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By Kent R. Van Horn, W. P. Sykes

Since Honda and Murakamil in 1918 proposed their constitutional diagram of the carbon-free iron-tungsten system, considerable effort has been expended by several investigators in attempts to define more positively the structural features of the alloys. The existence of an intermediate phase corresponding to the formula Fe3W2 (68.7 per cent W) was proposed from evidence of a purely metallographic nature by one of the present authors2 in 1926. Since that time the identity of this phase has been confirmed by Arnfelt3 and by Takeda,4 both of whom employed X-ray methods as well as the microscope and the chemical analysis of isolated microconstituents. According to Arnfelt, Fe3W2, as crystallized from the iron-rich melts at a temperature above 1450° C., contains by analysis 68.7 per cent W. The lattice of this phase is characterized by trigonal symmetry. Arnfelt, moreover, proposed a second intermediate phase formed at some temperature between 1450" and 1000" C. by a peritectoid reaction involving Fe3W2 and the iron-rich solid solution. A melt containing 25 per cent W was cooled to 1000" C. and heated for 100 hr. The precipitated tungsten-rich constituent was separated and found by analysis to contain 62.6 per cent W. This composition agrees closely with that represented by the formula Fe2W (62.2 per cent W). Diffraction patterns from the concentrated precipitate showed a hexagonal unit cell. Takeda confirmed the data of Arnfelt regarding Fe3W2 but was unable to detect Arnfelt's second intermediate phase. While Takeda failed to describe in detail the treatments employed, he stated that in alloys containing 40 per cent W which were quenched after heating at various temperatures between 1200" and 1450" C. no evidence of the second phase (Fe2W) was observed 'either in the microstructure or in the diffraction patterns of isolated residues. He therefore considered the existence of this low-temperature hexagonal compound as disproved.

Jan 1, 1933

By Robert R. Dorfler

AMPS[. has completed a rationed grinding ball test in a 2.93 m x 2.93 m ball mill at Climax Molybdenum Company. The test consisted of purging the ball distribution formed by charging 100%, 76 mm carbon steel balls with a distribution formed by charging 50% 76 mm and 20% 51 mm alloy steel balls. The resulting change in ball surface area yielded improvements in both tons ground and fineness of grind with a significant reduction in total ball consumption. This paper summarizes preliminary studies leading to the plant test, grinding efficiency results, and future plans to optimize the ball charge.

Jan 1, 1981

By M. Sanchez, I. Imris, G. Achurra

The Smelting and Converting El Teniente Process for copper concentrates as well as Slag Cleaning Furnace Technologies to treat slags coming out from the El Teniente Furnaces are widely applied today in Chile and around the world. Several industrial applications of this process have shown their capability to treat copper concentrates in a wide range of chemical and mineralogical compositions. Main operational parameters determining performance of the process are: oxygen enriched air flow rate, degree of oxygen enrichment, moisture content of the solid materials processed, molten material levels inside the vessel, frequency of molten materials tapping, bath temperature and copper losses in slags. In this work, the copper losses in the slags from El Teniente pyrometallurgical process are predicted by calculation from thermodynamic data and compared with those determined by microscopic examination and slag industrial data. Results obtained show that the main part of copper losses in the slag from El Teniente Furnace are mechanically entrapped or floated unsettled droplets of the coexisting matte phase. by the contrary the very low copper losses in the slag from slag cleaning furnace are limited by the physico-chemical form.

Jan 1, 2004

By D. K. Deardorff, Laurance L. Oden, H. Kato, M. I. Copeland

The equilibrium relationship of hafnium and tantalum was studied to facilitate alloy and property investigations . The data obtained are presented graphically as the equilibrium diagram . Alloys were prepared from high - purity components by nonconsumabletungsten- electrode arc melting . Data for the equilibrium diagram were obtained by optical pyrometry , metallography , X- ray diffraction of heat treated specimens , X- ray diffraction using a high- temperature camera , and differential thermal analysis . During the investigations , a casting apparatus was constructed , and the existing melting - point apparatus was improved . The bcc allotrope of hafnium forms a continuous series of solid solutions , called beta , with tantalum which exhibit a minimum melting point at 20 wt pct tantalum and 2,110 ° C. At 24 wt pct tantalum and 1,050 ° C , hafnium- rich beta decomposes in a monotectoid reaction to yield alpha and tantalum- rich beta . The monotectoid isotherm extends from 5.5 to 60 wt pct tantalum . The twophase region , in which hafnium- rich and tantalum- rich beta solid solutions are immiscible , rises to a maximum temperature of 1,265 ° C at 38 wt pct tantalum . The solubility of hafnium in tantalum decreases from 40 wt pct at the monotectoid temperature to 20 wt pct at 750 ° C.

Jan 1, 1964

By R Cowen

Past successes of low impact mineral exploration and rehabilitation of mined areas in developed land of subdued contour provide little guidance for similar activity in more sensitive high country or mountain environments. Land management agencies and environmental pressure groups have expressed considerable concern about mineral development in these areas by land especially where the land involved has high environmental or productive values. Mineral explorers are responding with detailed proposals for integration of environmental assessment and mineral exploration at an early stage. A model programme for Fiordland National Park presented in this paper illustrates this approach.

Jan 1, 1981

By Lee W. Abramson, James E. Crawley

Caltrans is studying alignments for a 160-kilometer-long high speed ground transportation system from Los Angeles to Bakersfield across the Tehachapi Mountains. This link is needed to connect southern California with San Francisco by a short passenger rail service. None presently exists. The system will require tunnels and viaducts along the route with sections crossing two major active fault zones. High speed ground transportation technologies are being evaluated for achieving rail speeds of between 200 and 480 kilometers per hour. This paper presents the technical requirements for tunnels along the alternative routes being considered for the project.

Jan 1, 1995

By P. Brad Marchant

"To properly evaluate bioleaching as a commercial alternative for sulphide concentrate oxidation, to enhance cyanidation response, it was necessary to define and optimize critical operating variables outside of the laboratory under less than ideal conditions. A complete bioleach testing laboratory was installed at Equity Silver Mines to aid in pilot plant flowsheet development.A continuous pilot scale bioleach circuit was constructed to provide data for meaningful valuation of biotechnology on a plant scale. The important operating and design parameters for pilot plant testing are described. Plant scale feasibility and design considerations, to treat a refractory pyrite/arsenopyrite concentrate produced from flotation tailing, are discussed. 1.0 BACKGROUNDEquity Silver Mines Limited is located 37 km southeast of Houston in central British Columbia. A 70% owned subsidiary of Placer Development Limited, Equity is Canada's largest open pit silver producer. Ore reserves were estimated at 28 million tonnes grading 106 g Ag/t, 0.96 g Au/t, and 0.38% Cu from two pits, the Southern Tail and the Main Zone. Detailed geology and mineralogy has been described previously(1,2).The concentrator flowsheet consists of conventional crushing, grinding, flotation, and dewatering circuits processing 5 300 tonnes per day of new mill feed. The resultant Cu/Ag/Au concentrate is trucked to Prince Rupert for shipment to market. Mill tailing reports to a closed circuit pond from which mill process water is recycled. Details of the concentrator process have been reported( 2,3).Production in the Southern Tail pit, from July 1980 to March 1984, resulted in mill tailing averaging 0.9 g Au/t and slightly more than 20 g Ag/t. Historic data indicate that unrecovered gold is associated with arsenopyrite and silver losses with unliberated tetrahedrite or minor silve,, bearing sulphosalts. Main Zone mill tailing, which commenced production in March 1984, contains approximately 0.5 g Au/t which is probably associated by majority with silver bearing minerals and pyrite while silver losses, 30-40 g Ag/t, are associated with unliberated silver and antimony bearing minerals."

Jan 1, 1985

By Satoshi Itoh

Phase equilibria and activities of the components in the liquid lead-antimony-oxygen ternary system, which is of fundamental importance for discussing the' recovery of lead and antimony from a used lead-battery, have been investigated at 1173 and 1223 K. The two liquid phases of metal and oxide were observed at the temperatures studied, and the tie lines indicating isoactivities were determined. The activities of PbO, SbO1.5 and Sb2O3) in the PbO-SbO1.5 and PbO-Sb2O3 pseudo-binary systems were then obtained by applying the Gibbs-Duhem equation to the phase relation of metal-oxide equilibrium. Both in the pseudo-binary systems the activities exhibit negative deviations from Raoult's law. The vapor pressures of lead, antimony and lead oxide, antimony oxide were calculated by using the activities of the components in the lead-antimony-oxygen ternary system. As a result, an oxidation of antimony concentrated in an anode slime followed by evaporation as antimony oxide Sb406 was found to be considerably effective for the recovery of lead and antimony from a used lead-battery.

Jan 1, 2003

By Y Mita, T Iwama, R Inoue, S Ueda

In the iron and steel manufacturing industries, efforts are being made to achieve carbon neutrality by 2050, and the transition from a coal-based steelmaking process to that utilising renewable energy is being pursued. An alternative process in which directly hydrogen-reduced iron is melted in an electric furnace is being investigated. It is known that foaming slag reduces heat loss from the steel bath in electric arc furnace, but iron loss due to the suspension of steel particles in the slag is indispensable. To improve the separation of steel particles from the slag, the control of the slag viscosity is important. Although the slag viscosity has been extensively studied, in those studies the slag was considered to be a simple liquid. However, in actual operations, slag is a multiphase fluid consisting of solid, gas and liquid phases. Therefore, in this study, by measuring the sedimentation velocity of titanium, stainless steel and glass spheres in an aqueous glycerin solution containing bubbles generated by the reaction between NaHCO3 and C2H2O4, the apparent viscosity of the gas-liquid fluid was evaluated based on Stoke’s law. It was found that the apparent viscosity of the gas-liquid fluid is larger than the viscosity of liquid phase and depends on both the bubble volume ratio in solution and the density of the falling solid sphere, and the apparent viscosity was different from that previously obtained by the rotation method. The apparent viscosity derived from the sedimentation velocity of solid spheres changed depending on the specific gravity of the ball. This is because the apparent viscosity is derived from the velocity of a ball falling in a static bubble in this method, whereas that is derived from the force applied by a stationary flow in the rotational method.

Aug 21, 2024

The pyrite-sphalerite-galena and barite orebodies at the Rosebery mine are concordant with the shale host rock and have been deformed into one system of folds with an associated axial plane cleavage. The folds are tight and overturned with east-dipping axial planes. Folds in the sulphide ore are commonly disharmonic, particularly between adjacent bands of different composition.Concentric style folds occur in the competent bands, e.g. pyrite-rich bands. Similar style folds are predominant in the less competent sphalerite-galena-rich bands and also in the shale of the host rock. The trends and plunges of the fold hinge-lines are variable but axial planes are of reasonably constant orientation throughout the mine area. The folds in the orebodies are of limited axial extent, approximating to conical folds, and are arranged in en echelon patterns. The fold system was possibly formed in one period of folding by heterogeneous strain that may have been caused by the presence of a mass of tectonically mobile sulphide ore. Lineations parallel to the ore/host rock contacts appear to reflect movement between the ore and the host rock during folding.

Jan 1, 1972

By R. V. Ramani, W. Miola

The MSHA prescribed method for the determination of quartz in airborne respirable-dust samples from underground coal mines is the P-7 method, a combination of low-temperature, radio-frequency ashing (LTA) and infrared analysis (IR). There is no prescribed procedure for quartz analysis in bulk samples of coal and host rock. Dispersive infrared (IR), Fourier-transform infrared (FTIR) and X-ray diffraction (XRD) methods are most commonly used for the analysis of quartz in powders. Several aspects of the experimental procedures, such as the preparation of the analysis sample from bulk samples, ashing techniques, scanning procedures, peak measurement location, calibration techniques, sample amounts, size consist and data interpretation, affect the results from each of the methods differently. Significant differences in analytical results obtained from X-ray diffraction (XRD) and infrared spectroscopy (IR) on the same samples are reported. All studies point to the need for reliable quartz analysis methods. In a recent research program, a procedure for preparing bulk-coal and host-rock samples for quantitative quartz analysis was developed. Further, the results from X-ray diffractometry and infrared spectroscopy for quartz content on identical samples were compared. Calibrations with pure and mixed standards were used to assess the influence of particle-size distribution, matrix and calibration on the analytical results. In this paper, several issues concerning the measurement of quartz in the samples of coal, host-rock and airborne respirable dust from mines are outlined and quantified.

Jan 1, 1996

By Steven I. Baskin

Cyanides are utilized in many industrial applications including preparation of chemical intermediates, electroplating, and' mining, Cyanide has been utilized in chemical warfare operations as well Cyanide is also synthesized and found in plants and animals including man where it is thought to perform multiple functions. A variety of enzymes are known to detoxify cyanide under different conditions. These include rhodanese, 3-mercaptopyruvate-sulfur transferase, thiosulfate reductase, cystathionaseand albumin. Cyanide appears tQ exert its toxic effect primarily by inhibiting cytochrome oxidase? although other enzymes are also inhibited. Therapeutic antagonist categories to treat cyanide include methemoglobin formers such as nitrite, sulfane-sulfur donors such as thiosulfate, metal salts or complexes such as cobalt and cyanohydrin-forming compounds such as dihydroxyacetone or alpha keto-glutaric acid. Advantages and disadvantages of each category will be discussed. Newer compounds under development have been found that may allow for prophylactic therapy for cyanide poisoning with minimal side effects; In addition, portable co-oximetry devices may provide real-time measurement of cyanide in field units.

Jan 1, 1998

By Roland C. Walker

Traditional headed rebar has existed in the mining industry as a ground support product for many years. The head of a rebar bolt is most commonly produced by hot upset die forging. Upset die forging produces a rugged, simple head that performs well. Certain elements of the head must comply with regulatory standards, such as ASTM F432-95, which offers a standard test procedure to ensure quality of the product. The head style produced by all major manufacturers has been optimized to reduce manufacturing costs, provide greater miner safety and provide an excellent performing product. Observations were made in some mines of heads failing under in-situ loading. These observations could not be replicated according to the ASTM testing method. This paper highlights the problem and how a solution was developed. The development includes pictures of in-situ failures from the underground operations, laboratory replication tests indicating how this loading occurs, and then the use of this calibrated test method to validate the new design created.

Jan 1, 2009

By Nunna Malakondaiah

Plant samples collected from the mined sites of Beulah, Center and Zap and the test sites of North Beulah 1, North Beulah If, South Beulahh and Center were analyzed for their nutrient concentrations. The vegetation from the mined areas generally showed lower concentrations of Na, P and Cu and failed to meet the nutritional requirements for beef cattle as defined by National Research Council (minimum requirements are: Na, 600; Cu, 4; P, 1800 µg/g dry weight). Plants from Beulah showed generally higher concentrations than from Center or Tap. Tissue concentrations of K varied significantly between sites for 5 species due to the low tissue concentrations at Center. Deficiencies are difficult to isolate as the sampling was done in mid-summer and generally during that season the tissue concentrations tend to decrease in several species. All of the plant species at the unmined sites, with the exception of western wheatgrass at Zap, had lower concentrations of P than the minimum nutritional requirements for beef cattle. Sodium concentration was low but Cu was marginal to adequate in plant species at the unmined sites. Concentrations of K, Mn and Cu in western wheatgrass were greater at Center than at Zap while the opposite was true of the concentrations of Zn, Cu and P in blue grama and Cu in green needlegrass. Amending the spoil with slack at North Beulah I decreased the concentrations of Zn, Cu and P in wheatgrasses grown on spoil from 0-2, 5-10, and 20-25 foot depths, respectively. In general, the mean tissue K+/Na+ ratios were greater in plants on slack amended spoils, primarily due to the reduced Na concentrations in the tissue. At North Beulah II test site, only wheatgrasses grown on spoil amended with slack showed significant increase in K and decrease in Na and Mn concentrations. At South Beulah test site which received 12" topsoil over graded spoil, leonardite amendment decreased P concentrations in all of the grasses as compared to control, whereas fertilizer treatment increased the same. Nutrient concentrations were lower in both fescue and needlegrass with leonardite treatment and higher with fertilizer treatment although not significantly different from control. The concentrations of Ca, Mg, Na, Fe, Cu and N in grasses grown on topsoil at Center test site were significantly higher than on slack amended spoil. Legumes grown on topsoil at Center site contained higher concentrations of P than those grown on spoil; there were no significant effects due to slack on spoil or topsoil. The data presented in this report act only as an indication of between-treatment and between-species differences in tissue composition of plants harvested in mid-summer season. With respect to the nutrients analyzed, since none were found to be toxic, the cattle can safely feed on the vegetation of these mined areas.

Jan 1, 1982

By Laura Bustemante, Bruce Vandenberg, Fred Huettig

Recent advances in solid-state, field portable, fast framing video camera systems and PC based frame capture hardware now allow blast imaging up to 1000 frames per second. Up to 8 seconds of data can be stored directly into the unit, downloaded to a PC or archived to a standard VCR without data compression. Since no film processing is involved, motion analysis can be performed instantly and on-site within a few minutes. This paper will describe the design features and applications of the KineView 1256P system and compare these with the analogous aspects of fii based cameras.

Jan 1, 1998

By R. Winand, M. Degrez, C. Temmerman

"The influence of the copper electro crystallization inhibitors (mainly thiourea, gelatin and chloride ions) is studied in a new fully automatic pilot plan. This paper describes the conception and the building of this plan. The new approach is to reproduce the experimental conditions observed in the industry with the three additives present simultaneously in the electrolyte and secondly to study the influence of a slight modification of the concentration of one inhibitor, the others being present in the electrolyte with their industrial nominalconcentrations.1. INTRODUCTIONDespite the fact that gelatine, thiourea and chloride ions have been used in copper electrorefining for a long time, precise knowledge concerning their influence on the cathode deposit, metallographic structure and associated properties is still lacking.Many authors studied the influence of each additive separately, or of two added at a time. Only a few authors studied the combined influence of the three additives added simultaneously. The general conclusion that can be drawn is that the combined influence is far from that forseen from the influence of each additive separately, or even from two additives used at a time. Moreover most of the experiments described in the literature were performed by adding all additives at once initially. It is however, well known that gelatine looses a great part of its activity during the first half hour due to degradation by sulfuric acid (as shown by the cathode overpotential drop). Thiourea is rapidly replaced by a number of degradation mole,cules and complex ions including cations from the solution, changing even the equilibrium between Cu, Cu(I) and Cu(II).Chloride ions are consumed by precipitation.A number of successive research projects [1-9] led pregressively to the concept that, in order to obtain reproducible results representative of industrial cathodes, it was necessary to simulate as far as possible industrial conditions. It was essential that all additives were added continuously during the electrolysis, with, as consequence, a continuous bleed.The purpose of this paper is to describe the concept of a new fully automatic pilot plan for copper electrorefining and to present the first results."

Jan 1, 1997

By Manuel Estrada

"El presente texto señala un breve estudio sobre el aspecto técnico y de ingeniería de La Planta Sacracancha del Banco Minero del Perú. Dicha planta se encuentra a 4 600 m.s.n.m. en la zona denominada Sacracancha del distrito minero de Morococha, perteneciente a la provincia de Yauli, departamento de Junín. Se utiliza la planta Flow Sheet y los minerales tratados son los sulfuros de plomo, cobre, zinc y planta. Asimismo se describe el proceso de producción de la planta, procedencia, operación de la planta y servicios auxiliares como los laboratorios, almacenes, talleres, etc. "

Aug 20, 1965

By R. P. Walters, M. J. Lynch, D. R. Flinn

The Bureau of Mines evaluated tthhee feasibility of substituting platinum- coated metals for bulk platinum shapes as a means for conserving platinum . Platinum coatings were prepared using four different methods of electrodeposition , then tested and evaluated . In order for platinum coatings to be useful in process environments , they must be thick , adherent , stress - free , and pore - free . The Bureau evaluated direct - current , current reversal , cathode shielding , and pulsed- current plating techniques for producing a pore-free platinum electrodeposit from a molten cyanide bath . Aqueous corrosion tests of Fe - 10Cr substrates coated with approximately 25 μm of platinum showed that pulse plating yielded the most corrosion- resistant and , hence , the most pore -free coatings . The morphology of coating cross sections was in all cases columnar . The average grain size of pulse -plated deposits was independent of thickness , while all other plating techniques produced grains that increased in size as the coatings became thicker . It is believed that the constant grain size in the pulse - plated deposits resulted from better mass transport during the electrodeposition .

Jan 1, 1965

By Peter Amelunxen, Javier del Río, Marcial Medina

El presente documento técnico tiene como objetivo mostrar las mejoras implementadas en la planta de cobre y molibdeno durante los primeros años de operación de Constancia, las cuales permitieron incrementar en forma sostenida los principales indicadores de producción. Se demuestra la optimización de cuatro principales indicadores: troughput, recuperación, disponibilidad y utilización. Los resultados obtenidos hasta el momento, que servirán como guía a nuevos proyectos mineros en construcción o en desarrollo, son el resultado de múltiples iniciativas de mejora y nuevas tecnologías implementadas principalmente en el año 2018.

Sep 20, 2019

By G. G. Hatch

FOLLOWING World War II there was an urgent need for the development of domestic sources of ilmenite to take care of the expanding needs of the titanium dioxide pigment industry. In addition, there was the interest by the pigment manufucturers and others in titanium metal. Prior to the war the pigment industry in the United States had obtained its major tonnage of ilmenite, analyzing 55- ?60 per cent Ti02, from India. However, as a result of the shipping situation which developed during the war, the pigment manufacturers had to consider the use of lower grades of ilmenite located on this continent .and several companies undertook extensive exploration programmes to locate and develop such orebodies. Probably the most significant deposit that was found as a result of these ?programmes was the orebody .at Allard Lake, Quebec, owned by the Quebec Iron and Titanium Corporation. This ?Company was formed in 1948 by the Kennecott Copper Corporation and the New Jersey Zinc Company to mine this ilmenite ore and treat it in electric furnaces to produce titanium dioxide slag for the pigment industry and iron for the steel industry.

Jan 1, 1956