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By E. Roman, M. Brissette

"For its end of life, Kemess Mine processed its difficult-to-treat hypogene ore from the east pit, which is a lower grade copper and higher pyrite content gold ore. Metallurgical testwork showed that improvement was possible with finer grinding. In July 2010, small grinding media were introduced into the regrind mill resulting to a nearly 50% decrease of the power draw with a finer grind, an increase of 1.1% in the final copper grade, an increase of 1.2% in copper and 2.9% in gold recoveries at the cleaners. The overall recoveries of copper and gold increased by 0.6% and 1.3% respectively.INTRODUCTION Kemess Mine was located at 430 km North West of Prince George in North Central British Colombia. Its production started in May 1998 by Royal Oak Mines and was acquired by Northgate Exploration in 2000. Kemess reached its end of life production with its last of production on March 9th, 2011. The concentrator nominal capacity was 56,000 TPD consisting of a primary gyratory crusher feeding two identical conventional SAB circuits totalizing 35,840 kW available for grinding. Rougher flotation consists of four parallel rows of eight 130 m³ tank cells to produce a concentrate of 2% Cu and 6 gr/t Au which was pumped to a 5 m x 10.8 m regrind ball mill. The regrind installed power was 4,480 kW to generate a final grind of 80% passing 40 microns. This product fed the two stage cleaner flotation circuit, first stage being two parallel rows conventional 17 m³ Denver cells and second stage, two 3.3 m x 11.0 m flotation columns in series, designed and constructed by Kemess, to produce a 22% copper concentrate grade. The cleaner flotation middlings were returned back to the regrind mill (Froehling, Mohns, Roman & Grady, 2005; Froehling, Mohns, Rajwani & Fullam, 2007). The large copper-gold porphyry deposit was composed of 15% of oxidized supergene and leach cap ore and 85% of hypogene ore having three major alteration zones, mainly characterized by their sulphur/sulphide content. Chalcopyrite is the main copper mineral species with minor bornite. Gold was mainly present as free gold or electrum. The first alteration zone consisted of a phyllic alteration characterized by moderate and intense sericite alteration which had the highest mill throughput and twice the mine grade when in contact with the supergene horizon. The second zone consisted of a potassic alteration characterized by more competent groundmass and moderate to intense quartz stockwork which had a slightly lower mill throughput. Finally, a third alteration found beneath and on the east side of the deposit having almost no quartz stockwork and hardened groundmass, sulphide content is two to four times more. This zone had the lower mill throughput with significant drop in the mine average gold and copper grade. Through its mine life, the average life of mine copper head grade was 0.21% Cu and 0.64 gr/t Au. Head grades began to decrease from 2008 to be substantially lower in 2011 as shown in Table 1."

Jan 1, 2012

By T. Copland

"The decreasing availability of resources amenable to surface operations has led to increasing numbers of underground mines, with trends indicating this will continue into the future. As a result, there is a need for additional optimization processes and techniques for underground mines, with many analogous methods having already been developed for surface mining. Current methods for design and optimization of stope boundary selection and scheduling mainly involve heuristic methods which focus on a single lever. Individual optimality may be approached, but globally optimal results can be obtained only by an integrated, rigorous approach. In this paper we review previous methodologies for stope boundary selection and medium- to long-term scheduling and highlight the need for an integrated approach. Previous integrated approaches are reviewed and an improved modelling system proposed for shorter solution times and greater applicability to mining situations. Randomly generated data-sets for gold-copper mineralization are used to investigate the model performance, describing solution time as a function of data complexity.IntroductionThe increasing need for mineral resources is driving an increase in underground mines. Lower grade mineralization with larger amounts of overburden is becoming economically viable due to technological advances; however, the software and tools available for strategic underground mine planning are not well developed. Advances in the methods used to determine underground layouts and scheduling must occur to ensure underground mining is as optimized as open pit operations, as underground mining involves many more technical restrictions.The process of determining stope boundaries and scheduling is an example of an aspect of underground mining amenable to optimization (Topal and Sens, 2010). The current industry standard for medium- and long-term planning for sublevel stoping (SLS) is to exclusively determine stope outlines and then determine an appropriate sequence and schedule accordingly. This process violates the concept of optimality as integrating the constraints imposed by pre-determining stope outlines does not allow for considerations in scheduling to influence boundary planning (Ataee-Pour, 2005). An integrated planning process that combines both stope outlines and scheduling would approach the optimal solution and hence generate more value for operations. This investigation specifically deals with the underground sublevel stoping (SLS). Other underground mining methods such as block caving, sublevel caving, and room and pillar mining have unique characteristics and therefore require specific stope boundary/production scheduling considerations."

Jan 1, 2016

By Wilson G. L, Lord J. H

A detailed analysis of faulting indicatcs that blocks of "greenstone" have been thrust beneath the southern end of the Mt. Isa orebodies.This "greenstone" basement is considered to be a major structural control in the localization of these orebodies.INTRODUCTIONThis paper is based on exploration carried out by Mining Corporation (Aust.) N.L. from 1956 to 1960 in the area immediately south of Mt. Isa, Queensland. During this period over 20,000 ft of diamond drilling was completed together with costeaning and geochemical exploration.Early in 1959, it became apparent that diamond drill information could not be correlated with the current geological concepts of this area and a detailed geological appraisal became necessary. In all, sixty square miles were mapped at a scale of 1 in. to 500 ft, using enlarged aerial photographs. All drill core was logged and sections re-interpreted.Professor K. C. Dunham of the University of Durham consulted on this project and contributed through valuable discussion. Dr. A. Day of the University of Sydney carried out a gravity survey in February 1960 and Dr. H. Wilshire of the same University undertook microscopic examination of rocks from the area. Certain sections of the area were investigated geochemically by Mr. K. K. Hughes of New Consolidated Gold Fields (Asia) Pty. Limited in 1960.In outlining a theory of ore genesis in the area the writers have drawn heavily on the invaluable data published by many previous workers on the Mt. Isa field, in particular...

Jan 1, 1963

By A. V. Bradshaw, R. I. L. Guthrie

The behavior of large bubbles in the size range 4 to 25 cm3, rising through molten silver, has been studied. It was found that rising velocities were equivalent to those in aqueous systems of low viscosity. Mass transfer coefficients for oxygen bubbles dissolving in silver were found to be 0.036 ± 0.007 cm sec-1, being close to those predicted for transfer through the front surface of the spherical cap bubble only. It is suggested that the surface active nature of oxygen in silver could account for the relatively low coefficients obtained. MANY metallurgical processes involve interactions between gas bubbles and liquids. Examples include the removal of carbon monoxide in Open Hearth Steelmak-ing, the removal of sulfur by blowing air through copper matte during converting, and the removal of hydrogen from steel during vacuum degassing or inert gas flushing. The steps involved in such refining processes include; transport of the dissolved species to the bubble interface, adsorption and chemical reaction of the species at the interface, desorption of product molecules from the interface, and transport of product gas into the bulk gas phase of the bubble. It has been concluded1 that all the interfacial steps involved proceed so rapidly at steelmaking temperatures that transport of the solutes, present in the metal, become the important rate controlling factors provided nucleation phenomena are not restrictive. The O-Ag system was chosen for the investigation into gas bubble-molten metal interactions due to the relatively high solubility of oxygen that enables rates of oxygen transfer to be measured from changes in bubble volume. Other advantages of this system include the absence of a stable oxide phase at an oxygen pressure of 1 atm and the relatively low melting point of the metal which permits the use of a metallic container, providing that it is resistant to oxidation. In those metallurgical processes where bubbles have an important influence, bubble volumes are usually greater than 5 cm3. For this reason the present study relates specifically to single large bubbles of oxygen rising in silver. These bubbles adopt the characteristic spherical cap shape similar to that shown in Fig. 1 for a 30 cc bubble rising in water. After an initial investigation to determine the velocities of inert (nitrogen) bubbles rising in molten silver, experiments were carried out with oxygen and the rates of mass transfer between the oxygen bubbles and the silver were measured. EXPERIMENTAL Apparatus. The apparatus, Fig. 2, for containing molten silver, was constructed from "Nimonic 75" Alloy (75 pet Ni, 20 pet Cr, 5 pet Fe, Mn) and provided for the release of single bubbles from an hemispherical cup, situated at the bottom of the column. The cup was turned by translating the rotation of the drive shaft through 90 deg. This was accomplished by the use of a bevelled gear system, and a smooth drive was provided by the lubricating action of the silver on the gears. Since reliable high temperature seals at 1000°C were found to be impracticable, the filling and drive shaft tubes were extended outside the 3.5 kw resistance wire tube furnace, where connections were made using easily accessible O-ring seals. The apparatus remained gas tight to the atmosphere at pressure differentials far in excess of those used. The filling tube was connected via a small bore tube to the differential pressure transducer. Gas could be bubbled into the inverted cup from two i-in. tubes which passed down the inside of the column to preheat the gas. The temperature of the silver was maintained at 1020°C during all experiments. Measurement of Bubble Volume. In order to calculate mass transfer rates, it was necessary to obtain a continuous record of the bubble's volume during its passage through the column of molten silver. The method adopted for measuring the bubble volume involved closing off the top gas space to the atmosphere prior to each experiment, and recording the variation in gage pressure of this space during the formation and rise of the bubble. Since any change in bubble volume results in an equal change in top space volume, Boyles Gas Law may be applied (for isothermal con-

Jan 1, 1970

By Brian E. Davies, Bobby G. Wixson

INTRODUCTION The impact of modern mining and ore processing on the environment is readily minimised. Our improving knowledge of how pollutants are released to and move through the environment has been accompanied by better expertise in controlling these emissions. For example, when the new mines and smelters were developed in the Viburnum Trend of Missouri a sulfur dioxide pollution problem was quickly recognized and soon controlled. (Wixson 1974) But older operations were not efficiently organized and, despite their smaller scale, they often caused major pollution problems. The British mining fields are among the world's oldest and during the heyday of their operation (approximately 1750-1900) they were worked with- out regard to their environmental impact. The Rivers Pollution Commissioners in the mid-nineteenth century were led to remark that ore dressing was carried on in a slovenly and wasteful manner and the complaints by farmers, that river borne mine wastes were poisoning both their crops and stock, were justified. (Frankland and Mortan, 1984). The Comissioners report led to the 1876 River Pollution Act of Parliament, the first modern environment protection legislation. The development of mining since the last century is characterized by improved regulation of the pollution potential of ore dressing, smelting and refining. The collective memory is unfortunately long and pessimistic. A serious problem arises when old mines are reopened especially if the mine has not been worked for several years since local action groups may soon blame the new owners for causing problems which, in reality, are longstanding and were caused by the use of earlier state of the art technology. It is therefore essential that during the early development stages prior to reopening that comprehensive studies be carried out to identify and quantify local contamination problems. These baseline studies should include surveys on the nature and composition of old tailings disposal areas and other wastes on the mine properties. The composition of air and water should be monitored. Soils are long term sinks for all heavy metals and particular attention should be paid to soils within any city areas near the mine since there are sources of heavy metals in urban areas which are not connected with mining and ore processing. This paper describes some of the results of such a study around a prospective cobalt mine in Southeastern Missouri. It is restricted to the soil survey of forest and agricultural land which took place in and around Fredericktown, Missouri. The city is located at approximately 37° 30' North and 90° 20' West and lies 143 kilometers south of St. Louis. There are several metal mines near Fredericktown, including Mine La Motte, which is the oldest and was first opened in 1720. [Figure 1] is a location map of the area. The survey described here was in connection to the reopening of the Madison Cobalt Mine which was first worked in 1947.

Jan 1, 1985

By D Tuazon, M Powell, M Ziemski, G D. Corder

Although mining companies have made broad corporate-level commitments to adopt sustainability, there continue to be problems when attempts are made to adopt higher-level sustainability aspirations and translate them into appropriate targets and methods at the more-specific operational level. The integration of sustainability principles into minerals processing operational decision-making processes has unique challenges that are not addressed adequately by current tools and methodologies, yet impacts from operational decisions can have longer-term effects realised at closure and rehabilitation.This paper describes a proposed methodology to achieve the integration of sustainability at the operational level through a systematic and rigorous process of identifying and qualifying sustainability issues and opportunities in an operation. The methodology, starting from a sustainability point of view rather than an operational one, guides the identification of process issues and opportunities by examining the operation, unit-by-unit, similar to a Hazard and Operability (HAZOP) process. Each issue or opportunity is qualified according to its measurability, scopes of impact and consequences so that it may be understood fully and the correct engineering problems are formed. Through improved decision-making to account for broader sustainability factors, operations can better address environmental and social expectations and pressures (both corporate and community, as well as immediate and in the longer-term), whilst still delivering on operational and business goals.The methodology has been tested with two case studies at minerals processing operations. At one site, the methodology identified a dust issue which had considerable business risks (loss of valuable product) compared to conventional engineering analysis processes. The other site also benefited from using the methodology as an opportunity to improve the operation of the milling and flotation circuits was identified. The opportunity not only showed a potential to improve operational efficiency, but also potential improvements in water and energy efficiency and a resulting increased resilience against water and energy supply risks. It was important to utilise the holistic approach of the methodology in the identification of opportunities at this site; the goals of the operation showed a strong coupling between water and energy issues which would be difficult to overcome using the operationÆs current organisational model, which deals with such issues separately of each other.CITATION:Tuazon, D, Corder, G D, Powell, M and Ziemski, M, 2012. A practical and rigorous approach for integrating sustainability principles into decision-making processes at minerals processing operations, in Proceedings Life-of-Mine 2012 , pp 233-242 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By R. V. Ramani

"A computer simulation model of a dragline has beer developed for the study of alternative dragline deployment schemes for varying geological and mining conditions. In this paper, the mathematical aspects of the model, the input data and output results are discussed. An application of the model to a coal mine in eastern Kentucky is presented.IntroductionDraglines are very productive machines. To extend their operating ranges, they are operated in several modes such as advance benching, key cut, extended benching and pullback. Unfortunately, these variations result in low machine productivities. Appropriate methods to operate these machines must be developed on the basis of detailed analyses of dragline performance under varying geological and mining conditions. There are several standard engineering procedures for the selection of dragline, and design of a dragline pit (Ramani, Iroegbu and Manula, 1976). However, the complex interrelationship which exists among equipment, methods and natural conditions can be quantified only through orderly and systematic experiments.Computer simulation is well suited to studying these types of equipment selection and method layout problems. Several alternatives can be analyzed in a relatively short time by the modification of input variables. Also, the application of computer simulation models can significantly reduce the manpower and cost required for such analysis."

Jan 1, 1985

By J. L. Lehman, J. D. Sudbury, J. E. Landers, W. D. Greathouse

A full scale field experiment on cathodic protection of casing answers questions concerning (1) the proper criteria for determining current requirments, (2) the amount of protection provided by different currents, and (3) the transfer of current at the base of the surface pipe. Three dry holes in the Trico pool in Rooks County, Kans., were selected for cathodic protection tests. The three holes were in an area where casing failures opposite the Dakota water sand often accur in less than a year. Examination of the electric togs showed the wells to be similar to other wells in the field where casing in four of seven producing wells has failed. The three holes were cleaned out and cased with 75 joints of new 51/2-in. 14-tb J-55. Each joint was visually inspected and marked before it as run. The casing was bull plugged and floated in the hole 50 that the inside might remain dry and free of excessive attack. Also, if a leak occurred, a pressure increase could be observed on gawge at the surface. Extensive testing was done, including potential profiles, log current-potentid curves and electrode measurements from both surface and downhole connections. Based on these data, a current of 12 amps was applied to one well and 4 amps to mother. The third well was left to corrode. During the two-year period when the casing was in the ground, [he applied current was checked weekly, and reference electrode measurements were made about every two months. Three sets of casing potential profi1e.c were run. When the three strings were pulled, each joint was examined for type of scale formed, presence of sulfate-reducing bacteria, extent of corrosion nttnck and pit depth. Since the pipe was new when run, quantitative determination of the protection provided by current was possible. This is the first concrete field evidence to help resolve the many arguments about the proper method for selecting adequate current for cathodic protection of oilwell (-using. INTRODUCTION A casing string is run when a well is drilled. This pipe is supposed to protect this valuable "hole in the ground" for the life of the well. Often the casing does not last the life of the well; it is with these casing failures that this work is concerned. The cost of repairing a casing failure varies from field to field—from as much as a $30,000 per leak average in California to $5,000 per leak in Kansas. Additional costs other than actual repairs are also important. These include formation damage, lost production, etc. Casing damage caused by internal corrosion is important in some areas. Treatment normally consists of flushing inhibitor down the annulus, but further research is being done on control measures. The test described in this paper is concerned only with external corrosion. The problem of casing failure from external attack has appeared in several areas including western Kansas, California, Montana, Wyoming, Texas, Arkansas and Mississippi. Cathodic protection is currently being used in an attempt to control external corrosion. From reports in the NACE there are thousands of wells currently under cathodic protection. The quantity of current being applied ranges from 27 amps on some deep California wells to a few tenths of an amp being supplied from magnesium anodes on wells in Texas and Kansas. Considerable field and laboratory effort1,9,5,6 was exented on the problem of cathodic prctection of casing, and it became fairly obvious that this method could be used to protect wells. Early workers showed that current applied to a well distributed itself over the length of the casing and was not concentrated on the upper few hundred feet. Basic cathodic protection theory had shown that corrosion attack could be stopped by applying sufficient current. The problem resolved itself, then, into one of trying to decide just how much current was necessary. Various criteria were utilized in installing the many existing cathodic protection installations. These methods included the following. 1. Applying sufficient current to remove the anodic slope as shown by the potential profile." 7. Applying enough current to maintain all areas of the casing at a pipe-to-soil potential of .85 v.' 3. Applying the current indicated by a log current-potential (or E log I) curve." 4. Supplying the current necessary to shift the pipe to-soil potential .3 v." 5. Applying 2 or 3 milliamps of current per sq ft of casing."

By Tassos Grammatikopoulos, Mike Johnson, Niels Verbaan

Seabed polymetallic nodules, which contain significant quantities of metals key to electrification (nickel, cobalt, copper, and manganese) can be processed using several different metallurgical processing options, including direct smelting and subsequent hydrometallurgical refining of the copper/nickel matte, ammoniacal leaching (gas reduction or Cuprion), and acid leaching (often reductive). Many of these approaches suffer from reduced cobalt extraction, difficult physical performance, or overall circuit complexity in general, leading to increased risk to the overall project. SGS has considered pressure acid leaching of nodules for further investigation, as publicly shared data on this processing route stems from the 1970s and 1980s and is not always easily accessible. This paper will detail the series of tests conducted and provide updated results obtained (high Ni/Co/Cu recovery with limited Mn/Fe), as well as comment on the potential treatment options on the product solution and residue.

Feb 1, 2025

By Oscar A. Glaeser

MINE VENTILATION is an important factor in mine maintenance as well as having direct bearing on labor efficiency. Effective ventilation systems are costly, especially those for the deeper mines, but with intelligent direction the worth of a system is usually greater than its cost. In most mines using mechanical ventilation, and practically all deep mines, it has been found beneficial to equipment, timber, and the ground, to run the fan or fans continuously even though production has been curtailed or entirely suspended. Therefore, economies in ventilation may be overlooked when general cost reductions are necessary. The operating costs of a well-designed ventilation system should be capable of reduction during periods of curtailed or suspended operations. A mine that is ventilated by splits, or that can be sectionized, can reduce its fan-power costs considerably, and provisional divisions can sometimes be made in other mines, in which the air is ordinarily coursed through all the workings, without harmful effects.

Jan 1, 1932

By A. T. Haile

Detailed monitoring of the response of the rock mass between rockbolt reinforcement units subjected to a simulated seismic source has been successfully conducted. This work has shown the increase in amplification of the Peak Particle Velocity (PPV) with distance from a rock bolt unit, and, a minimum PPV for rockburst damage for the given site characteristics. This understanding, at this site, will allow the design of a suitable rock bolt spacing to prevent unravelling of the rock mass between the rock bolt units for a given level of seismicity. Or, alternatively, an estimation of the requirement for a suitable fabric support system, for the anticipated level of seismicity, can be made.

Jan 1, 2001

By Jie Ma, Bo Wang, Jieyu Zhang, Jian Zhao, Guangxin Wu, Shunli Zhao

"Nucleation and growth model based on a 3D CAFE model, which was incorporated with macro heat transfer calculation within ProCAST software was used to predict the solidification microstructure of austenitic stainless steel in twin-roll strip casting. The simulation results of solidification microstructure agreed well with experimental results of austenitic stainless steel. The effect of different casting process parameters on the solidification microstructure was simulated. The predicted results show that solidification microstructure is obviously sensitive to superheat and convection heat transfer coefficient. With the increase of superheat, the grain density decrease and the proportion of columnar crystal increase. In addition, the proportion of columnar grains increases when convection heat transfer coefficient increases. Thus, it was demonstrated that the solidification microstructure evolution of twin-roll strip casting could be predicted reasonably by using this model.IntroductionNear-net-shape casting technology is an important research area in the iron and steel industry today. Twin-roll strip casting represents a major area of concentration of near-net-shape casting technology. It has been widely used for its outstanding advantages, such as extended solubility of alloying elements, refined solidification microstructure and reduced microsegregation [1]. Furthermore, it is the most environmentally friendly, energy saving, and C02-sensitive way to produce steel strips [2]. Therefore, much attention remains to be paid to this aspect. A lot of published works indicated that the solidification microstructure of twin-roll thin strip has obvious effect on the thin strip properties [3, 4]. For the accurate control of parameters of the process are made difficult due to the complicated process and the multi-fold factors, great attentions have been paid to numerical simulations to provide insight into the solidification behaviors of the thin strip formed by twin-roll strip casting [5, 6].Simulations of casting solidification can provide a method to predict microstructure and to improving strip quality by controlling the process parameters."

Jan 1, 2014

By T. A. Henrie, D. C. Fleck, D. G. Kesterke

Uranium metal was electrowon from uranium dioxide dissolved in fluoride melts . The UO₂ was fed directly to the cell in a continuous manner . Electrolysis was performed at 1 , 200 ° to 1,300 ° C in electrolytes composed of UF4 , LiF , and BaFa . A single regulus of metal was collected in a confined area of the crucible . Product purity of 99.8 percent was attained . Carbon was the major contaminant . Compartmented cells were studied as a means of confining the oxide feed to the vicinity of the anodes .

Jan 1, 1964

By Cang Daqiang, Bai Hao, Li Ning, Liu Xueting, Lu Xin, Zhao Lihua, Li Hongxu, Wei Wei

"Based on the principle of carbon balance, a model was built to calculate C02 emissions of each process and correspondingly the total course of production in iron and steel making. The data from a typical integrated steelworks in China was applied in the model. The results show that the BF and coking process account for the most emissions. Generally, C02 emissions in integrated steelworks depend on three factors, resources utilization efficiency, energy utilization efficiency and energy consumption structure, which were considered in an equation in this paper. Especially, General Emission Factor (GEF) was proposed to assess the relationship between C02 emissions and energy consumption. The results show that, higher GEF will result in more C02 emissions with the same energy consumption and in iron and steel making, the optimization of energy structure and development of eco-industrial park both have significant benefit on the carbon reduction.IntroductionThe Global Warming resulting from the increase of Greenhouse Gases (GHGs), especially C02, in the atmosphere has become the main reason of global climate change, and the carbon reduction is one of the most important ways for the sustainable development [1]. The iron and steel making is a manufacturing industry based on iron-coal high temperature chemical process, in which plenty of C02 is emitted. According to the data from IPCC (Intergovernmental Panel on Climate Change) in 2001, iron and steel making emitted about 650 million tons ofC02 every year, which is the fourth largest industry of the fossil energy consumption [2]. According to the data from EEA (European Enviromnent Agency) in 2006, iron and steel making is the largest source ofC02 emissions, which accounted for about 18% of the total C02 emissions in European manufacturing industry [3].It is estimated that the application of various well developed energy-saving technology, such as Coke Dry Quenching (CDQ), Top Pressure Recovery Turbine (TRT) and Coal Moisture Control (CMC), can make the C02 emissions reduced by 0.5%-3% in iron and steel making, and the further C02 emissions reduction can be achieved if more new energy saving technology is applied, such as sintering plant heat recovery, electricity generation with steam generated from converter and the various by-products gas and the hydrogen making process from COG[4,5]. In addition, the application of membrane separation technology is well expected in iron and steel making [6]. For example, the application of C02 Capture and Storage (CCS) in blast furnace combined with the Pure Oxygen Top Gas Recycled BF (TGRBF) technology can reduce the C02 ennss10ns greatly by about 50%-60% [4].That is, as a kind of C02 end-treatment technology, CCS applied with other technology of C02 recovery would be more meaningful. Actually, reduction of the C02 emissions by changing the structure of energy consumption and raw materials with new process of iron and steel making, such as direct reduction process or smelting reduction process [4,7,8], is the trend of ferrous metallurgical engineering, which is regarded as a kind of source-treatment technology. In this sense, source-treatment technology is more pivotal for the solution of carbon reduction in the future than the current popular energy saving technology. Hence, it is necessary to build the C02 emissions model based on the iron and steel making process and evaluate the relationship between the energy saving and C02 emission reduction."

Jan 1, 2012

Paper written on project work carried out in partial fulfilment of B. Eng (Mining Engineering) degree The stability of a ferrosilicon dense medium suspension is one of the most important parameters to keep under control since it determines the density gradient of the medium in the separation zone and thus directly influences separation sharpness. The stability of ferrosilicon suspensions were characterized using settling tests employing a differential pressure method. Particles smaller than 45 µm and especially the ore fines played an important role in the settling behaviour of the solids. High medium stability is favoured by ore fines, fine medium particles, and high medium densities. Keywords: dense media, ferrosilicon, dense medium stability, ore fines

Jan 1, 2002

By K. J. Gill, P. Chiotti, J. T. Mason

Thermal, metallographic, and vapor pressure data were obtained to establish the pkase boundaries and the standard free energy, enthalpy, and entropy of formation for the compounds in the Y-Zn system. Three coinpounds with stoichiometric formulas of YZn, YZn2, and Y2Zn17 melt congruently at 1105", 1080°, and 890°C, respectively. Four compounds with stoiclziometric formulas of YZn3, YZn4, YZn5, and YZn,, undergo perztectic reactions at 905", 895", 870º, and 685ºC, respectively. Three eutec-tics exisl in this system with the .following eutectic temperatures and zinc contents in wtpct: 875ºC, 23.2 Zn; 1015ºC, 51 Zn; 865ºC, 82 Zn. The YZn, pkase undergoes an allotropic transformation. In the two phase YZn2 -YZn alloys the trans.formation gives a weak thermal arrest at 750°C, whereas in the two phase YZn2-YZn3 alloys no thermal arrest is observed and the transformation occurs over a temperature range below 750°C. At 500°C the free mzergies of formation per lnole vavy from —18,090 for YZn to —53,430 fov YZr11 and corresponding enthalpies vary from -24,050 to -92,080. The free energies and enthalpies per g atom as a function of composition show a maximum for the YZn2 phase; the 500°C values are -9580 and -13,180, vespectively. 1 HE only information found in the literature on Y-Zn alloys was the observation reported by Carlson, Schmidt. and speddingl that Y-20 wt pct Zn forms a low melting alloy. The alloy was produced by the bomb-reduction of YF3 and ZnF2 with calcium in an investigation of methods for producing yttrium metal. The solubility of yttrium in zinc has been determined by P. F. woerner2 and reported by Chiotti, Woerner, and Parry.3 In the temperature range 495" to 685°C the solubility may be represented by the relation In these equations N represents atom fraction of yttrium and T is the temperature in degrees Kelvin. The purpose of the present investigation was to establish the phase diagram for the Y-Zn system and to determine the standard free energy, enthalpy, and entropy of formation for the compounds formed. MATERIALS AND EXPERIMENTAL PROCEDURES The metals used in the preparation of alloys were Bunker Hill slab zinc, 99.99 pct pure, and Ames Laboratory yttrium sponge. Arc-melted yttrium buttons contained the following impurities in parts per million: C-129, N-12, 0-307, Fe-209, Ni-126, Mg-13, Ca < 10, F-105, and Ti < 50. Some of the alloys containing 70 wt pct or more of Zn were prepared from yttrium containing 5000 ppm Ti as a major impurity. Tantalum containers were found to be suitable for all alloys studied and were used throughout the investigation. The pure metals, total weight about 30 g, were sealed in 1 in. diam tantalum crucibles by welding on preformed tantalum covers. A 1/8 in. diam tantalum tube was welded in the base of each crucible for use as a thermocouple well. Welding was done with a heli-arc in a glove box which was initially evacuated and filled with argon. The sealed crucibles were enclosed in stainless steel jackets and heated in an oscillating furnace at temperatures up to 1150°C. Homogeneous liquid alloys were obtained within a half hr at these temperatures except for alloys containing less than 20 pct zinc. The latter alloys were held at 1000º to 1100°C for 2 to 3 days in order to obtain equilibrium. After the initial equilibrations the tantalum crucibles containing the alloys were removed from the steel containers and used directly for differential thermal analyses. Further annealing heat treatments for alloys in which peritectic reactions were involved were carried out in the thermal analyses furnace. After thermal analyses the tantalum crucibles were opened and the alloys sectioned and polished for metallographic examination. In the following discussion alloys referred to as "quenched" were obtained by quenching the sealed stainless steel jacket containing the tantalum crucible and alloy in water. The differential thermal analyses apparatus used was a modified version of the one described in an earlier paper., The graphite crucible was replaced by an inconel crucible, the nickel standard and sampie container were separated by a 1/8 in. MgO plate, no getter was used, and provisions were made to

Jan 1, 1963

By Liangying Wen, Xuewei Lv, Yuelin Qin, Feng Zhu, Guibao Qiu, Chenguang Bai, Meilong Hu, Shengfu Zhang

"The COREX process is the first reduction ironmaking technology with coal and pure oxygen to get high quality hot metal, which consumes a lot of high quality lump coal and some coke. In order to increase the utilization of fine coal, reduce coke consumption and enhance the competitiveness of the technology, the combustion behavior of pulverized coal injection in melter gasifier is studied experimentally. The results show that the combustion rate of PCI increases with the increase of temperature. And the combustion rate increases with decreasing coal particle size. Compared bituminous coal with anthracite, the former’s burning ratio is higher than the latter in the same granularity. The combustion effect is remarkable when coal blend of bituminous coal and anthracite with the smaller particle size is pulverized in COREX process.IntroductionThe COREX process is the first reduction ironmaking technology with raw coal and pure oxygen to get high quality hot metal, which consumes a lot of high quality lump coal [1-3]. However, the proportion of lump coal in raw coal is very small, and it is avoidless to produce fine coal because of mechanical coal cutter and storage and transportation process, so it is important to resolve utilization of fine coal in COREX ironmaking process in order to energy conservation and reduce the cost of hot metal [4]. Currently, Coal briquetting technology is adopted to utilization of fine coal in COREX process [5], but coal briquetting system has high investment cost and requires feasible adhesive agent. The pulverized coal injection (PCI) into a blast furnace is being used on a global scale to improve the stability and reduce the cost of blast furnace operations [6]. The successful development of PCI in blast furnace is contributed to pulverized coal in COREX melter gasifier. However, it is different in PCI process between COREX melter gasifier and blast furnace, and the differences are as follows: firstly, The air is injected into blast furnace, which temperature is about 1200 ?, but in COREX melter gasifier the normal temperature oxygen is blasted, so PCI in blast furnace begin burning in blowpipe, but the combustion of PCI in COREX melter gasifier is only in raceway. Secondly, the racway of COREX is smaller than that of blast furnace of the same size. So, the combustion behavior of PCI is complex in COREX melter gasifier, which is not use for reference."

Jan 1, 2012

By Marcela C. Santini, Luiz A. Teixeira

"Surface conditioning (also referred as etching) of plastics prior to metallization is generally conducted with sulfuric I chromic acid solutions. Although these baths perform well technically, the presence of Cr (VI) imposes serious operating problems of an environmental nature. The present work reports ·the results of a study of surface conditioning o(ABS using solutions based. on sulfuric acid, with hydrogen peroxide and/or nitric acid, replacing chromic acid, as oxidants. Process performance was evaluated by SEM and by the uniformity and adherence of electroless nickel coatings applied on selected conditioned samples. The results showed that the evaluated types of solutions could be optimized to perform as well as the chromic-based baths, with a much superior environmental quality.IntroductionMetallization of plastics is normally undertaken for either decorative or functional purposes. Through metallization, the specific properties of plastics such as light weight, design flexibility, and low-cost of manufacturing are enhanced by the addition of properties usually associated with metals. These include reflectiveness, abrasion resistance, electrical conductivity, and a variety of decorative effects (1).The available processes that can be used for metallization of plastics are vacuum metallization or vapoµr deposition; indirect metallization and plating (1). Plating can be sub-divided into electroless plating and electroplating. In electroless plating, metal ions in aqueous solution are deposited on the .activated plastic surface by oxi-reduction reactions without the aid of an external electric potential, forming a thin metallic layer. This electroless deposited film has two functions: (a) it provides an electrically conductive substrate that allows further coating by electroplating; and (b) provides a secure bond between the plastic substrate and the electroplated layer (1,2). In case the electroless metallic part requires an additional layer for finishing purposes, or just an increase in thickness, the part can be additionally electroplated with a· variety of metals - in most cases those are copper, nickel or chromium (3)."

Jan 1, 2000

By Chetan P. Malhotra

This paper describes an online control system and simulation environment for reheating furnaces. The system can be configured for implementing manual control as well as automatic control using either look-up tables or online model predictions. The simulator is also used for offline generation of optimized normal operation and delay setpoints for look-up tables and generating ideal heating curves for model-based control. Finally, it is employed to compare the performance of the above control strategies over a typical period of operation of a pusher-type reheating furnace. Keywords: Reheating furnace, control strategy, model-based control

Jan 1, 2003

By W. H. Langer

At the start of the 20th century Denver?s population was 203,795. Most streets were unpaved. Buildings were constructed of wood frame or masonry. Transport was by horse-drawn-wagon or rail. Statewide, aggregate consumption was less than 0.25 metric tons per person per year. One hundred years later Denver had a population of 2,365,345. Today Denver is a major metropolitan area at the crossroads of two interstates, home to a new international airport, and in the process of expanding its light rail transit system. The skyline is punctuated with skyscrapers. The urban center is surrounded with edge cities. These changes required huge amounts of aggregate. Statewide, aggregate consumption increased 50 fold to over 13 metric tons per person per year. Denver has a large potential supply of aggregate, but sand and gravel quality decreases downstream from the mountain front and potential sources of crushed stone occur in areas prized for their scenic beauty. These issues, along with urban encroachment and citizen opposition, have complicated aggregate development and have paved a new path for future aggregate development including sustainable resource management and reclamation techniques.

Jan 1, 2009