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By Dr. Rory Cameron, Dr. Terry Cheng, Dr. Nadia Mykytczuk, Ian Bedard, Kristie Tarr, Ruth Joseph

Pyrrhotite-rich tailings from Sudbury, Ontario mining activities are known to contain significant amounts of EV metals, such as nickel and cobalt.  CanmetMINING has developed a novel bioleaching process for recovering the nickel and cobalt (both critical for vehicle electrification) from tailings that incorporates partial neutralization and iron removal in the bioleaching circuit; bench- and pilot-scale tests have resulted in excellent nickel and cobalt recovery over a range of temperatures.  However, this process generates a new bioleach residue, which is heavier and more voluminous than the original tailings due to pyrrhotite oxidation and jarosite formation during the bioleaching process. This residue can be problematic for long-term disposal. A possible solution being studied for this issue is using mine backfill as a disposal mechanism.  Underground backfilling allows for effective re-purposing of mine waste, however the backfill must also be able to withstand a certain load, since in most cases it is used as an underground construction material, such as in cut-and-fill mining methods.  Therefore, the composition of the mill tailings must be such that when combined with a binding agent and pumped underground, the slurry or paste is then able to withstand a certain load within a certain period of time.  Unfortunately, high-pyrrhotite content tailings, commonly found on mine sites in Ontario and Quebec, are reactive and can easily oxidize and produce acidity and/or metal-laden drainage under some disposal conditions. This means that the pyrrhotite in the tailings can lead to acid mine drainage if stored on surface, however, it can also cause strength degradation if re-purposed in too high a concentration in underground mine backfill.  The research being done at CanmetMINING related to the bioleaching process is aimed not only at recovering nickel and cobalt from mine tailings, it is also being used in an attempt to neutralize the tailings to reduce acid mine drainage and backfill strength degradation. This paper reports on research designed to evaluate different options for transforming the bioleaching process residue into iron oxide phases, for better environmental footprints if stored on surface, as well as increased disposal possible, if re-purposed as underground mine backfill material.  

May 4, 2025

By Zsuzsanna Zborovszky

Investigation of the discharge duration power and current relation required for ignition. The current and power amplitude-discharge time curve was found to flatten out over 3 ms. It is concluded that discharges having at least 3 ms power maximum are required for reliable testing of the ignition limit for resistive circuits. Investigation of the effect of molten cathode on the discharge duration and igniting ability of the discharge. The surface tension of the liquid metal causes a very fast separation and consequently a much shorter discharge duration than the solid electrode would have. The minimum discharge voltage effect overrides the effects of the temperature of electrode, material, or atmosphere. Investigation of the effect of different surface layers on the discharge duration. Oxides and sulfates were found to give significantly longer duration than the "clean" metal itself in most cases. The lowest ignition current was obtained with CdS04 coatings. Ignition was obtained with 0.7A at 30V, which is below the corresponding minimum igniting current obtained from the BASEEFA curve for circuits containing Cd, Zn or Mg.

Jan 1, 1977

By Michel G. Drouet

Dross, a major by-product of all processes involving molten aluminum, forms at the surface of the molten metal as the latter reacts with the furnace atmosphere. It generally represents 1 to 5 wt% of the melt, depending on the process, and contains on average about 50% free aluminum dispersed in an oxide layer. Since aluminum production is highly energy-intensive, dross recycling is very attractive from both the energy and the economic standpoints. The conventional recycling process using salt rotary furnaces is thermally inefficient and environmentally non-acceptable because of the production of salt slags. Hydro-Quebec has developed and patented a new salt-free technology using a rotary furnace heated by an electric arc between two graphite electrodes, called DROSCAR®. A 600-kW pilot plant in operation at LTEE is in use to demonstrate the process. This process provides aluminum recovery rates over 90%, using a highly energy efficient, environmentally sound production method. In 1994, 400 tonnes of aluminum dross were treated in this facility and several tests on various types of dross have also been conducted in early 1995. A report on the results will be presented.

Jan 1, 1995

By Woodcock J. T, Sparrow G. J, MacRae C. M

The external urfaces and interiors (as polished sections) of particles of coconut hell and extruded peat activated carbons taken from everal Australian carbon-in-pulp operations were examined with an optical micro cope, a scanning electron microscope, and an electron microprobe.Calcium carbonate (calcite) precipitated from the pulp was the major inorganic material on the external surfaces of the carbon particle, but several ore minerals, including quartz, hematite, pyrite, arsenopyrite, and clay minerals were also identified, along with trona, gypsum, a nickel cyanide, and a magnesium salt. Sections of carbon particles showed that calcite was virtually the only introduced inorganic material inside the carbons.It was distributed in the pores and cracks throughout the coconut shell carbon particles but tended to be concentrated in the outer layers of the extruded peat carbon particles. The mechanism of calcite formation and deposition is uncertain. Gold X-ray dot maps showed that gold was distributed through to the centre of coconut shell carbons and to a depth of at least 500 µm in extruded peat carbons. The distribution of gold within the carbon particles was similar to that of calcite.

Jan 1, 1988

By J. B. Gayle

Although heated circuits frequently have been employed in the conditioning stases of certain flotation processes, particularly the flotation of fluorite, the control of temperature is not generally considered economically feasible for the flotation of coal. This viewpoint, although widely held, can neither be substantiated nor refuted by reference to published data. Some evidence is available, however, that temperature is an important variable in the floatability of coal as well as other minerals. For example, Gayle and Swelley4 found that contact angles for coal and related substances were definitely dependent on temperature. Bailey and Whalan5 showed that changes in pulp temperature may exert a pronounced influence on recoveries of coal in batch flotation tests. The present laboratory-scale investigation was undertaken to obtain information about the effects of changes in pulp temperature on coal flotation recovery and also on the selectivity of separation possible using different reagents. The results indicated that flotation recoveries were markedly affected by temperature variations when certain reagents, particularly simple aliphatic alcohols, were used. For other reagents, particularly kerosine, flotation recoveries were substantially independent of variations in pulp temperature. Release-analysis results indicated that temperature variations did not greatly affect the selectivity of separation possible with the reagents tested.

Jan 1, 1961

By Edward Martinez

The reactions occurring in the copper segregation process were studied by heating mixtures of chryso-colla, salt, and a reducing agent. The techniques used in this investigation were differential thermal analysis (DTA) and thermal gravimetric analysis (TGA). The initial chloridizing of the oxide copper occurs below 500°C and cupric chloride may be the compound formed. Volatilization and reduction of the copper chloride take place above 550°C, although these reactions do occur to some extent below 550°C. A difference in the distribution of the metallic copper in the reducing agent was found when sodium chloride was used compared to magnesium or calcium chloride. Segregation was obtained with mixtures of cupric oxide, salt, and charcoal with no quartz or silicate present. Preliminary tests indicate that segregation may occur even in the absence of water vapor. The DTA and TGA techniques were found to be of great value in studying these reactions. The copper segregation process is a method for treating oxide copper ores. The ore is heated, most commonly in a kiln, with a reducing agent and a halide salt, generally sodium chloride, to approximately 700°-750°C and held for 30 to 60 min. The addition of the salt results in the migration and reduction of the oxide copper to metallic copper on the surface of the reducing agent rather than in the original mineral structure. The metallic copper can then be recovered by a subsequent leaching or flotation step.1-4 Experimental work in 1923 on oxide copper ores from the Sagasca mines in Chile led to the discovery of the reduction process. It was found that during the reduction of the copper mineral with coal, at about 700°C, the copper migrated to the surface of the coal instead of remaining disseminated in the ore. The unusual behavior of the copper, which caused it to migrate from the ore particles to the coal, was traced to the presence of a small quantity of sodium chloride occurring in the ore. Further experiments with oxide copper ores proved that the presence of a halide, either occurring naturally or admixed with the ore, caused the copper to migrate from the ore particles and to segregate in the charge. The ratio of salt to reducing agent may vary somewhat, but in general 0.5% to 1.5% sodium chloride and 0.5% to 1.0% coal or coke have been mixed with the ore. Less than stoichiometric amounts of salt are required to convert all the oxide copper to a chloride, so that a cycle of reactions appears to be occurring. Several investigations reported in the literature have proposed reactions to explain the mechanism of the process.5-10 There appears to be general agreement that water is necessary for the reactions to occur; that once the sodium chloride reacts with silica or silicates in the ore, the hydrochloric acid formed will convert the cupric oxide in the mineral structure to cuprous chloride. However, there appears to be a conflict of opinion on the reactions involved in the reduction of the cuprous chloride to metallic copper on the surface of the carbon. Rey has indicated that salt, water vapor, and

Jan 1, 1968

By A. Fleming

The exploration process, like any other commercial activity, can only succeed if the objective of the exercise is clearly defined and persistently pursued. Successful exploration requires properties, funding, personnel and persistence. Many of us have years of experience in conducting exploration in our countries of residence. Conducting exploration in a foreign country, however, requires a number of significant other criteria.

Jan 1, 1997

By A. E. Nash

This title is somewhat of a misnomer, because it does not accurately describe the phase of heat generation and application coming within the scope of this discussion. This paper is concerned primarily with that particular phase of radiant-heat transfer sometimes erroneously referred to as "shielded" radiant heat, to differentiate it from the open radiant heat of either flame or settings, in which the actual source of the radiant heat is a small incandescent furnace composed of a highly conductive superrefractory, within whose walls the combustion of the fuel is completed. This small furnace is usually located directly in the furnace proper, and although its refractory walls do shield the heat-absorbing surfaces from contact with the gases of combustion, there is no interference with the radiant heat given off by the furnace itself. We do not believe it either necessary or advisable to shield or screen radiant heat when properly controlled and applied. We do believe it essential to prevent the excessively hot gases of combustion from coming in contact with those parts of the heat-absorbing structure that are already receiving heat at high rates by radiation. In connection with any process for the refining of oil with which we are familiar, we are convinced that it is most advantageous to transfer the maximum of the heat generated in the form of radiant heat, applied directly to the heat-absorbing surfaces without the interposition of any form of shield or screen to prevent or reduce the radiant-heat transfer. While the term radiant heat is broadly used to cover all heat energy transferred from one body to another by radiation, in contradistinction to heat given up by gases in direct contact with the heat-absorbing structure (convection) or transmitted simply by conduction, in furnace work it is perhaps more often limited to the heat rays given off either by

Jan 1, 1928

By Joseph Chalmers, J. S. Desmond, R. Van A. Mills

[Because of the limited space in this volume and the fact that a description covering the oil recovery buildings and equipment (see page 4, Technical Publication No. 144) will be given in a forthcomnig U. S. Bureau of Mines publication, and because the paper was published in detail as Technical Publication No. 144, and is available as a separate at the Institute, it is impossible to include here more than the following brief extract.] Problems Being Studied The selection of the first problems to be studied was based largely upon the following very practical questions asked by several of the largest operators in the Mid-Continent field. 1. What are the causes for the formation of excessive amounts of bad thick oil on properties that are being repressured with compressed air and how can this trouble be prevented? 2. Why, in some areas, does the oxygen in the air injected into an oil sand during repressuring operations apparently change to carbon dioxide? Is carbon dioxide formed by the oxidation of some of the oil in the sand'? How can the formation of inert or low B.t.u. casinghead gas, loaded with nitrogen, carbon dioxide and oxygen, be prevented? 3. What percentage of the oil originally present in an oil sand can be recovered by the ordinary methods of operation when the gas originally dissolved in the oil is the main propulsive agent? 4. What percentage of the amount of oil produced by ordinary methods can be recovered under average conditions by repressuring a so-called depleted oil sand? 5. What are the relative propulsive efficiencies of compressed air and natural gas in repressuring operations? 6. What are the practical advantages of pressure maintenance and early repressuring as compared with late repressuring?

Jan 1, 1929

By Cz. Mora, A. Pawelczyk, D. Hreniak, P. Nowak, A. Dyonizy, S. Strek, W. Strek, K. Grabas, A. Ostrowski

Globalization and a growing demand for limited raw material resources have forced changes in the approach to the supply chain. This is particularly true in the case of rare earths, which are regarded as one of the most important development indicators of modern technologies. To ensure a secure supply of commodities, the European economies have been prompted to investigate REE recovery from sources which until recently, for technical or economic reasons, were considered not sufficiently attractive. An interesting example is apatite phosphogypsum waste dumps. The REE content in these waste dumps averages around 0.5-1 %. One of the most important phosphogypsum locations in Poland is the Lower Silesia region where a phosphoric acid Chemical Plant "Wizów" operated for several dozen years. In this work, rare earths are leached from the phosphogypsum crystalline structure by a chemical treatment and can then be separated into individual chemical compounds. The technology used in these recovery tests, matches up to a coherent European raw materials policy supporting effective management of resources and promoting waste materials recycling.

Jan 1, 2014

By Bryan Ulrich

On March 15, 2012, about 24 attendees from several western states attended Roundtable 2012, hosted by Knight Piésold and Co. at the Red Lion Hotel and Casino in Elko, NV. The focus of this year?s discussion was ?Acid Rock Drainage for Engineers and Environmental Scientists.? Other names may have been more suitable for the event, perhaps combining geochemistry, with air and water quality and their long-term effects on soil and rock mechanics. Bryan Ulrich (senior vice president, Knight Piésold?s Nevada operations) and Steve Lange (senior geochemist, Knight Piésold, Denver, CO), helped facilitate the discussion. Attendees included personnel from a dozen mining properties, various corporate offices and academia. There were also attendees from a geochemical testing laboratory to help respond to specific questions pertaining to testing protocol and procedures.

Jan 1, 2012

By R. A. Hill, J. D. Pitts

"Long distance slurry pipeline systems have been successfully trans-porting steam coal, iron concentrates, copper concentrates and limestone for an aggregate of nearly 60 years and nearly three billion ton-miles annually. A phosphate concentrate pipeline is nearing start-up and systems for coking coal, lead/zinc concentrates and fly ash are planned. The solids pipeline concept, first patented in the early 1900's and commercialized in the 1950's, is now a proven technology providing an economic, environmentally pleasing and safe method for long distance bulk transport.The challenge for larger tonnage and longer distance movements of solids, for traversing increasingly rugged terrain in grass roots mineral developments, for transporting untried materials and for shipping more economic forms of proven materials still remains. This has necessitated continued refinements and optimization of the technology. The economic and environmental incentives for slurry pipelines when compared to other transport alternatives has justified substantial activity in this area. The scope of planned systems in coal, iron and other minerals is indicative of the firm place slurry pipelines will have in worldwide mineral development.In this presentation, the state-of-the-art in long distance slurry pipelines is reviewed with a focus on major systems of interest to the mineral processing industry. An overview of new developments in the application of this concept is presented, and finally, a projection of the future of pipelines in mineral development both worldwide and in Canada is discussed."

Jan 1, 1978

By R. F. Balazik

By March 2001, shrinking global markets, reduced consumer spending and declines in domestic manufacturing and industrial output ended the longest economic expansion in US history and pushed the nation’s economy into its first recession in a decade. Aggravated by the terrorist attacks of Sept. 11, the recession led to large reductions in the domestic production of processed mineral materials. Some of the most significant production declines in the US metals industry were registered by aluminum, copper and steel producers. They faced strong foreign competition, higher energy costs and lower prices for their products. However, homebuilding and other domestic construction sectors — major users of nonmetallic mineral products such as cement, brick, glass and stone — remained strong enough to help raise the output of industrial mineral materials slightly above previous year levels. A strong US dollar continued to weaken the competitive stance of US metal and nonmetallic mineral materials companies alike against foreign producers in markets at home and abroad.

Jan 1, 2002

By Jun Yi

In this paper, single-component gas sorption and transient diffusion processes are described within coal matrix exhibiting bimodal pore structure. The coal matrix is treated as a poroelastic medium manifesting swelling and shrinkage effects due to the sorption of gas under effective overburden stress. Gas transport is considered Fickian with molecular (bulk) and surface diffusion processes simultaneously taking place in the macro-and micropores of coal, respectively. The numerical formulation is intended to be explicit in nature to investigate the influences of sorption phenomena on the macropore volumes and on the overall gas transport for the cases of gas uptake by and release from coal. Results of the study show the presence of hysteresis during a sorption?desorption cycle of the gas. It is also found that the overall gas transport takes place at a rate significantly less than that in the macropores only. Thus the existence of a retardation effect in the overall gas transport is concluded. This retardation effect is primarily due to the micropore resistances, in particular gas adsorption, and is independent of the changes in the macropore volumes. It is shown that macroporosity of the coal matrix may change during gas transport due to combined effects of pressure and sorption-induced swelling or shrinkage of the coal. It is estimated that the macroporosity variation is non-uniform in space and time, as it is expected in reality, and typically taking values less than ±10 percent of the initial porosity.

Jan 1, 2009

By V. Kecojevic

Environmental and economic costs related to equipment fuel consumption and carbon dioxide (CO2) emission present a substantial challenge to the mining industry. Haul trucks are an integral part of the overall surface mining system and they consume a significant quantity of fuel. Consequently, they produce a significant amount of CO2. The objective of this research is to (i) establish a mathematical relationship among a truck?s fuel consumption, power and engine load factors and (ii) determine the amount of a truck?s CO2 emission and the associated cost that may arise from potential CO2 legislation. In order to achieve these objectives, the authors have considered original equipment manufacturer (OEM) haul trucks, which are commonly used in surface mining operations. The research presented here may be used by mining professionals to help determine the cost and environmental burden of the trucks? application and efficiently manage energy consumption.

Jan 1, 2010

Kinetics of Reclamation of E-Waste by a Bioleaching Route

Sep 13, 2010

By P. G. Kovalchik

Overexposure to noise remains a widespread, serious health hazard in the US mining and other industries despite 25 years of regulation. Most categories of illnesses and injuries associated with mining have improved, with the exception of hearing loss. The drilling of rock in a confined work environment contributes to high levels of noise exposure in mining. The National Institute for Occupational Safety and Health (NIOSH) is conducting research to reduce the noise exposures of jackleg drill operators and to prevent additional cases of noise induced hearing loss (NIHL) by developing and evaluating low-cost retrofit noise controls for equipment. This report describes the procedure for the measurement and reporting of noise from portable pneumatic tools such as jackleg drills. The technique used in this research allows for the determination of the source A-weighted sound power levels and the radiation patterns in octave and 1/3 octave bands. Overall sound power level is also determined. This paper also reports the results obtained by using this procedure to evaluate a SECO S215 standard production drill and a CSIR Miningtek prototype rock drill incorporating engineering noise control measures. It was found that by using the manufacture?s recommended operating pressure of 496 kPa (72 psi) that the CSIR prototype?s sound power was 10 dB(A) less then that of the SECO S215.

Jan 1, 2009

By Tainan Ferreira Muniz

O presente trabalho estudou a influência de alguns tratamentos térmicos sobre a microestrutura e as propriedades mecânicas de um aço microligado visando à adequação de parâmetros que o classifiquem como um ao do tipo API X65 paraaplicação na prospecção e condução de óleo e gás. Diferentes ciclos de tratamentos térmicos envolvendo normalização, têmpera e revenimento foram aplicados a amostras deste aço. Estas foram submetidas a ensaios de tração, dureza Vickers e impacto Charpy, além de terem sido microestruturalmente caracterizadas com o auxílio de microscopia ótica e eletrônica de varredura. Observou-se que as microestruturas e propriedades mecânicas foram fortemente influenciadas pelos tratamentos estudados. Entretanto, apenas a amostra temperada e revenida atendeu integralmente aosrequisitos para o grau API X65no que diz respeito às propriedades mecânicas.Estaamostratambémapresentou maior a tenacidade ao impacto, o que está associado ao alívio de tensões e à decomposição da martensitae da bainita em carbonetos de ferro e ferrita. A amostra normalizada apresentou microestrutura constituída por perlita e ferrita, possuindo assim os menores limites de resistência mecânica e a maior ductilidade. Já nas espécies normalizada-temperada, assim como na simplesmente temperada, observou-semartensita e bainitacomo principais constituintes, supondo-se a presença de uma pequena fração de constituinte MA.

Aug 16, 2017

By Teresa M. Bodas Freitas, Arianna Lupattelli, Peter J. Bourne-Webb, Diana Salciarini, Martina Zito, Donatella Sterpi

The thermomechanical response of thermally-activated (TA) piles under monotonic thermal loads is quite well understood and the remaining uncertainties relate to the effect of long-term, cyclic loading of individual TA piles and pile groups. Recent studies undertaken by the authors have provided insights into the behaviour of TA pile foundations undergoing cyclic thermal loading. Despite their simplicity, the analyses show that key aspects of the observed response of piles in sand, under cyclic thermal loading can be reproduced, providing confidence in the outcomes of the analyses. The studies examined isolated piles and pile groups, and concluded that irrecoverable thermally-induced settlement may be mitigated through the choice of an appropriate margin of safety on the pile shaft resistance under service mechanical load conditions, and the maximum thermal stress can also be readily estimated. This paper consolidates these works and provides guidance regarding the safe geotechnical and structural design of the piles, then looks towards the remaining issues around the safe provision of thermally-activated pile foundations.

May 1, 2022

By L Mariani, G. Mendoza-Suarez

In this investigation, TiH2 powders were coated with copper and nickel by electroless plating to delay hydrogen evolution. Copper-coated samples were found to have a mixed acicular (2D growth) and cauliflower (3D growth) morphology whereas the nickel-coated samples had a cauliflower morphology. Examinations of the coated powder cross-sections revealed that the coating thickness ranges from 0.2 µm to 4 µm. Uncoated areas on the powder surface and coating flakes unattached to TiH2 particles suggest poor adhesion between the coating and the substrate. The phase transformation undergone by the TiH2 during dehydrogenation was studied in samples taken at intermediary points in the heating cycles and examined by XRD. The findings reveal that as the powder is heated from room temperature to 800°C, it changes from TiH1.971 to Tiu and to aTi. Differential Thermal Analysis (DTA) was performed to study the effects of the coatings on the temperature of hydrogen release. It was found that increasing the number of plating iterations, and therefore the thickness of the coating, creates a significant shift in the temperature of gas release.

Jan 1, 2006