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Commercial explosives range from pure emulsions to pure ANFO, with blends of these providing interesting alternatives: energy is often adjusted through addition of aluminium, or the control of density. The energy rating of explosives is derived chiefly from detonation codes, which are used to derive expressions for the internal energy change of the detonation products as they do work under expansion. While all codes used for this purpose work on the basis of Ideal detonation, it is common knowledge that commercial explosives operate in the Non-Ideal domain, which affects the mode of energy delivery to the environment. However, since Ideality represents the foundation from which actual performance evolves, it is valuable to examine the intrinsic energy release of a formulation before attempting to understand the influence of Non-Ideality. In examining the Ideal pressure profile of fundamental formulations, remarkable correlation has been found with field performance, and this increases understanding of the influence of various formulation modifications, especially in regard to the stage at which energy is released, and the effect on rockbreaking. This work has emphasised the value of attempting to understand and define better the non-ideal detonation process.

Jan 1, 2001

By G. Castillo, G. Thies, C. Bissue

"Newmont’s Phoenix mine began gold production in 2006 and has since experienced difficulties in reaching design throughput due to variability in ore hardness. In 2010, a debottlenecking study was conducted, generating multiple options to increase throughput of the existing Phoenix Mill through a series of phased expansions. An option was selected in early 2011 to increase the current concentrator capacity by approximately 25% through two phases. The first phase of the project was the installation of a secondary crushing and screening circuit in order to reduce SAG feed size from a P80 of 6 inches to 2 inches. The second phase focuses on downstream unit operations in the concentrator aiming to relieve existing bottlenecks such as flotation. This paper analyzes the design, commissioning, and operation of a recently installed SAG Pre-crush circuit (Phase 1). The design discussion will focus on concept development, flowsheet design, design criteria, process models, design limitations, and control philosophy. Discussion on the integration of operating data and flowsheet into design during engineering will be presented. Actual operating data of major equipment is gathered from the commissioning and operation of the circuit and compared to the initial design models. Conclusions will be drawn on equipment design factors used during engineering, and the success of model integration into operation. The paper concludes on the successes of the project and where improvements can be made during design.INTRODUCTIONThe Phoenix mine is located within 25 miles of the town of Battle Mountain, Nevada. The mill processes copper, silver, and gold ore. Production started in 2006 and has since struggled to reach the designed tonnage of 33,600 stpd due to the variability in ore hardness. In production year 2010-2011, the Phoenix mill average daily throughput of 33,000 stpd. In 2008, a larger primary crusher (FLS 60/89 gyratory crusher) was installed to operate in parallel with the originally supplied primary crusher (Metso 50/65 gyratory crusher), in order to provide additional capacity upfront in the circuit so that the primary crushing circuit could keep up with the mill.In 2010, a mill debottlenecking study was completed to assess the various options that could be implemented to increase the current mill capacity. The study was completed in late 2010 and contained four tonnages that Phoenix could achieve through various expansion scenarios. A single option was selected in early 2011 to increase the mill capacity from 33,000 stpd to 48,000 stpd. The selected option looked at a four phased expansion that would increase the capacity of the Phoenix mill and address the mill’s current bottlenecks:"

Jan 1, 2013

By Barry Olson

The Peñasquito deposit in Mexico is one of the largest grassroots precious metal discoveries to be developed in recent years. Goldcorp Inc. acquired the gold-silver-lead-zinc property with the acquisition of Glamis in 2006. The company has since committed US$1.5 billion to construct the mine, mill and associated facilities. The first of two 50-kt/d (55,000-stpd) mill and flotation lines is currently being commissioned while engineering and construction continues on the second line. A high-pressure grinding roll (HPGR) will ultimately take total throughput to 130 kt/d (142,000 stpd). The Peñasquito property is located in the northeast corner of Zacatecas state, Mexico. The elevation of the property averages 1,900 m (6,200 ft) above sea level and it is situated in a wide east-west valley. Except for one small outcrop (Peñasquito), the area is covered by up to 30 m (98 ft) of alluvium.

Jan 1, 2009

By W. E. Robinson

Oil-shale kerogen was processed into oil and oil products before the first oil well was completed by Drake in 1859. However, because of economic and other advantages, natural petroleum has been the principal source of liquid fuels and lubricants since 1859 and is a convenient root of many [organic] chemicals in common use today. In recent years the difference has narrowed between the cost of producing liquid fuels from well petroleum and other sources. This narrowing of cost difference has resulted both from the increased cost of finding new sources of petroleum in the United States and the experimental demonstration of lowered costs for synthetic liquid fuels by the Federal Bureau of Mines and by industry. Available petroleum resources of this country are being reduced and eventually may be inadequate to meet the demand. Alternate means of assuring an adequate supply of liquid fuels for this country include the development of processes for utilizing other carbonaceous materials such as oil shale and coal.

Jan 1, 1960

By Binbin He, Baiwei Lei, Rehamutula·Rouzi, Zheng Wang, Chao Li

Methane explosions are highly destructive and constitute a primary hazard affecting mine safety. Seals are commonly employed to obstruct the propagation of methane explosions within tunnels, with the aim of reducing the damage caused by methane explosions. In order to study the influence of the seals’ position on the parameters of methane explosion damage, this study takes the Lake Lynn Experimental Mine No. 501 in the United States as a background case. It investigates the methane/air explosion damage parameters at different positions of seals in a fully sized roadway using the GASFLOWMPI code. The coupling mechanism between methane explosion gas expansion and reflected waves is analyzed. Finally, the variation patterns of explosion damage parameters are analyzed based on explosion damage criteria. The results show that as the distance increases between the seal and the explosion source, the maximum overpressure and impulse at the seal decrease exponentially, and the decrease is more significant when the seal is closer to the explosion source. The maximum velocity and maximum dynamic pressure increase first and then decrease, reaching their maximum values at approximately 115 m. They are approximately 163.355 m/s and 30.485 kPa, respectively. According to the analysis of explosion damage criteria, it is found that overpressure damage is the main form of methane explosion damage. But the damage of impulse and dynamic pressure is not be ignored. The relative position between the seal and the gas expansion area significantly impacts the parameters of methane explosion damage due to the coupling effect of gas expansion and the overpressure reflected wave from the seal. When the seal is set in the gas expansion zone, the further the seal is from the explosion source, the greater the dynamic pressure damage and the more minor the overpressure and impulse damage. The closer to the explosion source, the more significant overpressure and impulse damage changes. When the seal is set outside the gas expansion zone, the further the seal is from the explosion source, the more minor the overpressure and impulse damage to the seal, and the dynamic pressure damage increases first and then decreases.

Apr 24, 2024

By Yin Zhang, Xiaoyu Huang, Mi Wang, Bencheng Du, Youduo He

"Burners are important facilities for blast furnace stoves to raise hot-blast temperature up to 1200°C. Common types of two-ring ceramic burners have very long flames so that part of combustion occurs in the upper part of the chequers and will cause damage to the refractory materials. Using computer simulation to analyze the turbulent diffusion flame in the combustion chamber, some good results were obtained. A new type of ceramic burner will be installed by Anshan Steel Complex in stoves of blast furnace number 4. A pilot experiment was done on the new burner. The experimental data have shown that the mixing condition was improved and the length of flame was shorter with the new type of ceramic burner.IntroductionPulverized-coal injection can give significant operating saving, reducing coke rate in blast furnace(BF) operation. However, during high rates of coal injection, extra heat must be compensated in hearth to maintain certain raceway adiabatic flame temperature. One of the effective methods for heat compensation is to raise hot-blast (HB) temperature up to 1200°C. Nowadays, since the fuel being combusted in stoves is BF gas only, in which the calorific value is down to round 3000 kJ/m3 , to increase the combustion ability and to provide a suitable length of flame in combustion chambers of stoves becomes more important. In other words, designing a good ceramic burner which will affect to HB temperature and stove lifetime is drawing more attention."

Jan 1, 1999

By Bernardo J. Jiménez Vega, Edy L. T. Montalvan

During the last phase of the Circunvalacion Norte project in San Jose, Costa Rica, preliminary designs for an underpass structure of over 16 km (10 miles) considered drilled shafts as an earth retaining system. Since the project’s execution was delayed and close to the deadline, it was necessary to optimize this structure, with the drilled shafts being the most critical aspect. The key element in order to obtain an improved design was characterizing the job site with a specific site study for seismic demand, and the use of advanced numerical modelling, considering soil-structure interaction. The site investigation comprised the CPT, PMT, MASW geophysical tests, deep exploration drilling, and triaxial compression tests. The terrain was modeled using an advanced constitutive model with hardening plasticity calibrated from the triaxial tests. Plaxis software was used to calibrate the seismic model for the terrain and for the dynamic analysis. Two conditions were considered for the retaining structure: free-head and fixed head. A parametric study with drilled shafts of 1.0 m (3.3 ft) and 1.2 m (3.9 ft) in diameter, and center-to-center spacing of 1.3 m (4.3 ft) and 3.0 m (9.8 ft) was conducted in order to obtain an optimized structure. For each condition of the drilled shaft wall, the computed deformations were compared for two spectrum designs: site-specific spectrum and seismic code generic spectrum. Finally, a dynamic analysis was performed to check the performance of the drilled shafts with optimized spacing using a control earthquake. Based upon seismic performance curves, the analysis showed the possibility of greater spacing for the drilled shafts compared to the original design, obtaining a 32% reduction in the total length of the drilled shafts in the project.

Oct 1, 2022

By J. H. Zhang

An atomic force microscope has been used to measure the forces acting between two silica and two rutile surfaces in the presence and absence of cationic surfactants, CnTACl (n = 12~18). The forces measured in the absence of surfactant can be fitted to the DLVO theory. At short separations, however, the silica surfaces exhibited repulsive hydration forces, while the rutile surfaces did not. On the other hand, the forces measured in the presence of the cationic surfactants show long-range attractions that are larger than the van der Waals forces. The long range attractions are the strongest at of the point of charge neutralization (p.c.n.), which decreases with increasing surfactant chain length. The possible origin of the long-range attraction has been tested in view of the charged-patch model of Miklavic et al. (1994). However, the sizes of the patches back-calculated from the model were much larger than those the patches (or hemi-micelles) determined experimentally and reported in the literature. It is, therefore, suggested that the long-range attractions observed in the present work are due to the structural response of the water molecules in the vicinity of hydrophobic surfaces.

Jan 1, 2014

By B Chi, A Mahanta, R A. M Maddever, O Dominguez

BHP Billiton, in collaboration with Sodern and CSIRO, has developed a downhole logging tool for measuring geochemistry in situ. The FastGradeTM 100 (alternatively, FG100), exploits pulsed fast and thermal neutron analysis (PFTNA) to analyse the rock. This method is based on the detection and measurement of characteristic gamma rays emitted from isotopes in the material that become briefly radioactive when they are bombarded with neutrons. The tool outputs raw spectra arising from three types of neutron interaction, namely, inelastic scattering, neutron capture and neutron activation, which occur in successive time-windows (Smith et al, 2015). The spectra contain peaks at specific energies that are characteristic of the different elements interacting with the neutrons, the gamma count of which is related to elemental concentration. BHP Billiton uses in-house data processing software to convert the measured spectra to elemental concentrations.Much work has been done to understand the tool response under a wide variety of environmental and operating conditions, including logging speed, borehole rugosity, the presence of cavities, water etc. Effort has also been directed at understanding and quantifying the current sources of error in our conventional assays due to sample collection, preparation, and laboratory instrumentation in order to use this information as a baseline to compare against the FastGradeTM 100 results.To date, the FastGradeTM 100 primary use has been as a verification tool (JORC, 2012). However, beyond this, it has considerable potential to improve productivity in both exploration and production environments due to its ability to provide geologists with assay results soon after a hole is drilled.This paper presents initial test work and tool performance, including accuracy and precision under various conditions. Results are illustrated by comparing tool measurements to assays from laboratory samples collected from both reverse circulation and diamond-drilled holes.CITATION:Chi, B, Maddever, R A M, Mahanta, A and Dominguez, O, 2017. Near real-time assay with downhole assay tool (FastGrade™ 100), in Proceedings Eighth World Conference on Sampling and Blending , pp 137–144 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

The Development of a Non-Roasting Technology for Polymetallic Gold and Silver-Bearing Sulfide Concentrates Treatment

Sep 13, 2010

By A Croll

A panel cave using LHDs for ore extraction came into production at Premier in 1990 at a depth of 630 metres below surface on the western side of the mine in the BA5 mining block. A post-undercut mining sequence was used with all development on both the undercut and production levels completed prior to the undercut being advanced over the pre-developed drawbells. Support and rock mass damage on the production level was extensive as the undercut moved overhead. Undercutting and coarse fragmentation created problems. The mining sequence was changed to an advance undercut with the minimum of development and support undertaken on the production level prior to the undercut moving overhead. Only once the abutment stresses had stabilised were drawbells developed and final support installed. The height of the undercut drill design was decreased from 18 to 13 metres. The changes resulted in markedly less rock mass and support damage on the production level. Lessons learned in the BA5 mining block on the 630 level were incorporated into planning and scheduling the BB1E mining block which came into production on the 732 metre level on the eastern side of the mine in 1996. An advance undercut mining sequence was planned, undercut height was minimised and undercutting parameters were optimised in terms of the BA5 experience. Numerous problems still occurred. As the undercut area increased in size severe spalling from the cave back resulted in vertical propagation of the cave to a height of 30 metres instead of the planned 13 metres. The resultant coarse fragmentation created secondary blasting problems and an excess of undercut ore that had to be loaded and trammed, slowed the rate of undercut advance. The planned mining sequence was compromised and considerable support and rock mass damage resulted on the production level below. Once these problems had been overcome the undercut advanced at the planned rate and continuous caving initiated at the predicted hydraulic radius. At a later stage the unexpected ingress of water hampered undercut drilling and slowed the rate of undercut advance in a section of the cave. Leads and lags between adjacent tunnels and the overall face shape could not be developed as planned. The rate of natural horizontal cave propagation exceeded the rate of undercut advance and three undercut drilling tunnels were extensively damaged. More tunnel development on the production level prior to undercutting than was planned resulted. The slow advance of the undercut and high abutment stresses caused extensive damage to installed support and the rock mass on the production level, 15 metres below. Experience in the BB1E mining block on the 732 metre level has taught that an advance undercut mining sequence reduces damage on the production level markedly. Extremely tight control on the rate of undercut advance, leads and lags between adjacent tunnels and overall undercut face shape as well as extraction ratio, tunnel development and support sequence on the production level below is required. Premier Mine plans to implement a block cave at a depth in excess of 1000 metres within the next decade. All the experience gained on current mining levels together with data collection and numerical modeling is being used to plan the proposed mining operation. The geotechnical challenge of mining at this depth in weak rock has been identified as the greatest risk to the project. Challenges centre around adopting the correct mining sequence, limiting the extent of rock mass damage associated with undercutting and effective support. The hydraulic radius needed to initiate caving, fragmentation, drawpoint spacing, secondary blasting and the possibility of seismicity are geotechnical concerns that are being addressed. Results to-date suggest that a pre-undercut mining sequence with all development and support on the production level carried out only after the undercut abutment stresses have passed overhead will have to be implemented.

Jan 1, 2000

By S. Kamalpour

It has been observed that the productivity of ferromanganese furnaces, and the stability of metal and slag compositions, vary considerably according to the type of coke used as reductant. However, the desired properties of coke for optimum furnace performance are not well understood. In this investigation, the behaviour of four cokes, which exhibited a wide range of performance in ferromanganese production, was investigated by means of laboratory simulations of reducing conditions in the furnace. The Stationary Charge in Controlled Environment (SCICE) technique was used to simulate the conditions in the furnace shaft. Batches of raw materials, mixed in the same proportions as used in practice, were heated at fixed rates to 900, 1100 and 1300°C then cooled. The mass loss was used as a measure of the degree of reduction. Conditions in the lower part of the furnace were simulated by means of melt-reduction experiments in which lumps of coke were drilled out to form crucibles in which enriched ferromanganese slags were reduced at 1500 and 1550°C then cooled. An examination of the raw materials and the cooled, reacted charges using a variety of analytical and characterization techniques enabled the sequence of reaction and changes in morphology of the raw materials to be followed. This enabled an understanding of the behaviour of the cokes during reduction to be developed, which was then used to explain the observed performance of the cokes in practice. By relating the observed behaviour of the cokes in the laboratory tests to measurable properties of the unreacted cokes and to their observed performance in practice, it was shown that to achieve high productivity and good furnace performance, cokes should be selected to have moderately high reactivity towards CO2 (Boudouard reactivity) relative to conventional iron blast furnace cokes.

Jan 1, 2004

By R. G. Henley

Mount Isa copper concentrate was combusted in a laminar-flow furnace. The conditions simulated those likely to be encountered in flames in flash smelters of the Outokumpu (air as oxidant) and INCO (oxygen as oxidant) types. The range of conditions studied was as follows: T 400-1400°C, 02 0-100%, SO2 0-95% for residence times up to 0.23 s. The distribution of sulfur, arsenic and lead between the particles and the gas phase was studied. Combustion was very rapid provided the concentrate was adequately dispersed, i.e., no agglomerates. The importance of the latter is discussed. It was possible to oxidize 80% of the sulfur present in the con¬centrate after only 0.1 s reaction time at 1000°C in an atmosphere contain¬ing 8.5% 02 and 12.5% SO2. Best volatilizations (90% of the As, 52% of the Pb) were obtained under localized conditions attained in an air-type flame. Average volatilizations were: air-type flame, As 50%, Pb 32%; oxygen-type flame, As 40%, Pb 30%. The substitution of oxygen for air reduced the arsenic volatilization. The products of combustion were mainly cuprospinel and cuprite; small inclusions of elemental copper were found in some of the particles. At high temperatures, there was a loss of copper due to vaporization of CU( g) CuO kg) (g)

Jan 1, 1983

By James M. Harrington, A. Azra Bilgin, JoAnn Silverstein

The prevention of AMD in situ is more attractive compared to subsequent downgradient treatment alternatives that do not involve source control. AMD source control can be achieved by shifting the microbial activity in the sulfidic rock from pyrite oxidation to anaerobic heterotrophic activity. This is achieved by adding biodegradable organic carbon amendments to the sulfidic rock. This technique was applied in an abandoned mine pool with a pH of 3-3.5. Following treatment, near-neutral pH and decreased effluent heavy metal concentrations were achieved. In situ bioremediation by enhancement of bacterial iron and sulfate reduction is a promising technology for AMD prevention.

Jan 1, 2005

By David Burgess, Hershiel H. Hayden

Experiments at the Somerset mine, Colo., under an agreement between US. Steel Corp. and the US. Bureau of Mines are described. A test was made of the tube bundle method of mine air sampling which was developed for European longwall mines; some 300,000 running feet of tubing provided continuous monitoring at 38 locations. Carbon monoxide concentrations were obtained with standard deviations of less than 1 ppm and oxygen concentrations with standard deviations of less than 0.2%. A base level of CO index (ppm CO evolved per percent 0, removed) was determined to be zero to 20 through most of the passageways of the mine. However, in one working section where the coal was initially hot (about 180°F within a pillar) the CO index was demonstrably higher, 120 trending upward to about 60 when smoke appeared and the section was sealed. The data are discussed in terms of laboratory experiments on CO evolution from coals.

Jan 1, 1977

By Henry Kreisinger, F. K. Ovrız

Some of the investigations conducted by the Bureau of Mines have for their object the collecting and disseminating of information regard- ing methods by which the fuels of the country may be most effi- ciently used. As the analysis of flue gases tends to develop better methods of firing, which in turn reduces waste of fuel, the Bureau of Mines in this bulletin presents for the benefit of those in charge of boiler plants and all other persons interested detailed information on methods of sampling and analyzing flue gases, and on the utilization of the analyses in promoting boiler-room economy. This bulletin is intended to be a companion to Technical Paper 80," and is written in plain and nontechnical language, as far as pos- sible, so that it may be readily understood by persons who have not had the advantage of a technical education. Whenever possible, illustrations of apparatus and methods of handling have been used rather than elaborate descriptions. The material presented in this report is arranged in two parts. The first part contains the description of the apparatus and the methods used in sampling and analyzing flue gases. The second part gives experimental results obtained with the different methods of sampling and collecting flue gas that are recommended in the first part of the report. Only simple apparatus and methods are considered, as they are accurate enough to show the large heat losses due to the use of too much air, and are also accurate enough to indicate any incomplete combustion losses of economic importance. Without doubt the loss due to large excess of air is the greatest one in the boiler room, and can usually be greatly reduced by making proper use of gas analysis. Before engineers in the isolated industrial plants can be induced to analyze for small traces of combustible gases, they must be first taught how to analyze for carbon dioxide (CO), and they must learn to appre- ciate the great possibilities of reducing loss from large excess of air. Furthermore, in the face of the great difficulty of obtaining a fair

Jan 1, 1915

By Jason Rock, Rob Thompson, Lee Julian

This paper presents an innovative shift in inhibited bulk products with specific reference to their manufacture and application.

Feb 1, 2020

During the past three years Lurgi's Circulating Fluid Bed (CFB) technology has been successfully applied to roasting of refractory gold ores and con- centrates. In comparison with the so-called Stationary Fluid Bed roasting systems, a considerable improvement of gold recovery, to around 95 per cent, has been demonstrated and achieved on many occasions in pilot CFB units and in commercial CFB roasting plants as well. The major reason for such improved gold recoveries is the excellent controllability of the roasting process in the CFB reactor system. Here, temperature, gas atmosphere and solids residence time are more precisely controllable at optimal values during roasting operation in order to achieve the highest possible gold recovery in the subsequent leaching process step. Further dominant benefits of CFB roasting systems are their flexibility with regard to feed material, throughput capacity, dry or slurry feed, almost unlimited oxygen enrichment, direct fuel addition and in situ capture of SO2 in the presence of limestone and dolomite. The system will accept 50 per cent turndown ratio, large variations in feed composition and particle size, as well as a variety of different fuel types. The commercial applications of CFB roasting systems for gold con- centrates have been realized so far at Fimiston, Kalgoorlie/Westem Australia and for whole ores at Cortez, Nevada/USA.

Jan 1, 1991

By John Nunes, Frank R. Larson

Temperature-dependent functions of various ten-sile flour stress and fracture parameters were investigated on iron and low composition alloys of Fe-C, Fe-Cr, Fe-Mn, and Fe-Ni. Data were obtained over a range of test temperatures from 200" to -196"C at an initial strain rate of 0.01 min". It was found that the strain-hardening exponent, n, for the Fe-Ni alloys increased significantly at very low testing temperatures with increased alloy addition. Also, the stress and strain at fracture followed a predictable transitional type of behavior. The flour stress-temperature dependence was evaluated employing the relation: M where it is shown that composition can strongly influence the constant M. An empirical formula describing this effect is as follows: M = MI (equivalent at. pct Ni)-'" Some preliminay, tests were run on several commercial steels to test the generality of this relationship. One of the phenomenological explanations of the ductile-to-brittle transition encountered in bcc metals is based upon the difference in the temperature dependence of the flow and fracture stresses.' It states simply that the fracture stress is relatively insensitive to temperature and that the yield or flow stress rises rapidly with decreasing temperature so that, when the flow stress reaches the fracture stress, brittle fracture occurs without appreciable plastic deformation. This behavior is illustrated schematically in Fig. 1 where the ductile-to-brittle transition is shown to occur at two possible temperatures. The lowest temperature, TB, represents essentially completely brittle behavior while the higher temperature, TN, represents "notch" brittle behavior. Support for this theory is obtained when it is observed that fcc metals, which do not commonly have a ductile-to-brittle transition, also do not commonly exhibit any strong temperature de- pendence of the yield stress. This relationship of yield or flow stress behavior with the ductile-to-brittle transition has been generally observed for most metals representative of these two crystallo-graphic structures. One exception to this generalization appears in the case of tantalum where no apparent ductile-to-brittle transition has been observed. However, this may simply be an indication that this type of behavior is not directly related to the flow stress and that some other mechanism such as twinning must also be operative. A comparison of the typical temperature dependence of the yield stress of some representative metals is shown in Fig. 2. In the study of the temperature dependence of the strength of metallic materials, considerable ef-

Jan 1, 1963

By W. W. Odell

Engineers interested in the manufactured-gas industry have witnessed p pronounced improvements in gas-generating equipment and marked changes in operating procedure during the past decade. In spite of these changes, however, the trend of development in the near future seems to be doubtful. Uncertainty exists mainly because no one can yet accurately calculate the number of years which will elapse before petroleum products become too expensive for, general use in making gas. Research in this field has been active, and the ultimate results are awaited with interest. Some engineers predict that in the future coking coal will be carbonized on such a large scale that coal gas will be used (straight or modified) for city distribution; others maintain that gas oil will be used in large quantities in the production of base gas; they believe that it will be economical to use oil even at appreciably higher prices. The question involves, among other; factors, consideration of initial and relative costs of equipment, flexibility of operation, salability of coke, cost of distributing different gases, and the relative value of by-products, It is common belief that for many years large quantities of oil will be used in gas-making, particularly in the generation of peak gas or that water gas will be used for the synthetic production of hydrocarbons to enrich additional water gas. In this paper interest centers in a discussion of the practicability of employing synthetic processes in view of reported investigations of the chemistry of the synthetic reactions. For many years it has been known that the chief components of water gas would react chemically under proper conditions to form methane. As long ago as 1903 a patent3 was issued in this country for a gas-making process which included the synthetic production of methane. More recently the studies of numerous investigators here and abroad have shown that besides methane it is possible to produce other paraffins, olefins, and additional, materials adaptable for enriching water gas or for other uses. The question arises: In what manner, if at all, can such processes be incorporated, as a part of the gas-making scheme in a city-gas plant?

Jan 1, 1928