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By R. J. Corfield

MODERNIZATION of the entire electrical system and improvement of Rotation process efficiency is the twofold goal of the improvement program underway at the Arthur and Magna concentrators of the Utah Copper Div., Kennecott Copper Corp. Copper ore from the Bingham pit goes to these two concentrators where an interlocking program calls for complete electrical modernization and increased flotation process efficiency through additional capacity and flow scheme revisions. Flotation plants at the two mills are essentially duplicates, and while this article deals with the changes at the Arthur mill similiar improvements are being made at the Magna mill.

Jan 3, 1953

By G. Sedelnikova

This paper is aimed to elucidate the problem of copper losses in pyrometallurgical slag. Currently, flotation is used to recover copper from the slag and return the metal into the pyrometallurgical process, but the percentage of recovery frequently remains unacceptable. The process of copper leaching from the slag flotation tailings using biologically regenerated ferric sulfate is considered here as an approach to the issue. A sample of the slag flotation tailings containing 0.67% Cu and 4.99% Zn was supplied by the Urals Mining and Metallurgical Company (UGMK, Russia). The Cu and Zn speciation analysis of the sample demonstrated that Cu occurred as 58.1% oxide, 15.4% native Cu, and 18.1% secondary sulfides whereas chalcopyrite proportion was as low as 8.4%. Prevailing Zn species were refractory (58.9% Zn ferrite), and zinc oxide and silicate species made just 37.2% of the total metal content. The silicate generated silica gel that strongly hampered filtration. As demonstrated, Cu recovery is a possibility, which is apparently not the case with Zn. In this work, the stirred tank bioreactor acid leaching employing bacterial Fe3+ sulfate solutions was studied, with ferric sulfate being a product of Fe2+ biological oxidation and not the chemical reactant adding of Fe3+ sulfate. Acidithiobacillus, Sulfobacillus, and Leptospirillum bacilli were employed in Fe2+ biooxidation. Temperature, pH, Eh, S:L ratio, leaching time, and Fe3+ concentration in the source leachate as the process controls were considered. As demonstrated, the process employing biologically regenerated ferric sulfate proved to be more efficient than conventional chemical leaching. Under the optimum conditions, the proportion of Cu extracted into leachate during 2 hours was 79.1%, and that of Zn 27.2%. Precipitation of high-grade Cu sulfide served to extract the metals from the leachate, and Cu extraction was 99.7%. All in all, 23.2% Cu, 0.03% Zn, and 0.02% Fe was returned into the pyrometallurgical process. Keywords: slag flotation tailings, copper leaching

Sep 1, 2012

By Lynn Huntsman

INTRODUCTION The Sunnyside mines of Kaiser Steel Corp. are lo¬cated on the west flank of the Book Cliff Range, a tongue of the Wasatch mountain range in Utah. The mines are 193.12 air km (120 air miles) southeast of Salt Lake City and 40.23 km (25 miles) east of the town of Price. The area has a semiarid climate with an an¬nual rainfall of 304.8 to 381 mm (12 to 15 in.) and a temperature range of -23.3 to 32.2°C (-10 to 90°F). The base of the Book Cliff Range is approximately 1981 m (6500 ft) in elevation with some mountain peaks in excess of 3048 m (10,000 ft) (Fig. 1). The Sunnyside mines were opened in the late 1890s and have been operated continuously since that time. Kaiser Steel leased the No. 2 mine in 1942 and pur¬chased the entire property in 1950. There are three mines adjacent to one another, each with its separate access, ventilation, and haulage. The three mines en¬compass an area extending 12.87 km (8 miles) along the outcrop and dipping northeasterly 2.41 to 3.22 km (11/z to 2 miles) into the Book Cliffs. During 1975, only the No. I and No. 3 mines were operating to sup¬ply 908 184.7 t/a (1,000,000+ stpy) of clean coal to the Kaiser Steel mill at Fontana, CA. Sunnyside coal is blended with coal from the Kaiser Steel mine near Raton, NM, and with purchased coal from noncompany sources to form the mix for the coke ovens. At that time, Sunnyside operated three longwall units and five to seven continuous miner units. Typical production for that time came from one miner unit pillaring an area not conducive to longwall mining; one or two miner units on construction or modernization projects, and the remaining units used to develop future longwall panels. Longwall mining has been a part of the Sunnyside scene since 1961 when the first panel was set up in the lower Sunnyside seam of the No. 3 mine. Through 1975, 27 longwall panels were mined (Fig. 2). Of the more than 47 173 604 t (52,000,000 st) of clean coal that were taken from the property through 1975, 6 350 292.9 t (7,000,000 st) were mined by longwall methods. Coal was brought to the surface in 4.5-t (5-st) mine cars and crushed to -152.4 mm (-6 in.) before entering the preparation plant. Coarse coal is cleaned by Baum jigs and fine coal (-28 mesh) is cleaned in flotation cells. The coal is reduced to 50.8 x 0 mm (2 x 0 in.) and belted to an aboveground storage pile with a ca¬pacity of approximately 113 398.1 t (125,000 st). The coal is gravity fed through two 1.52-m (5-ft) diam culverts directly into railroad cars, which pass beneath the storage pile through an arched excavation. Eighty-four 90.7-t (100-st) cars make up a unit train which makes the round trip to the steel mill in four days. Additional trains are scheduled in as demands dictate. Loading rates in excess of 13 607.8 t/h (15,000 stph) have been attained. Geology The coal seams of this area are of Cretaceous age and are classed as a medium volatile bituminous coal. coal, with a sulfur content less than 1 % and 6 to (20-mile) zone of the Book Cliffs, and this area is owned or under lease by either Kaiser Steel or US Steel. Coal in adjacent areas is noncoking but an excellent steam coal, with a sulfur content of less than 1 % and 6 to 7% ash. Sunnyside coal contains 40% volatile, 53% carbon, less than 1 % sulfur, and 51/2 to 61/2 % ash after washing. There are two minable seams throughout most of the Sunnyside property known locally as the upper and lower Sunnyside. Separation between the seams varies from less than 300 mm (1 ft) near the southern boundary adjacent to the US Steel Columbia mine, to over 12.19 m (40 ft) in areas of the No. 3 mine in the center of the Sunnyside property. The upper seam varies in height from 1.2 to 1.98 m (4 to 61/2 ft) while the lower seam varies in height from 1.52 to 4.28 m (5 to 14 ft) in areas of No. I mine where the two seams apparently come together. The majority of early work was con¬centrated in the upper seam which has a stronger roof and a lower sulfur content. When Kaiser Steel began mining the No. 3 mine in the early 1950s, it mined in the lower seam beneath the old workings with conven¬tional and continuous mining equipment. Numerous bounces and pressure points created by unextracted pillars and barriers in the upper seam made this a low¬production, high-cost mine and brought about the ad¬vent of the first longwall system. The first unit, while small by today's standards, successfully mined panels that had been all but given up and saved the mine from closure. There were areas that could not even be mined by longwall because of the erratic extraction in the upper seam. The system was successful enough to allow operations to gain access to and develop virgin areas of the upper seam. Development of longwall mining in the No. 3 mine has been confined to the upper seam since late 1964. With the almost complete extraction afforded by the longwall system, it is felt the lower seam can be successfully worked in future years (Fig. 3). In most of No. 1 mine, only the lower seam (or lower seam and upper seam combined) is minable, except in the northwest portion where a rock split has again separated the seam into two 1.83 to 2.13-m (6 to 7-ft) thick beds. In this area, the upper seam or upper split is being mined. The separation between seams at the present workings in this area varies from 0.609 to 6.1 m (2 to 20 ft). It is hoped that most of the lower split can be mined using shield supports and/or what¬ever new technology is developed in the coming years. The coal seams in this area dip to the northeast at an average grade of 10%. The dip near the outcrop reaches 22% and gradually decreases downdip. Over¬burden ranges from a few meters at the outcrop to 762 m (2500 ft) over some of the deeper workings. In the next several years, some overburden will be in excess of 914 m (3000 ft) as the lower mine workings extend ever deeper under the Book Cliffs. To cope with the

Jan 1, 1982

By Jerry J. Gray

The utilization of secondary titanium was determined in a study by the Bureau of Mines, and a 10-year statistical table showing supply and distribution patterns is presented in this report. Over the total 10-year period, estimated scrap consumption is larger than estimated scrap supply. Trends from the estimated data indicate that titanium is in short supply and probably will continue to be in the future. Because of higher processing costs for recycle scrap, scrap will tend to migrate to the steel and aluminum industries and to ferrotitanium production and exports. Nonrecoverable losses of titanium metal during processing was determined to be a potential area for research.

Jan 1, 1971

By G. R. Addie

The Hydraulic Institute has completed the task of developing a new ANSI/HI standard 12.1-12.6 (2005) for rotodynamic (centrifugal) slurry pumps covering nomenclature, definitions, applications, and operation. The standard provides examples of the different slurry pump types and contains an extensive section on pump and slurry definitions. The effect of slurry on pump performance is covered along with the pumping of froth. Reference is also made to ANSI/HI standard 9.6.7 (2004), which contains a new method for pump performance correction when handling viscous fluids. Classification of slurry services is established and then is used to determine limitations on velocities and total head per pump in order to obtain acceptable wear performance. The new service class, head per stage and other limits are directly related to capital and other cost considerations that will affect solids transport system economics. The writers review the contents of the new standard, highlight the main points, and discuss the reason for the slurry classification, corresponding limits and expected implications, particularly with respect to operating costs of the pumps in solids transport systems.

Jan 1, 2007

By Orlando Ramírez

El presente trabajo describe el sistema integrado de seguridad a través de la norma OSHAS 18001 - 1999 y calidad ISO 9001 – 200m, donde la aplicación de la integración controla las desviaciones de los procesos oportunamente. Es decir, que a través de la procalsedad se reúnen tres elementos: productividad, seguridad y calidad,logrando una ventaja competitiva en el mundo globalizado.

Sep 12, 2005

By Liu Wei

In order to make clear the dissolving characteristic of the chrysocolla (CuSiO3?H2O) in the ammonia-ammonium chloride solution, a thermodynamic model of the chrysocolla (CuSiO3?H2O)-ammonia- ammonium chloride-water system is established using the exponential computation method based on both mass balance and charge balance equations. The equation group of the thermodynamic model is solved by the MATLAB Soft on PC. The condition which is favorable for dissolving high concentration of copper in solution is making out. The stable area of chrysocolla (CuSiO3?H2O) and the condition of chrysocolla (CuSiO3?H2O) converting to atacamite (Cu(OH)1.5Cl0.5) is also studied. A group of experiments are designed to validate the veracity of the results of the thermodynamic calculation.

Jan 1, 2010

By Lok M. Sharma

"Construction of a new bridge in a seismically sensitive area requires careful assessment of earthquake impact on the serviceability of the facility. Not only is the superstructure vulnerable, the foundations play a key role in the bridge’s survivability. A new bridge in eastern part of the state of Missouri in the U.S.A. is located in a seismically active area and hence subject to additional thrust on the foundations and superstructure and potential damage due to liquefaction. An eleven span bridge with foundation soils varying from shallow bedrock to over 30 m (100 feet) overburden soils were considered for the bridge support piers. Two of the bridge support bents located within the flood plain area through over 30m (100 feet) of alluvial deposits were considered most affected by an earthquake event due to the additional thrust and lateral ground spreading. This paper describes the determination of site specific seismic hazard, numerical modelling of the foundation system, and methodology of dynamic analyses, effects of lateral spreading and liquefaction potential on bridge support bents. From numerical modelling using FLAC, the increase in thrust on piers and deformations were computed to predict the behavior of the foundations.INTRODUCTIONA newly constructed bridge on route US 40 crosses the Missouri River west of St. Louis, Missouri and upstream of Mississippi River in mid-west USA. The west abutment area has near surface bedrock while the east abutment area has overburden deposits over 30m (100 feet) thick, mostly river sediments comprising of silts, lean clays and sands overlying bedrock. Softer layers of silts and sands in the east river bank area are assessed to be liquefiable during a high magnitude earthquake event. St Louis area has a potential for a high magnitude earthquake due to the New Madrid Fault some 160km (100 miles) south. The bridge foundations were designed as drilled piers, 2 m (8 feet) in diameter and socketed into the bedrock. Bents No. 10 and 11, located in the lower flood plain area of the river, are considered to be most affected by a seismic event.In order to perform dynamic analyses of the foundations, earthquake ground motion time history was developed for the specific site using a Probabilistic Seismic Hazard Analysis (PSHA) and selecting and scaling of a recorded time history. Relying on the U.S. Geological Survey (USGS) Earthquake Hazard Program for the PSHA and AASHTO Guide Specifications for LRFD Seismic Bridge Design, spectral acceleration values for the site were developed. The spectral acceleration values were for a 7 percent probability of exceedance in 75 years (1000 year return). Numerical modelling using FLAC computer program was performed. This paper presents the seismic design parameters, methodology used in the dynamic analyses, static and dynamic analyses, impact and mitigation of liquefaction on Bents 10 and 11 and the abutment fills, and effect of lateral spreading on the foundations in the lower flood plain area of the bridge. From the numerical modelling, increase in thrusts on pier foundations and estimated deformation were computed."

Jan 1, 2017

By Wilson Quispe, Luis Silva, Rubén Alvarado

El presente trabajo nos permitirá compartir los desafíos que en el pasado reciente se enfrentaron, cuando se pusieron en marcha las primeras operaciones de gran minería que contemplaban los molinos SAG el cual fue resuelto acudiendo a empresas extranjeras para poder cubrir la necesidad de realizar el cambio de los revestimientos. Esto porque los molinos SAG eran nuevos en el país y las empresas prestadoras de servicios mineros carecían de experiencia para poder ejecutarlo.

Sep 29, 2023

This geometallurgical study examines the gangue mineral variability at the Bingham Canyon porphyry copper mine in Utah. Understanding an orebody?s mineralogy is important for mine and mill planning because it provides information on the size, texture, and distribution of ore minerals, the relationship between ore and gangue minerals, and the extent and type of alteration. Quantification of the mineralogical variability and properties of an orebody provides valuable input to the ore model and may have a significant effect on recovery optimization. This study was designed to be carried out on an initially detailed scale in order to develop a robust methodology for measuring and quantifying specific parameters, such as the distribution of mineral phases, alteration assemblages and fractures from key ore domains at the Bingham Canyon mine (Figure 1). Details of the methodology are reported below. This technique can be applied to testing the impact of mineralogy on a number of processing parameters. [ ] Figure 1. Ore domain map of Bingham Canyon (Kennecott Utah Copper, 2003) showing the 33 geometallurgical ore domains. The samples for this study were collected from the northwest part of the deposit circled on the map. PROJECT BACKGROUND Geology The Bingham Canyon deposit is a large porphyry Cu-Mo-Au deposit with associated skarn and base-metal replacement deposits mined in an open-pit mine measuring about 2.5 miles across and 4,000 feet deep. The deposit is hosted by the Bingham Stock, a Late Eocene to Mid-Oligocene intrusive complex. The skarn is hosted by the Late Carboniferous-age Bingham Mine Formation, which is comprised of quartzites and basal limestones (Babcock Jr. et al., 1998). The Bingham Stock is a composite intrusive complex that was emplaced over a period of about two million years. The oldest phase is described as a fine-grained equigranular monzonite (MZ), which intruded the country rocks at 39.8 ± 0.4 Ma (U-Pb zircon TIMS age) (Parry et al., 2001). Subsequently, the quartz monzonite porphyry (QMP) was emplaced, followed by intrusion of a latite porphyry (LP). The final intrusive phase, which forms narrow dikes that crosscut the Bingham Stock, is represented by a quartz latite porphyry (QLP), which is dated to 37.5 ± 0.4 Ma by 40Ar/39Ar dating of sanidine (Deino and Keith, 1998). Also present, are a minette dike in contact with a QLP dike (Waite et al., 1998; Deino and Keith, 1998), and a biotite porphyry (BP), a quartz latite porphyry breccia (QLPbx), and a pebble dike (Redmond, 2002). The copper orebody is centered above the Bingham Stock and forms an inverted cup shape with three high-grade copper zones extending to depth. Molybdenite mineralization occurs within and extends below the copper orebody, but is not correlated with copper mineralization. The main sulfide assemblage is chalcopyrite, bornite, molybdenite, and pyrite. Gold is locally intergrown with chalcopyrite and bornite (Babcock Jr. et al., 1998; Phillips et al., 1998). The surrounding country rocks host skarn deposits with three main ore types - garnet skarns, massive sulfides, and iron oxides. The garnet skarns contain chalcopyrite and pyrite with magnetite veins. In the massive sulfides chalcopyrite and pyrite occur either in banded sulfides or in unconsolidated microbreccias. The iron oxides contain disseminated chalcopyrite with minor chalcocite and bornite (Harrison and Reid, 1998). The deposit is overprinted by several stages of alteration. Potassic alteration is concentrated at the center of the deposit. It is surrounded and partially overlapped by a propylitic alteration zone. Both zones are overprinted by sericitic alteration. In the northern part of the deposit evidence for argillic alteration can be found (Bowman et al., 1987). Similarly, the skarn deposit was also overprinted by several stages of alteration: wollastonite, idocrase, and garnet in cherty limestones, and quartz and diopside forming in calcareous quartzites. Distally, diopside was replaced by talc, tremolite, dolomite, secondary calcite, and pyrite, and quartz and sulfide veinlets with biotite and actinolite selvages are present. Andradite garnet, diopside, quartz, magnetite, hematite, and copper sulfides were overprinted by wollastonite (Babcock Jr. et al., 1998). Because the monzonite, quartz monzonite porphyry, latite porphyry, and quartz latite porphyry host the bulk of the mineralization, our research is focused on these lithologic units. Geometallurgy On the basis of geological (lithology, alteration assemblages, fracture density, copper mineralization) and metallurgical properties, the deposit has been divided into 33 ore domains by mine geologists and metallurgists (Figure 1). In map view, these domains cross geologically defined boundaries (MZ, QMP etc.). These domains reflect regions of the deposit that have particular, mapable attributes or properties. They reflect a combination of geological and mineralogical characteristics that combine to impact processing. Alteration, for example, as shown by talc mineralization, is one such key feature. Hardness may reflect the absence of sericitic but presence of potassic alteration. Structural discontinuities such as faulting, fracturing, or development of void

Jan 1, 2009

By Diler Katircioglu-Bayel

The effects of the operating parameters of media filling ratio, solid mass fraction, grinding media size and grinding time on the stirred media milling of talc were studied. The findings were assessed based on the product particle size (d50, d10), surface area (Sw) and energy consumption (Em). Furthermore, after determining the optimum grinding conditions, Box-Behnken statistical design was used to determine the effect of parameter interactions on the d50 size. The media filling ratio significantly affects d50 size decrease compared with solid mass fraction and grinding time. The minimum d50 size was also achieved under optimum grinding conditions.

By W. A. Young

Bull Lake is one of several saline lakes situated a few miles north of Rawlins, Carbon County, Wyo. (figs. and 2).. The Bureau of Mines conducted preliminary investigations of sodium sulfate deposits in many of the lakes and performed detailed work on Bull Lake. This investigation consisted of drilling 11 vertical holes through salt beds using diamond core bits and Iwan-type auger bits. Bull Lake lies in a shallow, closed depression in loosely consolidated sand. The salt beds, ranging in thickness from 2.5 to 26 feet, occur above a thick bed of shale of upper Cretaceous age. The salts appear to have been deposited in the lake from surface and subsurface drainage. The source of salt is undoubtedly the enclosing sedimentary rock's exposed to the west of the basin. Sodium sulfate in the deposits probably is present as mirabilite or Glauber salt (Na2SO4-10H2O). Chief impurities in the deposits arc mud and sand. Other soluble salts present average approximately 1 percent combined. Cores from the 11 holes were analyzed in the Bureau of Mines laboratories at Salt Lake City. Drilling totaled 512 feet. Results of analyses are given in the appendix.

Jan 1, 1951

By I. Hague

Support liners for underground applications include steel and timber sets, meshing and lacing, screen/mesh, shotcrete and thin support liners (superskins). Over the past few years, major advances have been made in the design and application of liners; especially shotcrete and thin support liners. For shotcrete in mines these advances include the common use of slick-lines to solve logistics problems, the design of alkali free accelerators, the use of synthetic fibres and the new generation application equipment. The field of thin support liners is a new one but advances have been dramatic. This paper discusses the progress made and the need for standardization in definitions and testing for thin support liners. It concludes that the newer technologies have a huge potential positive impact on the industries, from both safety and cost points of view. Le chemisage de soutènement pour extraction souterraine comprend des cadres d’acier ou de boisage, mailles et chapeau, cribles/mailles, béton projeté et des chemisages minces de soutènement (super-peaux). Dans les dernières années, des progrès considérables ont été fait dans la conception et application des chemisages, en particulier les chemisages de soutènement en béton projeté et les chemisages minces. Pour le béton projeté dans les mines, ces progrès comprennent l’utilisation courante de lignes de minerais broyés fin pour résoudre des problèmes de logistique, la création d’accélérateurs sans alcali, l’usage de fibres synthétiques et d’une nouvelle génération d’outillage. Le domaine des chemisages minces de soutènement est très récent mais les progrès ont été rapides. Cette étude présente les progrès accomplis et discute du besoin de standardisation dans les définitions et les tests pour chemisages minces de soutènement. La conclusion est que les technologies nouvelles présentent un énorme impact potentiel positif sur les industries, du point de vue à la fois de la sécurité et de la rentabilité. Unterstützungsverkleidungen für Untertaganwendungen inkludieren Flecht und Seilwerk, Gitter/Geflecht, Spritzbeton und dünne Unterstützungsverkleidungen (superskins). Während der letzten Jahre wurden grosse Fortschritte im Design und in der Anwendung der Verkleidungen gemacht; besonders bei Spritzbeton und dünnen Unterstützungsverkleidungen. In Bezug auf Spritzbeton in den Gruben schließen diese Fortschritte den allgemeinen Gebrauch von Rutschbahnen ein um Logistikprobleme zu lösen, das Design von alkalifreien Akzeleratoren, den Gebrauch von synthetischen Fasern und die neue Generation von Anwendungsausrüstung. Der Bereich der dünnen Unterstützungsverkleidungen ist neu, aber die Fortschritte sind drastisch gewesen. Diese Arbeit behandelt den erzielten Fortschritt, die Notwendigkeit der Normierung in den Definitionen und in der Prüfung dünner Unterstützungsverkleidungen. Sie kommt zum Schluß, daß die neueren Technologien, sowohl vom Gesichtspunkt der Sicherheit als auch der Kosten, eine sehr große potentielle positive Auswirkung auf die Industrien haben.

Jan 1, 2003

Flinders Power, formerly NRG Flinders, is considering the possible use of low rank coal from Lake Phillipson, South Australia (SA) in its power stations at Port Augusta, SA. Typically, this coal contains about 35% moisture and 10% ash. Unfortunately, it also contains high levels of sodium (1% Na) and chloride (0.95% Cl) with a Na2O level in ash of 18.9%. Such levels cause serious problems during coal combustion, making the use of as-mined coal impractical for power generation. This paper describes the development of an aqueous leaching technique to remove 90% of the sodium and chloride and to yield a product with a Na2 O level in ash of less than 3%. Small-scale agitation leaching tests with good quality tap water at ambient temperatures showed that the coal needed to be crushed to minus 5.6 mm to obtain maximum removal of water-soluble sodium and chloride in 30 min. Leaching kinetics, but not the ultimate removal of salt, were enhanced by the use of higher temperatures (up to 150°C), but this was deemed uneconomic. Varying the pulp density between 20% and 50% had little effect on extractions and there was no benefit in multiple stage water washing. The best results by water leaching were 69%~74% extraction for sodium and 95%~97% for chloride, meaning that the sodium removal was well below the target level. From SEM examinations of the leached product it was concluded that the remaining sodium was organically bound to the carbon atoms in the coal. Further tests using aqueous solutions containing cation exchange additives such as calcium chloride (CaCl2) or ammonium chloride (NH4Cl) or sulphuric acid (H2SO4) showed that significantly enhanced sodium extractions were possible and target specifications were met. Two options, namely a single-stage and a two-stage leach, were then investigated. In a single-stage leach with additive, minus 5.6 mm coal was leached at 33%~50% solids for 30 min at ambient temperature and then filtered and washed with fresh water. This gave a sodium removal level of about 81% and a Na2O level in ash of about 5%. These levels do not quite meet tar-get specifications. In a two-stage leach, the coal was first leached with water alone without an additive as in the single stage leach, and the washed residue re-leached under similar conditions for about 5 min with an additive (CaCl2), and then filtered and washed. This gave a cumulative sodium removal of 96% and a Na2O level in ash of 1.4%~2.4%. These levels are well within target specifications.

Jan 1, 2014

By Guangqing Zhang

The paper presents results of a systematic study of synthesis of titanium oxycarbide and its chlorination. Titanium oxycarbide was produced by carbothermal reduction of titania in hydrogen, argon and helium. Formation of titanium oxycarbide started at 1200°C in all gases. The reduction was the fastest in hydrogen. Formation of titanium oxycarbide in hydrogen was close to completion in 120 min at 1300°C, 60 min at 1400°C and less than 30 min at 1500°C. Reduction in argon and helium progressed at a similar rate and reached 90-95% after 300 min at 1400-1500°C. The chlorination of titanium oxycarbide was ignited at 150-200°C. Chlorine partial pressure and gas flow rate strongly affected the chlorination rate. Chlorination of titanium oxycarbide produced with carbon to titania molar ratio 2.5 at 235-400°C was close to 100% in 30 min.

Jan 1, 2009

By E. W. Dewing

The solubility of A14C3 in cryolite melts has been determined by holding the melt with aluminum in a graphite crucible for 4 hr at temperature, quenching the crucible in water, and analyzing the frozen salt by CH4 evolution. The solubility is given by log(wt % Al4C3) = 1.298 -1.l74 (wt ratio NaF/AlF3) independent of temperature in the range 985" to 1080°C. Additions ofA1203, .NaCl, CaF2, or LiF up to 10 wt pct do not affect the solubility, provided that LiF and CaF2 are replaced by equivalent NaFin calculating the ratio. The variation with ratio can be accounted for quantitatively on the hypothesis that the Mechanism of solution is Al4C3 + 2AIF3 = 3Al2CF2 since the solubility varies as (aAIF3) 2/3; Mechanisms involving C", C2- , AlC- , A12C2+, and Al2CF+are re-jected. At ratios above 1.5 truces of c;- are also present. It was noticed some years ago in this laboratory that carbon specimens made cathodic in a cryolite bath decrease in diameter over a period of time.' It was also found that cryolite which had been melted with aluminum in a graphite crucible was sometimes yellow, and that A14C3 could be seen intimately embedded in the cryolite crystals. CH, could be recovered by acid attack. There was thus reason to believe that A14C3 had a genuine solubility in molten cryolite, and the object of this work was to measure it. EXPERIMENTAL AND RESULTS A graphite crucible, 2 in. ID and 2.5 in. deep with a close-fitting lid, contained about 150 g of cryolite (plus additives) and about 20 g of 99.99 pct pure Al. It was placed in a vertical Inconel furnace tube, covered with refractory brick to provide thermal insulation, and the top of the tube was roughly sealed with disks of asbestos paper. An alumina tube led argon down to the level of the top of the crucible to expel air, and an alumina sheath with a Pt-10 pct Rh ther-mocouple inside was positioned between the crucible and the wall of the Inconel tube. The tube was heated in an electrical resistance furnace for the desired length of time; the refractory bricks were then removed, and the crucible was lifted out with tongs and quenched in water. After such a crucible was broken open it could be seen that its inner surface was yellow owing to the presence of A1,C3, and sometimes needle-like crystals could be observed (at X75 magnification) growing out into the nielt. It was concluded that Al,C, had been present as a separate phase when the crucible was at tenlperature and that the melt had been saturated: in

Jan 1, 1970

By I. E. Wahn, E. A. Boutin

"The Manibridge Mill is unique in its treatment of relatively high grade nickel-copper ore because in the mill design are included one 10' diam. x 10' Maxwell cell, and three 12' diam. x 12' tank cells. These large cells are used as rougher-scavenger cells. Three 8' diam. x 8' tank cells as well are used for cleaning and recleaning of the tank cell concentrate.Flexibility of flow is the main criterion in the tank cell circuit. Targets from these cells are a high grade nickel-copper product with a minimum of talcose gangue.The operation of the tank cells has been encouraging and they have performed well with both low and high grade heads, yielding a high grade concentrate product.Manibridge Tank CellsDescription:The tank cells at Manibridge consist of one 10' x 10' Maxwell cell, three 12' x 12' tank cells, and three 8' x 8' tank cells. The four large cells are currently being used as rougher scavenger cells. The three small cells are used as cleaner cells.Both sets of tank cells consist of Denver steel tank and Super Agitator Mechanisms with steel beam super-structures. The agitator mechanism has a totally enclosed ball bearing spindle housing with a cold rolled steel shaft, and a stanclard standpipe with adjustable collar.The air rings for the tanks were fabricated by Nelson Machinery. Both large and small cells have injection rings with equally spaced air holes in the bottom centre line of the ring.Air is supplied to the tank cells by a Dresser Clark low pressure air blower.The following is a table of pertinent data on the tank cells:"

Jan 1, 1974

By A. W. Deurbrouck

The Bureau of Mines analyzed 13 samples collected from three Randolph County coalbeds. The Peerless and Sewell bed samples were generally of metallurgical quality as received from the mines or could be easily upgraded. How-ever, the Lower Kittanning coa1bed samples proved to be quite inimical to upgrading to metallurgical quality.

Jan 1, 1966

By D. Allan Coutts

Demonstration projects using hydrogen as a fuel are becoming very common. Often these projects rely on project-specific risk evaluations to support project safety decisions. This is necessary because regulations, codes, and standards (hereafter referred to as standards) are just being developed. This paper will review some of the approaches being used in these evolving standards, and techniques which demonstration projects can implement to bridge the gap between current requirements and stakeholder desires. Many of the evolving standards for hydrogen-fuel use performance-based language, which establishes minimum performance and safety objectives, as compared with prescriptive-based language that prescribes specific design solutions. This is being done for several reasons including: (1) concern that establishing specific design solutions too early will stifle invention, (2) sparse performance data necessary to support selection of design approaches, and (3) a risk-adverse public which is unwilling to accept losses that were incurred in developing previous prescriptive design standards. The evolving standards often contain words such as: ?The manufacturer shall implement the measures and provide the information necessary to minimize the risk of endangering a person?s safety or health.? This typically implies that the manufacturer or project manager must produce and document an acceptable level of risk. If accomplished using comprehensive and systematic process the demonstration project risk assessment can ease the transition to widespread commercialization. An approach to adequately evaluate and document the safety risk will be presented.

May 1, 2007

By L. Ferland, D. LaRonde, J. C. Caron

"The free-world production of columbium ore concentrates has doubled in the last five years. St. Lawrence Columbium and Metals. Corporation has contributed largely to this expansion, its production rate increasing from 720 tons of concentrates per year in 1961 to 2 200 tons in 1965.To follow the normal market development, the Company initiated an engineering study aimed at establishing the most economical mining methods, thus permitting it to increase its milling rate from 1,000 tpd in 1964 to 2,000 tpd in 1967 and possibly to 3,000 tpd in 1968. The results of this study pointed out the advantages to be gained in converting from an open pit to an under-ground operation. This paper describes how the mining engineering department has successfully developed ""stopes"" from the walls of its No. 2 open pit, in order to assure continuity of its operation during the interval required to develop its underground mine."

Jan 1, 1967