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By B. Waterman, R. Collins, V. R. K. Paruchuri, P. Gonzalez, H. Dijkman

"INTRODUCTION Mining and processing of sulfide ore bodies has the potential to solubilize sulfate. Gypsum in the host rock, as well as oxidation of sulfides during milling and processing can solubilize sulfate. Acid rock drainage (ARD) also has the potential to generate waters high in sulfate. Even after treatment of the ARD with lime, the treated water can have sulfate present in gypsum saturation levels. Most mine-sites reuse sulfate impacted water but as a mine nears closure, reuse options may be limited and water treatment becomes an option. Furthermore, sulfate discharge requirements, particularly for anti-degredation narrative standards, can be very strict. Freeport has investigated many new technologies to economically remove sulfate from these types of water. A Dutch company, Paques B.V. developed one of these technologies and it utilized biological reactors to convert sulfate into elemental sulfur in a 2-step process. In 1992 the first industrial reference of the SULFATEQTM technology was commissioned at the Nystar Budel zinc refinery in the Netherlands. PILOT PLANT TECHNOLOGY AND DESCRIPTION As shown in Figure 1, the plant contains several process steps, which can mainly be divided into the following sections: 1. Anaerobic biological system in which sulfate is reduced to hydrogen sulfide by sulfate reducing bacteria. 2. Aerobic biological system in which hydrogen sulfide is oxidized to elemental sulfur by sulfide oxidizing bacteria. 3. Solid/liquid separation in which sulfur, calcium carbonate and biomass solids are separated and dewatered. Sulfate impacted ground water is pumped to the feed water tank through a plate and frame heat exchanger to maintain the solution temperature around 95°F. A custom mix of micronutrients is dosed to the feed tank. This nutrient mixture provides essential elements for the growth of anaerobic and aerobic biomass. Urea is added to the feed tank and provides the required nitrogen source to the biomasses. The pretreated feed water is pumped into the anaerobic reactor. The reactor works on the gas lift principle. Sulfate reducing bacteria utilize hydrogen gas as electron donors and reduce sulfate to hydrogen sulfide. This reaction increases the alkalinity of the solution. Carbon dioxide gas is added in order to control the pH within working range of the reactor. Due to the low solubility of the hydrogen gas, the anaerobic gas mixture is recycled through the system. The gas mixture recycle also provides the gas lift for mixing within the anaerobic reactor."

Jan 1, 2016

By M. G. Manzone

Approximately two-thirds of the annual 210,000 tons at copper refined by AMAX Inc. at the United States Metals Refining Company in Carteret, New Jersey, comes from a wide variety of copper scrap ranging from low-grade smelter scrap to wirebar-grade material. The equipment and methods used to effect such large-scale metal recycling in an urban area and the measures taken to collect and recover metal values from smelter and refinery byproducts while protecting the environment from pollution are described and discussed.

Jan 1, 1977

By S. Schwartz, T. Bilney

"Over recent years a number of techniques have been developed as part of the AMIRA1 P9 project to represent mathematically or measure directly sub-processes occurring in flotation cells. These include the determination of:•,?a machine parameter (bubble surface area flux, Sb);•,?a froth parameter (froth recovery, Rf );•,?entrainment and drainage parameters (???and d); and•,?an ore floatability parameter (Pi).These flotation parameters allow the plant engineer to develop a model of the flotation circuit that can be used as a powerful tool to diagnose the performance of that circuit. The recently developed JKSimFloat V6 flotation simulator uses these parameters to predict the flotation circuit performance that would arise from changes in operating conditions and circuit configuration.This new flotation technology was applied to the Placer Kanowna Belle Gold Mine in Western Australia. A series of plant surveys, cell characterisation measurements and laboratory batch tests were conducted to determine the flotation circuit model parameters to be used within the JKSimFloat V6 simulatorA thorough flotation circuit analysis was then performed at Kanowna Belle using JKSimFloat V6. The recommendations that were provided by this circuit analysis have resulted in large improvements in the flotation performance at Kanowna Belle. These include a 1.3% increase in flotation gold recovery and a substantial decrease in operating costs. The analysis is still ongoing, however, the benefits already obtained from applying this technology have resulted in a US$1.3 million a year improvement to the mine."

Jan 1, 2005

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By Zhang Chuanfu

The fibrous nickel oxide powder was prepared by the method of chemical precipitation and pyrolysis, that is, the NiO precursor was firstly precipitated from nickel ions solution with addition of oxalate salt and then the final NiO powder was obtained by pyrolysis of the prucursor. The effects of the pH, reaction temperature, reactant concentration, addition of surfactant on the morphology of the precursor particles were investigated. The influences of the various conditions, including the temperature and time, the air flow and the speed of the temperature increase on the morphology, average size and specific surface area of the NiO particles were also addressed. The fibrous NiO particles with IOO~ 120 in axis/diameter ratio and 5.5 m2/g of the specific surface area may be produced under certain operation conditions by this process.

Jan 1, 2003

By T Baard, A Pieters

This paper deals with the design and implementation of a 17 MW (nominal) surface cooling installation at Impala Platinum No 14 shaft located in Rustenburg, North West Province, South Africa.The cooling requirements included the installation of a surface ammonia refrigeration plant complete with the storage of hot and cold mine service water for underground use. It was also necessary to install a surface bulk air-cooling facility, which cools 400 kg/s of ventilation air going to the underground workings. Primary cooling is to the surface bulk air cooler. The cooling duty of a surface bulk air cooler is heavily dependent on the ambient wet-bulb temperature. Because of the daily wet-bulb temperature variation in this part of the world, use was made of a cold thermal storage facility of four million litres. The excess chilled water is stored during the night, for use by the main drilling shift during the day. This keeps the refrigeration machines as close as possible to full load during the summer, thus maximising the use of the capital expenditure. This paper discusses the control philosophy used to maximise the cooling output, as well as the thermal process. The project consisted of two phases resulting from the underground development phases of the mine. The first phase started in January 1999 and was commissioned by the end of the same year in record time. The final commissioning of the second phase took place at the end of 2002. The most difficult part of the construction phase was the tunnelling of a subsurface air duct from the bulk air cooler to the operating vertical shaft. This was done without disruption to the hoisting of men, material and ore in the shaft. Owing to the size of the refrigeration machines, the ammonia quantities involved and the application on a mine (no ammonia can go underground, either in the service water or in the mine air) special precautions had to be taken. South Africa has developed high standards for ammonia refrigeration plants used on mines, which will be partially dealt with in this paper.

Jan 1, 2005

By S. G. Hardcastle, C. K. Kocsis

"Worldwide, metal mines are going deeper. For example, in Canada there are six such mechanized mines planning production at 3000 m (10 000 ft). Working at such depths challenges all aspects of mining including the provision of ventilation to supply an equitable working climate for personnel and machinery.This paper explores the overall challenges of supplying ventilation in Canada’s deepest mines and how the volumes required could be minimized. This is essential because it must be remembered that ventilation and refrigeration are not only costly items to supply, but the magnitude of their cost is also very sensitive to the volume supplied. For the primary ventilation system this is obvious because of the cubic relationship between volume and cost.In deep mines, the main function of ventilation is the removal of heat transferred from the strata and generated by the mining machinery, and the air volumes supplied are designed accordingly. The second consideration is the removal of other pollutants that could be harmful to humans such as diesel and explosive fumes. However, the need for ventilation at its present design levels could be reduced. This paper discusses the implications of such technologies as: tele-remote mining and alternatives to diesel equipment on the magnitude of the volume supplied; ventilationon- demand which recognizes ventilation as a costly and limited resource; plus other aspects, such as the benefits of controlled recirculation, local cooling, and possibly heat rejection back to the strata to gain further advantage from new developments.Furthermore, this paper advances the need to be able to design ventilation systems more cost effectively and how such new advances as process simulators can be used in conjunction with ventilation simulators to explore the diverse options that could affect the air volumes required and provide more realistic economic data upon which to base design decisions."

Jan 1, 2004

By J Planner

As Australia’s coal and iron ore export volumes increase to meet international market growth, port terminals, mining operations and rail transport systems can be the source of increased dust emission. Current and future sustainable expansion must minimise dust emission from bulk handling and transport operations located in close proximity to residential areas. Lower level dust emissions can be controlled by operational measures such as water addition to products, and use of water spray on stockpile surfaces. Recent research has shown that higher levels of dust emission can be more effectively controlled by understanding and treating the dust characteristics of each individual bulk product. Application of this research, progressively being applied at Australia’s coal and iron ore port terminals and rail transport systems, is achieving compliance with health standards and minimising dust nuisance effects to an acceptable level.

Nov 22, 2011

By H. S. Price, R. L. Reed, J. E. Warren

The behavior of the reverse-combustion process in a linear adiabatic system is theoretically investigated by means of an idealized physical model. T his model is described by a pair of non-linear equations involving heat and mass transfer which are coupled by a concentration-dependent reaction-rate function of the Ar-rhenius type. The differential equations governing the quasi steady-state temperature and concentration distributions are approximately solved by using either physical or mathematical simplifications. It is shown that the reverse -combustion process can be mechanistically described by simple physical models whose behavior equations can be solved formally. It is further demonstrated that the derived reverse-combustion equations can be solved numerically within the error limits for the experimental data. The theoretically predicted peak temperature-flux-velocity relationship exhibits reasonable agreement with experimental data obtained from Athabasca tar sand. The principal contribution of this work lies in its usefulness as a starting point for developing a more comprehensive theory. A description of the vaporization-coking process must be obtained; then, the theory must be extended to three dimensions to include geometrical effects and heat losses. INTRODUCTION In another paper,'" he physical processes visualized as occurring during reverse combustion have been described. In this paper, the extent to which an elementary theory can account for experimental observations is determined. Theoretical results that can be used to estimate some of the behavior characteristics of importance to this process are also presented. Since it is not possible to include all the features of the combustion mechanism of which we are currently aware, the mathematical formulation refers to the highly idealized system developed herein. This simplified physical model is based on the simultaneous transfer of mass and heat accompanied by a chemical reaction: it is described mathematically by a pair of coupled, nonlinear differential equations. Similar sets of equations have been studied extensively in the field of flame propagation; an excellent review of these investigations has been published by Evans.1 FORMULATION OF THE PROBLEM It will be recalled that the experiments are performed with a thin-walled cylindrical tube that is uniformly packed with sand and oil. The system is maintained substantially adiabatic by means of heat supplied externally in such a way that the radial temperature gradient in any plane normal to the axis of the tube approaches zero. Initially, the tube is at ambient temperature, except at one end where it is rapidly heated to a predetermined temperature. When the prescribed temperature is achieved, air is caused to flow into the cold end of the tube. As the oxygen in the air stream contacts the hot oil, a localized exothermic reaction takes place. The generated heat is conducted and convected away from the reaction zone so that definite temperature and concentration profiles are rapidly established and move uniformly in a direction opposite to that of the air flow (Fig. 1). As a consequence of this mode of oxidation, all of the oxygen in the air is consumed; then, the remaining nitrogen and the gaseous combustion products sweep out all vaporized hydrocarbons and leave an immobile hydrocarbon-coke on the sand.

By PHILIP N. MOORE

THE development of the power of the Tennessee River at Muscle Shoals has become a matter of political interest as well as engineering possibility. The controversy over it has been so active that the facts have been obscured, the possibilities exaggerated. Although the members of the American Institute of Mining & Metallurgical Engineers are not generally specialists in hydroelectric development, those who visited Muscle Shoals in October, following the Birmingham meeting of the Institute, were interested, and many of them surprised to learn the actual conditions. These have long been familiar to those who have studied the matter through the reports of the U. S. Engineers on the subject. The approved plan contemplates three dams-No. 1, a low dam close to the City of Florence, planned in the interests of navigation, since the construction of the other dams has rendered impossible the use of the river without it. No. 2-named the Wilson Dam is now under construction. Concerning it political argumentation has waged. No. 3 Dam-much smaller, is planned to be erected several miles above No. 2.

Jan 1, 1925

By AIME AIME

Further details of the 97th meeting of the Institute, at Spokane, have been sent to members in the Special Circular of May 8, 1909, and for convenience a summary of the additional information is given later in this announcement. In spite of the present small number who have joined the party, final arrangements have been made to complete the itinerary given in the circular. It is greatly to be desired, both in behalf of the Institute and in recognition of the special courtesies to be extended on the trip, that the party be made larger. Exceptional facilities to visit the many mines and smelters have been freely provided; and members are requested to make all reasonable effort to attend the meeting at Spokane and participate in the excursions. . For those who cannot take the entire trip, it may be possible to provide special Pullman accommodations after leaving the Yellowstone Park. In order to make the necessary arrangements, however, the names of members and guests contemplating this partial trip should be sent at once to Mr. Theodore Dwight, .39 West 39th St., New York, N. Y. A special train of Pullman cars will leave Chicago September 16. This train will be side-tracked at all places visited, and the sleepers will be available for lodging and the dining-car for meals (luring the entire trip, except while taking the tour through the Yellowstone Park. The general cost of the trip per member will be $300, which includes transportation, berth, and meals for the entire trip from Chicago back to Chicago, almost 6,000 miles, and the tour through Yellowstone Park, occupying in all about 30 days. Special accommodations on the train will be furnished at the following rates

Aug 1, 1909

By J. H. Dietz

The electric assist option for diesel-electric trucks can improve truck productivity while maintaining the inherent flexibility of a truck and shovel operation. In addition, the resulting cost reductions offer a rapid investment payback for many mine situations. A review of the present technology and performance experiences verify the projected benefits in productivity and operating cost. New technologies can further improve the productivity/cost scenario.

Jan 1, 1984

By J. E. Udd, L. P. Geldart, B. B. Dhar

"Solutions for the stress distributions around simulated underground openings have been limited to calculations of boundary stresses for simple openings in which the boundaries may be expressed in mathematical terms. Studies involving circles, ellipses and ovaloids are re-ported in the literature.The stresses on the boundary of an opening and those at a distance from it in the medium are of concern to the engineer. The former may be related to the greatest concentrations of stresses encountered; the latter have a bearing on the identification of the ""zone of influence"" of the opening.Recent advances, in the form of a derivation for the stresses at a distance from an opening of elliptical shape, together with a solution derived previously for stresses in depth around ovaloidal openings, have been combined with computer programming techniques to provide complete solutions for a wide range of cases and variables. Some typical results which, it is hoped, may have some application to the design of underground openings are given herein."

Jan 1, 1970

By N. Greninger

The Bureau of Mines conducted a laboratory study of the measurement of the water and rock dust (RD) contents of synthetic mine-type coal dust (CD) mixtures using a commercial unit for measuring water content and several prototype radiometric units for measuring the RD content. The RD content ranged from 50 to 100 wt pct and the added water (AW) ranged from 0 to 15 wt pct. The total water (TW) content (intrinsic (IW) and AW) of a small dust sample could be readily measured automatically by essentially untrained personnel using a commercial unit. The RD content of a sample containing only IW could readily be measured by moderately trained personnel using several radiometric units. With gamma-ray devices, about 300 g of sample is needed. With the improved beta-ray device, about 25 g of sample is needed. With dry mine dust samples, the estimated RD error range for gamma-ray devices is 0.8 to 2.3 pct and 0.5 to 1.0 pct for beta-ray devices. However, the radiometric measurement of RD content was questionable if the dust mixture also contained AW or if it was uncertain whether the dust mixture contained AW.

Jan 1, 1988

By H. R. Manouchehri

"In all electrical beneficiation methods, the difference in electro-physical properties of the contributed mineral particles, essentially frictional charge, electrical conductivity and dielectric constant properties are exploited to achieve separation. The composition of the raw material determines what kind of either corona charging, conductive induction, or triboelectric separation method should be employed. The process is versatile and is influenced by different parameters related to mineral characteristics, surrounding ambient conditions and electrical and mechanical attributions of the separating device. Electrical separation is surface based beneficiation method which is mainly affected by the surface and surface changes of the minerals. Therefore, it is essential to understand how the electrophysical properties of the minerals can be changed/modified. During electrical/electrostatic separation process, both charge magnitude and its polarity that developed on the particles and therefore, their electrical beneficiation potential is essentially defined by surface phenomena. Therefore, it is essential to understand how the main electro-physical parameters can be changed/modified with applied surface treatment/pretreatment methods to promote separation. Surface treatment of minerals is carried out by different means, including chemical conditioning, irradiation, thermal treatment, etc. This paper discusses and analyze the electrical separation process, electrophysical properties of the minerals with special focus on the effect of surface pretreatment/treatment methods to affect electrical beneficiation potential of the minerals. The surface treatment methods vary in a wide range from simple surface cleaning to more complicated chemical conditioning and doping. The knowledge of the solid-state physics and chemistry leads to improve the beneficiation potential of different mineral systems by choosing suitable treatment method(s). Despite the complexity and multiplicity of the charging mechanisms, difficulties in separating fines it seems to be beneficial make our attempts to further investigate and develop the process as dry, low cost beneficiation process, especially nowadays when environmental concerns, as well as energy and water consumptions are main concerns for mining industry."

Jan 1, 2018

By Mike Trovant, Stavros A. Argyropoulos

"A fixed grid numerical model for phase change problems is proposed. The model solves for heat transfer and fluid flow, via the coupled solution of the energy, continuity and momentum equations. In addition, the numerical scheme accounts for temperature varying thermophysical properties and determines the shrinkage profile resulting from phase and density change. Simulations are run to determine the effect of varying model parameters and wall cooling rates on the location and shape of the shrinkage void formation in cylindrical casts. Results are shown for both aluminum and magnesium.IntroductionThe mathematical modeling of phase change processes (be they solidification or melting problems) entails solving for many interrelated phenomena. A comprehensive numerical simulation of the casting of a metal, for example, would have to account for: (a) heat transfer in both the solid and liquid portions of the metal and in the mold, (b) the release of latent heat during phase change, (c) fluid flow behavior in the liquid portion of the metal, (d) temperature induced shrinkage caused by liquid contraction and solidification contraction, and (e) the development of thermal stresses with accompanying shrinkage in the solid portion of the cast and mold. A schematic of the relationships that exist between the coupled equations which govern solidification is shown in Figure 1."

Jan 1, 1994

By J. B. Clark

In 1933, R. paris1 published a phase diagram for the entire Mg-Ca-Zn system. He reported the existence of a ternary intermetallic phase, Mg5Zn5Ca2, which formed a quasi-binary with the magnesium solid solution. Since then, no extensive work has been reported on the system. Recently however, indications of the existence of a second ternary in-termetallic phase in equilibrium with the magnesium solid solution led to a reinvestigation of the solid phase equilibria involving the magnesium solid solution. The 335°C (635°F) isothermal section was chosen for study. Metallography and powder X-ray diffraction were selected as the best mutually corroborating methods for determining the solid phase constitution. Seventy-six alloys were prepared from singly sublimed (99.95 pct) magnesium, electrolytic (99.95 pct) zinc and USP calcium. The analyses of some of the alloys are shown in Fig. 1. The alloys were melted in a graphite crucible under a chloride flu and chill cast in a split graphite mold. Dif-fusion couples (see Fig. 2) were prepared by casting molten Mg-20 wt pct Zn alloy around a cylinder of Mg-30 wt pct Ca alloy. The alloy samples and the diffusion couples were sealed under argon in Pyrex vials and annealed in a furnace capable of controlling within 1/2°C of 335°C. At the conclusion of the anneal, the alloy samples were quenched in ice water and the diffusion couples were air cooled. Procedures standard for magnesium alloys were used for metallographic examination. Powder X-ray diffraction patterns were taken on a G. E. camera with a 14.32 cm dim using nickel-filtered copper radiation. The redetermined 335°C (635°) section of the Mg-Ca-Zn phase diagram is shown in Fig. 1. TWO ternary intermetallic phases, designated w and

Jan 1, 1962

By C. M. Davidson

Contamination of by-product: sulfuric acid, by dissolved oxides of nitrogen ('nitrates') occurs under some operating conditions encountered in sulfide roasting and smelting,, notably when oxygen-enriched air is used. This 'nitrate' lowers the value of the acid and increases the effective cost of smelter gas desulfurization. The present paper describes measures taken at one smelter acid plant to remove this 'nitrate'; it discusses the mechanism by which 'nitrates' in some cases concentrate in one part of the plant and can be purged for more efficient treatment; and it describes a process developed by C-I-L Inc. for removal of 'nitrates' from such a purge stream. Advantages of the process include very low reagent cost, recovery of all sulfuric acid values and safe handling of nitrous fumes.

Jan 1, 1983

By Richard A. Andre, R. Larry Grayson, Thomas Simonyi

"INTRODCICTIONThe search for the cause(s) of coal workers' Pneunoconiosis continues despite the vast amount of research that has been undertaken over the past forty to fifty years. Good correlation between the mass of dust inhaled over workers' lifetimes and the incidence of the disease has led to the development of effective environmental standards and implementation of good procedures for the control of dust generation and dispersion in the working place. Research has only begun, however, to uncover the biochemical mechanisms involved in initiating the disease.Correlation between the rank of the coal seam in which miners worked and disease incidence and severity is acknowledged worldwide, but the agents in the higher rank coal seams which cause CWP arc still not defined. The basic components of the coal seams, i.e., the elements and minerals, are generally known, but the way in which they interact with human pulmonary cells is largely still a mystery.The process of disease development is a biochemical one which depends on the characteristics of the pulmonary cells within their immediate biochemical environment and the characteristics of invading respirable coal mine dust particles, probably both chemical and physical ones. The cell-particle relationship, therefore, must be defined, and both cells and particles must be characterized according to properties which potentially are involved in the disease process.Following such characterization, specific respirable dusts from different coal seams, which appear to have different effects on coal workers, must be obtained or constructed and then used in experiments designed to determine dust toxicity or the response of animals exposed to the dusts.The results presented here focus on characterizing properties of respirable coal mine dust particles collected from operating longwalls in West Virginia and Virginia Longwall panels were selected for analysis because the respirable dust in the coal face areas is largely uncontaminated by rock dust and analysis of the dust yields results unconfounded by rock dust."

Jan 1, 1990

By F. Hassan, M. A. Arafa

At El-Gedida iron ore deposits there is a block of about 30million tons neglected due to its higher sulfur content due to the presence of barite gangue minerals. From this bluk by magnetic separation dual concentrates of high grade iron concentrate (~65%Fe and total Sulfur of 0.26%) and the second concentrate is barite of (60.87% BaO and total impurities of less than 3%).

Jan 1, 1999