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By Steven R. Musselman

The bending strength and flexural stiffness of a micropile at its threaded connection is less than its intact strength and may fail due to thread slippage or by fracture through the pin (reduced cross-sectional area of male threads in the threaded zone of the casing). The mode of failure depends on the reduction in cross-section necessary for machining the threads, and details of the threaded connection such as the length of threaded connection, size and shape of threads, and the thread density (threads per inch). Based on data from bending tests conducted on 9-5/8 inch diameter micropile casing, a method has been developed to predict the ultimate moment capacity and initial bending stiffness of round threaded micropile connections. Two modes of failure were observed from four-point bending tests conducted at the University of Illinois on 9-5/8 inch casing with round threads. Threaded micropile casing connections with an effective thread length of 1.35 inches typically failed by slippage at the threads (jump out), while connections using an effective thread length of 1.89 inches failed by fracture of the pin. These two failure modes were described by W.O. Clinedinst in his report to the American Petroleum Institute on tension tests of threaded pipe casing. Clinedinst developed an empirical formula to determine the tensile strength of threaded connections. A method to predict moment capacity for threaded micropile connections by modeling the micropile cross-section and applying Clinedinst?s equation to determine the max tensile stress along the threaded connection while satisfying force equilibrium is proposed. The predicted moment capacity for threaded connections using this approach is within ten percent of measured for both modes of failure observed from the bending tests.

Jan 1, 2007

By K. J. Kruger

Aluminium alloys have gained popularity in many industries due to their high strength and low weight. One shortcoming of aluminium alloys is their poor resistance to abrasion and erosion wear compared to materials such as stainless steels. In this project, aluminium alloy 2014 (AA2014) was coated with a 1.5 mm thick laser-deposited layer composed of silicon, copper, and aluminium with the aim of increasing the wear resistance. The amount of silicon, copper, and aluminium added to each sample was determined by a mixtures model. It was discovered that the Al-Cu system is very sensitive to silicon additions and that wear resistance depends on the primary phase to solidify as well as on the final phase distribution. Two primary phases were identified; alpha aluminium and theta intermetallic. It was observed that the clad layer increases both the hardness and wear resistance of AA2014, and that the material solidifying as primary alpha aluminium displayed a lower hardness but higher wear resistance than the samples containing primary theta phase. All clad layers performed better in terms of wear resistance than the unclad samples. The knowledge gained and principles used in this project could be applied to many other aluminium alloys.

Jan 1, 2014

ARTHUR PHILLIPS,* Bridgeport, Conn. (written discussion?).-It is to, be regretted that the very valuable paper by Messrs. Bassett and Davis did not appear in the early war period. The data presented would have been of inestimable service to inspectors, of cartridge brass who, admittedly, had little or no knowledge regarding the relation of grain size to temperature of anneal, and no real appreciation of, the significance of the Brinell hardness test. The paper is of considerable interest to, metallurgists also. WALTER R. HIBBARD, ? Bridgeport. Conn. (written discussion§).-The writer has carefully studied Messrs. Bassett and Davis's paper with considerable interest, inasmuch as our laboratory has tested cartridge brass by means of a Brinell machine. In March, 1917, at the suggestion of the Technical Department of the American Brass Co., we started a comparison of grain-size measurements and Brinell hardness of-cartridge brass with a gage of 0.1 in. or greater. This was continued until March, 1918, when we adopted the Brinell hardness test as standard for brass 0.1 in. gage or greater, and discontinued grain-size measurements upon this metal. The data collected during the test showed that the Brinell hardness indicated more accurately how the metal acted in actual working operations. It was also more reliable because two manipulators check themselves closer by the Brinell test than by the grain-size measurements. It also consumed less time in making the tests. Alfred V. de Forest, formerly assistant research engineer of our laboratories, has described the apparatus and some of the checking results in a paper read June, 1918, before the American Society for Testing Materials.1 The writer hopes that a more satisfactory. method for testing cartridge brass and gilding in gages thinner than 0.1 in. may be devised than the present method of grain-size measurements.

Jan 3, 1919

By R. E. Grace

WHEN an Fe-C alloy, partially reacted to pearl-ite, is quenched rapidly enough to suddenly stop the growth process, it may be expected that any carbon concentration gradients will freeze in situ in the newly formed martensite. A short tempering treatment should precipitate finely dispersed iron carbide particles in approximately the same distribution in which carbon existed during the growth process. Examination with the electron microscope of areas of tempered martensite adjacent to the pearlite-martensite interface should reveal the existence of preferred areas of precipitation. Fig. 1 is an example of an electron micrograph used in this study. Small sections of a commercial steel (0.9 pct C, 1.6 pct Mn, 0.25 pct Si) were austenitized at 945°C in air for 45 min, furnace-cooled to 697°C, iso-thermally reacted to pearlite for 30 min, and quenched into iced brine. Two samples were tempered 5 and 20 min, respectively, in air at 498°C and were subsequently quenched in water. The samples were mechanically polished and etched in 1 pct picral. Collodion replicas were made by the conventional technique; these were shadowed with chromium at about 650' from the horizontal, and electron micrographs were taken at a linear magnification of 14,200X. Prints were made at a magnification of 44,100X. Lineal analysis of the prints was made as a function of the interlamellar spacing and volume percent of iron carbide. Straight lines were drawn into tempered martensite between adjacent lamellae at a distance S/4 or S/6 apart, where S is defined as the interlamellar spacing measured at the pearlite-martensite interface. The volume percent of iron carbide was measured along each of these traces with a "gage length" of S/10. The results of analyses of two samples are shown in Table I. The area included between the S/2 and S distance from the interface could be considered homogeneous within the sensitivity of the measuring technique. This value was used as a proportionality factor to evaluate an arbitrary carbon content of homogeneous austenite, and also as a parameter by which error in measurements could be evaluated. Results of the lineal analysis are shown in Figs. 2 and 3. Fig. 4 shows the statistical nature of the interlamellar spacing for all lamellae measured in this

Jan 1, 1954

By J. Kunze, R. Degal

During the last 100 years, the submerged arc furnace has been one of the most amazing diversified melting units. These furnaces have found their application in more than 20 different main industrial areas such as iron, ferro alloy, chemical industry, lead, zinc, copper, refractory, titanium oxide, recycling, phosphorus etc. Such an evolution was only possible because of tremendous efforts in research and development and due to the large range of design solutions. The worldwide strong competition also forced the industry and plant suppliers to develop highly efficient, economically balanced units in optimized sizes and with long lifetimes, to adapt to the market conditions. Regarding the environment, the plants improved significantly in terms of water treatment plants and off-gas treatments as well as on site recycling units. This paper will give a short overview regarding the history of the furnace and the latest developments in today?s main application fields: ferro alloys, non-ferrous, special application and recycling. In addition new activities in research and developments are briefly discussed.

Jan 1, 2004

By Paul M. Jr. Musgrove, Donald C. Moore

Conventional Smelting Practice Conventional copper smelting practice varies from smelter to smel¬ter, but generally consists of some or all of the following unit processes: roasting, smelting, converting, and fire refining. Roasting. Copper sulfide concentrates can be smelted directly or after an initial roasting step. Roasting is used in some smelters because roasting prior to smelting increases smelting capacity, less energy is required to melt hot roaster calcines than wet sulfide concen¬trates, roaster off gases are high in Sot concentration, 5-15% SO2, and some volatile impurities are removed from the concentrate prior to smelting. However, many smelters do not use roasters, because the problems associated with handling hot dry calcines outweigh the advantages mentioned. Concentrate roasting is performed in multiple hearth or fluid bed roasters. If the moisture is low, roasting can be performed autogenously, usually at 500-600°C. High roasting temperatures are avoided because excess oxidation of the iron compounds may lead to magnetite formation. Magnetite is detrimental to reverb operation because mag¬netite can combine with refractory minerals to form a highly viscous slag. This slag prohibits efficient matte-slag separation and leads to excessive copper losses. Also, magnetite can settle through the matte layer, deposit on the furnace bottom, and consequently reduce furnace capacity. Roasting is carried out only on sulfide concentrates prior to smelt¬ing in reverb or electric furnaces. For smelting processes, such as the flash and continuous that rely on the exothermic heat of oxidation of the sulfur minerals, roasting is not practiced. Reverberatory Smelting. The predominate copper smelting fur¬nace for the past 50 years has been the reverb. These furnaces are typically 100-120 ft long, 30-35 ft wide, and 12-15 ft high. A typical furnace layout is shown in Fig. 2. Refractory brick linings cover all internal surfaces of the furnace. Originally the flame was directed to reverberate or reflect off the furnace ceiling and melt the feed material. Current practice is to direct the flame down the furnace length to melt the concentrate. A method of charging the concentrates or calcines, generally along the side walls to minimize refractory erosion, is incorporated in the furnace design. The copper concentrates, calcines, and fluxes charged into the reverb undergo a series of complicated reactions as the temperature of the mixture increases. The reaction of the iron and copper sulfides with the oxygen in the furnace produces a molten Cu25-FeS mixture called matte. Copper smelting metallurgy is based on the fact that sulfur has a greater affinity for copper than for iron and most other common metals. Therefore, in a system containing copper, the copper will preferentially remain as a sulfide compound until all of the other metals have been oxidized. The oxidized metals combine with silica to form a silicate slag that floats on the matte and is removed from the system. Reverberatory furnace smelting chemistry can be approximated by the following chemical equations: FeS2 + O2 - FeS+ SO2 (1) The formation of FeS ensures that any copper present other than as sulfides will be reduced by the relationship: CuO2 + 2FeS + O2 - CuS + 2FeO+SO2 (2) or 2Cu +FeS - Cu2S + Fe (3) As the molten charge travels down the furnace, continued oxida¬tion of the iron minerals and sulfurization of the copper minerals occurs. When all of the copper has been converted to sulfides, the iron sulfides can then be further oxidized as: FeS + (3)2 O2 FeO + SiO2 (4) The FeO reacts with the silica added as flux in the furnace charge. A simplified equation is: FeO + SiO2 -FeO SiO2 (5) The iron silicate slag formed is skimmed from the surface at the end opposite the burners. The copper content of reverb slag is usually less than 0.6% Cu and is discarded. Matte is removed along the side wall and is taken to the converter for oxidation of the remaining sulfur and iron. The main objectives in reverberatory smelting are to produce a molten Cu2S-FeS matte containing 30-60% Cu and a throwaway slag. Production of matte permits complete conversion of all copper minerals into copper sulfides, which can migrate because of specific gravity differences, through the lighter slag layer. Also, the molten matte droplets collect the noble metals, gold and silver, as the matte settles in the furnace. The large settling area of the furnace provides enough separation time to produce a low grade slag, which can be discarded without further processing. High heat losses are associated with reverberatory smelting be¬cause of the large volume of gases sweeping through the furnace. Therefore, an outside source of heat is required to keep the smelting reaction going. Natural gas, fuel oil, or pulverized coal are used as this heat source.

Jan 1, 1985

By Robert D. Pehlke, Weldon L. Daines

The reduction of manganese oxide from a basic slag by silicon dissolved in liquid iron at steelmaking temperatures was studied to determine the rate-controlling step for the process. The experiments were carried out under an argon atmosphere in a resistance-heated vertical-tube furnace. The two liquid phases, slag and metal, were held in zirconia crucibles. Sampling and chemical analysis of the slag phase led to time-concentration curves for the system. Results obtained by varying parameters such as temperature, stirring rate, concentration, and melt geometry defined the limiting reaction mechanism. The reduction of manganese oxide by silicon is a fast reaction and reached equilibrium within 90 min. The rate of stirring has a marked effect on the reaction rate, while, on the other hand, the effect of temperature is very small. This identifies the rate-controlling step as diffusion rather than interfaciul chemical reaction. The variation of other parameters revealed that a) diffusion of manganese in the iron phase is the slow step, b) the value of D/6 for manganese in iron at 1550°C is 7x 10-4 cm per sec, c) the energy of activation for the apparent rate constant is 7 kcal per mole, and d) increasing the amount of silicon in the iron decreases the diffusion coefficient of manganese. THE equilibrium relations pertinent to the reduction of manganese oxide from a steelmaking slag by silicon dissolved in liquid iron have been studied, but little is known about the mechanisms that control the rate of the process. The purpose of the present investigation was to study the rate of reduction by silicon and to determine the rate-limiting step. The effects of stirring rate, temperature, composition, and melt geometry were investigated as a means of identifying the controlling step. On the laboratory scale, relatively little work has been done in the area of slag-metal kinetics, primarily because of the problems confronted in attempting to contain liquid slags and metals in laboratory crucibles at steelmaking temperatures. Since graphite is an ideal material for a crucible, several investigations have been carried out on the reduction of various oxides from a slag by carbon in graphite-saturated iron and on the transfer of sulfur between a slag and graphite-saturated iron. Most of this work has been performed in induction furnaces. Studies where the container was not graphite are extremely limited. A single kinetic study of manganese transfer between molten iron and basic slags was carried out by Sano, Shiomi, and Matsushita.' These investigators prepared calcium oxide and titanium oxide crucibles to contain the two-phase system. Only a few experiments were carried out and the results had to be treated qualitatively. Despite the paucity of kinetic data, a large quantity of information is available in the literature concerning the thermodynamics2-12 and physical properties'3-21 of the slags containing manganese oxide and the dilute liquid iron alloys containing manganese and silicon which were involved in this research program. EXPERIMENTAL METHOD A vertical-tube resistance-heated furnace was used in this investigation to study the slag-metal reaction Although most previous slag-metal studies were carried out in induction furnaces, a resistance furnace has several advantages including better control of temperature and stirring rate. Hence, a resistance furnace was selected for this study, and its design is shown schematically in Fig. 1. Slip-cast, fine-grained, low-porosity, lime-stabilized cubic zirconia crucibles were used for the kinetic experiments. The crucibles were 4 1/2 in. high and 2 1/8 in. OD with a 1/16-in. wall. The crucibles were only slightly

Jan 1, 1969

Treatment of the Siirt-Madenk÷y Ores by Flotation

Sep 13, 2010

By Samuel S. Wyer

Over 8,000,000 people in the United States depend on natural gas for their cooking, heating and lighting service. This service has been made possible only by the investment of large amounts of capital in transportation lines connecting the gas wells to the various communities, thus combining a hazardous mining operation with a public utility service. The effect that making these lines " common carriers" will have on the present and future service to these 8,000,000 or more people is of far reaching ethical and economic importance, and deserves careful consideration. As an introduction, it must be conceded that: 1. Natural gas, although a mineral and obtained by a mining operation—with more uncontrollable and uncertain features to cope with than exist in the mining of coal or other minerals—when served to the public becomes a public utility service. 2. The governmental power to regulate all public utilities in the interests of the public cannot be successfully disputed. 3. Mere suggestion of inconvenience to the utility is wholly irrelevant, as it cannot be considered or allowed to influence in making a defense against governmental regulation. Unfortunately it is not generally appreciated that:.. I . 1. Legislative enactments are not necessarily laws, and cannot abrogate economic laws or alter engineering facts. 2. There is a clear distinction between "common carrier7' and "public utility," although the terms are frequently confused. "A common carrier is one who undertakes for hire to transport persons or goods, or both, from place to place for all persons indifferently, the term implying indifference as to whom shall be served, and an equal readiness to serve all who apply, in the order of their application." On the other hand, property becomes a "public utility" only "when for a particular purpose the public have a right to resort to the premises and make use of them." It is, therefore, important to note that not all public utilities can be regarded as common carriers. The U. S. Supreme Court has already

Jan 1, 1915

By P. A. Wright

The note describes the steps involved in the combination of results reported by Shiraishi and Bell in 1968 and 1970 and by Mills and Turkdogan in 1964. Shiraishi and Bell derived from their vapour-pressure measurements an expression for the activity coefficient of tin implying that the miscibility gap in the two-liquid region is symmetrical about the N = 0-5 axis. The limits of the miscibility gap were reported by Shiraishi and Bell and measurements were reported graphically by Mills and Turkdogan. Least-square parabolas are fitted to the transformed results of Shiraishi and Bell and of Mills and Turkdogan for the miscibility gap in the liquid tin-iron system. Back-transformation from these curves gives limits at 1438 K and equations are derived that appear to be a fair average of existing data, although a third term for the activity coefficient equation needs to be investigated

Dec 1, 1971

By Victor S. Sazhin, Alexander Kostenko

The hydrochemical method, which is based on the separation of aluminium oxide and silicon oxide by the hydrothermal decomposition of aluminosilicates by alkaline solutions in the presence of calcium oxide, can be effectively used for the complex processing of high-silicon aluminium ores. In this case, the silica is bound to a slightly soluble compound: Na20.2Ca0.2Si02•H20 (under the conditions: [&k]= 9, CaO/SiO2 = 1.05, alkali concentration in the solution: over 300 g/l Na20, T = 240...300 °C). If alkaline solutions of 100...150 g/l Na20 concentration are used, Ca0•SiO2•H20 or 2Ca0•Si02.0.5H20 compounds, depending on calcium oxide dosage, are formed at 280...320 °C. New methods for the crystallization of Na20.Al203.2.5H2O from concentrated alkaline solutions rand low-concentration solutions are proposed to isolate aluminium from solutions. The hydrochemical method, which involves no sintering process allows one to decrease the expenditure of heat by a factor of two, to reduce the investment and to exclude the pollution of the ambient air by dust-laden gases. The expansion of the raw-material resources base of

Jan 1, 1984

By Antonio Augusto Gorni, Kenji Camey, José Herbert Dolabela da Silveira

Recently several studies have been developed on the use of microalloyed steels with low Mn content (below 1%) in the controlled rolling of heavy plates for the manufacture of pipes. However, this novel concept of alloy has peculiarities in its thermomechanical processing. Lower Mn contents should lead to the acceleration of NbCN precipitation kinetics during rolling, leading to a reduction in the soluble Nb content in austenite that delays its recrystallization by drag effect. This fact, plus the heavy and fast passes applied under virtually isothermal conditions in a heavy plate rolling mill with high power, increases the risk of partial recrystallization during the finishing stage of the controlled rolling, since strain hardening of austenite becomes significant and the interaction between precipitation and recrystallization is increasingly delayed. The objective of this study was to analyze the evolution of mean flow stress during the finishing stage of controlled rolling in these low Mn, high Nb microalloyed steels, in order to better understand the metallurgical mechanisms acting during this process and identify conditions that allow full compliance with the requirements of this product class.

Oct 1, 2019

By M. R. Julien, A. Maqsoud, J. Martschuk, B. Bussière

Acid mine drainage (AMD) from mine wastes is one of the most challenging environmental problems currently facing the mining industry. When mining wastes have the potential to produce AMD, the effluents produced have to be managed to meet existing regulations on water quality. The LTA impoundment (property of Barrick Gold Corp.) located near Malartic, Quebec, contains sulphide tailings that have the potential to generate an acidic leachate. The closure option selected by Barrick was to construct a cover with capillary barrier effects (CCBE), in which the moisture- retaining layer is made of non-acid-generating tailings. Since its construction in 1996, the cover has been monitored to evaluate its performance. For that purpose, various parameters have been measured, including the volumetric water content and matric suction in the different layers of the cover. This paper presents some of the main results from the monitoring program that started eight years ago. The results show that the cover is able to maintain a high degree of saturation in its moisture- retaining layer, acting as an oxygen barrier. The actual performance of the CCBE on the flat surface of the 60 ha site is better than expected at the design stage. The only concern with the LTA cover is the effect of slopes that can reduce the performance of the CCBE during dry periods. However, these effects appear only for short periods of time, and are limited to very localized areas, so that they do not significantly affect the overall performance of the CCBE and its ability to limit the production of AMD.

Jan 1, 2006

By N. H. Jensen

SINCE the sixties, Utah has been one of the leading metal mining states of the Union. During the last fifteen years its mines have supported the largest smelting center in the world. Its rank as a metal producing state is reflected by its 1924 production which had a value in excess of $65,000,000 making it the leading silver producing state, third in both copper and lead and sixth in gold production. During the past year, metallurgical developments for the recovery of zinc contained in lead ores has made rapid progress so that the future zinc output will be of substantial importance. The largest silver mines of the nation and the world's largest open cut copper mine are within its borders. Settlement of Utah started in 1847, with the advent of the "Mormons," and originally the area of the state was much greater than now. The first metal mining

Jan 1, 1925

By William R. Adamson

This paper describes some of the results of previously unpublished research studies conducted in underground operations in Chile and Australia, where cross-hole seismic measurement profiles were interpreted in terms of dynamic modulus. This work dates from a period between 1987 and 1990 and the Author suggests that 30 years on, applying modern day technology, instrumentation and modelling methods, more meaningful, practical and applicable results may be obtained.

Feb 1, 2020

By M. K. Foster

Ten horizontal retort zinc blocks of a modified Hegeler design are in operation at Nueva Rosita, Coahuila, Mexico, and produce approximately 170 t of spelter daily, or 62 000 t/year. A block consists of two furnaces of 448 retorts each, making 8960 retorts as the plant complement. Each furnace block is fired with natural gas and air maintaining the combustion mixture in the furnace always slightly reducing. No attempt to recover energy through waste heat boilers is made. The spelter moves to market by rail and truck either in palletized bundles weighing approximately 1060 kg, as loose slabs weighing 26.5 kg each, or as 1088 kg ingots. At present 46% of the metal is exported and 54% is consumed domestically in Mexico. The present day trend toward equalized or alloyed spelter, as well as special shaped castings results in sales of 35% of the entire plant's production. Sulfuric acid is also produced by the Contact Process using vanadium pentoxide as the catalyst. The plant is basically a Monsanto contact system, producing approximately 68 t of 100% sulfuric acid daily. Both 98.5% sulfuric acid and 20% oleum are available. All of the acid made is consumed in Mexico. Shipments are made in 26,900 dm3 tank cars.

Jan 1, 1970

Geostatistical methods have become well established in the last two decades for the evaluation of ore reserves in base metal, industrial minerals, coal and gold deposits of the Witwatersrand type. However, there has been considerable debate about the applicability of geostatistical techniques when applied to vein-type gold deposits with hydro or epithermal mineralisation. The main problems stem from a lack of spatial continuity and the highly erratic sample values that characterise these deposits. This paper reviews some of the current geostatistical techniques that are applied to the evaluation of gold prospects.

Jan 1, 1992

By Th. G. Sahama

This paper contains some new heat-of-solution measurements of geikielite (MgTiO3), limonite (FeTiO3), fayalite (Fe2SiO4), and a natural forsterite in mixed acid (HF +HCl) and gives the results of a thermodynamic attack on the problem of stability of geikielite in rocks.

Jan 1, 1949

By Neale R. Neelameggham

"Ferrous and non-ferrous metal industries are used to handling several billion tons a year of ore bodies, fuel and fluxing agents by mineral processing techniques and varieties of extractive metallurgy ""Reduction"" processes. Metal industry know-how can be applied to meet the challenge of Reducing CO2 in the atmosphere. Processes for generating alloys of carbon and hydrogen by Reducing the CO2 and water mixture, [carbonated water or water vapor] called Soda, to easily stored fuels are normally endothermic. The processes are similar to generation of hydrogen alone from water which is also endothermic. But hydrogen is more difficult to store than compounds [or alloys] of carbon and hydrogen. This recycling of CO2 and water are possible by using other forms of energy by innovative carbon capture methods.Thermodynamic Diagrams developed for Soda [CO2 and H2O] - metal reactions provide hints for using low cost unused stored energy in un-recycled metallic waste for thermal conversion. Choices for conditions for the electrochemical approaches [using solar - wind - hydropower] are also discussed.INTRODUCTIONIn 2006, I was reading some of the arguments put forth by learned scientists on the benefits and lack of benefits of bio-fuels. I found that the arguments rose partly from the differing system boundaries that were chosen by one versus the other. Some part of the argument may have been based on political climate or atmosphere rather than the analytical science. This situation is seen when scientists discuss which came first - the chicken or the egg, the fuel or biological matter, the oxide or the element, and so on.Then I thought –[just like many of the learned persons participating in this symposium] that common fuels - regardless of them being simple hydrocarbons or oxygenated hydrocarbons or carbohydrates - can all be made from the respective oxides of carbon and hydrogen by simple chemical reductions efficiently carried out in an economical fashion. This is the systematic approach we take when designing a chemical or metallurgical process facility."

Jan 1, 2008

By Haydn H. Murray

Although alumina constitutes about ii percent of the earth's crust, it is expensive to separate and purify for the production of aluminum with the exception off the alumina in bauxite. The United states has a variety of non-bauxite resources that could substitute for bauxite, including high alumina clays, alunite, dawsonite in oil shale, anorthosite, and nepheline syenite. Each of these resources are discussed from the standpoint of geology, geography, processing, potential recovery, and environmental problems. Potential by-products include silica from clays, potash and sulfuric acid from alunite, soda ash from dawsonite, and soda ash and potash from anorthosite and nepheline syenite.

Jan 1, 1982