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By Pengkai Wang, Huimin Lu, Xiaoxiang Zhang

"In this paper, it was studied an electrochemical reduction process of carbon dioxide in ionic liquids such as 1-n-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF6) as the electrolyte. The electrolysis experiments were carried out under current and potential controls. The cathode products contained carbon nanotubes, carbon nanofibers, nanographites, and amorphous carbon. To establish the actual current and potential ranges, the electroreduction of carbon dioxide dissolved in the ionic liquid was studied by cyclic voltammetry on glass-carbon (GC) electrode at room temperature. The electrochemical mechanism of carbon dioxide electroreduction was studied for explanation of all obtained results. Carbon dioxide in ionic liquids was electroreduced, similar to metals oxides being electroreduced in molten salts.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the most concerning environment problems, so the solution to this greenhouse effect is very urgent. However, the carbon dioxide is also a cheap and abundant raw material that represents a potential source for the production of chemicals and fuels. Therefore, the development of the technologies that achieve simultaneous reduction and conversion of carbon dioxide to fuels is important. The electrochemical reduction of carbon dioxide is one of the effective approaches to transform CO2. Many investigations have been carried out on the electrochemical reduction of CO2 in both aqueous [1] and non-aqueous [2] electrolyte solutions with different electrodes. The solubility of CO2 in water is very low even under high pressure of CO2, and some investigators have brought focus into the electrochemical reduction of carbon dioxide in organic solvents, because they dissolved much more CO2 than water did. However, the hazardous or toxic properties of organic solvents hinder their use."

Jan 1, 2009

By D Crequer

A Peer Review Panel for the Golden Cross Mine in the upperWaitekauri Valley, Coromandel was initiated in December 1989, before mining, as a requirement of the conditions of the Mining Licence and Water Rights. The panel's function is as a technical audit and advisory team - to provide independent technical review of design, construction, and execution of mining operations, slope remediation works, and reclamation/mine closure activities. The primary role of the panel is to act in the public interest by providing assurance to regulating authorities that the design and application of on-site mining operations accords with 'good industry practice'. Panellists are not involved in design nor as advisers, although until 1997 when explicit terms of reference were written, the panellists were a sounding board for some operational proposals. The panel functions to ensure that best mining industry technical standards are met. The costs of the peer review process are met by the mining company. Review of mining operations includes environmental matters such as land rehabilitation and water quality. The focus of this paper is on the process of peer review for environmental management factors rather than for structural and mine engineering.

Jan 1, 1998

By Joachim Klein, Frank Reimann

Nodular-graphite cast iron (GGG) is a material similar to steel, and one which exhibits excellent properties, in particular for components exposed to pressure. GGG cast iron has been used in many cases when sinking mine shafts with conventional tubbing. With linings made of cast iron tubbings (the backfill concrete is not integrated into the calculations, and merely serves as bedding) the properties of the cast iron can be made full use of, provided the tubbing is made to the appropriate cross-section. Calculations have shown that better static values can be arrived at when using cross-sections other than those of tubbings made to conventional German standard. The cross-sectional design of the new types of shaft lining made from GGG is to be developed on these lines irrespective of the cast iron structure being only stressed component or its restistance function being combined with the one of concrete. GGG 50 is used for the first time to make the reinforcing inner liner of a main shaft currently sunk in Germany. The physical properties of nodular-graphite cast iron, strength and deformability, suggest that, in the future, its application will not be restricted to shaft support but also in tunneling. New moulding techniques with better three-dimensional modelling resulted in new tubbing designs as installed e.g. for the Hannover underground at present. Shield-driven tunnels have to withstand earth and water pressure, apart from axial machine loads. In this field time is money as well. Therefore easy handling and quick installation are necessary for successful, use. Last but not least, safety is of first-order importance for work in shaft sinking and tunneling. Cast iron lining systems, accordingly, are adequate systems, in particular for excavations underneath water for transport systems and for goods and passengers.

Jan 1, 1987

By S. Soren, K. Deo Mehta, G. Jha

The paper aims to find a sustainable sintering process through cleaner means, in order to achieve the desired outputs with zero environmental impact. At present, sintering has no control over its environmental impacts. These impacts occur when fossil fuels such as coal and coke are used in metallurgical sintering. These fossil fuels are undoubtedly effective in their assigned reducing task, but simultaneously emit about 220 kg of GHGs (greenhouse gases) per tonne of sinter produced. The current attempt has focused on reducing these emission levels by switching from coke to a renewable fuel source such as biomass. Biomass is a cleaner fuel source with a significantly lower emission footprint compared to coke. In the experimental campaign, sawdust and wood-charcoal were used in substitution for coke. Experiments were designed in a progressing substitution to obtain the maximum substitution ability without compromising the sinter properties. Sawdust as raw biomass source optimally substituted 10% of coke. The substitution levels were remarkably higher (30%) for wood charcoal due to its low moisture and high calorific values. A fuel blend with 30% biomass and remaining coke succeeded in producing a sinter with acceptable quality indices. Sinters prepared with or without biomass contribution shared an identical phase transformation and microstructures. In order to to maintain consistency in the process, every effort was made to maintain all operational and process parameters identically, except for the fuelling framework. Keywords: Sintering, sustainable, biomass, GHGs, fuel substitution

Jan 1, 2020

By J. H. Gray

"IntroductionIn 1980, Fording Coal Limited started conceptual planning studies which led to major changes in the long-range mining plan at their Fording River Operations. These new plans have been completed and are now in operation.To assist personnel in a timely completion of this major revision to the long-range plan, existing in-house drill hole data base and scheduling systems were used and a computerized Mine Modelling and Planning System was purchased. With these tools, plan s were developed which led to completion of initial access to the peak of Eagle Mountain and the start of mining operations in March 1983. As mining area s open up and new geo logical data is obtained, detailed plan s are being extended and revised.With the geology and mine plan s on line, this work can now be done with less effort and plans ca n be adapted to provide flexibility in mining operations. Changes in market conditions can be accommodated by moving mining operations into different seams for different coal types. The computer systems are used to revise pit designs and schedules accordingly."

Jan 1, 1986

By P. R. Stephenson

"The Australasian Code for Reporting of Mineral Resources and Ore Reserves (JORC Code) has been operating successfully for 14 years, and has an ancestry dating back over 30 years. Together with complementary developments in stock exchange listing rules, the Code has brought about substantially improved standards of public reporting by Australasian mining and exploration companies. The Code is regarded as a world leader in its field, and has been used as a basis for the development of resource/reserve reporting standards in other countries. The reasons for its success are varied, foremost among them being its adoption in full by the Australian and New Zealand stock exchanges, and the ability and willingness of mining industry organizations to bring Competent Persons to account when necessary.The latest revision of the JORC Code was undertaken in 2002-2003, based in part on releases of upgraded reporting standards in Canada, the United Kingdom/Western Europe, and South Africa, and the 2003 edition is expected to be released mid-year. Two of the more significant changes are: the introduction of a requirement for a Competent Person to be responsible for the documentation upon which Exploration Results are reported; and inclusion in the definition of a Competent Person of a reference to “Recognized Overseas Professional Organizations” being overseas professional organizations to which Competent Persons may belong for the purpose of preparing documentation for the submission of reports to the Australian Stock Exchange."

Jan 1, 2004

By Jr. Napolitano, Jr. Sanders

"Morphological evolution of a dendritic growth front in a binary alloy is simulated using a cellular automaton approach to establish the feasibility of modeling such growth with a local rule-based scheme. The motivation for this work is derived from the need to predict the development of solidification structures within real components of complex geometry, where significant constraint of the thermal and solutal fields may exist. Such cases present complex boundaries and large domain sizes, which may preclude the effective use of more conventional methods. In this work, a model is presented which couples a two-dimensional alternate-direction-implicit finite-difference diffusion solution with a cellular automaton growth algorithm to simulate morphological evolution in alloys solidifying under directional growth conditions. Temperature, composition, and interface curvature are incorporated into a local growth potential which is used by the automaton, allowing the interface to evolve. Alloy solidification is simulated over a range of experimental conditions, producing various structures. Issues addressed include morphological instability, primary spacing selection, interface curvature, microsegregation, and tip conditions.IntroductionThe development of dendritic structure plays an essential role in alloy solidification. Virtually every microstructural feature, within a cast alloy component, is related to the interface morphology present during solidification. Conventional solidification theory, describing dendrite tip kinetics and mushy zone phenomena, provides a means for estimating overall microstructural parameters for an alloy solidified under steady-state conditions. Microstructural prediction for actual components, which are finite in size and complex in geometry, requires a description of the evolution of the interface morphology under transient conditions and geometrical constraint and an understanding of how the structure propagates through the mold. Any useful simulation tool must be equipped to handle these circumstances within the limits of computational feasibility."

Jan 1, 1998

By ANDREW McVILLIAM, WILLIAM H. HATFIELD

AT the 1902 May meeting of the Iron and Steel Institute, the, authors presented a paper on " The Elimination of Silicon in The Acid Open-Hearth," wherein they recorded a few typical examples of certain Siemens charges out of a very large number specially watched for the purposes of that research. The main deductions drawn from those experiments have been accepted in all the intelligent criticism during or after the discussion on the paper. One opinion, however, was rigidly held by all who mentioned the matter, with the single exception, perhaps, of Mr. Lange, and that was the necessity for the attainment and the maintenance of an abnormally high temperature in order that the percentage of silicon in the metallic bath might increase, or that an unusually large proportion of silicon might be retained in the metal. The original decision was ar-rived at on the results of scores of trials, and has since been the subject of frequent experiment. The authors still retain their opinion that although, naturally, a higher temperature will accelerate the (probable) action between the carbon of the steel and the excess silica of the slag, they then fairly proved, and have now abundantly confirmed the fact, that around the temperatures occurring in Siemens steel-making practice the chemical composition of the slag, particularly with regard to its acidity, is the factor which determines whether the percentage of silicon in the molten steel shall increase or decrease. In the discussion in 1902 Mr. Saniter called attention to Mr. H. H. Campbell's work, and in the reply the authors also mentioned that of Messrs. Winder and Brunton of 1892, the two

Mar 1, 1905

By Pierre Mousset-Jones

A questionnaire was sent out to three classes of mines to determine the extent of the heat problem in U.S. and Foreign underground mines. The following list shows the replies received from this questionnaire, however not all the known hot mines in the US replied. A complete listing of the results can be seen in Appendix I. 1) US coal mines - 37 replies 2) US non coal mines - 23 replies 3) Foreign non coal mines - 36 replies. At the present time there are approximately eleven non coal and one coal mine in the US experiencing heat problems which require special efforts to maintain an acceptable working place climate. However since the survey was completed some of them have been placed on standby. The Mine Safety & Health Administration (MSHA) does not have any specific regulations relating to heat stress. Informally the American Conference of Governmental Industrial Hygienists guidelines are followed which use wet bulb globe temperature (WBGT) with values ranging from 26.7°C to 31.1°C for a moderate workload, and different rest regimes. An MSHA report (Misaqi 1976) recommended that conditions should not exceed 26.1°C WBGT for men and 24.4°C WBGT for women. However, quite recently the organizations involved with planning two of the proposed nuclear waste repositories in the United States, have opted for the criteria of an air cooling power of 300 w/m2, and a WBGT of 27'C respectively.

Jan 1, 1986

By Jeffrey J. Daniels

Advances in borehole geophysical research for mineral assaying, and remote detection of mineralization away from the borehole. Nuclear activation measurement research has provided accurate in situ assays of economic metals with neutron-gamma activation, using a high resolution intrinsic-germanium detector. Although nuclear activation analysis is the present "best-hope" for obtaining in situ assays for some elements, gamma-gamma and magnetic susceptibility measurements can provide accurate assays for lead-zinc and magnetite, respectively. Borehole optical spectroscopy and x-ray fluorescence are being investigated as possible in situ assaying techniques for some minerals. More laboratory and field calibration research is needed before nonlinear complex resistivity (NLCR) can be routinely used as a quantitative assaying tool. Field tests have shown that variations in the local geologic environment can affect the quantitative accuracy of assay values from downhole NLCR measurements. Deeply penetrating borehole geophysical methods are increasingly being used for mineral exploration as drilling costs and exploration have increased. Borehole electrical measurements have been shown to be useful for detecting conductive orebodies that are not interesected by a drillhole. Hole-to-surface resistivity, and surface-to-hole time-domain electromagnetics are demonstrated to be particularly effective for defining mineralized zones in a massive sulfide environment. Borehole gravity meters and three-component magnetometers have been developed and should prove useful for defining geologic anomalies away from the drillhole.

Jan 1, 1985

By ANNE FUZESY

Soluble potassium salts in bedded underground salt deposits supply most of The world demand for potassium f or agricultural and industrial use. The potassium salts, sylvite and carnallite, were f irs, noted in drillcores in southern Saskatchewan during The search for oil and gas in ihe early /940s. Problems in shafi sinking beset pioneering potash companies, however, and cominuous production did no, begin uniil 1962. Powsh deposits in southern Saskatchewan occur within ihe uppermost 60 111 of the Middle Devonian Prairie Evaporite a, depths in excess of 900 m. Four groups of po/ash-bearing haliie beds have been distinguished: the Esierha-::,y, White Bear, Belle Plaine and Paiience Lake members. Powsh deposiis extend a jell' kilomeires into Manitoba and south imo orth Dakoia and non heasiern Moniana. Individual potash-rich beds are extensive and consistent in grade and Th ickness. Local th ickening occurs where carnallite is the dominani poiash mineral. Th e preferred ore, sy lviniie, is a clean mixiure of sylvite and haliie. Carnalliie and insolubles are avoided wherever possible because of Their detrimenwl effects on mine stability, grade and refining. Sy lvin ite is exTracted by underground mining or brought TO swjace as brine in solution mining. Poiash is separaiedfrom halite byfloiation or sequential crystallization. The refined produci, potassium chloride, is employed as a fertilizer ingredient as well as in chemical and other industrial capaciiies. The ten poiash mines of Wesiern Canada all are in Saskatchewan and account for aboui 25 per cem of world production. Faciliiies are being expanded, and a new mine and refinery was planned for ihe Breden bury area. Deposiis in Manitoba also were being evaluaied.

Jan 1, 1984

By H. C. de Wet

The predevelopment and preparation of a total infrastructure in a deep level mining environment, prior to the shaft system being commissioned has major advantages. This paper intends to indicate these advantages and outline an understanding of the disadvantages. These benefits can be classified in three basic groups: the financial and timing advantages, a knowledge of the ore body and the development of required technology to meet the design parameters. The required technology in many aspects was still to be developed prior to successful application. Stemming from the technological evolution are some secondary advantages which will be described in each of the groups. Safety and health considerations and some practicalities made some of the new technology redundant prior to the actual application. In each case the actual achievements and the anticipated benefits will be indicated to allow the reader to distinguish clearly between planned and actual achieved advantages.

Jan 1, 1997

By Matthew I. G

A new process for leaching zinc sulphide concentrates with gaseous mixtures of SO2 and O2 in aqueous solution is described.The reaction of SO2/O2 with Rosebery, Mt. Isa, Broken Hill and Elura zinc concentrates yields zinc and iron sulphates, elemental sulphur and some sulphuric acid. Rates of zinc extraction are controlled by a surface chemical reaction without apparent interference from the elemental sulphur layer for SO2 concentrations up to 9 per cent in the gas phase. Pyrite in concentrate exerts an activating effect, possibly through galvanic interaction with the sphalerite. Metal extractions are dependent on SO2 and O2 tenors of the gas, particle size, and the acidity and zinc content of the solution, but are independent of the ferric ion level. Extractions also reach maxima at about 85°C.Generation of acid may be prevented by conducting the reaction in the presence of ferrous iron and at acidities of 40 g/l or greater. Zinc and iron levels in Elura lead concentrate may be reduced by leaching with SO2/O2.

Jan 1, 1981

By Aalbers J. P A

The State Electricity Commission of Victoria (SECV) operates 13 excavators, 3 travelling stackers and 4 mobile slew conveyors in their three open cuts in the Latrobe Valley. The majority of these machines have been designed and constructed to a German design code current at the date of order. The SECV has always ensured that the machines were manufactured and erected to the appropriate standards. The SECV has a policy of having all machines inspected by an independent inspector every two years. These inspections are based on those carried out in Germany. The inspections have been carried out by inspectors from Germany who have the necessary experience to do similar work in German open cuts. Major faults found during the inspections have been repaired, however,the gradual breakdown of corrosion protection system has continued. The structures on some machines have areas of bad corrosion. This, coupled with wear on major mechanical equipment, would require an extensive outage to overhaul the machines. Refurbishment of Hazelwood Power Station will result in higher levels of production and extended life for the station. This will require improvement in the total output from Morwell Open Cut (MOC). To meet this increased coal demand, the open cut equipment will need to operate more efficiently and for a longer period of life.

Jan 1, 1989

By Susanne Pignolet-Brandom

Flash smelting products of a copper sulfide concentrate collected at successive levels in an experimental reactor have been studied by reflected light microscopy, scanning electron microscope - energy dispersive analysis and electron nicroprobe analysis. Chalcopyrite, intermediate solid solution, bornite, chalcocite, metallic copper, magnetite, iron-copper spinel, pyrrhotite, hematite, delafossite and cuprite have been identified in the product samples. The detailed reflected light microscopy study of these phases and their abundance in the samples has resulted in the identification of the series of reactions during flash smelting.

Jan 1, 1985

By L Klemettinen, J Biswas, W Malan, D Sukhomlinov, D Lindberg

In order to mitigate the effects of climate change, our society must be able to drastically reduce its CO2 emissions. As the metallurgical industry is a considerable contributor to these emissions, new greener technologies must be invented and developed. One option could be the direct production of metals from oxides using renewable electricity. The aim of this study was to investigate the possibility of using high-temperature molten oxide electrolysis (MOE) for iron and ferrochrome production. FactSage™, ver 8.2 (by Thermfact Ltd and GTT-Technologies) was utilised for estimating a feasible equilibrium electrolyte composition, and the experiments were conducted at 1550–1580°C in conical alumina crucibles with iridium wire as the cathode and platinum wire as the anode. The sources of iron and chromium were either pure FeO powder or industrial chromite pellets. Voltage was applied to the electrolysis cell for 6 hrs and the resulting current was measured, along with oxygen concentration in the off-gas line. The electrolyte comprised of SiO2, Al2O3, MgO and CaO. First, the effect of FeO concentration on iron reduction efficiency was investigated using only pure oxide powders as starting materials. The results indicated that 10 wt per cent FeO mixed with the electrolyte resulted in more efficient iron reduction compared to 20 wt per cent. In further experiments, industrial chromite pellets were ground and mixed with the CaO-free electrolyte. Iron and chromium reduction efficiencies were higher when approximately 19 wt per cent of the total sample mass consisted of pellets compared to increasing the pellet amount to 37 wt per cent. Generally, the chromium solubility in the liquid electrolyte was relatively low, and most of the chromium was confined to the spinel solid solution, from where its dissolution to the liquid electrolyte was very slow, resulting in slow reduction kinetics. For larger scale applications, economically more viable electrode materials should be investigated.

Jun 19, 2024

By G. G. Li

"A dynamic ventilation-modeling package, VREX, was used to simulate the mine activities through tracking the equipment movements in underground workings and determine the airflow demand for a new production scenario in a ventilation-on-demand (VOD) system. It incorporates the mine development data from a discrete event simulation and balances the ventilation network using the CANVENT ventilation solver. A case study was performed to demonstrate the capabilities of the software, evaluate the performance of the network and determine the potential energy savings for implementing VOD in a deep mine operation.INTRODUCTIONThe ventilation cost of an underground mine can be significant—up to 50% of the mine’s energy consumption could be used to run fans and provide heat/refrigeration to meet the specified production environment for workers and equipment. The VOD system has proven to be more efficient in operating the fans and supplying the amount of air corresponding to the mine activities taking place in underground workings (Hardcastle, Kocsis, & O’Connor, 2006). In order to properly solve and evaluate the VOD system, a dynamic ventilation modeling software VREX—the ventilation rules engine has been developed to simulate the mine activities and determine the airflow demand for each production scenario within an operation period (Dasys & Cameron, 2011).VREX is a decision support tool, backed by the CANVENT mine ventilation solver (Li, Kocsis, & Hardcastle, 2009), for determining the outcomes of network configuration changes over time. The software incorporates the mine development data with ventilation modeling through the discrete event simulation (DES) performed by SimMineTM. As it simulates the air requirements for different vehicles and activities, VREX can evaluate both the performance of the ventilation system and the potential economic benefits of making operational or technological changes (Pritchard, 2010). For example, the model can be used to assess the economic and environmental impacts arising from modifying regulations to support the use of electric or lower emission vehicles. The combination of DES and ventilation modeling provides a new technology to generate the production scenarios according to mine schedules and activities and to determine the potential benefits for various levels of ventilation control, such as time interval and work shift change."

Jan 1, 2019

By C. D. Smith

Numerous studies have shown the potential of air rate profiling to significantly improve the flotation performance of a bank of cells. To date many profiles have been implemented; balanced, increasing, decreasing and combinations of these. Previous work has typically shown using an increasing air rate profile, where the air rates are increased proportionally to each cell down the bank, yields a higher grade for a given recovery compared to other profiles. Air rate profiling can then be thought of as having two distinct components; determining the correct distribution of a given volume of air and, perhaps more importantly determining the correct total volume of air to add to the bank. To date no method for this second component has been established. In an alternative technique the air rate to each cell is adjusted in order to optimise the air recovery from that cell. Air recovery is the fraction of the inlet air which overflows the weir of a cell as unburst bubbles. The peak in air recovery (PAR) is a robust measurement that indicates optimal performance for the operating conditions in the cell, and sets the PAR air rate. By doing this for each cell in the bank, the optimal total air rate to the bank and the optimal distribution of that air can be simultaneously determined. In this study plant trials evaluated different air rate profiles, and profiling based on PAR. The total air rates to the bank for all profiles tested were approximately equal, allowing direct comparison. The results showed that the highest cumulative mineral recovery was achieved by operating at air rates which gave the PAR for each cell down the bank. Different distributions of the same total air rate to the bank gave the same cumulative upgrade ratio, but lower cumulative recoveries. In this study, the increase in cumulative mineral recovery, at the same upgrade ratio, was more than 33%. Peak in air recovery (PAR) based optimisation of air rates to banks of cells and to the individual cells has been shown to significantly improve flotation performance as it simultaneously determines the optimal air rate to the bank, and the optimal distribution of that air.

Jan 1, 2009

By J. A. Eisele

The Federal Bureau of Mines is engaged in a continuing program on the recovery of alumina from domestic source materials. Of the six processes being studied, current efforts focus on HCl leach of clays. A key step in the HCI process is the removal of iron from the aluminum chloride leach liquor. This was accomplished .by solvent extracting the iron with a tertiary amine in kerosine to which decanol was added as a phase modifier. In a mixer-settler operation, iron in the raffinate was reduced to <10 ppm in two extraction stages from a feed containing 1.4 gil Fe. Iron was stripped from the organic phase in three stages with dilute HCl.

Jan 1, 1976

By A. L. Mular

A great deal of effort is being expended by mineral processing engineers to acquire a basic knowledge of modelling and optimization techniques. Stimuli such as immediate process improvement, expanded process understanding, optimal flowsheet design and re-design, and the development of new and better control systems are goals which excite the imagination in terms of increased profits. To reach these goals, process models and efficient optimization strategies, regardless of their purpose, assume an important role. Consequently, few of us can argue that such efforts are of no value. The purpose of this paper is to review empirical modelling methods and optimization strategies which appear to be of value to mineral engineers.

Jan 1, 1972