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By M. Ribeiro, P. So, P. Wong

Electrowinning is a process by which metals, such as copper or nickel, are recovered from aqueous electrolyte solutions resulting from the extraction of the metal ion from an acidic or basic leach solution. The electrolyte or “pregnant” solution is customarily forwarded to an electrowinning "tankhouse." In the tankhouse, the metal ions are deposited on cathode plates by electrodeposition and then recovered from the cathode plates. Other processes may be employed with other metals, such as nickel, zinc, among others, to produce an electrolyte from which their respective metals are obtained. During the electrowinning (electrodeposition) stage, elemental metal is plated out at the electrowinning cathode and oxygen evolves at an insoluble anode. The evolution of oxygen gas forms bubbles which entrain strong acid electrolyte, carrying it into the air above the electrowinning tank in the form of a fine mist or spray when the bubbles break. An acidic mist is generated above the electrolyte. This mist or spray then spreads throughout the electrowinning tankhouse. The acidic mist is corrosive and a health hazard and can cause extreme discomfort to the skin, eyes, and respiratory systems of tankhouse workers, especially during hot weather conditions. Polyfluoroalkyl based products (PFAS) have been widely applied as anti-misting agents in the electrowinning of metals in an acidic electrolyte. Functionalized PFAS compounds, however, have come under increased scrutiny by the EPA due to their impact on human health and the environment. There remains need for improved acid mist suppression agents for electrolysis and electrodeposition, particularly for products free of fluoroalkyl components.

Feb 1, 2023

By Ming-Feng Ye, Guang-liang Wu

The microstructure and mechanical strength variations of chromite pellets preheated and roasted in air were studied systematically. The results show that the chromite (Fe,Mg)(Cr,Fe,Al)2O4 is oxidized to magnesium-rich (Mg,Fe)(Cr,Fe, Al)2O4 and ferrochromium complex oxide (Cr,Fe,Al)2O3 in the preheating process over 500 °C. When the temperature is higher than 1000 °C, the new phase (Cr,Fe, Al)2O3 is formed, which is mainly distributed in the outer layer of a single chromite particle. Inner the particles there are acicular (Cr,Fe,Al)2O3 and unoxidized (Fe,Mg) (Cr,Fe,Al)2O4, which forming an interwoven structure together. The oxidation rates of pellets can reach to superior limits in 20 min. With the temperature increasing from 950 to 1300 °C, the mechanical strength and oxidized rates increase to varying degrees correspondingly.

Mar 1, 2018

By Richard E. Ray

INTRODUCTION Main mine fan installations at underground coal mines must be designed to comply with the requirements outlined in 30 CFR (Code of Federal Regulations) Part 75. However, very little emphasis is typically placed on the aerodynamic optimization of shaft collar designs, ductwork configurations, and the selection of a fan isolation, or "closing door," system. Field testing has shown that poorly designed systems may produce large pressure losses between the shaft and fan inlet, as well as air turbulence problems which adversely impact fan efficiency and sometimes fan structural integrity. This paper analyzes each component of a surface exhaust fan system for an underground coal mine: • The shaft collar arrangement, • The 45 or 90-degree turning duct that isolates the fan motor from the return airstream, • Alternative ductwork arrangements for parallel fan installations, • The self-closing doors or dampers that are required for multiple fans, and • Horizontal and vertical evas6 arrangements on the discharge side of the fan. While discussion is limited to axial fan installations at shaft mines, most of the recommendations would also apply to centrifugal fan installations and to main mine fans for drift mines. FEDERAL REGULATIONS The mandatory safety standards for underground coal mines that apply to the installation of main mine fans are listed in 30 CFR Part 75.310. Stipulations which impact the design of the fan sys- tem arrangement are contained in paragraphs (a)(l), (a)(5), (a)(6),(d), and (1) of 75.31 0: • Each main mine fan shall be installed on the surface in an incombustible housing; • Each main mine fan shall be protected by weak walls or explosion doors in direct line with possible explosive forces; • Explosion doors or weak walls shall have a cross-sectional area at least equal to the area of the return air shaft or drift opening through which the pressure from an underground explosion would be relieved; • Each main mine fan shall be offset by at least 4.57 m (15 feet) from the nearest side of the mine or shaft opening; • Automatic closing doors shall be provided to prevent possible air reversals through the fans in mines ventilated by multiple main mine fans. The installation of main mine fans underground is prohibited by 30 CFR Part 75.310, (a)(l). Providing explosion doors or weak walls in line with a possible underground explosion and offsetting the fan 4.57 m (1 5 feet) from the edge of the shaft preclude the installation of the fan directly over the shaft. In addition, 30 CFR Part 75.507-1 specifies that all electrical equipment used in return air courses be permissible, which requires locating the fan motor outside of the airstream exhausted through the fan. To comply with the Part 75.310 regulations, explosion doors are typically located directly over the shaft as part of the shaft cover or 'bonnet." A sufficiently long section of ductwork placed between the shaft enclosure and fan, equipped with a 45 or 90- degree turn, enables the fan to be offset at least 4.57 m (1 5 feet) from the shaft and the motor to be isolated from the airstream. The need for the turn in the ductwork can be eliminated by driving the fan from the discharge side, instead of from the inlet side, and providing for a 90-degree bend in the evas6. For multiple main mine fan systems, self-closing doors can be located on the inlet or discharge side of the fan. FAN SYSTEM COMPONENTS A poorly designed exhaust fan arrangement will produce turbulent conditions at the fan inlet and significant pressure losses between the shaft and fan. Field tests have shown that pressure losses through inlet ductwork at some installations may constitute as much as 30 percent of the total mine head. Unfavorable flow conditions may cause a change in the operating point on the fan performance curve, resulting in reduced fan efficiency and pres- sure generation capability. In some instances, poor airflow distribution through the fan may create mechanical stresses that lead to fan blade or fan housing fatigue failures. The objective in designing an air duct arrangement for a fan system is to provide a low cost duct that will move the air from the shaft to the fan in a uniform air distribution and with minimum energy requirements. The optimum solution is a compromise between technical and economic factors. Aerodynamic design considerations for the shaft collar and cover, fan inlet ductwork for both single and parallel fans, self-closing doors, and evas6 are discussed in the sections below. Shaft Collar/Cover To prevent excessive turbulence and non-uniform air distribution through the fan, a smooth transition for the change in direction of airflow at the top of the shaft must be provided. However, the concrete lining of the shaft is abruptly terminated at the surface at many coal mine installations (see Figure I), creating a sharp 90-degree bend. The airflow exiting the shaft becomes heavily concentrated in the upper portion of the horizontal fan in-

Jan 1, 1997

By W. H. Langer

Around the beginning of the 20th Century, annual aggregate production in the United States amounted to about 50 million short tons. Today annual aggregate production is nearly 2.5 billion tons. Over a third of the States in the country produce more aggregate than the Nation did at the turn of the century. I would like to describe some of the historical events that allowed this nearly 50 fold increase in aggregate production. You might wonder why I want to talk about history. Some of our best ideas lie buried in the past, waiting to be rediscovered in the present. Almost every issue that the aggregate industry experiences today has been recognized for at least a decade; many of those issues have been recognized for a half a century; and a few of them have been recognized for nearly a century. The main reason for this article is to save the past from the forgetful indifference of the present-to faithfully preserve the past, to illustrate the insights of our predecessors, and to demonstrate how little of what we know today is really new.

Jan 1, 1998

By Juan Carlos Lozada

YURA S.A. es una empresa industrial cuyo principal actividad es la fabricación y comercialización de Cementos Portland y adicionados, conglomerados de albañilería y concretos. Asimismo proyecta la construcción de una nueva línea de producción de Clinker. En ese sentido, el presente texto señala el sistema de gestión que se utilizó para mejorar las prácticas sugeridas por el PMI (Project Management Institute) en la Guía del PMBOK, y cómo se aplicaron las diferentes herramientas a las situaciones particulares del mismo.

Sep 12, 2011

By Donald J. Knight

HEAT Treatment at 1500' F of a mild steel containing 0.1 pct C, in an atmosphere which is oxidizing to both carbon and iron, results in the progressive oxidation of the metal surface with little or no change in the carbon content of the underlying metal. Further heat treatment of the scaled metal in either a neutral atmosphere or in a vacuum may or may not result in the decarburization of the metal depending upon the physical nature of the scale. It is apparent that if a continuous layer of oxide is present on the steel surface, the reaction OScale + Cmetal Cogas cannot progress since the SO formed gas would be unable to leave the oxide/metal interface. Thus, in order for the reaction to progress, the oxide must be cracked or porous. Vacuum heat treatment at 1500" F of samples with a thick continuous oxide scale showed no decarburization of the steel. However, when cracks were introduced mechanically into the scale prior to the vacuum heat treatment notable decarburization of the metal resulted and a structure as shown by Fig. 1 obtained, i.e., reduction of the crack walls to ferrite. With reference to the diagram of Fig. 2, it would appear that a mechanism of the following type takes place. Carbon atoms arriving at an oxide/metal/void interface, such as 'A', Fig. 2(a), can combine with oxygen atoms from the scale and leave the reaction site as Cogas thereby reducing the oxide to metal. On a greatly magnified scale, Fig. 2(b),this will appear as a ferrite projection along the crack wall. Carbon atoms entering this projection can react with oxygen atoms at point 'C', which is a new interface, and so on leading to a progressive growth of the ferrite along the crack wall and to the surface, Figs. 2 (c) and 1. It would appear that the only means by which thickening of the ferrite film can take place is by a diffusion of oxygen through the ferrite film to react with carbon at the newly formed ferrite/ void interface. Since the diffusion rate of carbon is reportedly much greater than that of oxygen, and since there is a low probability factor of oxygen and carbon atoms arriving simultaneously at the same site on the ferritehoid interface, there will be a tendency for more rapid lengthening than thickening of the ferrite layer, as is observed.

Jan 1, 1962

By P. Rusin

Toxic substances in On solutions can retard biological leaching of copper sulfide dump ores. On solutions were analyzed for metals, organics, and chloride, and showed inhibitory concentrations of aluminum, manganese, and chloride. Inhibition of bacterial activity by the solid fraction of On solution, with and without the organic constituents, was evaluated. Toxicity to bacterial species was evaluated by monitoring bacterial numbers, pH, Eh, and rates of iron oxidation. The On solution solids were toxic at 50 -60% of their field concentration. Most of the toxicity of the On solution was due to the organic fraction. Different SX reagents show varying degrees of inhibition of T. ferrooxidans. Bacterial inhibitory effects of carriers and lixiviants used in the SX plant should be determined so that entrained SX reagents do not retard biological dump leach systems. The reagents used should be the most cost effective and the least toxic.

Jan 1, 1994

We report the studies of Proton-Exchange Membrane Fuel Cells (PEM FC) and hydrogen storage materials at McMaster University for the last 14 years. From the initial investigation of ionic conduction mechanism to the revelation of the origin of non-Arrhenius temperature dependence, as well as the synthesis and characterization of high temperature polymer electrolytes, both experimental and theoretical works have been compiled for the fuel cell membranes. In addition to the discovery of suppressed ionic conduction in Electrode-Membrane Assembly (EMA) and novel hydrocarbon PEMs based on micro-emulsion, the first evidence of hydrogen adsorption saturation by carbon nano-tubes was also achieved, which has been the bottleneck for the application of PEM FC. Prior to our study, a number of controversial publications have claimed the hydrogen capacity of these materials to be between 0.1 to 10.0 wt.%, and none demonstrated a plateau of adsorption with pressure that is consistent with monolayer saturation. Others suggested that the tube bundle structure is opened under high pressure to enable higher adsorption on newly uncovered surfaces, but received no confirmation. Using our home made high-pressure instrument with in-situ electrical probes, we found that a plateau is nearly achieved at about 300 atm in the room temperature isotherm, and that nanotube bundles actually compress with pressure instead of splitting, using in-situ electrical measurements.

Jan 1, 2005

By N. Kubo

Sumitomo Toyo Copper Smelter and Refinery was commenced in 1971, and its production capacity of sulfuric acid was 550tpd at the beginning. In 2001 Toyo Copper Smelter and Refinery projected to expand its copper production capacity to 450,000tpy, and now the project is still in progress. To achieve this expansion project, 4,000tpd of sulfuric acid production capacity is necessary to the acid plant. So as a part of this project, the construction of the new converting and absorbing line and the improvement of the existing converting and absorbing line were carried out from 2001 until 2005. Then the production capacity of these 2 lines has already reached the target, 4,000tpd of sulfuric acid. Moreover, at the design of the new line, we adopted several latest technologies and materials in order to construct the world's leading acid plant. Basing on the operation performance of the new line, we have improved the existing line in 2005. Both of these 2 converting and absorbing lines are working quite well and contribute to big energy saving and excellently stable operation. Cu2007

Jan 1, 2007

By Rajesh Minda

160 numbers of double bulb underreamed piles were constructed based on the safe loads specified in IS code at Tripura. The pile load tests yielded a much lower capacity. A detailed investigation work was carried out to find out the reasons for anomaly. The work included soil exploration followed by extraction of two piles bearing numbers 72 and 151. It was seen that the bulbs were not formed as per specification. Some comments on IS Code have been made at the end.

Jan 1, 1996

By J Heyes, R Getty, M Sanapala

Closure is an inevitable part of the life cycle of every mine. Successful closure outcomes critically depend upon early and ongoing integration of closure planning and mine planning. Early and holistic integration minimises residual risk and maximises opportunity to leave a cost-effective, positive legacy for the company, investors and future land users. Both disciplines are inherently interconnected and aim to maximise ‘value’ via trade-offs. Historically, integration of closure into mine plans has been poorly implemented across the industry. There is still a perception that closure planning only starts as the end of a mine life approaches. This inevitably leads to tension when making business decisions, with progressive closure often being deferred due to short-term drivers and incentives. To create a positive legacy after production has ceased, this tension can be managed by transparently and fully informing business decision-makers, such that the impacts of short-term decisions on long-term closure objectives are understood. BHP recently updated a business-wide standard ‘Our Requirements for Closure and Legacy Management’ designed to strengthen collaboration, education and integration of closure across the entire life cycle of the asset. Concurrently, the ‘Life of Asset’ definition was refined to include the postproduction phase, until closure objectives have been met. This paper discusses the criticality of mine planning integration with closure and how updates to Our Requirements sharpen the focus from transactional to transformational planning. These concepts are applicable to any mining operation aiming to achieve successful closure across the full asset life cycle, from exploration to post-production.

Sep 18, 2023

By G. V. S. Murthy

Beach Placer Ilmenite is an important source for production of titanium metal, titania slag and pigment grade titanium dioxide. Besides, these well known applications for which Ilmenite is mined and processed, there are other emerging processes that are being tried for obtaining highvalue products. Synthesis of Ilmenite based materials for varistor applications and direct electrochemical reduction of Ilmenite to produce ferrotitanium are two such attempts being discussed in this work. In this paper, recent efforts undertaken to study the electrical and magnetic characteristics are discussed. Ilmenite, FeTiO3, is one of the mixed-valence transition metalbearing minerals, inwhich Fe can be in two different oxidation states, Fe2+ and Fe3+.. Similarly, Ti can be in Ti3+ and Ti4+.Ilmenite is inherently suitable for making Varistors, which are devices, used for limiting the transient voltage surges in a circuit. Varistors produced from Ilmenite can withstand harsh environments seen in nuclear reactors and outerspace. Electrochemical reduction of Ilmenite can be used to prepare ferrotitanium directly without any reductant. The process essentially involves removal of oxygen from the mineral through electrolytic action using calcium chloride as electrolyte and graphite as anode. At a temperature of 950°C, it is shown to be possible that all the oxygen can be removed from the Ilmenite sample, which passes through the electrolyte, to form CO/CO2 at the anode. The process has immense potential for cost effective production of titanium metal as well. Results of the above developmental works are presented in this paper. Keywords: beach placer ileminite, varistor applications

Sep 1, 2012

By Yong Li, Tao Jiang, Xiangxin Xue, He Yang

"In this paper, we describe the current status and research progress on the utilization of typical industrial solid wastes in China. We propose a creative method called “eco-utilizing wastes” with an aim of both integration and increment but without second-time waste and pollution, in terms of the characteristics of typical industrial solid wastes, such as titanium-bearing blast furnace slag, high-silicon iron tailing and boron-enriched slag as well as oil shale.Situation of Typical Industrial Solid Wastes in ChinaThough mineral resources in China are abundant, most of these are low grade ores. Moreover, the distribution of mineral resources is asymmetric, which causes the increase of cost and decrease of the economic benefit. Over-exploitation of mineral resources results in a large number of solid wastes. The accumulation of solid wastes not only means the waste of valuable resources, but also causes environment deterioration. There exist some problems in the current practice of the disposal of industrial solid waste, such as only emphasizing the final results and causing new pollution and waste [1]. So the research and development of a high value-added method has a high practical relevance to our nation. Based on the present status and research progress of industrial solid wastes in China, a creative new idea and method for eco-utilization of solid wastes is proposed in this paper."

Jan 1, 2012

By Paul M. Price

The Mouat mine, Nye, Mont., was reopened in 1953 by the American Chrome Co. under a Defense Minerals Production Administration contract. Operations were terminated in 1961 after completion of the contract. Mining methods employed during this period are described in detail, and cost data are presented by years for 1953 through 1959. Ultramafic rocks of the Stillwater complex in Montana contain the largest domestic resource of chromite, and the Mouat mine has been the largest producer. Mine reserves were estimated in 1960 to be about 4.4 million tons containing 22.5 percent Cr2O3. The chromite deposits occur as a series of overlapping bands or lenses roughly paralleling the steeply dipping layers of the complex. Only two of the chromite layers have proven to be of economic importance. One layer is 2 to 16 feet wide; the other is 3 to 8 feet wide. Shrinkage stoping was generally used throughout the mine, but various methods of ore breaking, stope drawing, chute construction, etc., were tested to improve output and lower costs. Long-hole stoping proved to have limited use. Breasting down benches, developed outward from the center of the stope with air-leg drills, was satisfactory only in wider stopes. At the close of operations, the company had standardized the use of lightweight stopers to advance a flat back by breaking from a centrally located face. Mining costs were reduced 47 percent during 7 years of operation.

Jan 1, 1963

By David R. Maneval

In 1956 the Legislature of the Commonwealth of Pennsylvania created a "Coal Research Board" in the Department of Mines and Mineral Industries. Over the years through amendments to the original legislation, the scope of authority for research has been expanded from the narrow area of improving and increasing the utilization of coal to covering all aspects of coal technology and any other area of interest which would be of value to the coal industry. In January of 1964, the Board commenced a vigorous program using appropriated funds and funds donated by the coal industry to finance a research program devoted to seeking solutions to the mine drainage problem. A review of published literature on the treatment of mine drainage indicated that much work done up to that point in time concerned only the mechanism of mine drainage formation and theoretical chemistry. Very few applied, developmental, or engineering studies had been devoted to finding practical solutions to the problem of polluted waters being discharged from active or abandoned mines. Projects were therefore undertaken on a wide variety of more utilitarian approaches. This paper will discuss briefly some of the pollution abatement approaches which have been funded by the Coal Research Board of this State, and will describe in some detail a multistage flash evaporator treatment plant now under construction.

Jan 1, 1970

By Levent Ozdemir, Robert J. Evans, Russell J. Miller, William Sharp

This paper describes the specifications and capabilities of a 6 ft (1.83 m) diameter laboratory rotary cutting machine which was designed and fabricated under a Bureau of Mines (USBM) contract awarded to the Colorado School of Mines (CSM). The machine will be used for carrying out research and development programs aimed toward improving the design and operation of mechanical tunnel, raise and shaft boring equipment.

Jan 1, 1983

By R. Frank Chiappetta

A new blasting technique has been developed by International Technologies, LLC. to eliminate subgrade drilling, lower ground vibrations, improve fragmentation and reduce explosive consumption. The new technique utilizes a uniquely designed borehole plug, with a bottom hole air deck and a predetermined stemming mass on top of the plug. This combination is referred to as the Power Deck?. Single holes and full scale tests were conducted by Blasting Analysis International, Inc. (BAI) to determine how the system works, the mechanisms behind its success and the best design parameters to use for the given rock conditions. Results have shown reduced or eliminated subgrade drilling, ground vibration reductions of up to 33%, reduced explosive consumption by 16 to 25%, and improved fragmentation by up to 25%. This paper summarizes the methodology, field test setups, analyzes procedures and results for one series of single hole and full-scale tests which were performed in a Pennsylvania, USA quarry.

Jan 1, 2004

By D. O. Kennedy

"INTRODUCTION During the recent war attention was directed to prevent the destruction of American industries by sabotage. By Executive order of Lay 19, 1942, the Bureau of Mines was required to conduct investigations and make recommendations that would prevent loss of production of essential war minerals. The Health and Safety Branch of the Bureau of Lines was able to extend its activities with minimum loss of time to include security surveys of the important mineral facilities in the United States.A Mineral Production Security Division was established in the Health and Safety Branch with funds appropriated for that purpose by Congress in April 1942. From July 1942 to July 1945 engineers of this division, under the direction of D. Harrington, Chief, Health and Safety Branch, and J. J. Forbes, Chief, Mineral Production and Security Division, conducted investigations of 1,560 metallic and nonmetallic mines and associated facilities in accordance with the requirements of the Executive order.PURPOSEAn analysis of losses in the production of minerals shows that failure or destruction of equipment either from deliberate or accidental causes produces essentially the same result. Maximum production is insured by the prevention of subversive activities, fires, and industrial accidents."

Sep 1, 1946

By H. Y. Sohn, M. K. McCarter, Bradley C. Paul

"A computer model was constructed for bacterial leaching of the major sulfides found in porphyry deposits, including bornite, chalcocite, chalcopyrite, covellite, cubanite, enargite, native copper, pyrite, and pyrrhotite. The model incorporates equations for the sulfide minerals dispersed in the rock matrix. Leaching occurs by reactions with ferric ion diffusing into the rock fragment: Ferrous ion is resenerated to ferric with oxygen by bacteria at a temperature dependent rate. The model keeps track of the net acid generated, oxygen consumed by the bacterial oxidation of ferrous ion, heat generated, jarosite and hematite precipitated, and copper leached. The model was used to predict the rate of copper recovery, heat generation and oxygen demand for a variety of run-of-mine sized porphyry ores. These results were used in the design of a ventilation system and the economic analysis of a modified in situ extraction method that may be cost competitive with conventional copper production involving open pit mining.IntroductionA study was undertaken at the University of Utah to evaluate the technological and economic feasibility of mining copper by a method referred to as Flood Drain Leach Cell (FDLC) mining. Cells 60 by 75 meters in plan and 70 meters in height are created throughout the ore body by a modified Vertical Retreat Mining technique that includes the removal of 25% swell material. The swell material is leached in finger dumps on the surface while the cells underground are bulkheaded, flooded, drained, and artificially aerated to promote bacterial ferric sulfate leaching. Solutions are cycled through several cells to reach pregnant grade of 1 gram copper per liter of solution. These solutions are then fed to an underground solvent extraction plant and then a surface electrowinning tankhouse."

Jan 1, 1988

By Stephen C. Tadolini, Thomas M. Barczak, Peter (Yunqing) Zhang

A cooperative study was conducted with Emerald Coal Resources, L.P., an affiliate of Foundation Coal Corporation, and the National Institute for Occupational Safety and Health (NIOSH) to evaluate the effectiveness of (partially) pre-driven longwall recovery rooms supported with pumpable roof supports. This paper evaluates the load transfer mechanics associated with the advancement of the longwall face into the pre-driven recovery room and the widening of the room to recover the longwall shields. The results show that the yielding of the panel fender produced uncontrollable convergence that caused yielding of the shields and stiff pumpable roof supports when the face was approximately 10 ft from the recovery room. The shields continued to yield until the face advanced into the recovery room. Convergence in the pre-driven recovery room typically reached 6-8 in once the pumpable supports yielded and shed load through a declining residual load capacity prior to being cut out by the longwall shearer. Roof deformations occurred beyond the 32-ft horizon with total deformation ranging from 2 to 4 in, indicating that standing support was necessary to help control the span as the longwall face advanced into the pre-driven recovery room. Stability improved as the pumpable supports were cut out, thereby reducing the span between the shields and the outby pillars. In the end, the shields were successfully recovered under stable ground conditions. However, a disconcerting discovery was the load shedding of the outby pillars as the recovery room was mined into. It is postulated that this may be due to the progression of the rear “abutment” moving toward the recovery room as the panel fender and standing support in the recovery room yield and shed load. This behavior was not expected with a relatively narrow room that is fully supported with standing support. If this mechanism is indeed occurring, the width of the room and performance of the standing support becomes even more critical. Premature failure of the support can lead to excessive convergence on the shield line that cannot be controlled even with modern shields, resulting in roof instabilities that can lead to catastrophic results.