan 1, 1968

By R. A. Friedel

Data on compositions of natural substances are important in the study of possible interrelationships. The similarity of the low molecular weight alkane isomers from crude oil and Fischer-Tropsch catalytic synthesis product has been reported (8).3 A similar composition for the alkane isomers from high-temperature coal carbonization has been found. The composition of the C4 to C 7 alkane isomers from these three sources can be calculated quantitatively with the equations previously developed to calculate alkane isomers in Fischer-Tropsch product. An KM sting reversal of the concentrations of the monomethyl isomers from C6(2 Me > 3 Me) to C7 (3 Me > 2 Me) occurs in all three products; fragmentary comparisons at higher carbon numbers indicate some dissimilarities. Naphthene isomers in the C6 to C7 range for crude oil and high-temperature coal carbonization also have similar compositions. Aliphatic hydrocarbons from low-temperature coal carbonization processes are considerably different, consisting mainly of normal alkanes.

Jan 1, 1968

By Akira Yazawa, Alžbeta Gubcova

RECENT lead-smelting techniques have tended toward use of high-grade concentrates with minimum amounts of flu, accompanied by profitable employment of roast reaction.1-5 In order to better understand these smelting processes, thermodynamical calculations have been carried out on the Pb-S-0 system, and the results obtained have been presented in isothermal reaction diagrams in which log Ps, and logPo, were the axes. The diagram thus constructed seems to be more convenient to grasp the equilibrium aspect than those published hitherto.6-8

Jan 1, 1968

By George Boulter

Draglines 8.2-1 Introduction. The nature and characteristics of rock and rock derivatives forming the crust of the earth vary so greatly from place to place that it is impossible to use the same numerical factors to show the, productive ability of excavating equipment on different jobs or projects. Factors for each project must be developed individually and applied as the conditions and requirements dictate. TYPES' OF DRAGLINES. Types of draglines are differentiated by the propelling method used and are generally divided into four classes, as follows: 1. Wagon mounted 3. Crawler mounted 2. Truck mounted 4. Walking Figure 8.2-1 shows a truck-mounted dragline. This type is considered to be the most mobile unit. In order to increase stability over the side, outriggers are installed as part of the truck chassis. This feature is not shown in .this figure. Figure 8.2-2 shows a crawler-mounted dragline. The long, wide crawlers are used to increase the stability and reduce the bearing pressure of this unit. These features allow for use of these units on surfaces too soft for the wagon- or truck-mounted types. Figure 8.2-3 shows a walking-type dragline. The large diameter tub and the well-supported boom through the gantry gives high stability for rugged works over a long life. BASIC PARTS OF A DRAGLINE. The basic parts of a dragline are illustrated in Fig. 8.2-4. A deck layout is shown in Fig. 8.2-5 with the main components named. OPERATION OF A DRAGLINE. Following is a description of the steps and controls present in a typical cycle of operation of a large dragline having independent hoist and drag motors. Starting the cycle with positioning the bucket on the ground under the point of the boom, the next step is

Jan 1, 1968

By J. M. Wetherill

"This paper presents the results of an investigation into the level of radon, as against the natural background, at the Vicary Creek coal mine in Alberta. The concentrations of radon and daughter products detected in the mine were considered to be insignificantly higher than the concentrations of naturally occurring radon and thus do not constitute a health hazard to the miners.INTRODUCTIONTHE HIGH INCIDENCE OF LUNG CANCER among miners exposed to radon was established some thirty years ago. The presence of this gas in mines is primarily associated with pitchblende extraction operations, al-though coal contains detectab`e quantities of U30s. A previous study bas shown that coal from southwestern Alberta (Exshaw and Banff) contains lower than average concentrations of this element (1).As part of a general investigation into the occupational health environment of coal miners in Alberta, field measurements were made to establish the level of radon and to investigate the natural background radiation in the Vicary Creek coal mine, located some 16 miles north of Coleman, Alberta, on the easternmost slopes of the Rocky Mountains."

Jan 1, 1968

By C. R. McClure

The objective of this papef is to summarize briefly the practical use of rock mechanics in design and construction of various types of structures. These range from foundation for industrial facilities, nuclear power plants, bridges and dams to tunnels and underground caverns. The use of rock mechanics has varied from performing a few laboratory unconfined compressive tests on core samples to complete field and laboratory tests for underground power caverns. The primary difference between the rock mechanics studies we hare for construction projects and those most commonly found in the literature is that our tests must provide immediate answers to specific questions facing a design or construction engineer. For example, when we make a plate-bearing test we arrive at a load-deformation relationship. We realize that this is not a true modulus of elasticity. Yet, when considering the resistance the rock will provide against forces occurring in a pressure tunnel it is a far more useful value than the true modulus of elasticity of the rock. Another example of this difference in interest is in the use of flat jacks. Many people criticize the use of flat jacks because they measure the stresses in the disturbed zone very near the surface and do not represent the undisturbed stress condition in the rock. However, in actual construction it is frequently those near-surface stresses with which we must cope. We are interested in both the stress conditions present prior to excavation and those as modified by construction of an exploratory adit or drift. Fundamentally, we are interested in the practical application of rock mechanics in the solution of problems of design and construction of civil engineering works.

Jan 1, 1968

By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

By M. J. Blackburn

The phasal equilibria in TI':Al alloys has been studied Ry transmission electron microscopy, electron diffraction, and X-ray diffraction. It is shown that three-phase fields exist below the transformation, viz.: a disordered hexagonal solid solution a; an ordered hexagonal phase based on Ti3Al, aa; and a two-phase region. (a + (YZ) , occurring between the single-plzuse fields. The size. disiribution, and morphology of- the a, phase in the two-phase region is shown to be dependent upon the alloy composition and heat treatement. The ordering process in the a, phase leads to the formation of anliphase domain boundary networks; the contrast and stability of these networks is shown to be dependent on alloy composition. A new and relatively simple phase diagralil for the systemm is constructed. The phasal equilibrium at the titanium-rich end of the Ti:Al system has long been the subject of considerable controversy. crossleyl has recently reviewed the phase diagrams that have been advanced for the system and in his turn proposed yet another one. There would seem to be general agreement that a phase exists at a composition at or near Ti& with an ordered hexagonal DO,,-type structure. However, several other phases have been proposed; for instance, Ence and ~ar~olin's' diagram includes two phases, Ti2A1 and Ti3A1, in the region up to 25 at. pct Al. The position of the proposed phase boundaries varies over a considerable compositional and temperature range, a point graphically illustrated in Fig. 1 of Crossley's paper.' It is perhaps germane to briefly examine the techniques used by other workers in the establishment of the phase structure. These fall into three categories: 1) X-ray diffraction, the only limitation of which is the rather low intensity of superlattice reflections in this system.3 Thus, superlattice reflections become increasingly difficult to detect in the more dilute aluminum alloys. 2) A considerable amount of optical microscopy has been performed"2'4 and it will be shown in a later section that many of the obscure mi-crostructures that have been observed can be attributed to hydrogen contamination. It is concluded, therefore, that such observations should be interpreted with considerable care. 3) The variation of some physical property with aluminum content has been measured.5"7 These methods are a useful indication of the existence of a transformation, but are usually insufficient in themselves to identify the transformation. The results using these techniques will be considered in more detail in the discussion. In this paper, the phase structure of alloys containing up to 25 at. pct A1 has been studied by transmission electron microscopy and X-ray techniques, and the results are used to generate a new and relatively simple diagram for the titanium-rich end of the Ti:Al system. EXPERIMENTAL A series of alloys containing 5.05, 10.16, 13.39, 13.99, 14.40, 20.83, and 25.05 at. pct A1 were obtained in the form of hot-rolled sheet 0.02 in. thick. These alloys contained 0.10 to 0.15 pct 0. Thirty-gram arc-melted buttons were prepared from iodide titanium and 99.99 A1 which contained 16.1, 16.9, 18.2, 19.0, 21.6, 22.2, 23.0, and 23.9 at. pct A1 and had an average oxygen content of 0.03 pct 0. The differences in oxygen content did not appear to influence the nature of the phase transformations which were found. Oxygen content may affect the temperature of these transformations, but insufficient samples of the high-purity alloys were examined to answer this question. The heat treatment of alloys was performed in dynamic atmosphere and vacuum furnaces or in helium -filled silica capsules. A special vacuum furnace was constructed to provide a high quenching rate in which rates of 4000°C per sec were obtained using water as the quenching medium. As pointed out by Crossley,' it is important to avoid heat treatment in the a - [} phase field as the resultant segregation of the alloy into the two phases containing different amounts of aluminum can persist through subsequent treatments leading to ambiguous results. It will be demonstrated later that step cooling of specimens from the a phase region can also lead to anomalous effects. Thus, all solution treatments were carried out in either the a or 3 phase fields followed by water quenching and subsequent isothermal annealing at various temperatures. X-ray analyses were performed on a diffractometer on fine-grained bulk specimens. The value of long-range order parameter, S, wa_s calculated from the integrated intensity of the (1211) reflection. In general, the intensity of the (1011) superlattice reflection was compared with that of the (2021) fundamental reflection to correct for experimental differences between measurements. Thin foils for electron microscopical examination were produced by electropolishing using the technique described in an earlier paper.8 Dark-field techniques were employed to a large degree in this investigation using the gun-tilt method. Finally it should be noted that the lattice parameters of the D01,-type superlattice are approximately related to the disordered hexagonal phase parameters by Crf - c, and 2ad - a, where the subscripts s and d refer to the ordered and disordered unit cells, respectively.

Jan 1, 1968

By E. J. Kloos

Bureau of Mines-approved self-contained breathing apparatus of the compressed air demand type were evaluated for performance at low temperature. Apparatus durations, breathing resistances, and airflow rates were measured on machine tests at room temperature and -25° F. Man tests under actual wearing conditions verified the machine test results. Many serious functional changes in apparatus performance occurred at low temperature. Pressure regulators malfunctioned when diaphragms lost flexibility. Under certain conditions frozen condensed moisture sealed exhalation valves and fogged eyepieces. High-pressure leaks, not encountered at ordinary temperature, developed at low temperature. Tests results are discussed generally and specifically for each apparatus. Recommendations are given to obtain optimum performance from demand type breathing apparatus at low temperatures.

Jan 1, 1968

By Darrel W. Hansen

Morrow Point Dam and Power Plant are principal features of the Bureau of Reclamation's Curecanti Unit of the Colorado River Storage Project. They are under construction on the Gunnison River 20 miles east of Montrose, Colo. Johnson-MK is the prime contractor, and represents a joint venture of Al Johnson Construction Co., Minneapolis, Minn., and Morrison-Knudsen Co., Inc., Boise, Idaho. The power plant will be housed in an underground chamber in the left abutment, approximately 250 ft behind the original canyon wall. The chamber is 206 ft long and 57 ft wide. The distance from the foundation to the spring line of the roof arch varies from 51 ft in the service bay to 120 ft in the control bay. The roof arch has a rise of 16 ft. The longitudinal center line of the chamber is orientated east-west with the draft tubes discharging nearly due north. Access to the power plant chamber was possible through the cable tunnel, access tunnel, two draft tube tunnels, two penstock tunnels, exploratory tunnel, which became the ventilation tunnel, or the grouting and drainage tunnel leading to the dam. (See Fig. 1.) The shortest and fastest access was through the cable and access tunnels, and the contractor drove these two tunnels simultaneously. The cable tunnel and cable gallery excavation exposed a transverse section, at the west end of the chamber, that was 15 ft wide and extended from the crown to 5 ft below spring line. It was here that arch excavation began. The first 34 ft of advance along the arch was driven on three headings, and the muck was removed through the cable tunnel. Meanwhile, the access tunnel was completed, and a raise was driven from its crown to intersect the advancing arch excavation near the longitudinal centerline

Jan 1, 1968

By C. L. Sainsbury

Lode and placer tin deposits of the western Seward Peninsula, Alaska, have produced more than 2200 tons of metallic tin and constitute the only known domestic deposits of economic grade and size. The lode deposits consist of quartz-topaz greisens containing cassiterite and wolframite as well as numerous base-metal sulfide minerals, and most are in or near altered biotite-granite that forms isolated stocks or in rhyolitic dikes near granite. Within the main lode-producing area in the central York Mountains, nonpegmatite beryllium deposits, consisting principally of fluorite, chrysoberyl, diaspore, tourmaline, and white mica, with minor euclase, bertrandite, phenakite, hematite, and todorokite, are distributed zonally around the tin deposits and locally are transitional with them. All the known beryllium deposits are replacement lodes in carbonate rocks. In the area discussed, both tin and beryllium deposits are localized in a structural belt striking N70° to N85°E across the central York Mountains. The belt is characterized by numerous normal faults, which cut extensive thrust sheets, and by dikes of rhyolite, rhyolite porphyry, and lamprophyre that were injected along the faults. Ore deposits are localized where the dikes intrude brecciated rocks beneath thrusts and, although complex in detail, form tabular lodes that tend to lie along the thrusts. The granites contain abnormal amounts of tin, beryllium, lithium, and boron, and the tin and beryllium lodes are believed to be genetically associated with these enriched granites

Jan 1, 1968

By Charles S. Allbright

To develop a method for predicting the stability of a fuel during long-term storage from rapid aging tests at 200° F, the Bureau of Mines determined the stabilities of three gasoline base stocks and an alkylate blending stock in both sealed storage and aerated storage at 110° F for periods extending to 32 weeks. Stabilities of samples containing gasoline-additive compounds were compared by aging, using two methods--rapid aging in a bomb at 200° F for intervals up to 16 hours and storage at 110° F. The additives used were an uninhibited tetraethyllead motor mix, N,N'-di-sec-buty1-p-phenylenediamine and 2,6-di-tert-butyl-4-methylpheno1. Results were related by graphs that enable predictions of gum and sediment formation during storage from data obtained in bomb tests. A premium-gasoline base stock and the alkylate proved to be stable, but the two regular-grade gasoline base stocks were found to be unstable. Addition of the diamine antioxidant improved the stability of both of the regular gasoline base stocks, while the phenol antioxidant improved only one of them. The presence of the tetraethyllead decreased the storage stability of all four fuels, both with respect to formation of gum and precipitation of inorganic sediment. The rapid test at 200° F appears to offer promise as a basis for a method of predicting gasoline stability in long-term 110° F storage.

Jan 1, 1968

By Paul E. Melancon, Vincent C. Kelley, Dale F. Kittel

Uranium of the Grants region occurs predominantly in continental sandstones of the upper part of the Jurassic Morrison Formation, but significant lesser deposits are found in limestone of the Jurassic Todilto Formation and in black shale of the Cretaceous Dakota Formation. The deposits are disseminations that form runs ranging from a few hundred tons to several million tons. The ore consists mainly of uraninite, uraniferous carbonaceous material, coffinite, and such secondary oxidized minerals at tyuyamunite, carnotite, and uranophane. In sandstone, the ore runs were locallized by mudstone, interstitial carbonaceous material, and primary sand channel trends. In limestone, ore deposition was related to folds and fracture zones. The great bulk of production has come from the Ambrosia Lake mines in the Grants district and the Jackpile and Paguate mines in the Laguna district. The ores, which generally have been 0.20 to 0.30 per cent U3O8, are treated at mills operated by Kerr-McGee Corporation, Homestake-Sapin Partners, and The Anaconda Company, all in the Grants district. In 14·years after discovery in 1950, the deposits had yielded concentrates valued in excess of $800,000,000. Since deposition of the Jurassic host rocks, a geologic history involving tilting, faulting, erosion, changing ground-water environments, and oxidation has considerably influenced the existence and character of the deposits. It is evident that their ongm is not simple. However, a degree of agreement appears probable for a pre-Dakota age for the original ore runs, and, at Ambrosia Lake, two principal stages of ore formation, separated by Laramide faulting, are recognized. All earlier ores have been modified by Quaternary oxidation, solution, and enrichment during which time much secondary tyuyamunite, metatyuyamunite, carnotite were formed.

Jan 1, 1968