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By Willis Beckering

The Bureau of Mines designed a cell having four variable compartments in series to facilitate analysis of multicomponent mixtures. Use of the cell considerably decreases the time required for differential absorption analyses. A solution of a major component is placed in each compartment, and the light absorbed by each of these components is varied by increasing or decreasing the path length of the appropriate cell. Simple calculations then establish the amount of the component present. In analyzing unknown mixtures, compensation is made for compounds known to be present, and the differential spectrum representing components not accounted for is recorded and analyzed.

Jan 1, 1966

By L. H. Robinson

A proposed method of drilling utilizes sequential detonation of two types of explosive charges delivered to the hole by a conventional drilling fluid through pipe. A shaped charge first produces a long thin hole. A second charge, called a gauging charge, is pumped into the thin hole, explodes, and enlarges it to full gauge. In one suggested configuration, the explosives are contained in cylindrical capsules 4- to 5-ft long. A drilling head is positioned 2- to 3-ft off bottom. When a capsule is pumped to the bottom of the hole and stops, pressure inside the drill pipe increases and differential pressure detonates the explosive. Primacord along the length of the capsule disintegrates the capsule. The debris circulates out of the hole with the drilling fluid. The gauging-charge action was examined using 2-ft cubes of Berea sandstone. The sandstone (18 per cent porosity) was vacuum-saturated with water and surrounded by concrete. To prevent reflected tensile pulses, the acoustical impedance of the concrete matched that of the sandstone. A 750-psig pressure was applied to a drilling fluid within a shaped-charge-formed hole before detonating the gauging charge. In these tests, 190 gm of rock were removed for each gram of explosive detonated. A similar series of experiments on low-porosity (0.40 per cent) metamorphic limestone provided a more rigorous test. Extensive fracturing from the gauging-charge action prevented an estimate of the volume of the expanded hole. The diameter of the hole was irregular, ranging from about 2 to 4 in, or about fivefold larger than the hole created by the shaped charge. INTRODUCTION In the past, explosives have found a varied but somewhat limited use in the oil field. An early well stimulation technique, still in use today, in vo lves shooting ni troglycerin to en large the borehole and to increase matrix permeability near the wellbore. Bullets and jets are now the conventional method of perforating casing and tubing. Detonations are frequently used to "back off" or "shoot off" stuck pipe and, of course, seismo-graphic work has long depended on explosive-generated pulses to find attractive earth structures. Efforts to use explosives in drilling operations have received limited examinations1-3 which, in one respect, is surprising because explosives offer one way to transmit large amounts of energy directly to the bottom of the hole. Recently, Ostrovskii l described a Russian method of drilling with explosives that utilizes small capsules containing explosives which are pumped into the mud stream to the bottom of a borehole. As the capsules leave the end of the drill pipe, a detonation mechanism is armed. Impact detonates the explosive. In another configuration, two liquids (an oxidizing agent and fuel) in the capsule are separated by a frangible membrane. Separately, the liquids are nonexplosive. Near the bottom of the drill pipe, the capsule passes through a narrow constriction which ruptures the membrane. The mixing of the liquids produces an explosive. Impact is again used to detonate the explosive. About the time Ostrovskii was developing his method, Humble Oil & Refining Co. was independently doing research on another explosive drilling concept based on the sequential detonation of two types -of explosive charges. The proposed technique consisted of alternately pumping a shaped charge and then a "gauging charge" down a well. The shaped charge should drill a long, tapered hole, and the gauging charge should expand it to full gauge. This paper presents the visualized drilling concept and gives results of laboratory work which showed that sequential firing of charges can form hole at an attractive charge-to-rock removal ratio. An important finding was that increased environmental pressure, which is to be expected in wells, increases rock removal efficiency of the gauging charge.

Jan 1, 1966

By G. B. Walker

The success of Heavy Media Separation, the static sink-float process, is evidenced by the operation of an estimated 300 installations treating many millions of tons per year of a wide variety of mineral products ranging in value from gravel to diamonds. The static heavy media process is usually limited to the treatment of plus 1/4 inch material. Mr. Victor Rakowsky, who was largely instrumental in the development and application of heavy media separation, recognized the need for a new apparatus and process which would extend the application of heavy media into the finer size range without placing a restrictive limit on the top size of the feed. He recognized the requirement for the application of centrifugal force to augment the force of gravity in separating fines by sink-float techniques.

Jan 1, 1966

By Wallace W. Key

This report concerns types, quantities, specifications, and uses of non-metallic minerals as a basis for improving their supply, conservation, and utilization. Supply-demand details concerning mineral fillers, roofing granules, and roofing rock used in asphalt are incorporated in this report, along with highlights on production and sales of roofing, floor tile, and other related asphalt products of California. Comparable data for the United States are included. Although large quantities of commercially prepared mineral fillers are used in asphalt for paving and related applications in other States, addition of commercial fillers for these uses rarely is required in California because of the natural fines available. On the other hand, California manufacturers of asphalt products other than paving utilize about 300,000 tons of asbestos, diatomite, limestone, mica, soapstone, slate, and other nonmetallic minerals as filler, mainly for roofing and flooring. Also, about 500,000 tons of roofing granules is produced in California, most of which goes into roofing manufacture in California. In addition, a significantly large and growing tonnage of relatively coarse mineral aggregates are used on low-angle, built-up, asphalt roofs to produce an attractive surface and offer protection against the elements. Nearly all minerals used in asphalt products manufactured in California come from local sources, except asbestos and mica--and there are indications that local deposits of these commodities could be utilized in some use categories.

Jan 1, 1966

By William A. Kneller

A considerable range of composition exists in rocks that have been described as chert, jasper, or flint. Their composition may be opaline, chalcedonic, quartzose, or mixed. Certain cherts, when incorporated in concrete, are known to possess nondesirable thermal and chemical properties. The inability of chert to withstand thermal shock above the freezing temperature of water is an example of such a property. Cryothermal reactions may cause disintegration of concrete, due to repeated cycles of freeze and thaw. Thermal properties are significant because small temperature changes may cause inordinate expansion and resultant fissuring of concrete. Freezing of entrained water in chert may cause excessive physical failure in concrete. Some cherts react chemically with alkalies liberated during the hydration of the cement, with resultant cracking and deterioration. Sources of concrete aggregate in Ohio have been viewed with suspicion because they contain considerable chert derived from Middle Devonian and Pennsylvanian carbonate rocks. Light-colored porous cherts from the Middle-Devonian Colum- bus Limestone exhibit the least freeze-thaw durability of the samples studied. Denser cherts may also yield to freeze-thaw stresses, but tend to be more susceptible to thermal shock. Cherts rich in opaline and chalcedonic silica usually exhibit alkali-aggregate reactivity.

Jan 1, 1966

By B. R. Richards, B. G. W. Robinson

"This paper shows how metal values can be profitably won from a comparatively small and remotely located but high-grade orebody. To do so is not uractical for a large mining company, with its necessarily high overhead of services and organization essential to a large producer.To evaluate, develop and profitably exploit a limited but defined ore deposit becomes only a problem of determining the dollars required to win the dollars available. This paper will record how this was carried out during 1965 and at the same time describe the history, development and production plant of this property."

Jan 1, 1966

By J. H. Brown

"THE need for continuing education has been recognized only in fairly recent years as a major concern of the engineering profession. Formerly, it was acknowledged that engineers were required, at least informally, to follow the professional literature and to give some attention to new technical and technological developments. However, those relaxed days, when progress could be followed in a casual or incidental evening of reading, have disappeared in these days of mushrooming information. The engineer is now in the position of the man trying to control the flow from a fire hydrant with a child's pail. Our problem is that of developing an effective flow system -be it trough, hose, pipe or a bigger pail.The first step in achieving an effective means for continuing the education process is to realize that the need for the system is really an outgrowth of an increasingly sophisticated society. It is merely one more symptom of that society; others would• include the facts that new engineering graduates are more highly trained than those of several years ago, that graduate schools are now the norm and that even some fairly recent technologies are becoming outdated. There-fore, let us examine the education-al systems from which the bulk of the increasing sophistication has grown."

Jan 1, 1966

By D. N. Madge

A survey is given of production scheduling systems currently in use or contemplated for future use in Cominco operations. Emphasis in this presentation is made on the chain of decisions that are made with the help of mathematical programming models. Some attention is devoted to the structural properties of the models.

Jan 1, 1966

By E. J. Kloos

The Bureau of Mines developed a test for evaluating gas masks designed to protect against phosphine gas; phosphonium iodide is used as a source of phosphine. Gas masks approved by the Bureau for respiratory protection against phosphine include the GMC-SS-1, Mine Safety Appliances Co.; the LG-10 and LG-10G, Willson Products Division, The Electric Storage Battery Co.; and the 084-PHOV-R, Acme Protection Equipment Co.

Jan 1, 1966

By James J. Scott

To the safety engineer, mine planning engineer, and mine inspector associated with an underground operation, stability of the underground structure is of the utmost importance. In the United States in 1961 rock falls killed 167 miners, crippled many more, and cost the industry a fortune in lost equipment and production. Much research has been carried on to try to find ways to eliminate this loss of life and property. Within the past few years the interest in rock mechanics as a science has been at its highest point, Private industry, government agencies, universities and foundations have launched studies to gain a better basic understanding of the stability of underground openings.

Jan 1, 1966

By William Butler

El presente texto describe las oportunidades que tienen las naciones menos desarrolladas para un progreso en el campo de los recursos naturales. Para ello, se revisan los inconvenientes ocurridos en el manejo de recursos minerales tales como: los mercados mundiales tienen un sobreabastecimiento que son pocas las probabilidades de ingresos por exportación, la inestabilidad de los precios no permite basar la economía de la nación sobre su riqueza minera, la explotación de los recursos, reduce la riqueza de la nación, los beneficios que puedan obtenerse como resultado de una mayor eficiencia en la producción minera en los países menos desarrollados, se vuelca a favor de las zonas industriales. Por lo tanto, no hay mayor esperanza para aquellos países en propender a una mejor explotación de los minerales. En ese sentido, aquellas naciones que buscan un rápido desarrollo económico, deben buscar un manejo adecuado de sus recursos y así asegurar una fuente de ingresos en divisas extranjeras que les permitirá financiar las importaciones necesarias para su crecimiento y, a la vez, acrecentar sus conocimientos técnicos, como el bienestar de un sector importante de su población.

Jan 1, 1966

By Clarence Karr

RESINS from a bituminous pitch, a bituminous coal, a lignite tar, a subbituminous pitch, and an electrode binder pitch wore investigated by the Bureau of Mines. The compositions of these resins were determined by four independent methods of structural detemination: (1) Molecular formula and ring analysis, including ring (2) infrared and ultraviolet spectra; (3) combined pyrolysis/gas chromatography, and (4) catalytic dehyrogenation followed by spectra and pyrolysis. The resin structure was correlated with coal structure, and it was concluded that pitch resins probably consist of essentially unaltered coal molecules carried over with the tar vapors in low-temperature carbonization.

Jan 1, 1966

By D. A. Barr

"The Galore Creek copper deposits are situated in the Stikine River district, 640 miles northwest of Vancouver, British Columbia. The deposits are primary cupriferous replacements localized in highly fractured zones lying in altered sedimentary, extrusive and intrusive rocks near the contacts of a potash-rich syenite porphyry complex which forms the core of a structural dome in Upper Triassic volcanic and sedimentary rocks. Ten deposits are distributed over an area of 3.5 by 2 miles and through an elevation range of 4,000 feet. The deposits share many of the characteristic features common to both the porphyry copper type of mineralization and pyrometasomatic deposits.Primary mineralization includes chalcopyrite and bornite, and is associated principally with pyrite and magnetite. The daminant alteration products are hydrothermal biotite and potash feldspar. Gypsum, anhydrite, garnet, chlorite and carbonate are commonly associated with sulphide minerals. Copper oxides, al-though present, are quantitatively of minor importance. The distribution of certain of the primary minerals reveals hypogene zoning characteristics.The results of stream sediment surveys, and airborne magnetic, ground magnetic and induced polarization surveys show important relationships to geologic structure and mineral deposits."

Jan 1, 1966

By Kenneth B. Higbie

Expenditures to advance scientific technology in general reached an all time high in 1965 with some $22.2 billion estimated to have been allocated by government and industry. Federal Government expenditures were estimated at $15.4 billion, with almost 90 percent of the funds devoted to programs involving defense, atomic energy, and outer space efforts. With this massive effort in the United States and a very impressive effort elsewhere in the world, there is little wonder that many new metallurgical developments were announced in the technical press during the year. No effort has been made to cover all aspects of the industry, but a few of the developments are described in this chapter.

Jan 1, 1966

By R. F. Burdyn

The inadequate use of centrifugation to economically recover solids from weighted drilling fluids reflects the need for better equipment and techniques for this putpose. Laboratory studies in the development of an improved separator are described in which an operating equation is derived and tested. Results show that the concentric cylinder geometry employed effectively separates bnrite from a suspension and that the operating equation provides a good approxinmtion for scale-up. INTRODUCTION Our current drilling technology frequently requires a high-density drilling fluid obtained by addition of barite. In the course of drilling, formation solids which are too fine to be removed either by screening or settling become suspended in the drilling fluid and gradually the volume of solids in the mud increases. The volume fraction of solids must be limited (if a satisfactory set of rheological parameters are to be maintained). A centrifugal separatorprovidesan economical way of accomplishing this. The barite recovery process can be considered as a separation of two solids. One, the light solids, composed of formation and added solids, has a specific gravity of 2.6 to 2.7; the other, barite, has a specific gravity of 4.2 to 4.3. This density difference, plus the fact that the average light-solids particle size is much smaller than the average barite particle size, permits separation by a centrifuge. In drilling fluids some of the coarse particles of the light-solids-range will settle faster than fine particles of the barite-particle range. As a result a complete separation of the two species is not possible. since the object of the process is not merely recovering the maximum amount of barite but includes as well removing the maximum amount of light solids, an optimum barite recovery efficiency exists. From a practical standpoint this optimum cannot be determined in the field for each drilling fluid system, and in practice the separation is less than optimum, with some sacrifice of barite. Drilling technology has included centrifugal separators for barite recovery for more than a decade. Results have been reported by a number of investigators indicating that the process is practical and economica1. l-4 The decision to use a centrifuge is based on economics in which direct cost savings and the indirect benefits in rig time derived from improvement of the drilling fluid are important factors. One would expect that centrifugal separation of barite from drilling fluids would significantly affect barite consumption; however, this is not the case. The Minerals Yearbook shows an annual domestic barite consumption in the drilling industry of nearly 1 million tons.5 By rough estimate there are perhaps 80 separators presently in field use. Assuming half of these in use at any one time, operating an average of four hours per day, at recovery rates averaging 3,000 Ib of barite per hour, total annual recovery is about 90,000 tons. This is less than 10 per cent of he total barite used. I conservatively estimate that barite consumption in drilling operations can be reduced by 30 per cent through greater utilization of centrifugal separators. To encourage more widespread acceptance of centrifugal separators in the drilling industry, improved equipment and techniques would be very desirable. The present paper, covering theory and results obtained from a laboratory model, is the first in a series on he development of an improved mud separator for field use. THE CONCENTRIC CYLINDER GEOMETRY AS A SEPARATING DEVICE Consider the geometry shown in Fig. 1, consisting of two concentric cylinders separated by an annular space. These are arranged so that the outer cylinder is fixed and the inner one can be rotated about its axis on shafts sealed against the ends of the outer cylinder. If the outer cylinder is fitted with openings at either end, the inner

Jan 1, 1966

By Staff, G. M. Hogg

"The eastern portion of the Late Precambrian geosynclinal structure known as the Labrador Trough comprises a 16,000-square-mile sulphide-bearing belt of good potential as a base metal exploration area. Hollinger and Hanna mining interests have carried on exploration in the region since 1953, with encouraging results. This program has been considerable in terms of both effort and expenditure, and has resulted in an apparently successful primary evaluation of the entire belt.Much detailed work remains to be done in the area. Exploration to date has been largely of a reconnaissance nature, employing various methods in common use in Canada today. In the course of this work, several deposits of promise, containing near-economic quantities of copper, zinc, nickel and other metals, have been located. A broad classification of these deposits is proposed.Exploration in the sulphide belt was started on the basis of partial control of the area under mineral exploration concessions. This was necessary to justify operations in an area of difficult access and high operating costs. The results of this now-terminated arrangement are regarded as being of benefit to those directly concerned as well as to the mineral industry in general."

Jan 1, 1966

By A. J. Forney

This report summarizes the findings of methods of treating caking coals in a fluid bed to destroy their caking properties. In batch tests it was found that several coals, including those with a free-swelling index greater than 8, could be decaed at temperatures from 400° to 425° C with a fluidizing gas composed of inert gas or steam containing 0.2 percent oxygen and a minimum residence LS,-;,' of 5 minutes. When treatment decreased the free-swelling index from about 8 to 1-1/2 or lower, the resulting treated coal was noncaking. In a continuous unit with continuous feed and discharge of coal, slightly more severe conditions were required to decake the coal. For 18- to 100-mesh coal a temperature of 430° to 440° C and an oxygen-to coal ratio of 0.4 cubic foot of oxygen per pound of coal feed was necessary. Finer mesh sizes required lower oxygen-to-coal ratios. In tests using air only as the fluidizing medium and treatment temperatures well below the softening range, the caking properties of 150- to 200-mesh coal were destroyed in 30 to 40 minutes of residence time at 200° C. Coarser sizes of 18 to 48, 48 to 100, and 100 to 150 mesh required longer residence time.

Jan 1, 1966

By N. Mungan

Formation damage, i.e.. reduclion in permeability, has been generally attribuled to clay minerals which expand or disperse upon contact with water that is less saline than the connate water. Luboratory, studies show that penneahility reduction can also occur in formalions containing only nonexpandable clays such as illite or kaolinite, and can be caused also by changes in pH. Furthermore, pH changes can damage even formations that are essentially free of clays. It is suggested that permeability reduction is due to the small passages being blocked by particles, which may be dispersed clays, cemenlion material or other fine parricles. These particles are dislodged by dispersion of clays due to changes in salinity or by dissolution of calcareous cement by acids, or of silicaceous cement by alkaline solutions. In working with reservoir cores, it was found that extracted cores damaged more easily and extensively than nonextracted cores. The extent of damage depended also on tenlperatltre. INTRODUCTION Permeability is an important property of porous media and has been the subject of many studies by engineers and geologists. Many of these studies are conccrned with formation damage, i.e., reduction in permeability, resulting from exposure of oil-producing formations to water substantially less saline than the connate water. This effect causes understandable concern since during drilling, completion and production phases formations are often exposed to fresh water. The damage resulting from contact with relatively fresh water has been attributed to expansion and dispersion oF clay minerals. During laboratory investigation of the use of NaOH as a wettability reversal agent to increase oil recovery from oil-wet reservoirs, several cores used in the displacement studies suffered loss in permeability. Despite the traditional usage of NaOH for conditioning aqueous mud systems, the role of the caustic filtrate in wellbore damage seems to have been overlooked. Browning2 as recently reported on the effects of NaOH in dispersing clay minerals but he was concerned only with complications that may arise in drilling massive shale beds. The following study was made to examine the role of pH and salinity changes in core damage. Where cores from reservoirs were used, tests were performed with extracted and nonextracted cores both at room and reser- voir temperatures, since it was felt that the test environment and core condition may affect the results. Because of its limited coverage and exploratory nature, this study is not intended to provide answers to field formation damage problems. It is hoped that it will encourage research into new aspects of the permeability reduction problems, particularly those allied to new recovery and production processes. PROCEDURE In all permeability tests, fluids were pumped through the cores at a constant volumetric rate. Only deaerated fluids and reagent grade chemicals were used. The fluids were passed through two ultrafine filters before injection to remove any entrained particles. The cores, with the exception of the unconsolidated cores, were mounted in Hassler holders. Water was used to transmit pressure to the sleeve. The inlet endpiece had two entry ports which permitted scavenging one fluid with another to avoid any mixing in the small holdup volume. The cores were flushed with CO2 gas, evacuated for 5 to 6 hours and saturated with the first liquid at a pressure of 1,000 psi for 24 hours to eliminate any free gas from the cores. Pressure differences up to 20 psi were measured by transducers, calibrated in inches of water and continuously recorded. For greater pressure drops, gauges were used. All reservoir cores were cleaned with a light refined mineral oil, then with heptane, and finally dried with CO2. Compatibility tests showed that no precipitates formed when mineral oil and the crudes were mixed. Some cores were extracted in Dean-Stark-type solvent extractors using xylene and trichloroethane and dried in a vacuum oven at 450F. Each test consisted of a sequence of water, test solution, and again water flow. RESULTS AND DISCUSSION STUDIES IN BEREA CORES Salinity Contrast Berea cores 2-in. in diameter and 12-in. long were cut from sandstone quarried in Cleveland, Ohio. The clay minerals were identified by X-ray diffraction to be chlorite, kaolinite, illite and incerlayered illite. Flow of fresh water or 30,000 ppm brinc does not cause any permeability reduction (Fig. 1). However, after injection of brine the core is readily damaged by fresh water. Damage starts almost instantly as the fresh water injection is begun, and at a cumulative injection of 1.2 PV fresh water, the permeability has dropped from 190 to 0.9 md. Upon continued injection, the effluent contains clay minerals dislodged from the core. The final core per-

Jan 1, 1966

By A. Satter

Studies of wellbore heat transtnission during the injection of a hot fluid, as either gas or liquid, have appeared in he literature. The present investigation takes into account the effect of condensation, which is of practical sig-nificance when considering steam injection operations. Calculation procedures are given for superheated and for saturated and undersaturated steam. Effects of injection rate, time, pressure, temperature and depth of a well on heat losses have been analyzed. The benefits of using a packer are discussed. Also presented are correlations for estimating heat losses involved during injection of saturated steam. INTRODUCTION Studies of wellbore heat losses during the injection of a hot fluid have appeared in the literature. Ramey' has presented a useful solution for calculating temperature of a heated gas as a function of depth and injection time. Ramey and others have also presented solutions for the hot liquid case.'. ' No method is available to take into account the effect of condensation, which is of practical significance when considering steam injection operations. This paper presents a method of estimating the quality of a condensing fluid as a function of depth and time. The approach is basically the same as that used by Ramey. The following injected fluids and conditions are considered in this study: 1. Injection of superheated steam A. Decrease in temperature until cooled to the saturated state B. Condensation until condensed completely into hot (saturated) water 2. Injection of saturated or undersaturated steam; condensation until condensed completely into hot (saturated) water. Although this investigation does not include cooling of water after steam is completely condensed, Ramey's solution for the hot liquid case can be used for this purpose. The effects of various process variables on heat losses During the injection of steam into a well are investigated. THEORY QUALITY OF CONDENSING STEAM Predicting the behavior of condensing steam flowing down the injection wellbore requires an estimate of the quality of steam, i.e., the mass fraction of vapor in the mixture. Let us divide the total depth of the injection well into several segments which might be, but do not have to be, of equal magnitude. Consider condensation within a given depth interval AZ, the bottom of which is located at a depth Z from the surface (Fig 1). The following equation, derived in the Appendix- relates the quality of steam at the bottom of an interval to that at the top of the interval:

Jan 1, 1966

By Philip A. Bucci

The Florida phosphate industry successfully uses froth flotation to concentrate phosphate in: the particle size range of approximately 28 to 150 mesh. However, as recently as 1965, coarse particles in the range of 14 to 28 mesh generally had not been beneficiated by conventional flotation methods at recoveries high enough to be considered adequate. It has been customary to upgrade this coarse material; by "agglomerate flotation" or "skin flotation" using belts, tables or spirals. While these devices have proved commercially effective, their capacities are much lower than those of froth flotation cells. To determine whether coarse phosphate material could be recovered successfully by froth flotation, Armour Agricultural Chemical Company began a series of pilot and plant tests; in April 1965. Objective of the tests was to compare over-all performance of a froth flotation cell design relatively new to the phosphate industry with results from the belt circuit at the Bartow, Fla., plant.

Jan 1, 1966