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By J. A. Rusnak, M. M. Gadde, S. S. Peng

In situ stresses are one of the key inputs to a successful underground excavation design. Because of the complex mechanisms involved in arriving at the current state of stress at a point in the Earth’s crust, often the only reliable way of estimating in situ stresses is by actual measurement. In the United States coal mines, overcoring relief method is by far the most popular technique used for estimating the virgin stress field. Typically, for stress measurement with overcoring, a vertical borehole is drilled into the roof or floor of an underground coal mine opening to a certain distance and change in borehole diameter is monitored at multiple points along the length of the hole when this borehole is overcored. For the measured stresses to represent the pre-mining stress field, the measurement points should be located beyond the influence zone of the mine opening. Actual data from several US coal mines have been collected to check if the measured stresses by overcoring represent true in situ stresses. The data indicate that most of the stress measurements were within the excavation influence zone. A three-dimensional numerical modeling methodology was applied to one of the collected cases to correct the measured stresses for the excavation influence. The modeling approach demonstrated the usefulness of integrating numerical modeling into a stress measurement program to estimate ‘true’ in situ stresses.

Jan 1, 2006

By Fernando Ruiz Díaz

En aplicaciones a elevadas temperaturas como por ejemplo en cámaras de combustión y toberas de vehículos aeroespaciales se requiere el uso de aleaciones que permitan una elevada extracción de calor y buenas propiedades mecánicas. En este trabajo se realiza un análisis comparativo de las aleaciones Cu-Cr-Zr y Cu-Ag-Zr. Las mismas fueron sometidas a ensayos de resistividad eléctrica entre 25ºC y 700ºC y de tracción a 150ºC, 450ºC y 700ºC. Los resultados de los ensayos de resistividad eléctrica fueron convertidos a conductividad térmica mediante la relación de Wiedemann- Franz. A través de este análisis se observa que la aleación con mejor conductividad térmica es la de Cu-Ag-Zr presentando además un cambio de fase que no es observado en la aleación Cu-Cr-Zr. Respecto al ensayo de tracción la aleación Cu-Cr-Zr presenta mayores valores de resistencia a la tracción y tensión de fluencia a las temperaturas estudiadas.

Aug 16, 2017

By Francis S. Kendorski

INTRODUCTION Caving offers the lowest cost per ton of any large-scale mining method, but its successful application demands an ore body that conforms to several rigid requirements. The deposit must be of wide areal extent, massive and not spotty in ore values, and insensitive to ore dilution. It must also be a rock mass that breaks up readily. There are only three active caving operations in the US-Climax, Henderson, and San Manuel-but caving methods have recently taken on new importance as deeper lower grade mineral occurrences and ore bodies are found. These deposits are too deep for surface min¬ing methods, and too low grade to support any type of underground mining except a bulk method such as caving. Announced discoveries or indications that may be amenable to caving include: Climax's Mt. Emmons molybdenum discovery in Colorado; Molycorp's Goat Hill molybdenum prospect in New Mexico; the Phelps Dodge molybdenum deposit in Beaver County, UT; Arizona copper occurrences such as Asarco's Sacaton, Hanna's Casa Grande, Noranda's Lakeshore, and Ken¬necott's Safford; Anaconda's suspected deep copper de¬posit in Butte, MT; Anaconda's Carr Fork, UT, deposit; and perhaps others. CAVABILITY'S ROLE IN FEASIBILITY STUDIES Caving is a system of underground mining which removes support from underneath an ore body. As a result, the rock mass fractures, fails, and flows vertically downward by gravity to be collected in previously ex¬cavated funnels. Types of ore that have been mined by caving include molybdenum, copper, iron, nickel, as¬bestos, and diamonds (Julin and Tobie, 1973). It is primarily a large-scale method, with production rates of more than 45 300 t/d (50,000 stpd) having been achieved. However, the initial capital investment before return is very high, often in the hundreds of millions of dollars. The cavability of an ore body or mineral occurrence is a critical item in the feasibility study of a proposed mine, not only from the point of overall minability, but from the point of impact on other costs such as blasting, loading, hauling, crushing, and grade recovered. Aside from the often-asked question of, "Will it or will it not cave?" the real questions are, "Can we afford to make it cave, carry the rock away, and extract the mineral?" The last is not a topic of this chapter, but the first two are. The cavability of an ore deposit or mineral occur¬rence is based on many things, but clearly, if a large enough area is undermined, any rock mass will cave. The result could be a violent collapse as occurred at Urad, CO (Kendrick, 1970), or perhaps the rock mass will cave beyond the ore boundary. Another unfavor¬able result could be ore blocks that are too large for the equipment and orepasses to handle without considerable secondary blasting. Weak rock with numerous fractures may produce a very fine ore when it caves, resulting in dilution and ground control problems. DETERMINING STRUCTURAL DOMAINS It has long been recognized that the geologic nature of an ore body is important to cavability (King, 1946). Such items as weak rock material, intensity of fractur¬ing, and severity of faulting all contribute to the success of a caving operation, and information regarding these is required as a minimum for the cavability determination. In practice, the rock mass-defined as the blocks of intact rock together with the intervening fractures, joints, faults, bedding planes, and other discontinuities-that contains the ore body, as well as the surrounding and overlying rock, must be examined in a systematic and detailed fashion. Surficial geology maps must be pre¬pared, exploration holes drilled, and core logged for en¬gineering information. The fracturing of the rock mass must be studied to ascertain the three-dimensional dis¬tribution of fractures and their characteristics, and faults must be located and described. The strength and other mechanical properties of the rock material, the fracture surfaces, and the fault filling materials must be tested and reported for later use by designers and planners. With this basic information and an understanding of the geologic setting, the rock mass can be divided into one or more structural domains which tend to behave similarly in response to engineering activities (Robertson and Piteau, 1970). One must keep in mind that the determination of the structural domains goes beyond the geologic units present. Several lithologic units may be lumped together, while a single lithologic unit can be divided into multiple domains. Major faults often form their own domain, and the direction of engineering ac¬tivity-for example, cave advance to the north rather than the south-may alter rock mass behavior, resulting in different domains. As an example of the detailed rock fracture map¬ping required for such studies, the structural domain determinations at the Climax mine (Kendorski, 1973) are shown in Fig. 1. The circles are Schmidt equal area projections of the three-dimensional attitudes of frac¬tures (Ramsay, 1967) mapped in detail at various rock exposures. The attitude of fractures is important to the cavability determination since it dictates the directional behavior of the rock mass as it fails, and determines the effectiveness of arching, keying, and rock block inter¬locking. Low-angle fractures must be present to allow movement of the rock in the vertical direction during undermining (Mahtab and Dixon, 1976); if low-angle planes of weakness are absent, the rock mass may arch with a keystone effect, rather than moving vertically downward.

Jan 1, 1982

By M. B. Mooiman

Cyanidation of gold and silver ores by conventional mining and milling techniques has been practiced for over a century. During the past decade, heap leaching has emerged as a viable process for treating certain gold and silver ores. (1) The rapid development of heap leaching for gold and silver ores is largely a result of lower capital and operating costs and faster start-up time than that offered by conventional mining and milling. In general, these features make heap leaching an ideal approach for exploiting either small or large low-grade disseminated deposits of gold and silver considered to be uneconomic by conventional methods. The development of heap leaching technology has evolved from the operations initiated in the western United States. The basic components of a typical heap leaching operation are depicted in Figure 1. Run-of-mine or crushed ore (usually 1 to 5 ppm gold) is delivered to specifically prepared impervious pads. Alkaline cyanide solution is applied to the surface of the heap and allowed to percolate through the heap (typically 10-30 ft high). Pregnant leach solution which drains from the heap is collected and stored in tanks of sufficient size or in collection reservoirs. Gold and silver are recovered from the pregnant solution and the barren solution is recirculated back to the heaps after reagent make-up.

Jan 1, 1983

"IntroductionIn the 1970s, environmental concerns and associated liabilities were a new and unknown aspect of corporate risk. Today, social concerns and the associated conflicts that they can generate constitute a rapidly expanding aspect of risk. Although not a new phenomena — the Bougainville copper mine was forced into closure in 1988 — social risk has emerged as considerably more important, and increasingly visible, in the last few years. Social risk is now an aspect of all mining activities which needs to be calculated into project assessments, and to be managed throughout the life of a project. While social risk has a number of aspects at the corporate level, such as company image and shareholder relations, at the level of the individual project, its primary component is social acceptability, and the principal tool for managing it is the Social Licence to Operate.Social Risk in Latin AmericaThroughout Latin America there are newly modernized mineral codes and economic systems introduced over the last ten years which, together with new environmental legislation, look very much like regulations in developed countries. To the corporations, the existence of these instruments means that the risks from the environmental issues associated with the project are known; they are legislated, defined, quantifiable and hence manageable.It seems ironic that, just when comprehensive regulations for the environmental management of mining have been put in place throughout Latin America, there arise an increasing number of challenges to mining activities. For, in spite of the apparent guarantees provided by these new legislative reforms, communities in Latin America today are more frequently standing up and taking exception to the presence of mining companies, or the ways in which the companies are conducting themselves. The viability of projects becomes threatened because they are considered socially unacceptable, a phenomenon that we describe as social risk. These challenges are less about opposing mining activities than many people would think. Rather, they are based on an increasing desire on the part of the local population to have some measure of control over their own future, and to participate in the development process from the earliest stages."

Jan 1, 2000

By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012

By J. E. Sallee

An experimental study has been conducted on the level of arsenic contamination in samples of zinc oxide when the zinc oxide is contacted with gas mixtures containing As4O6(g). This contamination has been determined as a function of A4O6 saturation pressure, temperature, zinc oxide sample surface area, impurities, and oxygen level in the gas mixture. The results indicated a rather clean separation can be achieved between condensed zinc oxide and gaseous arsenic oxide as long as attention is given to temperature control, and the final zinc oxide surface area. For a 300°C operation temperature and an AqOg saturation pressure of 0.38 TORR (or 0.05% As406 by volume), the contamination level is expected to be approximately 100 ppm. This suggests that arsenical dusts can be treated in the HRD flame reactor process and a reasonable purity zinc oxideproduct produced. The results also show no evidence of zinc arsenite or zinc arsenate formation.

Jan 1, 1994

By Yuanhong Qi, Xun Fu Wang, Tao Fu, Kunkun Cui, Yingyi Zhang, Jie Wang, Junmao Qie

With the sharp decrease of sulfide nickel resources, the nickel laterite is becoming more attractive as nickel oxide, nickel matte, and nickel-iron. This study investigated the mineral phase structure, chemical analysis, thermal properties, and element distribution characteristics of the rotten rock layer deposited in the Southeast Sulawesi Ophiolite Belt. The results show that the nickel laterite deposited in Southeast Sulawesi Island, Indonesia, belongs to the typical high-nickel and low-iron garnierite-type laterite. The concentrations of nickel and iron of the nickel laterite are 1.99 wt% and 17.55 wt%, respectively. The serpentine, olivine, clay, chlorite, hematite, and magnetite are the major minerals, and the pyroxene, actinolite, limonite, and chromite are the minor minerals in the nickel laterite in Southeast Sulawesi, Indonesia. Serpentine and olivine are the main nickel minerals with an average nickel concentration of 3.65 wt% and 1.73 wt%, respectively. The Fe and Ni have homogeneity and symbiosis in the serpentine and olivine, and their concentrations are often positively correlated.

By R. K. Kandasami

"Naturally occurring geomaterials such as sandstone, limestone and other soft rocks, residual soils are composed of a particulates held together through a cohesive matrix, usually composed of argillaceous or siliceous cementing agents. Geo-materials such as these have been reconstituted in the laboratory using ordinary Portland cement in lieu of the naturally occurring cohesive matrix, in addition to using sand particulates. This cohesive frictional granular ensemble is an ideal model material for understanding the mechanical behaviour of transitional geomaterials such as soft rocks. An important consequence of this cohesion that pervades the inter particulate system is the enhanced tensile strength when compared to a purely granular ensemble. The assessment of strength of these soft rocks and cemented sands is often understood in the framework of continuum mechanics, i.e. considering the cemented sand to be a continuum, and performing simple elemental tests such as uniaxial compression or tension tests. A simple model to describe the behaviour of these cemented sands has been to use elements such as springs, sliders, and dashpots in parallel to describe the existence of a cohesive and frictional component of strength (Jiang et al. 2007). In the framework of continuum mechanics, the mechanical response of these cemented sands have been modeled using traditional plasticity theory, for example utilizing variants of the traditional Mohr Coulomb model, Modified cam clay (Sun and Matsuoka 1999) etc. The typical sand models are amended to include the effects of cohesion, as proposed by Lagoia and Nova (1995).The mechanical response of cemented sands is understood to be transitional to the behaviour of a typical particulate assemblage and a quasi-brittle material. However, the effect of length scale in these material systems has not been investigated. This paper presents a series of uniaxial compression experiments conducted on weakly cemented sand specimens of various sizes. The effect of length scale in these weakly cemented sands is investigated through unconfined compression tests."

Jan 1, 2015

By W. E. Rice

The ceramic industry has to do with forming or molding articles of clay, and imparting to them their characteristic properties of permanence, strength and color by subjecting them to heat treatment in kilns. This heat treatment is commonly known as "firing" or "burning." The art of firing clay ware antedates the industrial use of coal; hence wood was the fuel first used, and the earliest kilns were built to burn wood. The majority of the clay ware produced today is fired in periodic kilns that are essentially enlarged structures similar to the earliest enclosed kilns; a kiln consists of a large chamber 16 to 32 ft. dia. (or rectangular) in which the ware is charged and fired either in direct contact with flame or hot gases from the fuel, or in saggers which shield the ware from direct contact with the gases. The fuel is burned in a number of small furnaces built in the thick wall that encloses the chamber; these furnaces are from 16 to 36 in. wide and from 3 to 5 ft. long; some of them have horizontal or sloping grates, but many have no grates; the last are called "dead-bottom" furnaces. The temperature necessary to mature the charge in the kiln varies for different clays; for some it is as low as 1800°, and for others as high as 2700" F. Wood was an ideal fuel for the low temperatures that were used in early kilns; it burns freely and produces a long, clean flame, which promotes uniform distribution of the heat in the kiln; it does not coke and so restrict the passage of air through the fuel bed; the ash does not melt in the fuel bed to form clinker; and the ash that is carried into the chamber and deposited on the charge does not contain iron and sulfur to discolor the clay. The extent of the ceramic industry now precludes the general use of wood in kilns, so that today this industry is one of the large users of bituminous coal, burning more than eight million tons annually in kilns. Manufacturing plants usually are at or near the source of clay, with deposits of coal suitable for kilns occurring near the clay. The cost of coal is the largest single item of expense in the manufacture of clay ware, and, because all coals are not equally suitable for the process, the careful selection of coal is important. In this selection the desidera-

Jan 1, 1932

By Luana Ferreira de Carvalho, Aurelio Manço Garcia, Gustavo Sampaio Lopes, Jose Silvio Corsini, Davi Bastos Martins de Oliveira

The Enaex Mining Technical Solutions (EMTS) team, in partnership with the Anglo American Iron Ore Brazil drilling and blasting team, has developed a study aiming to optimize the blast design applied at the Minas-Rio project. The study consists of modeling the dynamic behavior of one lithological domain to determine the best configuration of drilling pattern, charge configuration, timing and sequencing of the blast designs applied at the mine in this particular rock.

Feb 1, 2020

By D. R. Corson

The Bureau of Mines instrumented two similarly backfilled stopes--one filled in the normal manner and the other with the fill densified using vibratory compactors--to evaluate the effect of fill compaction on subsequent vein-wall closure proposed as a adjunct process for strengthening cemented fill. Hydraulic pressure cells to monitor pressures within the fill and mechanical closure devices to measure vein-wall movement and the procedure for their installation are described. The field compaction work was generally performed manually by utilizing small commercial concrete vibrators. A prototype immersible vibrator using slusher cables to propel the vibrator in the stope was used on several lifts of fill. Although compaction efforts were less effective than anticipated in increasing the final density of fill, analysis of the field data does indicate somewhat improved strain characteristics and an increased pressure buildup for the densified fill. The effects of a prolonged period of inactivity and of rock burst occurrences in the immediate area are also reflected in plots of strain and pressure within the two instrumented stopes.

Jan 1, 1971

By E. T. Turkdogan, L. S. Darken, R. J. Fruehan

Further consideration is given to the application of the quadratic formalism to evaluate the thermodynamics of binary metallic solutions from experimental data. The use of the thermodynamic relation, in(r1/r2) dN2= 0, in the evaluation of activity data is discussed. The empirical correlations derived previously for enthalpies and entropies of solutions in Part II are shown to be predicted theoretically for a special case. The applicability of the quadratic formalism to the activity coefficients for binary organic solutions is demonstrated. DARKEN&apos; introduced a quadratic formalism describing the composition dependence of the activity coefficient in the terminal regions of binary metallic solutions. In a subsequent paper (Part II) Turkdogan and Darkeen2 extended this formalism to the enthalpy and excess entropy of binary metallic solutions, and showed that the available data for the activity coefficients and heats of mixing of many solid and liquid binary metallic solutions confirm reasonable applicability of the quadratic formalism. Much variation was noted, however, in the extent of the terminal regions from one system to another, commonly from about 10 to 70 at. pct. For the present purpose, equations derived previously need be given only for one of the terminal regions, e.g. region (I), 0 < N2 < N&apos;2: where subscripts 1 and 2 indicate quantities for components 1 and 2 and superscript ° the values at infinite dilution; other terms are: N = atom fraction, y = activity coefficient, = partial molar enthalpy of solution, ?HM = molar heat of solution, ?Sx = excess partial molar entropy, ?Sx = excess molar entropy. The heat and entropy like terms (constants) el, and S12 are defined in the following expression for the temperature dependence of a12, thus a12 £12 — s12 rnl 2.303RT 2.303 R l J Using this formalism, the thermodynamics of binary systems in the terminal regions may be described over a temperature range of experisental interest in terms of eight quantities: Lº1—Lº2, ?Sx1,?Sxº2 , £12 ,£21,fiai, S12, and S21. In the previous paper, these quantities were evaluated for many solid and liquid binary solutions, and two significant correlations were observed between these thermodynamic quantities pertaining to the terminal regions, thus [10] and [11] Combining Eqs. [9], [l0], and [ll] and rearranging gives a12 -a21 = 1.382R log rº2- 0.08(?S2xº- ?S1xº) [12] Since the second term involving entropies is small and Eqs. 1101 and [ll] are empirical relations, the above equation may be simplified to a12 = 2.74 log rº2 [13] Using the values of a&apos;s and y°&apos;s compiled in Parts I and 11, a12 - a21 is plotted against log(rº2/rº1) in Fig. 1; the line drawn has a slope of 2.74. For Hg-K at 300°C, log(yº2 /yº1)= —5.10, not shown in Fig. 1, and from correlation [13], a12 - a21 = -13.97; this is to be compared with -10.76 derived from the activity data (Part II).

Jan 1, 1970

By L. A. Cornish, L. H. Chown, M. Matema, R. Süss, L. Glaner, A. Douglas

Mintek has been developing Pt-based alloys for high temperature applications in aggressive environments, for example, land-based turbine engines, to replace the currently used nickel-based superalloys (NBSAs). The Pt-based alloys have a similar structure to the NBSAs, and since Pt is more chemically inert and has a higher melting point, the Pt-based alloys can potentially be used at higher temperatures. The greater chemical inertness of the Pt-based alloys compared to the NBSAs means that coatings can be simpler, or perhaps not even used at all, depending on the environment. TEM work was done at NIMS, Japan, to investigate the changes in the microstructure o f Pt-Al and Pt-Al-Ir alloys at elevated temperatures using in-situheating up to1100°C. Initial casting trials showed that work needs to be done to optimise casting parameters before commercialisation can take place. Room temperature tensile tests were performed and results were variable mainly due to microstructural differences. The alloy hardnesses were in the order of 300-350HV with ultimate tensile strengths of ~800 MPa and elongations of less than 10%. These results are comparable to other alloys used at high temperatures, which is very encouraging. Keywords: platinum, super alloys, hardness, tensile

Jan 1, 2006

By Sofoulis J

In the Archaean of the Kalgoorlie-Norseman area, the layered rocks have been subdivided into two sequences, both containing basic igneous rocks and sediments. The lower sequence is distinguished by the presence of acid volcanic flows and large acid sills. The upper sequence is unconformable on the lower one.In some areas, clastic sediments become coarser and pass into conglomerates. Th:s passage is accompanied by thinning of the beds.These features and their distribution suggest a basin of subsidence flanked by areas of shore-line conditions.Repeated igneous activity, including vulcanism, has occurred along the flanks of this basin. These different igneous and sedimentary environments have played an important part in the primary distribution of metals.A chronology of all basic and acid igneous activity, as well as sedimentat:on, has been established for the Precambrian of this area.INTRODUCTIONThe subdivision of Archaean rocks into those of basic igneous or of sedimentary origin has formed the basis for the nomenclature appearing in past literature. These subdivisions were distinguished as greenstones (predominantly basic igneous rocks) and whitestones (predominantly sediments), and it was generally accepted that the greenstones were stratigraphically lower in the sequence than the whitestones.Recent studies show that, between Kalgoorlie and Norseman, basic igneous rocks interfinger with and pass laterally to sediments, and that basic volcanic rocks occur at different stratigraphic levels. Younger Precambrian. units are also...

Jan 1, 1965

By M. C. Mound, E. Gallestey, C. Colbert

Continuous operating performance and high profit is one of the major concerns in the mining industry. Information systems are expected to reinforce and enable conformance to these requirements. The companion efforts of business management and production information systems press for tighter integration to avoid over-laps, multiple instances of similar data, and expensive maintenance of databases. Implementation of advanced intelligent systems throughout a mine operation can reduce costs, optimize investment and create a shorter payback via conversion of the data accumulated by field and process devices into information, and subsequently, into decisions. However, in order to harness the potential power inherent in these intelligent devices, adequate and flexible modular knowledge-based solutions are required. Fortunately, there has been at least one such practical response to this challenge, namely the ABB IndustrialIT portfolio. With these tools in place, production efficiency is reached via integration of process, production, and quality information. Moreover, they permit immediate detection and remedial action to changes to process and boundary condition variables. Finally, using advanced optimization techniques supported by dedicated mathematical models, they allow for economic process optimization (process set points and coordination thereof, energy management, production planning, energy supply contract optimization, etc) of the plant as a whole.

Jan 1, 2004

By J. B. Hess, C. S. Barrett

TO reach equilibrium between different phases in cobalt-rich alloys requires prohibitively long annealing cobalt-richalloystimes when temperatures are below about 700°C. The fact that a transformation from face-centered cubic to close-packed hexagonal readily tered takes place at temperatures below this in the cobalt-rich solid solutions is not an indication that thermally activated processes occur at an appreciable rate, for the transformation is well established as martensitic in nature. Wide divergence between heating and cooling experiments and high sensitivity to prior heat treatment make it difficult to judge temperatures of equilibrium between the phases.&apos; One object of the present work was to see if the information object of on the relative stability of phases could be gained by substituting plastic deformation for thermal agitation. Procedures were worked out that led to the determination of a diffusionless type of phase diagram, which represents the temperature of of phase equal stability for phases of the same composition, and the technique was applied to the Co-Ni system. Another object of the work was to see whether or not deformation would generate frequent stacking faults when these were thin lamellae of quentstackingfaultsa phase having higher free energy than the parent phase. The alloys were prepared in 80 to 100 g melts from cobalt (with metallic impurities estimated spectrochemically as follows: Ni, 0.05 pct; Fe, 0.001 pct.; Mg, Si, Cu, Cr, Al, < 0.001 pct) and Mond Car-bony1 nickel (with Fe, 0.05 pct; Si, 0.003 pct; C, 0.61 pct.; Cu, 0.001 pct; Co, Cr not detected, < 0.01 pct). The metals were melted in pure Al2O3 crucibles. An atmosphere of argon, that had been purified by passing over hot magnesium chips, was used for the alloys that, by analysis of the portions of the ingots actually used, were found to contain 15.3, 25.7, and 35.0 pct Ni, and vacuum melting (after degassing) was used for those containing 29.4 and 31.5 pct Ni. After induction melting the alloys were allowed to solidify in the crucible, and slices % in. thick x ½ in. in diam were annealed 12 hr at 1350°C for homogenization. These same specimens were used throughout the series of experiments, with annealing treatments of 4 hr at 900°C in purified hydrogen followed by furnace cooling, alternating with the deformation and X-ray tests discussed below. Results Spontaneous transformation was observed on cooling to room temperature in all alloys containing 29.4 pct Ni or less and by cooling the 31.5 pct alloy to — 195°C but was not observed in the 35 pct alloys after cooling to —195°C. These results are in satisfactory agreement with the cooling experiments of Masimoto.4 From these data it is clear that the temperature of beginning transformation M,,, drops to 20°C with the addition of about 30 pct Ni. The test for spontaneous transformation was metallographic. Specimens were thermally polished by annealing 10 hr in hydrogen at 1350°C, then furnace cooled; if trans- formation had occurred there were relief effects visible on the thermally polished surfaces. These markings were narrow straight lines, usually resolvable at high magnification as clusters of fine lines that resembled slip lines. It was concluded that they resulted from displacements on (111) planes, for the number of directions in individual grains often reached but never exceeded four, and lines could always be found parallel to the thermally etched (111) boundaries of annealing twins. The markings were thus consistent with the idea that the transformation occurs by (111) plane displacements (Shockley partial dislocations moving on (111) planes). This was further confirmed by X-ray tests for stacking disorders. Using an oscillating crystal technique previously employed to detect strain-induced faulting in Cu-Si alloys," streaks indicative of the stacking faults were looked for and found on X-ray films of the spontaneously transformed 25.7 pct Ni alloys, as expected by analogy with Edwards and Lipson&apos;s results on pure cobalt." The streaks were much intensified after rolling at room temperature. Transformation induced by plastic strain was investigated as a function of alloy composition and temperature of deformation. A series of tests was made to determine suitable straining and X-raying techniques. Filing was found inferior to abrasion in converting cubic samples to hexagonal, and abrasion was less effective than peening in producing smooth unspotty Debye rings in the X-ray patterns. Because the diffraction lines were broad, Geiger-counter spectrometer records of filings were less sensitive in revealing small amounts of transformed material than X-ray patterns recorded on films in a small diameter camera. After these exploratory tests the following methods were adopted. Specimens that had been annealed at least 4 hr at 900°C and furnace cooled were mounted in a block of aluminum, brought to temperature, and peened thoroughly with a mullite pestle preheated to the same temperature. The specimens were then quenched to room temperature. In peening, a circular area of % in. diam was given 500 blows. A few control tests showed that an additional 1000 blows did not detectably change the proportions of the phases present. The amount of transformation was judged by X-ray reflection patterns from the peened surface, using the innermost four lines of the cubic and the hexagonal patterns with filtered CoKa radiation,

Jan 1, 1953

By S. M. Runke

The pegmatite investigations at the Rapid City, S. Dak., Experiment Station during; the pact 3 years have been primarily a study of recovering beryl from nonlithium-bearing pegmatite rock by continuous-testing methods. Beryl concentrates containing 25 to 88 percent beryl were produced from rock that ranged in beryl content from 0.1 to 2.5 percent. The beryl recovery ranged upward from 70 percent but averaged better than 80 percent. Although promising results have been obtained with flotation methods for upgrading these concentrates to standard specifications, additional work is needed to improve and simplify the procedure. In addition, it was demonstrated that several potentially useful coproducts could also be recovered from pegmatite rock. The principal coproducts were mica, feldspar, and quartz. A heavy-mineral product also was made from pegmatites containing tin, tantalum, and columbium. The recovery if these minerals in products meeting the specifications of the commercial users has been reserved for future study. The investigations also included studies on extraction of beryllium from both high-grade beryl and flotation concentrates of medium beryllium content. The procedure investigated consisted of sintering beryl or beryl flotation concentrates with limestone, acid curing the resulting sinter with sulfuric acid to dissolve the beryllium, and water leaching to extract the beryllium. Over 90 percent of the beryllium was extracted by this procedure. Most of the optimum conditions and quantities of reagents were determined for dissolving the beryllium. As aluminum and iron also were taken into solution by the acid, further research is needed on methods of recovering high-grade beryllium salts from the solutions containing these elements.

Jan 1, 1957

By T. Grounds, K. Singh, W. R. Reed, R. Cross, G. Ross, S. Klima, M. Shahan

"A 2nd generation roof bolter canopy air curtain (CAC) design was tested by National Institute for Occupational Safety and Health (NIOSH) at a Midwestern underground coal mine. During the study, the roof bolter never operated downwind of the continuous miner. Using a combination of personal Data Rams (pDR) and gravimetric samplers, the dust control efficiency of the roof bolter CAC was ascertained. Performance evaluation was determined using three methods: (1) comparing roof bolter operator concentrations underneath the CAC to roof bolter concentrations outside the CAC, (2) comparing roof bolter operator concentrations underneath the CAC to the concentrations at the rear of the bolter, and finally, (3) using the gravimetric data directly underneath the CAC to correct roof bolter operator concentrations underneath the CAC and comparing them to the concentrations at the rear of the bolter. Method 1 dust control efficiencies ranged from -53.9% to 60.4%. Method 2 efficiencies ranged from -150.5% to 52.2%, and Method 3 efficiencies ranged from 40.7% to 91%. Reasons for negative and low dust control efficiencies are provided in this paper and include: incorrect sampling locations, large distance between CAC and operator, and contamination of intake air from line curtain. Low dust concentrations encountered during the testing made it difficult to discern whether differences in concentrations were due to the CAC or due to variances inherent in experimental dust measurement. However, the analyses, especially the Method 3 analysis, show that the CAC can be an effective dust control device. INTRODUCTION Canopy air curtains (CAC) have been shown to be an effective respirable coal mine dust control for roof bolters in a laboratory setting with dust control efficiencies ranging from 14% up to 75% [Goodman and Organiscak 2001, Listak and Beck 2012, Reed et al. 2017]. Unfortunately, there is limited information on their effectiveness for controlling respirable coal mine dust in the field. On continuous miners, CAC dust control efficiencies ranged from 23% to 69% [Krisko 1975]. Two underground tests of the CAC on roof bolters demonstrated dust control efficiencies of 35% and 53% [Listak and Beck 2012] before problems occurred with operation of the CAC. Since the implementation of the new respirable coal mine dust limit from 2.0 mg/m3 to 1.5 mg/m3 (Code of Federal Regulations, 30 CFR 70.100, 2015), roof bolter CACs are becoming more commonplace in underground coal mines as a dust control tool to prevent roof bolter operator overexposure to respirable coal mine dust. J.H. Fletcher & Co. has been instrumental in delivering an effective design which incorporates the filter, blower, and canopy plenum seamlessly into the design of the roof bolter, resulting in a successful operational roof bolter CAC."

Jan 1, 2018

By G. R. Hopkins

The petroleum-refining industry established a new record in fuel efficiency at refineries in 1936, when 597,000 B. t. u. of heat were required to refine a barrel of crude oil, compared with an average of 615,000 B. t. u. in 1935 (see fig. 1). The principal factor in the "indicated gain in fuel efficiency at refineries in 1936 was an increase in crude runs of 11 percent over 1935. A large part of the heat utilized at refineries is consumed elsewhere than under stills, or in ways quite independent of crude-oil distillation. In other words, as the operating ratio (crude runs divided by capacity) for refineries increases toward the maximum of 100 percent, the fuel requirements show progressively smaller increases and the average E. t. u. consumption per barrel of crude refined declines.

Jan 1, 1938