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The beach sand industry is the only Australian mineral industry which, so far, has used electrostatic separation on a full commercial scale. The main application of the process is for the separation of rutile from zircon. Laboratory work has demonstrated that electrostatic methods are effective for ilmenite-monazite and cassiterite-zircon separations, thus facilitating the production of high grade monazite and cassiterite products from top-strip table concentrates, but the commercial application of these processeshas been rather limited so far. Overseas, electrostatic methods are becoming more widely used for the treatment of granular material which is not amenable to flotation. The use of electrostatic separation for the treatment of ores other than beach sands has been investigated in this laboratory 1, 2, 3, and two pilot separators were built during i953 to carry out field tests. Of these, the first was an inclined feed plate separator for the removal of silica from granular lime-sand in Western Australia, the second a conductance roll separator for the removal of diamonds from alluvial gravel in New South Wales. In both cases the whole of the ore passed through the separator, not a gravity concentrate only as in beach sand practice. The two types of separator mentioned are shown diagramatically in Figs. 1 and 2.

Jan 1, 1954

By C. Goldberg, R. H. Wynne

WHEN using an optical goniometer to determine crystal orientation' it is advantageous to use a preferential etchant so that the etch pits have plane faces which are parallel to crystallographic planes, all of which are of the same "form." "Westinghouse Silver Etch" (WAg), a preferential etch for germanium, is made up as follows: 40 ml of 49.7 pct hydrofluoric acid, 20 ml of 70.7 pct nitric acid, and 40 ml of distilled water containing 2.0 g of silver nitrate. Examination of metallographs of WAg etched surfaces (Fig. 1, for example) indicates that, regardless of crystal orientation, the faces of the etch pits are (111) surfaces. Optical goniometer examination of these WAg etched surfaces also indicates that the faces of the etch pits are (111) surfaces, i.e., all bright reflections are from (111) planes. When using an optical goniometer of the type described by Barrett,' not only (111) reflections from a WAg etched germanium surface but also other reflections of lower intensity will be observed. These latter reflections can cause confusion. We have used an optical goniometer made from a war surplus astrocompass and a galvanometer lamp. The reflections are observed by using the goniometer in a darkened room and letting the reflected light be in- cident upon a piece of white paper. The resulting decrease of goniometer sensitivity enables (111) reflections only to be observed. This in turn permits the crystal orientation to be determined in a matter of minutes, since only two measurements are necessary. The authors wish to acknowledge the help received from R. E. Davis who assisted in making the metallographs and aided the authors in the interpretation of the metallographs.

Jan 1, 1954

By P. M. Gruzensky

A survey of the literature has been made covering the extraction of bismuth from raw materials, its separation from lead, and its subsequent refining. The use of aqueous, nonaqueous, and fused electrolytes in electrolytic refining is reviewed. This literature survey has been prepared preliminary to some proposed investigations concerning the electrometallurgy of bismuth, and, although an effort has been made to cover a majority of the applicable references, a critical review was not attempted and no assertion is made that this manuscript is exhaustive in nature. Titles of publications in parenthesis are translations from the language in which the reference was originally published.

Jan 1, 1954

By B. L. Averbach, M. Cohen, G. P. Conard

IT has been frequently observed that, when metal crystals are bent and annealed or when they are bent at elevated temperatures, the asterism of the Laue spots is split discontinuously into tiny intensity maxima. This finding indicates that segmented crystallites or subgrains are produced, which are relatively undistorted within themselves but which differ slightly in orientation from their neighbors. The following viewpoints have been put forward concerning the nature of this segmentation process: 1—Crussard' has described the phenomenon as "re-crystallization in situ." According to this mechanism, the deformed lattice recrystallizes on heating into an aggregate of comparatively strain-free subgrains separated from one another by low-angle boundaries and having nearly the same orientation as the original crystal. This process differs from the classical type of recrystallization in that the latter involves the formation of grains having quite different orientations from that of the mother crystal. 2—A similar but more detailed picture has been advanced by Cahn' who adopted the term "polygonization." In this interpretation, the plastic bending of lattice planes results in an excess of dislocations of one sign, but at suitable temperatures these dislocations migrate along slip planes and collect in localized regions to form an array of low-angle boundaries. Concurrently, the lattice segments between the boundaries lose their curvature and elastic strain. 3—The "cell formation" concept of Wood and co-workers: unlike the two hypotheses cited, postulates that the segmentation of the lattice is basically a mode of deformation and is not an annealing phenomenon. Cell formation appears to compete more effectively with respect to the normal slip process as the deformation temperature is increased and as the strain rate is decreased. The present work was performed on 3.2 mm diameter 99.99' pct Zn single crystals, grown from the melt in a gradient furnace. The major impurity was 0.003 pct Fe. The crystal orientations ranged from those with basal plane parallel to the rod axis to those with the basal plane almost perpendicular to the rod axis. The specimens were bent on templates to effective radii varying from 14.2 to 1.3 cm at the temperatures from —196" to 100°C. In each case, the axis of bending was parallel to the basal plane. Subsequent annealing was carried out at temperatures from —196" to 400°C. Back-reflection Laue pictures were taken on the convex surface of the bent specimens, before and after annealing. This procedure was found to yield better resolution of the detail in the diffraction spots than did the previously used Laue transmission technique. Some X-ray pictures of rods bent at —196" and —78°C were taken at these respective temperatures without intermediate warming to room temperature. In addition, bent crystals were acid cut" parallel to the basal plane, and double-crystal spectrometer rocking-curves were obtained from the etched (0001) face before and after increment an-

Jan 1, 1954

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954

By R. T. MacMillan

A number of chemical techniques have been applied to manganese ores from three areas of Aroostook County, Maine. Although large tonnages of these ores have been proved, they are low grade, and their exploitation has awaited a suitable beneficiation scheme. As conventional ore-dressing methods had failed to yield satisfactory results, attention was turned to chemical procedures. Leaching with dilute (7-percent) H2S04 extracted over 90 percent of the manganese from ore of the Dudley farm area, consuming 3.8 pounds of acid per pound of manganese extracted. Ores from the Littleton Ridge and Maple Mountain-Hovey Mountain areas were less amenable to this treatment, yielding approximately 80 and 60 percent of their Mn content, respectively. To increase the percentage extraction of manganese in the latter two ores, a number of factors were varied, including (1) acid concentration in the extracting solution, (2) ratio of acid to Mn in the slurry, and (3) preliminary heat treatment of the ore with a reducing agent. Other acids, including HNO3, HC1, and H2SO3, were tried also; however, no significant improvements in the Mn leached from Maple Mountain-Hovey Mountain ore were made. The manganese extraction of Littleton Ridge ore was raised to 90 percent by providing 9 to 11 pounds of HNO3 per pound of Mn in the ore.

Jan 1, 1954

By J. E. Hawley

"The zinc-lead deposit of the Lake Geneva Mining Company is on lot 7, con. VI, Hess township, Sudbury district, Ontario, about 10 miles northwest of the northern rim of the Sudbury Basin. Though a relatively small deposit, it shows some rather interesting relations to cross-cutting, pre-ore, quartz diabase dykes, which merit description.The deposit was discovered in October 1924 by J. H. Collins beneath iron-stained drift and oxidized sulphides. This proved to be the northwestern extremity of the orebody, the remainder of which extends southeast below swampy ground. Exploration began in 1927. In 1928 a vertical shaft was sunk to 250 feet and a level established at 235 feet. Later the shaft was deepened to 400 feet and new levels opened at 315 and 375 feet. In 1943 an inclined winze was sunk below the vein from the 315-foot level to a vertical depth of 640 feet, and two additional levels were opened at 525 and 615 feet respectively.The geology of the area has been described by T. T. Quirke (1), F. F. Osborne (2), F. J. Alcock (3), and Ralph Tuck (4). Private reports have also been made by Carl Tolman, J. E. Gill, and K. W. Fritzsche. Tuck's paper, covering the work completed to 1930, gives a detailed account of the character of the ore and enclosing rocks.Up to May 1944, when the property was closed, all ore above the 375-foot level and a small tonnage from below this elevation had been removed. Ore mined from 1941 to 1944 yielded the following:"

Jan 1, 1954

By Theo. Koulomzine

"The property of Consolidated Central Cadillac Mines, Limited, consists of 1,103 acres formerly held by Central Cadillac Mines, Limited, and Wood Cadillac Mines, Limited. Both mines have been partly developed to depths of 565 and 1,000 feet respectively, and from 1939 to 1943 they produced gold, with small amounts of silver and tungsten, having a total value of $2,208,528 from 377,489 tons of ore. The average grade of the ore was $5.85 a ton . Less than 10 per cent of the ore hoisted was discarded by sorting. New development work, carried out since the former Wood property has been purchased by Central Cadillac, has shown that the tonnage indicated by mine workings and diamond drilling exceeds 2,000 tons per vertical foot.The property lies between the claims of Kewagama Gold Mines, Limited, and Pandora Cadillac Gold Mines, Limited, and straddles the Cadillac 'break' for a length of nearly 1 ½ miles. The main workings are 1 3/4 miles east of the well-known O'Brien gold mine.GEOLOGYOutcrops are very scarce, with none at all of the most important horizons, so that the general geology shown in Fig. 1 is deduced mostly from underground workings and diamond drilling. Fig. 2 is a vertical cross-section and Fig. 3 a longitudinal section through the ore zone.The ore lies within a belt of Blake River volcanics which is approximately 600 feet wide and is flanked on the north and south, respectively, by Cadillac and Kewagama sediments. All the formations have a nearly vertical attitude. The Blake River belt consists essentially of well sheared volcanic tulfs, but associated with these in the northern part are a number of bands of iron formation and the central part, to a width of 100 feet, is occupied by talc schists, making the Cadillac fault proper. Intruding the volcanics south of the Cadillac shear zone are dykes of two types- finegrained aplite or quartz albitite, and porphyry; both consist essentially of albite and quartz and are distinguishable only by the grain size. They have the general east-west trend of the formations they intrude."

Jan 1, 1954

By L. D. Hall, D. R. Mash

The paper presents the results of experiments on the anelastic. behavior of gold, as manifested by grain boundary relaxation. Two grain boundary internal friction peaks are found for 99.9998 pct Au. It is found that the peaks are associated with primary and secondary recrystallization. However, the existence of two discrete peaks cannot be explained on the basis of grain size and shape alone. It is suggested that grain boundary stability, as determined by orientation, plays a role in the observed effects. EVIDENCE for the viscous behavior of grain boundaries in metals has been presented in recent years by several investigators, based upon studies of various anelastic effects, especially internal friction. KG1 has contributed greatly to this field, having put forward a coherent body of evidence for stress relaxation by the viscous intercrystalline flow mechanism. In this connection, he has made extensive use of pure aluminum (99.991 pct) as the test material, although he has also studied other metals and alloys, including pure iron (Puron).² Rotherham, Smith, and Greenough³ have studied the internal friction of pure tin, interpreting their results in a manner similar to that of KG. In view of the importance of such studies in shedding light upon the fundamental structure and behavior of the grain boundaries in pure metals, it appears that the use of a very pure test material which is inert to its environment should provide useful information on anelastic properties and the source of such behavior in pure metals. The present work was carried out on spectrograph-ically pure, 99.9998 pct Au, free of all impurities except for a trace of silver, estimated to be present to the extent of about 0.0002 pct. The term "pure gold" will hereafter refer to this very pure material. Gold of commercial purity, 99.98 pct, was also studied to observe the effects of small amounts of impurities. A pure gold "single crystal" specimen was also tested for comparison. The variation of the internal friction and rigidity modulus as a function of temperature was determined by means of a torsion pendulum apparatus employing extremely low stress amplitudes and a frequency of vibration of the order of 1 cycle per sec. A 12 in. length of 0.031 in. (20 gage) gold wire formed the suspension element. The apparatus was similar to that described by Ke.l The test procedure and the basic requirements to be met for obtaining useful experimental data by this method have been given elsewhere.1,2 It should be made clear that in all of the experiments to be described, the internal friction and rigidity were independent of the amplitude of torsional vibration. The semilog plot of amplitude of vibration vs ordinal number of vibration was a straight line. This was carefully verified for each internal friction measurement. The linear variation shows that the internal friction was independent of stress; i.e., that the specimens were not being cold-worked during testing. The reproducibility of the internal friction curves, which were obtained by cyclic heating and cooling, indicates that the gold was unaffected by its environment during the tests. The measure of internal friction adopted in the present study is the conventional "logarithmic decrement," defined as follows: log. dec. = l/n In A0/An [I] where n is the number of cycles or vibrations; A,, the initial amplitude of vibration; and An, the amplitude after the nth cycle. When the logarithmic decrement is small, the shear modulus, G, of the wire is proportional to the square of the frequency of vibration provided the length and radius of the wire are kept constant. A plot of frequency squared vs temperature gives the following ratio:' This expresses the fraction of the stress which has not been relaxed at a given temperature. Gr and Gv are the relaxed and unrelaxed moduli, respectively. The frequency of vibration in the polycrys-talline specimen is fp, and the frequency of vibration of a single crystal is f8. This latter quantity is obtained simply by extrapolating the linear, low temperature portion of the curve of frequency squared vs temperature for the polycrystalline specimens. The theory of viscous grain boundary stress relaxation as demonstrated by the anelastic behavior of metals has been discussed in detail by Zener4 and need not be reproduced here. Experimental Results Initial measurements of the internal friction of pure gold were carried out on specimens which had been drawn with no intermediate annealing, resulting in a material which had undergone approximately 99 pct reduction of area in final processing. Annealing was then carried out at successively higher temperatures starting at 400°F for 1 hr and proceeding in this manner to as high as 1600°F in 100°F intervals. After each annealing treatment an internal friction and rigidity vs temperature curve was obtained over the range from room temperature to the particular annealing temperature. The resulting internal friction curves did not exhibit well defined maxima (peaks), but rather several fairly flat

Jan 1, 1954

By W. A. Backofen, B. B. Hundy

THE pole figure interpretation in a recent paper' on the torsion texture of copper was questioned in discussion,2 nd a simpler alternative interpretation was proposed. In the hope of reaching a positive decision in favor of one or the other, further studies were undertaken with 70-30 brass and Armco iron. This additional work has not answered all the questions about torsion textures, but the new pole figures do offer support for the original interpretation and show that the texture is more complicated than the alternative suggests. From the previous paper,' the appropriate method of describing the texture in a twisted bar is known to be a pole figure plotted on a plane tangent to the surface of the bar. The axes of the pole figure are chosen to coincide with directions in the tangent plane which are parallel and at right angles to the bar axis (the longitudinal direction, L.D., and the transverse direction, T.D.), for these directions define symmetry axes of the texture. Therefore any ideal orientation that might be selected to represent the texture gives the crystallographic plane parallel to the tangent plane and the crystallographic direction parallel to the axis of the torsion specimen. A unique texture was assumed in the original interpretation, and the four ideal orientations, (112) [111], (111) [112], (110) [001], and (112) [131], were used in its description. Of the four orientations, the first three provide possible slip directions along the direction labeled T.D. in the pole figure, which is one of maximum shear stress in a specimen being twisted. The alternative, however, simply considered the texture to be made up of two components, one a [Ill] alignment along the specimen axis with a random orientation about the axis as in the wire texture, and the other a superimposed orientation (110) [0011. Experimental evidence for this simpler interpretation was derived from two observations: 1—twisting did not alter the orientation of a single-crystal torsion specimen of a brass in which an octahedral plane was perpendicular (and a [Ill] direction parallel) to the axis, and 2—deformation bands with approximately the (110) [001] orientation were seen to develop in the crystal during the test. The new pole figures were obtained with a brass and an iron torsion specimen of 3/4 and 1 in. gage length diameter, respectively. After annealing, polishing, and twisting, seven rods, about 0.030 in. in diameter and with different orientations, were prepared from material near the surface of each specimen; these were required for the method of constructing pole figures by using a Geiger counter as developed by Norton.5 Since the shear strain gradient in plastic torsion is linear, it was readily computed that the material supplying the brass rods had been subjected to a shear strain of about 3.2, and that supplying the iron rods had received a shear strain of about 2. All details concerning specimen design, testing procedure, rod preparation, and use of the Norton technique can be found in ref. 1. Only this procedure was followed in working out the (111) and (100) pole figures for brass, Figs. 1 and 2. However, X-ray photograms were also involved in the construction of the (110) pole figure for Armco iron, Fig. 3. The photograms were made according to the conventional transmission diffraction technique using a small sheet taken parallel to the specimen surface and etched to a thickness of about 0.0025 in. They were especially important in locating the boundaries

Jan 1, 1954

Jan 1, 1954

By H. Clare Horwood

"Two structures, a fracture zone and a shear zone, contained the two orebodies that yielded all the ore mined at the Gold Eagle mine. The orebodies are known as the Gold Eagle vein and the No. 1 shear zone. Both structures occur close to contacts between Timiskaming sediments, Algoman diorite, and later Algoman granite-granodiorite. The structures were produced by compressive forces from a south direction acting in the southern part of the McKenzie-Gold Eagle stock and in a cylindrically shaped inclusion of Timiskaming sediments.The mine, which exhausted its ore reserves and ceased operations in September of 1941, is on the east side of Mackenzie island, in the centre of Dome township in the Red Lake area.The Gold Eagle vein was located during the summer of 1933 by a surface exploration programme carried out under the direction of Alex Gillies. Sub-· sequent diamond drilling and underground exploration led to the installation of a mill, which came into production in October of 1937. The No. 1 shear zone was discovered and explored later from a drive on the 500-foot level. The mine produced a total of 40,204 oz. gold and 19,157 oz. silver from 223,628 tons of ore hoisted (180,095 tons milled) during its 4 years of mill operation.GENERAL GEOLOGYThe ore-bearing structures trend S.61°E. across Timiskaming greywacke, Algoman diorite, and later Algoman granite-granodiorite. The greywacke is a large, cylindrically shaped mass that is separated from the mai~ mass by the later intrusives. It is a massive, light-coloured, quartzose variety that has been recrystallized by the enclosing granite. The diorite and the granite-granodiorite are early and late components of the McKenzie-Gold Eagle stock. The diorite, which is a porphyritic rock containing large crystals of andesine-labradorite surrounded by hornblende, was injected early in the Algoman period. It was intruded and in large measure surrounded by the later granite-granodiorite. This rock varies from a granodiorite near the mine to a granite in the centre of the stock. All three intrusions are massive and homogeneous."

Jan 1, 1954

By A. J. Barry

Recent developments in mechanizing longwall it mining in Europe have aroused considerable interest among American coal-mine operators because this method provides an opportunity to improve safety, production, efficiency, and recovery. The success of longwall mining in Europe has depended to a large degree on development of effective roof-control systems. One of the major contributing factors in designing these systems is development off improved supports, which combine high load-bearing capacities with controlled yield characteristics, to use in the face areas. Other factors that relate to successful longwall mining involve knowledge of the structural properties of the strata above end below the coal bed being mined, movements of these strata induced by mining, and effects of the strata movements on the strata itself, as well as on the support system used. Extensive studies of the above factors relating to long-wall mining have been made in coal-mining countries abroad, and corresponding studies (1, 2, 3, 4, 5)3/ of room-and-pillar operations have been made in this country. Although descriptions and results of experiments of mechanized longwall operations in the United States have been published (6, 7, 8), this is the first instrumented study of roof behavior on a longwall operation. In view of the possible widespread application of this method of mining to American coal mines, where underground mining conditions are different from those found in European mines, an investigation was conducted at a mechanized longwall operation inn the Lancashire No. 15 mine, Barnes & Tucker Co., Cambric County, Bakerton, Pa., to study the factors that affect roof control. This report describes this investigation and discusses the results. ACKNOWLEDGMENTS This investigation was made under a cooperative agreement between the Bureau of Mines and the Barnes & Tucker Co., Barnesboro, Pa., end was conducted in the Lancashire No. 15 mine located at Bakerton, Cambria County, Pa. The authors acknowledge the cooperation given by Richard Z. Todhunter, Sr., president, Richard T. Todhunter, Jr., general manager, and other mine officials and employees of the Barnes & Tucker Co. Mr. Edward Thomas, chief, Roof Control Section, Bureau of Mines, Washington, D. C., and Dr. Leonard Obert, chief, Applied Physics Branch. College Park, Md., collaborated in the planning and promulgation of the program investigation.

Jan 1, 1954

By G. W. Jones

The Bureau of Mines has advocated the use of stenches as warning agents in metal mines and in gas-distribution systems since 1920 A considerable amount of research has been conducted on ethyl mercaptan and other compounds to determine their effectiveness when used for this purpose.4/5/6/7/8/9/10/11/12/13/ Miners are warned of danger by a stench injected, in measured quantity, into a compressed-air line through which it is rapidly carried to the working faces, where it escapes from the compressed-air equipment and imparts a characteristic odor to the air. This method is not applicable to mines where only a limited number of com-pressed-air lines are used, as for example, many coal mines; the ventilation currents available in these mines may be too slow for warning purposes.14/

Jan 1, 1954

By P. A. Fisher, J. B. Wilson, D. J. Whitehead, C. J. P. Ball, A. C. Jessup

The properties of a new magnesium alloy ZT1 containing 3.0 pct Th, 2.5 pct Zn, 0.7 pct Zr are described. The alloy possesses good creep and fatigue resistance up to 650°F, is free from microporosity, and is readily sand-cast. ZT1 is shown to be superior to zinc-free Mg-Th-Zr alloys. THE advent of the jet engine created a demand for a light sand-casting alloy capable of being cast into large complex shapes and capable of resisting creep at temperatures up to 500°F. This demand has been largely met by alloys of the magnesium-cerium mischmetal-zirconium types, containing about 3 pct Ce mischmetal and 0.7 pct Zr, typified by Elektron magnesium alloys MCZ and ZREI, the latter alloy also having a zinc addition of 2.5 pct. These alloys utilize the valuable properties at elevated temperatures conferred by the addition of rare earth metals to magnesium, a fact which has been known for many years and discussed by several investigators.1-1 Murphy and Payne8 showed that the addition of the powerful grain-refining element zirconium to Mg-Ce mischmetal alloys produced alloys with attractive room temperature properties combined with good creep properties and castability. With the increasing power of modern jet engines the temperatures to which some of the magnesium parts are subject are likely to exceed the safe working range of the cerium-mischmetal-containing alloys, and at the beginning of the research considerable interest had been shown by aeroplane engine designers in a magnesium sand-casting alloy suitable for service at higher temperatures, e.g., 600°F and above. At an early stage in the development of this type of alloy a check on the fatigue properties at elevated temperatures indicated that, since the fatigue limit even at 108 eversals was appreciably higher than any permissible creep stress, the main emphasis of the research could be concentrated on creep behavior. The primary aim in developing the new alloy has therefore been to attain maximum creep resistance; but due consideration has also been given to other important properties such as castability, tensile strength, and cost. It is by now well established that it is not possible to correlate creep strength with other short time mechanical properties such as are obtained in tensile

Jan 1, 1954

By F. R. Cattoir, R. W. Kimball, C. T. Anderson

ONE of the principal impurities in all steels is sulphur. Sulphur-bearing, manganese-free steels exhibit hot shortness. Manganese is added to steel to improve the hot-working properties. If no sulphur were present in steel, it is probable that hot shortness would be nonexistent. This paper is the first of a series to be issued by this Laboratory reporting the measurements of hot forgeability tests and the physical properties of Fe-C alloys to which additions of various alloying elements have been made. The present paper describes the results- obtained by the addition of varying amounts of sulphur to Fe-C alloys. To obtain control over residual elements in the various charges melted in the arc furnace, it was considered advantageous to use sponge iron from one source as the melting stock rather than scrap metal having an unknown history. Small amounts of unwanted alloying elements might be introduced into the charge when scrap was used, thereby influencing the results of the various heats. A sponge iron having a high silica-lime ratio was used. Ore from Sunrise, Wyo., had been reduced to sponge iron and briquetted at the Bureau of Mines sponge-iron plant at Laramie, Wyo. The briquettes were 5 in. in diam and 2 to 3 in. in thickness, and weighed about 10 lb each. The chemical analysis of the sponge iron is as follows: C, 0.67 pct; Mn, 0.10; SiO2, 4.75; CaO, 1.4; P, 0.044; S, 0.72; MgO, 0.4; A12O3, 1.1; total Fe, 87.5; Fe metallic, 79.2; and reduction, 90.5 pct. Where a reducing agent was required, crushed graphite electrodes usually were used. The charcoal available contained 0.20 pct S. An analysis of the available coke showed it to contain 0.70 pct S. Where high sulphur heats were required, elemental sulphur additions were made to the ladle. Limestone of good quality was obtained locally and had the following analysis: CaO, 53.7 pct; MgO, 0.8; ignition loss, 42.4; R2O3, 0.2; SiO2, 3.0; and P2O5, 0.014. Melting Procedure Sponge iron was melted to produce metal stock for the experimental alloys in a silica-lined, three-phase, direct-arc, size ST, Moore Rapid Lectromelt furnace with a 500 kva rating. Fig. 1 shows this furnace installation. About 25 tons of sponge iron was melted in 75 heats, averaging 927 lb of sponge iron to the heat. An addition of carbon was required to complete the reduction of a portion of the iron oxide remaining in the sponge to prevent high losses of iron oxide in the slag and a low carbon content in the resulting metal. As reducing agents in preparing the melting stock, charcoal, coke, and a carbon product resulting from the thermal decomposition of natural gas were used. The quantity varied from 20 to 60 Ib per furnace charge, with an average of 38 lb. An average analysis of the metal obtained gave 0.52 pct C, about 0.01 pct Mn, 0.070 pct P, and 0.092 pct S. The average yield of metal was 647 lb with 241 1b of slag, the sponge-iron recovery being 70 pct. The metal obtained in melting the sponge iron was cast into pigs weighing about 20 lb each to facilitate recharging into the furnace for further refining. The pouring of the pigs is shown in Fig. 2. The average power consumption for the production of the 24 tons of metal obtained was 1704 kw-hr per ton.

Jan 1, 1954

Jan 1, 1954

Jan 1, 1954

By L. B. Berger

This information circular is a revision of I.C. 7238, Danger from Carbon Monoxide in the Home, by L. B. Berger and H. H. Schrenk, issued in April 1943. Each winter brings its toll of deaths and serious accidents from the deadly gas, carbon monoxide. Newspapers carry warnings to the public of the, dangers of this gas, and frequent news items report the finding of persons dead at unconscious from the effects of carbon monoxide, yet these accidents continue. Either these warnings are not read, or they are unheeded by people who feel that, "It can't happen to me." It can happen to you carbon monoxide is no respecter of persons.

Jan 1, 1954

By J. P. Nielsen, H. Margolin, E. Ence

The Ti-Ni phase diagram has been investigated up to 68 pct Ni with iodide titanium base alloys by metallographic, X-ray, and melting point methods, and from 68 to 90 pct Ni by examination of as-cast structures of sponge titanium base alloys. NVESTIGATION of the nickel-rich portion of the I Ti-Ni phase diagram was first reported by Vogel and Wallbaum in 1938.' This work was subsequently extended to lower nickel contents by Wallbaum' who indicated the possibility of a eutectic reaction for nickel contents below 38 pct. Long et al.3 studied the titanium-rich portion of the phase diagram and found eutectic and eutectoid reactions below 38 pct Ni. However, the temperature of the eutectic indicated by Long et al. was considerably lower than that suggested by Wallbaum. Long and his coworkers synthesized their alloys by powder metallurgical techniques and encountered oxygen and/or nitrogen contamination. Thus the diagram which was obtained did not represent binary alloying conditions. However from these results the features of the binary diagram were predicted. At Battelle Memorial Institute4 the Ti-Ni diagram was investigated up to approximately 11.5 pct Ni with sponge titanium alloys. The range of temperatures used was not sufficient to define the eutectoid temperature or composition. The data of Wallbaum2 and Long et al.8 were of particular interest for the present study, and although the work was originally concerned with the region below 40 pct Ni, the investigation was extended to higher nickel contents in an attempt to resolve the differences between these workers. Experimental Procedure Preliminary work on the Ti-Ni system was carried out with duPont Process A sponge titanium alloys to reduce the amount of subsequent work to be done with iodide titanium base alloys. The sponge titanium used contained 99.71 to 99.77 pct Ti, 0.1 pct Fe and 0.005 to 0.009 pct Ni. The iodide titanium obtained from the New Jersey Zinc Co. contained 99.9 to 99.95 pct Ti. Nickel used with sponge titanium was 98.9 pct pure. The high-purity nickel alloyed with iodide titanium was cobalt-free with approximately 0.05 pct C and was obtained through the courtesy of the International Nickel Co. The 15 g sponge titanium charges for melting were prepared by compacting in a die or by placing the weighed portions of nickel and titanium directly into the furnace. Iodide titanium charges were made by drilling holes in the as-received rod and inserting the nickel or by wrapping the nickel in sheet. Sponge titanium alloys containing from 0.2 to 90 pct Ni and iodide titanium alloys containing 0.2 to 68 pct Ni were prepared by these methods. In addition to these alloys several 1/2 1b sponge titanium alloys were supplied by the Allegheny Ludlum Co. The charges were melted in an arc furnace under an argon atmosphere. The procedures used were similar to those reported in the literature5,' and the furnace has been described.' Except for iodide titanium alloys with 40 to 68 pct Ni (see section on copper contamination), each alloy was melted for 1 min, then either turned over or broken before re-melting for an additional minute. Currents of 200 to 400 amp were used depending on the melting point of the alloy. Prior to heat treatment, alloys containing less than 14.5 pct Ni were hot-forged at 750°C. With the exception of alloys in the homogeneity range of the compound TiNi, alloys of higher nickel contents could not be hot-forged. Heat treatment of iodide titanium base alloys was carried out in argon-filled quartz capsules which were broken under water at the conclusion of heat treatment to quench the specimens. Temperatures were controlled to ±5oC and annealing times up to 48 hr were used. For melting point determination, specimens were placed in carbon crucibles which were in turn en-capsuled in argon-filled quartz capsules. The start of melting was determined by rounding of corners and by metallographic examination. Complete melting was considered to have occurred at that temperature at which the specimen assumed the shape of the crucible. Specimens were prepared for metallographic examination by mechanical polishing or by an electrolytic procedure." For alloys containing up to 80 pct Ni Remington A etch7 50 pct glycerine, 25 pct HNO,, 25 8 HF) was used. For higher nickel alloys aqua regia and Carapella's etch (5 g FeCl,, 2 ml HNO,, and 99 ml methyl alcohol) were employed. Specimens to be exposed for powder patterns were prepared by filing, by breaking specimens in a

Jan 1, 1954