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By J. L. Ellenberger, T. Miller

"A limestone mine in Ohio has had roof instability problems that have led to massive roof falls extending to the surface. This paper describes a collaborative study of these events undertaken by the National Institute for Occupational Safety and Health and the mine owners. The study focuses on the roles that weak, moisture-sensitive floor and weak bands in pillars play in a general instability that led to roof falls at this mine. The NIOSH Stone Mine Pillar Design software (S-Pillar) does not include analysis for weak floor or weak bands and recommends that when such issues arise they should be investigated further using a more advanced analysis. It is important to recognize that without the impact of the floor or weak bands, the calculated inherent stability factor for these pillars is within the recommended design range. Therefore, to further investigate the observed instability occurring on a large scale at the Ohio mine, FLAC3D numerical models were employed to help determine the failure mechanism. Roof-to-floor extensometers were also installed in the areas predicted to have further instability. This case study will provide important information to limestone mine operators regarding the impact of weak floor causing the potential for roof collapse, pillar failure, and subsequent subsidence of the ground surface. This recent case demonstrates that weak floor can be a significant factor in pillar stability and should be assessed during the design stage of the mine.To an area-wide failure (Zipf, 2001). In that case, it appears that the pillars had actually remained intact. However, moisture-related yield of the weak floor caused deformations which passed through pillars and into the roof, triggering roof collapse around the intact pillars (Esterhuizen et al., 2011). This previous case and the case presented in this study, while not identical, both demonstrate that weak floor and/or bands within pillars can be a significant factor leading to instability."

Jan 1, 2015

This paper describes new research and development currently being undertaken by the CSIRO Mining Technology Group to advance the automation capability of continuous mining equipment in underground coal mining operations. The effort aims at increasing the overall rate of roadway development as well as providing a safer working environment for underground mine personnel. The activity is funded by the Australian Coal Association Research Program (ACARP) and forms part of a larger underground development initiative, known as the CM2010 project. The CM2010 is managed via a consortium of leading mining industry representatives through the Roadway Development Task Group (RDTG). The Task Group has identified three research areas requiring new development in order to realise the CM2010 project objectives: self-guiding (autonomous) continuous miner capability, an enhanced drilling and bolting process and improved mesh deployment. CSIRO's primary role in the CM2010 project is in the development of the autonomous continuous miner guidance capability.This paper reports on outcomes achieved at the half-way mark of a three year research and development project. It details the technical developments undertaken towards demonstration of a 'self-steering' capability to enable a continuous miner to automatically maintain a given mining heading and mining horizon under production conditions. A primary technical requirement of this automated functionality is the means to accurately determine both the location and orientation of the continuous miner in real-time. Testing and validation of the guidance system solution has been implemented using a combination of an instrumentation-grade inertial navigation unit and radar technology. Comprehensive performance evaluations have been conducted using a scale skid-steer mobility platform known as the Phoenix. Results achieved to the present stage of the project are highly promising and suggest that an automated self-steering functionality is achievable under production conditions. This new outcome represents an important move towards implementing a step change improvement for future underground roadway development.

Dec 6, 2010

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

By Jacob Miller, Phillip Mulligan

"Measuring the blast pressure associated with an explosion suspended above the ground (Free Air Burst)is a common research objective in Explosive Engineering. Theoretically, the shockwave from a Free Air Burst (FAB) configuration expands radially and the shockwave is assumed to have a smooth (uniform) shock front. The way in which the FAB explosive charge is suspended, packed, and the charge geometry can affect the shockwave expansion. These factors can generate a non-uniform shock front. As the scaled distance between the pressure sensor and the FAB increases, the shockwave expansion averagesnon-uniformities into a uniform shock front, at which point the FAB suspension system becomes less critical than when the scaled distance is “close-in” (Z <3)."

Jan 1, 2017

Innovative Technology for Optimised Thickening Sedimentation

Sep 13, 2010

By Enrique Solari

"El presente texto describe el trabajo de las minas de plata, oro y cobre durante la Pre-historia en Chile. En Hauntajaya y Yabricoya los indios trabajaron el cloruro de plata o plata córnea y la plata nativa. Sin embargo, los atacameños y diaguitas, fueron los únicos habitantes prehistóricos que practicaron la metalurgia, aunque no utilizaron el fierro en ninguna de sus formas, debido a su alto punto de fusión. Asimismo, en los primeros cateos o prospecciones que realizaron los indios, buscaban rocas y minerales, tales como la arcilla, el cuarzo, la cuarcita, el sílex, el lapislázuli, la obsidiana, la calcedonia, el jaspe, el ágata, el pedernal y los trabajaron con un gran conocimiento empírico de clivaje para la confección de herramientas y adorno. El método usado en la prospección de minerales fue a través del color, cobre, verde siticatado llamado por los indígenas 'Tanca"" y el carbonato de cobre (malaquita- azurita) llamado por los españoles como ""cardenillo"". Asimismo, los cateadores de minas prehistóricas contribuyeron en el norte de Chile, -en tanto bagaje de conocimientos- de los cuales, los cateadores hasta la época de la República, se sirvieron a la gran aventura de los derroteros de minas. "

Mar 1, 1967

By Carlos Gonzalez-Rivera

An alternative cooling curve analysis method focused on the experimental determination of the latent heat of phase changes and phase transformation kinetics is proposed in this work. The method analyses the cooling process of a metallic sample, initially liquid that is contained into a cylindrical metallic mold, both of known weight, thermally isolated at its top and bottom. The method is based on an energy balance associated with the experimental measurement of the temperature change of the sample and the mold during their cooling process. From the numerical processing of the cooling curves, are obtained approximate values of the acting global heat transfer coefficient as a function of temperature in order to describe quantitatively the energy exchange of the metal/mold system with its surroundings. These relationships and other experimental data are used to process the cooling curve of the sample and the mold during solidification, in order to obtain the latent heat of solidification.The method was applied experimentally to zinc and tin of commercial purity, initially liquids and contained into stainless steel molds in order to determine its ability to measure the latent heat of solidification. The obtained results suggests that this method shows a good potential to characterize the solidification of metals.

Oct 30, 2017

By W. A. Backofen, G. Y. Chin, W. F. Hosford

The effect of machine stiffness on discontinuous flow and fracture of the 2024 aluminum alloy was studied in tension at 4.2OK. An increase of machine stiffness was found to decrease the amount of elongation and drop in load during discontinuous flow, thereby postponing fracture to larger strains and higher stresses. The possibility of utilizing stiffened tools in deformation processing to suppress shear fracture originating from unstable flow was indicated. The problem of nucleating discontinuous flow and the role of the effective mass of the system in discontinuous flow were also considered. AT low temperatures the plastic flow of metals is often discontinuous, with sudden load drops and elongations.1,3 Basinski1,4 has presented strong evidence that discontinuous flow, at least in aluminum alloys, occurs under nearly adiabatic conditions. During testing the load may drop suddenly and flow become localized when the thermal softening, due to heat generated in plastic straining, is greater than the strain and strain-rate hardening. This instability criterion is more easily satisfied at low temperatures because 1) the volume specific heat is reduced so that relatively large temperature increases are possible in straining, and 2) the flow stress is relatively temperature-dependent. The important role of adiabatic shear in ductile fracture processes has been emphasized,5-1 and consideration has already been given to the influences of thermal and mechanical properties on the tendency of a material to undergo adiabatic shear.17677 By focusing attention on how the mechanical loading system influences low-temperature discontinuous flow, additional insight into adiabatic shear and its effect on fracture may be gained. EXPERIMENTAL PROCEDURE Because of its low thermal conductivity, the 2024 aluminum alloy exhibits a highly consistent discon- tinuous-flow behavior at 4.2°K and was therefore chosen as the material for study. Machined specimens of 0.113 in. diam and 1.125 in. gage length were solution heat-treated at 490°C for 3 hr, quenched into cold water, and immediately immersed in liquid nitrogen until just before testing. Testing was done at 4.2°K by immersion in liquid helium at a crosshead drive rate of 0.03 in. per min. As normally used (hard-machine basis), the spring constant of the testing machine was k = 25,000 lb per in. By inserting beam springs in series with the specimen, this value could be lowered by a factor of about 100. Details can be found elsewhere.? As a result of variable machine stiffness, the actual strain rate ranged from about 3 x 10 5 to 3 x 10-4 per sec from one test to another, as well as within any one test. However, preliminary tests had established that the tensile curves were not altered significantly by this strain-rate variation. Fig. 1 shows a typical load vs plastic-elongation curve for a solution heat-treated 2024 aluminum alloy specimen pulled in the standard hard machine (k = 25,000 lb per in.) at 4.2"K. The elastic extension has been subtracted. Plastic flow proceeded smoothly from yielding at approximately 22,000 psi (load = 220 lb) to a strain of about 4 pct at which point the flow became discontinuous. The magnitude of the load drops as well as the plastic elongation per drop increased with increasing strain until the specimen finally broke abruptly. The load-elongation behavior of a sample tested with a relatively soft machine under otherwise identical conditions is given in Fig. 2. In general, there

Jan 1, 1964

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

Demonstrate the technical feasibility of using nontraditional, low-rank, coal-based fuels and new coal-based technologies for mineral and metallurgical applications. Approach A cooperative research effort was initiated between the Bureau of Mines, U.S. Department of Energy and the minerals industry to extend the application of the fixed-bed gasification process to low-rank Western coals. The research effort enabled cooperators to gain operating experience in the use of hot, raw producer gas for iron ore pellet induration and other high-temperature mineral processes. Researchers were able to gather data regarding the fundamental engineering aspects of the fixed-bed process and gas cleanup for a wide range of solid fuel properties. Applying Fixed-Bed Gasification As a prerequisite to gathering the data needed for the study, the Bureau of Mines designed and installed, at one of its laboratories, a 6.5-ft-diam. single stage, fixed-bed, air-blown atmospheric pressure gasifier. The gasifier was coupled with a hot, raw gas combustion system and iron ore pellet in. duration kiln. The gasifier is rated at 1.5 ton/h capacity of bituminous coal.

Jan 1, 1987

By John A. Johnson

Conclusions regarding the use or omission of stemming in blasting have not peen reached, pending completion of all aspects of this investigation. The results from the dust phase of this study on six classes of stemming prove that the kind of stemming affects the amount of dust produced from blasting. In previous work at the Mount Weather testing adit it was demonstrated that blasting produces the highest dust concentrations of any of the mining processes.5/ Under the conditions prevailing at the Mount Weather testing adit, the average of all rounds having a break of at least 95 percent showed that the least amount of dust was produced when no stemming was used.

Jan 1, 1940

By Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.&apos;s Virginia Pocahontas No. S mine. Methane from the overlying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (l-S/B-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an underground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pet, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

By M. J. Lawrence

Independent natural resource Valuers are an essential link between miners and mineral explorers on the one hand and the finance industry on the other. Investors (and regulators) expect the mining and financial industries to be vigilant against the use of inappropriate methodology or use of illogical steps within the chosen valuation method. The Australian Corporations Law generally requires an Independent Expert Report to support mergers and takeovers (as well as for capital raising activities). The introduction of the VALMIN Code (1998) by The Australasian Institute of Mining as Metallurgy, has meant that such Reports, when prepared in compliance with it, are now much more comprehensible and reliable than before. This is because the key requirements of the Code are for transparency and materiality in the Technical Assessment and Valuation Reports prepared in connection with the transaction involved. Transparency is particularly important because it allows the reader to identify and understand the assumptions made to derive a value and to then form a view as to the reasonableness of the result. Even though many elements of resource asset valuation practice are undeniably subjective, there must be some basis of objective rationality to it. Where the reasoning is patently illogical or the inputs are chosen to achieve a particular result, the estimated value must be viewed as virtually worthless. Experience, qualifications, competence and repute are the hallmarks of a professional technical auditor and valuer.

Jan 1, 2000

The exploration methods used by the British Coal Corporation in 1990 improve the geological reliability of underground coal production. Although some of the techniques in common use have been proved to be effective, their limitations are recognised and concentration has been on the increasing integration of direct and remote sensing techniques. Attention is focussed onto first seam workings in sections of at least 2 metres in the depth range of 400-1200 metres and covers both surface and underground exploration. The case studies of exploration techniques and their effect on mine design at several existing collieries are representative of a wide range of geological environments within the more productive British coalfields. Notwithstanding such improvements in exploration and geological reliability, further new exploration technology is currently being investigated or trialled by British Coal.

Jan 1, 1991

By H. L. Gibbs

A portable radon monitoring instrument capable of making on-the-spot measurements of the radon gas content of uranium mine atmospheres was designed and constructed. The monitor was tested in the laboratory and in operating uranium mines. Good correlation was obtained between the monitor readings and radon measurements made on mine atmosphere samples taken in radon bottles.

Jan 1, 1973

By Gregory E. Smith

"Tensionable headed roof bolt systems are common in the U.S. mining industry. In the last 15 years or so, they have made a comeback as a hybrid system where a mechanical anchor is used in conjunction with resin. When such a system is used, it is common to use a spherical washer to comply with the requirements of 30 CFR Part 75.204(f)(8). This standard requires an angle-compensating device be used in installations where the bearing plate is offset from the roof bolt axis by an angle greater than five degrees. This paper evaluates system performance of four different traditional angle-compensating device/plate combinations including a new patented extruded plate/extruded washer system that improves overall load capacity and stretch.INTRODUCTIONA large western U.S. underground coal mine was using a fully grouted headed rebar system as their primary support. They had developed their component specifications over many years of working with suppliers to improve and optimize these components to integrate well as a system. As shown in Figure 1, the components included a patented 7 /8"" -diameter Grade 60 headed rebar bolt with a flange capable of full bar load (Walker, 2009) and a patented 8 in x 8 in Grade 3 extruded hole bearing plate manufactured by DieMatic Corporation.The mine decided to pursue a fully grouted tensionable system using a mechanical anchor as the tensioning device. Their primary goal was to eliminate the need for the roof bolt operator to secure (hold) the bolt during resin set time. An additional benefit was the increased initial tension on the bolt. To comply with the requirements of 30 CFR Part 75.204(f)(8), regarding tensioned roof bolts, they were required to include an angle-compensating device because a share of the bolt population would be installed at angles greater than five degrees from the perpendicular to the bearing plate. Also, to improve cycle time and torque/tension consistency, the mine desired to have the washers and anchors assembled at the factory. This required the use of a bearing plate with a center hole large enough to accommodate the 1-3/8-in-diameter mechanical anchor to pass though it during assembly by the roof bolt operator. The mine wanted to continue to use an extruded hole bearing plate in the tensionable system, and EMS was asked to propose a plate and angle-compensating device."

Jan 1, 2016

By Deming Wang, R. A. Overfelt

"This paper presents a computer-aided heat transfer simulation method to predict the thermal characteristics of an alloy sample in a special furnace for directional solidification. A two-dimensional transient heat transfer by conduction combined with radiation is developed to calculate the energy exchange between a directional solidification furnace and the sample. Finite difference equations with control volumes are used to calculate the transient heat transfer. A special boundary control volume is used to combine heat conduction and radiation in the transient heat transfer. Heat radiation effects on the surfaces of the special control volumes with a changeable view factor during directional solidification processing are also represented. The simulation results are verified by measurable experimental data. Using the computer simulation model, many thermal properties of the directional solidified castings can be obtained, such as temperature distribution, solidification velocity, the shapes and positions of the liquid/solid interface and thermal gradient at the interfaces. These are very important to analyze microstructure of casting alloys, avoid casting defects and control casting quality. 1 IntroductionIn directional solidification (DS) processing of castings, the temperature distribution, the interface between liquid and solid zone, thermal gradient in the mushy (pasty) zone and solidification rates are very important factors to analyze the microstructure and the casting quality. These variables affect the orientation and size of dendrites, shapes of grains, solute segregation and deleterious casting defects, such as microporosity, freckles and segregation channels. In order to avoid the casting defects, the temperature distribution and thermal gradients of castings during directional solidification must be strictly controlled. However, the structure of furnaces used for directional solidification is often complex. Heat transfer and temperature distribution within a casting not only depend on furnace temperature but also on the thermal properties of the casting alloy, crucibles, retorts etc. A more accurate heat transfer analysis."

Jan 1, 2001

By J. E. Campbell, A. W. Wesner, M. Pobereskin

This paper summarizes the results of an investigation sponsored by The Coates Steel Products Company. The objective was to determine the relative effects of certain chemical and physical properties on the wear resistance of grinding balls when grinding cement. In making this study, a number of types of balls were used in both dry and wet grinding in commercial ball mills. The radioactive-tracer technique was used in separating the test balls from the rest of the mill charge and in sorting the different types of halls that were all tested at the same time for each of the grinding operations. PROCESSING OF GRINDING BALLS In order to determine whether the properties of grinding balls, namely, composition, microstructure and hardness, can be related to the rate of wear, the halls used in this study were selected to represent various combinations of these properties. It was recognized that the mechanism of wear was not the same in the wet mill as in the dry mill. Therefore, the types of balls tested in each of the two environments were not necessarily the same. However, all of the types of balls evaluated in the dry mill were tested simultaneously for one time period, while those evaluated in the wet mill were tested simultaneously for three different time periods. All of the test balls were separated from the charge when the mill was dumped. All of the balls were of 0.940-inch diameter when charged, and all but the regular production balls were finish ground to this size to eliminate the decarburized surface layers. The steels and processing methods used, as well as the micro-structures and hardness levels of the balls, are described as follows: Regular production forged SAE 1095 steel balls were used in both the wet and dry mills. They were forged to a nominal diameter of 0.940 inch and quenched in oil from the forging temperature. Each retained a partially decarburized surface layer from the forging bar stock; the maximum depth of this layer was about 0.030 inch and the decarburization was negligible where the ball was sheared from the bar. The hardness at the surface was 40 to 46 Rock-well C in the partially decarburized area and 57 to 62 Rockwell C in the areas not decarburized. The hardened zone extended to a depth of about one-third of the radius. Below the decarburized layer, the hardened zone consisted primarily of hard as-quenched martensite with varying amounts of retained austenite. This structure changed to fine pearlite at a depth of about one-third of the radius. In order to eliminate the effect of the decarburized layer, a set of production balls of SAE 1095 steel was forged to about a 1-inch diameter, quenched in oil from the forging temperature, and ground on ball-bearing grinding equipment to a 0.940-inch diameter to remove the decarburized layer. The balls&apos; hardened zones were similar to those in the previous set. The hardness of the finished surfaces was 52 to 60 Rockwell C. A slight amount of decarburization apparently remained after the removal of about 0.030 inch from the surface. Balls of this type were tested in the dry mill only. Another set of forged SAE 1095 steel balls of 1-inch diameter was heated to 1500 F and quenched

Jan 1, 1961

By C. H. Bucknam, S. A. Wilson, G. E. McClelland

The Meteoric Water Mobility Procedure (MWMP) was developed in the State of Nevada during the 1980’s as part of their mine waste characterization programs. During the 1990’s the Waste Subcommittee of the Nevada Mining Association (NvMA) contacted ASTM Subcommittee E01.02 on Ores, Concentrates and Related Metallurgical Materials to undertake a standardization program for the method. A cooperative program was developed in conjunction with the Acid Drainage Technology Metal Mining Sector (ADTI-MMS)Prediction Committee, which involved eight of the NvMA labs performing duplicate leaching tests on two test materials: a coarse fraction of the USGS Hard Rock Mine Waste standard and a typical spoils sample from a heap leach operation undergoing closure in Nevada. Solutions for metals analysis were preserved and sent to the USGS Laboratories in Denver to determine the reproducibility and repeatability of the leaching. The history of the method and reference material and the results of the interlaboratory testing and statistical analyses will be presented.

Jan 1, 2003

By A. W. Sommer, H. H. Kellogg

It is shown that SO3-O2 mixtures react with sphalerite at an appreciable rate ill the temperature range of 361° to 527°C to fornz ZnSO4. The rate of reaction follows a parabolle lax. Oxygen, or O2-SO2 mixtures, have a negligible effect on sphalcrite in the same temperatuee range. PRACTICAL roasting of sphalerite is usually performed at 800°C or higher. The calcine is composed of zinc oxide unless the roaster atmosphere contains relatively large amounts of SO2 and the temperature is held to 800oC or lower, in which case zinc sul-fate may also form. Ong, Wadsworth, and assell&apos; have made a careful kinetic study of sphalerite oxidation under these "normal conditions" and have concluded that the rate of the reaction is controlled by the decomposition of an activated complex adsorbed on the sphalerite surface. They found the rate of oxidation to be small at 700°C. Extrapolation of their data to 400°C would indicate an almost negligible rate at this temperature. In our work sphalerite was reacted with air, mixtures of SO2, O2, and N2, and mixtures of SO3, O2, and N2 in the temperature range 361o to 527OC. Negligible rates of oxidation were found, except for the gas mixtures containing SOs. With this latter gas, the oxidation of finely divided sphalerite was fairly rapid and zinc sulfate was the product. Based on the limited evidence available, the rate of sphalerite oxidation by SO3 is postulated to be controlled by gaseous diffusion through pores or cracks in the zinc-sulfate coating. This evidence for the direct reaction of sphalerite and SO, at low temperature may prove of importance to the understanding of zinc-sulfate formation in the dust-collecting equipment usually associated with zinc roasters. The roaster gas carries off fine dust, much of which may be unreacted sphalerite. The temperature in dust-collecting equipment drops from the roaster temperature (about 800°C) through the range of temperature we studied, to ambient temperature. Such dusts are known to contain far larger amounts of zinc sulfate than the primary calcine. It has been assumed in the past that this sulfate is formed by reaction of ZnO dust with SO3 (or SO, plus 0,) in the partly cooled gases. Our work shows that an alternative possibility exists—the direct reaction of SO3 with ZnS dust. EXPERIMENTAL Reaction rates for sphalerite at 350° to 600°C are relatively small so that it was necessary to use finely divided material with a relatively large surface area in order to obtain measureable amounts of reaction. In the preliminary experiments, pure mineral sphalerite, ground to pass a 325-mesh sieve, and chemically precipitated ZnS (in the form of an impalpable powder) were used. In the quantitative rate experiments the ground mineral sphalerite was processed in an Infrasizer to obtain a product with particle size between 9 and 18 µ. The analysis of this material was 66.7 pct Zn, 0.09 pct Fe, and 32.7 pct S (theoretical sphalerite is 67.1 pct Zn, 32.9 pct S). The sized powder was carefully mixed and divided into l-g samples. The apparatus used for the quantitative rate measurements is shown in Fig. 1. For the preliminary experiments the following change was made: The external catalyst furnace (B, C)* was not used. *Letters refer to Fig._______1 .___- Rather, when catalysis of the SO2 + O2 reaction was desired, the glass beads in basket M were replaced by vanadium-oxide pellets. Procedure—A l-g sample of ZnS was placed on a shallow stainless-steel tray, I, and spread evenly to a depth of about 1mm. The tray was placed in the reaction assembly and the assembly inserted in the cold furnace. The furnace tube was flushed with dry argon and then heated to the desired reaction temperature. The temperature was controlled to ±0.5oC. Gas mixtures (O2 + N2 or O2 + SO2) were prepared from tank gases by means of a mixing device identical to that employed by Darken and Gurry.2 The total flow rate of gas was 205 ml per min to point A of Fig. 1. The accuracy of the individual and

Jan 1, 1960