Search Documents

By Chiharu Tokoro

Acid Mine Drainage (AMD), high acid water containing heavy metals discharged from mines, has been recognized as major cause of mine pollution. In Japan, the government spends billions of yen every year to prevent pollution caused by AMD in about 80 abandoned mines. It is widely recognized that the treatment could continue for long decades or an even century. However, costs and environmental loads are uncertain during the treatment because a predictive model for the quality of AMD, the dosage of neutralizer, and the amount of sludge that is applicable for abandoned mines with limited data has not yet been established. In this study, a two-steps predictive model for solution composition and neutralization chemical requirements of AMD in future was constructed based on the geochemical modeling. Requisite input data of the model was the past historical water quality data from AMD monitoring, such as metal concentration and pH in the solution, instead of the sample rocks as other conventional prediction methods. In the first step, solution composition of AMD in the future was extrapolated from the available historical data using geochemical simulation considering the first order kinetics for the mineral dissolution. In the second step, neutralizer dosage and sludge generation in the future was predicted based on the geochemical simulation supposing the chemical equilibrium and oxidation state for all of elements in the solution. Based on case studies of two abandoned mines in Japan, solution composition, neutralizer dosage and sludge generation were estimated. The results of this study demonstrate the effectiveness of our model for the prediction of AMD quality and chemical requirements of neutralization treatment after mine closing. The model is useful for the estimation of the neutralizer dosage and the sludge volume in abandoned mines with limited data. Keywords: acid mine drainage, predictive model, geochemical modeling, first order kinetics, water monitoring

Sep 1, 2012

By Nicholas Chlumecky

One of the oldest mine supports in use today is timber cribbing. In many mining operations material, installation and maintenance costs for timber cribbings are substantial. Their performance characteristics also add to mining costs. During the 1970'6, the U.S. Bureau of Mines recognized many of the deficiencies of timber cribbing and very successfully initiated the development of steel-fiber- reinforced (SFR) concrete blocks. Since the early 1980's this SFR concrete cribbing has been manufactured as a high quality product which has found increasing acceptance by mine operators. The rapid acceptance of the SFR concrete block cribbing has proven that its use is eliminating many of the deficiencies of timber cribbing while providing superior load carrying capability. The use of SPR concrete blocks to build the cribbing is based on the same principle as wood. That is, stacking longitudinal, rectangular blocks in layers in a crisscross manner. The blocks are positioned at right angles to the blocks of the layer below. With this situation, the possibility of misalignment exists when the concrete blocks at the base are not placed exactly parallel or when the blocks of the base are subject to unequal settlement. Such misalignments creates localized, high stress areas which reduces the load capacity of the cribbing made from SFR concrete blocks. Recognizing the problem of misalignment, the Underground Supports Division of Commercial Shearing, Inc., conceived a circular, one-piece, steel-fiber-reinforced concrete cribbing which is being marketed under the name - Donut Cribbing. This concept eliminates the possibility of misalignment and provides 100% bearing between layers of stacked cribbing as well as other advantages. The purpose of this paper is to discuss the performance characteristics, installation speed and economical factors of each of the three cribbing types -- timber cribbing, SFR concrete block cribbing and SFR concrete Donut Cribbing.

Jan 1, 1986

By A. S. Hall

Significant pyrite often does not dissolve in the Sobek (1978) nitric acid extraction; therefore, the standard conservative approach is to estimate pyrite using sulfur present in the sum of the nitric acid and residual sulfur fractions. Alunite, when present, appears as residual sulfur. Because alunite does not generate acidic effluents, overestimation of AGP can occur if all residual sulfur is assumed to be undigested pyrite. Evaluation of 16 samples from the Florida Canyon Mine revealed that petrographic examination coupled with a modification of the Sobek method to include a 6 hour hot (250°F) 'nitric acid extraction resulted in a more accurate estimation of AGP.

Jan 1, 1999

By L C. Taylor

Both the U. S. Navy and the U. S. Army are interested in knowing more about the loading applied to vehicles which are unfortunate enough to encounter a detonation of a buried mine in the course of performing their normal duties. The Dynamic Effects Laboratory at the University of Maryland has been involved in small scale testing for ten years to assist the Navy and the Army in understanding the loads that are applied to personnel carriers when a buried explosive detonates beneath them. This paper describes results from small scale tests conducted to determine the loading mechanisms on target plates when subjected to loading due to the detonation of a buried mine in saturated sand, dry sand, and water. Transparent target plates were utilized in order to determine the loading process beneath a floor board on armored vehicles. Various charge sizes were scaled in the laboratory accordingly to a standardized full size threat encountered in the battlefield. Tests were conducted in saturated sand, dry sand, and water keeping the stand-off distance of the target and the depth of burial of the charge constant. In the case of water impacting a transparent PMMA plate the crack propagation was recorded and the crack velocity is determined. Additional tests were performed in saturated sand by varying the stand-off distance of the target but keeping the depth of burial of the charge constant. The small-scale test results could be scaled to full scale by using verified scaling laws.

Jan 1, 2016

By M. Giralico

Optimized mixer settler designs will now handle flows of over 25,000 GPM. The size and expense of the equipment hamper experimental settler optimization efforts. Computational Fluid Dynamics (CFD) is a timely and predictable tool for settler design development. In the past, CFD has been used to evaluate only the flow field in pumped and auxiliary tanks. A similar numerical analysis is used to evaluate settler flow and phase separation. Phase separation is analyzed using multiple species for the aqueous and organic phase. Experimental validation shows good agreement between the computational and experimental solutions in both flow field and phase separation. The computational model is used to show performance differences between various choices of settler geometry, liquid depth, with variable flow rates. Understanding the differences allows the development of optimized settler designs. System improvements are predicted to lower entrainment levels further and/or allow new smaller footprint designs. This paper focuses on the major design components of the settler and how future technological advances will lead to further improvements in their design. LIGHTNIN?s new designs will handle tomorrow?s production requirements, while maximizing profits.

Jan 1, 2003

By M. A. Giralico

Solvent Extraction (SX) technology has undergone significant refinements including outright process changes to achieve greater copper production rates with lower organic entrainment levels. LIGHTNIN has completed a detailed study aimed at improving on the conventional Holmes & Narver and Davy Power Gas type impeller designs1 by optimizing the mixing through the use of high efficiency pumper turbines instead of making system changes as others are doing. Since each individual installation requires a different design head and flow, LIGHTNIN has developed the R320 "family" of high efficiency, curved blade pumper turbines. These impellers are designed to maximize head and flow while reducing entrainment through lower power consumption, less shear generation and turbulence, elimination of air incorporation, production of the optimum droplet distribution, and lower tip speeds. These improvements also maintain the required mass transfer and copper recovery of the traditional impeller designs. The R320 impeller benefits have been quantified using Laser Doppler Velocimetry (LDV) and proven in multiple domestic and foreign installations at flow rates exceeding 15,000 GPM. Design comparisons of this improved impeller type versus traditional technology impellers in head, flow, power and entrainment are presented for review. In addition, the inherent benefits of axial flow, high efficiency impellers like the A3 1 0 and A6000 in auxiliary mix chambers will be discussed. The high flow, low shear characteristics of these patented impellers provide the necessary dispersion stability for mass transfer while speeding phase disengagement in the settlers due to low power and low shear input.

Jan 1, 1995

By G. Kugler, M. Tercelj

"The use of the up-to date light alloys and their development are in the sharp ascent especially in transportation industry. In the last years the use of the magnesium alloys for the various purposes was strongly increased. The aim of present research was to study the influence of solidification rate on hot workability and on obtained mechanical properties of AM60 magnesium alloy. The study was also focused on possibility to omit prior homogenisation process which would result in cost reduction. The solidification of gravity cast alloy has been investigated with various methods of the thermal analysis: in situ simple thermal analysis and simultaneous thermal analysis. In order to reveal optimal hot working conditions the deformation behaviour was studied in the temperature range 200-450°C and strain rates between 0.001-lOs-1. Mechanical properties have been studied with tensile and impact toughness testing.IntroductionIn recent years, the increased demand for magnesium alloys has been mainly driven by the need of automotive and transportation industry to reduce the weight, as this is the most important parameter to reduce the energy consumption. Beside their very low weight in comparison to other metals, the magnesium alloys are characterized by good machinability, corrosion resistance and good mechanical properties, and can thus compete with aluminium alloys and for some applications even with steels. Due their decreased workabilty they are typically used as cast alloys, but in recent years also the research of their wrought state has become more extensive [1-7]. Decreased hot workability of magnesium alloys originates from their hexagonal close-packed structure. One of the most popular magnesium alloys with great potential for many applications is AM60 (MgA16Mn), which is predominately used for casting. But its application could be increased if the mechanical properties, could be improved. This can be done by hot working. Namely it is well known that wrought microstructure is characterized by better mechanical properties in comparison to as-cast state. On the other hand due to its low hot workability the homogenization process is required prior hot deformation, which results in increased production costs. Thus the aim of the present research was to study the influence of solidification rate on hot workability of AM60 alloy in order to improve its mechanical properties and to check the possibility of producing near-net-shape casting products omitting homogenisation process by employing small additional deformations after casting. Within the framework of this research the solidification of gravity cast AM60 alloy has been investigated with various methods of the thermal analysis."

Jan 1, 2011

By R. Padilla, M. C. Ruiz

Arsenic, antimony and bismuth are commonly found in copper concentrates usually as the minerals enargite, stibnite and bismuthinite, respectively. Concentrates having high levels of arsenic and antimony must be pretreated before smelting. Roasting is the preferred method for removing these toxic impurities from concentrates; However, the removal of As, Sb and Bi in oxidizing roasting by volatilization may not be complete due to the slow reaction rates at 500- 700 °C. Oxidizing/volatilization data were obtained from pure mineral mixtures and from arsenic rich copper concentrate. The reaction mechanism for the volatilization of arsenic and antimony were discussed. Near 100% As and over 95% Sb volatilized in the oxidation of a mixture of pure minerals at 700 °C, 1% oxygen, while over 95% As, and 35% Sb volatilized at 600 °C in 1% oxygen atmosphere when using a copper concentrate containing 3.51% As, 0.14% Sb, and 0.01% Bi. Bismuth did not volatilize.

Jan 1, 2015

By A. Alfantazi, L. Choudhary

Gold leaching in thiosulfate solution has attracted widespread research interest through the last two decades primarily due to its perceived environmental benefits in comparison to the conventional gold cyanidation technique. However, the data on the corrosion and/or corrosion-induced failures of plant infrastructure materials in the solutions relevant to thiosulfate gold leaching are very limited. Accordingly, this study aims to characterize the electrochemical corrosion behavior of stainless steel 316L in the thiosulfate gold leaching solutions. Electrochemical corrosion response was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy. The morphology of corroded specimens was analyzed using scanning electron microscopy.

Jan 1, 2014

By M. A. Selim, W. H. Somerton

Thermal expansions and heats of reaction of three typical sandstones were measured in the temperature range of 25°to 1,000°C. The significance of these data in subsurface heat-transfer calculations is discussed. Linear thermal expansions were measured both parallel and perpendicular to the bedding planes. Volume expansions are reported as the perpendicular expansion plus two times the parallel expansion. Expansion behavior of the sandstones was found to be controlled by the expansion characteristics of the quartz content. Differential expansion of the quartz grains and other minerals included in the sandstones caused permanent deformation of the heated samples after they were cooled to room temperature. Structural damage resulting from heating is probably an important cause of the reduction of thermal conductivity of heated samples. Measurements of heats of reaction were based on the known heat required for a- quartz inversion. Thermal reactions, which probably include deby-droxylation of clay minerals and decomposition of carbonate minerals contained within the samples, were found to require more than one-fourth of the amount of heat necessary to raise the temperature of the rock alone. In shales and limestones, the reaction heat could be substantially greater than that required from specific heat considerations alone. INTRODUCTION In earlier work, l-3 methods of measuring thermal properties were developed and thermal data for several sedimentary-rock types were reported. Data included thermal conductivity, specific heat and thermal diffusivity. In addition, calculations of heat transfer in subsurface formations may require data on the thermal-expansion characteristics of rock and the heats of reaction of mineral constituents. Thermal expansion of rocks is relatively small in magnitucle and, from the standpoint of change in bulk density, has only minor effects on heat-transfer cliaracteristics. Thermal-expansion behavior, however, may have significant effects on the structure of rocks. Differential expansion of different minerals and along different crystal-lographic axes may result in structural damage which could effectively reduce the thermal conductivity of the rock. Many mineral constituents of sedimentary rocks undergo phase or related changes when heated to sufficiently high temperatures. Although some of these reactions (such as the a-ß quartz inversion) are reversible and the heat absorbed is returned to the system upon cooling, many of the major reactions are irreversible. Through certain temperature ranges, the additional heat energy required to complete the reactions may be nearly as great as that necessary to raise the temperature of the rock in the absence of thermal reactions. If the heat requirements for these reactions are not considered, serious errors in heat-transfer calculations may result. Thermal-tzxpansion and thermal-reaction data have been obtained for three typical sandstones. Methods of measurement and results obtained are reported and discussed in the following. THERMAL EXPANSION OF SANDSTONES The linear expansions of three outcrop sandstones (Bandera, Berea and Boise) have been measured in the temptbratue range of 25° to 1,000° C. Expansion measurements were made in the directions parallel and perpendicular to the bedding. The differential expansion apparatus used is that described by Mitoff and Pask.4 The test sample is heated in an electric furnace with a temperature rise of 6°C/minute. The lengthening of the samples upon heating is compared with the small and known expansion of a fused silica rod. The change in length is transmitted to an X-Y recorder by means of a Statham transducer. A maximum error of ± 1.5 per cent has been obtained with this apparatus

By Christof Metzger

This paper discusses the process utilized by the Kiewit?Bilfiger Berger Joint Venture (Contractor) to select, design, and procure the largest mixshield tunnel boring machine (TBM) ever implemented in North America. The mixshield will excavate the 8,534 linear m × 6.7 m ID (28,000 linear ft × 22 ft ID) tunnel for the City of Portland Oregon?s, Bureau of Environmental Services (Owner) East Side CSO Tunnel Project. TBM selection was conducted under a preconstruction contract in which the Contractor, Owner, Construction Management Consultant and Designer collaborated on TBM selection prior to commencement of construction. This paper focuses on TBM design considerations, including the use of one versus two machines, machine configuration,extended-wear protection, hyperbaric interventions, boulder digestion, and erection of a steel-fiber-reinforced segmental lining

By V. Lessels, D. J. Buckwalter, D. H. Rose

At White Pine Copper Co.'s operation in the Upper Peninsula of Michigan, the company has been losing more than four lbs of copper in each ton of sand tailings. With an average rate of 12,000 tpd of sand going to the tailing pond daily, the company has been losing more than 14 million lbs of the red metal annually. With an eye aimed toward lessening this loss, White Pine engineers in 1959 initiated a study on techniques for recovering this "lost" copper from the sands. Inasmuch as the flotation operation was considered to be optimized, a logical approach seemed to be leaching. For various reasons ammonia, ferric chloride, acid, and biological leaching were ruled out as impracticable. This led to a consideration of cyanide leaching as practiced in the precious metals industry.

Jan 8, 1967

By AIME AIME

FRANK T. SISCO is a native of Lawrence, Kansas. He received his earlier education in Clinton, Iowa and his university training at the University of Illinois. His experience in the steel industry has included service in the chemical, testing, and metallurgical departments of the Illinois Steel Co., of South Chicago; the Hess Steel Corp., of Baltimore; the IJ. S. Naval Ordnance Plant at Charleston, W. Va.; and the American Steel and Wire Co., Waukegan, Ill. He severed for seven years as chief of the metallurgical laboratories of the U. S. Army Air Corps at Wright Field, Dayton, before coming to New York in 1930 to become metallurgist and editor of the Alloys of Iron Research, the position he now holds.

Jan 1, 1940

By Bernard L. Cohen

INTRODUCTION The most serious occupational radiation episode in U.S. history was the exposure of uranium miners to radon daughters in the 1945-1968 time period. Although the maximum permissible dose at that time was 12 WLM (working level months) per year, average exposures were several times that figure, and ten times higher exposures were not uncommon. Starting in the early 1960s, mounting epidemiological evidence appeared for an excess incidence of lung cancer among these miners; up to 1974, there was an excess of 134 cases (159 observed vs 25 expected) among the 4000 in the group under study (NAS-1980). When this excess became apparent, the Federal Government took jurisdiction, greatly tightened enforcement, and in 1969 lowered the maximum permissible exposure to 4 WLM per year. These standards were met largely by a great improvement in ventilation. As a result of these measures, average miner exposures were reduced 5-fold from 1965 to 1968 and by another factor of 3 by 1970. In 1978, the 4 WLM/year maximum permissible exposure was exceeded by only 37 of 7500 underground miners, for only 16 wars it exceeded by more than 25%, and for only 8 was it exceeded by 502 (AIF-1980). The average exposures to the various groups are listed in Table 1. We see that the average exposure for all miners was 1.03 WLM, and for those who worked essentially full time underground it was 1.45 WLM. For purpose of later discussion, it will be convenient to choose a single value for average exposures. In view of the fact that employment situations and job categories are bound to vary over a lifetime of work, we take this to be 1.3 WLM/year. The purpose of this paper is not to dwell on history, but rather to address the question of whether or not this present situation is satisfactory. This question was considered recently by a study group under the auspices of National Institue of Occupational Safety and Health (NIOSH-1980) and it answered the question in the negative, concluding that the maximum permissible exposure should be substantially reduced. However, their arguments were incomplete and were lacking in perspective. The principal thrust of this paper is to provide some of the material overlooked. RISK TO URANIUM MINERS FROM RADON EXPOSURE In order to quantify the risk to uranium miners under present working conditions, it is first necessary to estimate the risk of lung cancer per WLM of exposure. The most straightforward way of doing this is to use the data on the group of uranium miners under study. These are listed in Table 2 for 8 exposure ranges and for the total group (NAS-1980). If all data are given equal weight, the risk is seen to be 3.5 x 10-6 per year per WLM. Much can be said in favor of using this value for the risk as dose independent; it is within one standard deviation (SD) of the observations in 5 of the 8 dose categories (as expected from the definition of SD), and within 2 SD for all 8, and for the three cases differing from the mean by more than one SD, two are above and one is below. However, the uranium miner exposures in the present situation will be far below those covered in Table 2, so it is worth considering the possibility that the risk differs from this at low doses. From the last column of Table 2 we see that the experience from all exposures below 600 WLM indicates a risk higher than the mean for the entire group by more than two standard deviations (the value 600 WLM in this comparison was deliberately chosen to maximize this deviation; for exposures below 360 WLM and 840 WLM, the excess is only 1.0 and 1.6 standard deviations respectively). In view of this tendency for the risk to be higher at lower dose, we will take the risk to be 5.0 x 10-6 per year per WLM in what we will refer to as model A. This risk estimate is based entirely on exposures much [higher] than those that will be experienced by

Jan 1, 1981

By Jonathan Duncan, Tim Burgess, William Kendall, Jens Lange

"Steel wire mesh is the accepted standard for roof and rib skin control at most coal mines in the United States. Wire mesh is delivered to the mine in bundles that are heavy and awkward to handle. The large size, stiffness, and weight of the wire mesh can present a safety hazard in transporting underground and storing on the roof bolter. Installing wire mesh on the roof and ribs with the roof bolter can be a challenge as well.Synthetic mesh is lighter than wire mesh and can be folded and rolled into a safe, manageable size. A single synthetic mesh roll large enough to cover the roof and ribs in a deep cut can be safely handled by two men. The roof bolter is designed to carry and dispense the roll as it advances and installs primary roof support, resulting in a single pass roof and rib ground control solution. This paper focuses on the design and implementation of the roof bolter synthetic mesh handling system developed by J. H. Fletcher & Co., Huesker, Inc., and Oxbow Mining.INTRODUCTIONRoof and rib skin control in some coal mines has been an issue since mining first began. Roof and rib skin problems vary from mine to mine. The type of roof rock material exposed after mining; the mine atmosphere; and stresses from depth of cover, over mining, and/or undermining are some of the variables that can contribute to roof skin problems from mine to mine.Potential roof and rib skin problems can be time dependent as well. Some mines have roof skin rock, sometimes called draw rock, that falls when drilling the hole for the roof bolt as the initial roof support is installed. Some roof skins are more stable but can fail over time. The failure of roof skin can even be between properly installed roof bolts with roof plates (Figure 1).Mines have most commonly used a wire mesh that comes in individual panels anywhere from 5 ft x 5 ft (1.5 m x 1.5 m) all the way up to 5 ft x 16 ft (1.5 m x 4.9 m) in size. They are typically constructed of 8- or 9-gauge wire welded on a 4 in (102 mm) square pattern. A 5 ft x 16 ft (1.5 m x 4.9 m) panel weighs approximately 35 lbs (16 kg). These steel wire mesh panels can make it a difficult and sometimes dangerous task to deliver them from the surface to the roof bolter and then store on the machine. Manipulating the mesh panels from the storage area on the machine to the final installation position on the roof or rib can also be a daunting task (Figure 2)."

Jan 1, 2010

By O. C. Blade

A summary of the characteristics of motor gasoline for the summer 1951 is presented in table 1, and for comparison, a similar summary for the summer 1950 is shown in table 2. Trends of some of the more important characteristics over a period of years are shown in figures 1 and 2. As indicated, octane numbers of motor gasolines sold in the United states decreased approximately one-half to one octane unit from the record levels attained during the winter of 1950-51 and are a little below the octane numbers of summer 1950. However, average vapor pressures of the summer gasolines did not change, and certain distillation temperatures varied only slightly from those of the year before.

Jan 1, 1952

By G. A. Moore

A brief review is given of methods designed to produce metallic iron of high purity, and typical results are listed. A recent method, utilized at the National Bureau of Standards, consists of the extraction of ferric chloride by ether, reduction of this ferric chloride to ferrous chloride, further purification of this chloride, and the subsequent electrolytic deposition of metallic iron. iron produced by this procedure apparently is softer than, and otherwise different in properties from, any iron previously prepared and contains appreciably smaller amounts of impurities. THE history of attempts to produce "pure" iron reaches to antiquity and it may be presumed that each ancient armorer who succeeded in making a better steel concluded, correctly, that he had done a better job of removing the "base metals," and incorrectly, that he now at last had a "pure" metal. Early metallurgical papers mentioned use of "pure iron" in making alloys—this "pure" iron in most cases being inferior to some commercial stocks of the present time. Improvement has been continuous, and usually at a sufficient rate to convince each succeeding group of workers that they, at last, were using the really pure metal (until the analysts also improved their techniques to again discover the impurities). These adventures were reviewed in some detail by Cleaves and Thompson.' Although the ores of a metal may be abundant, difficulties in extracting it may make the pure metal very rare. When impurities are restricted to a total of a few parts per million, nearly all pure metals become rarities. Lead, copper, gold, mercury, silver, zinc, aluminum, bismuth, and the six platinum metals are claimed to be available with total impurities ranging from 2 to 50 ppm. The present small and scattered world supply of so-called "pure" iron holds an unimpressive place in another group of 16 metals having approximately 100 ppm of foreign material. Of about 20 less rare metals, only the platinum metals are more costly to prepare. While the production of such rare varieties of iron may appear insignificant in the presence of thousand-ton operations with 95 to 99 pct metal, it must be emphasized that all researches on commercially interesting irons and steels are in fact studies of the modifications of the properties of iron by additional materials. Until the properties of high purity iron are directly measured, all ferrous research must operate without known base values. Traces of impurities may affect the properties of a metal in many ways. Infinitesimal traces of solutes, by disturbing the electronic configuration, greatly change the electrical properties of transistors and semiconductors2-3 and slightly larger traces might alter these quantities in iron. Soluble impurities which disturb the perfection of lattice arrangement not only may alter the magnetic constants and electric properties, but by their close association with dislocation phenomena probably control the very existence of the "yield point"; determine the value of yield stress; and perhaps control the selection of slip and cleavage planes. It has been speculated that impurities might even cause the allotropic transformation in iron, but in any case their rearrangement must contribute to the unreliability of heat capacity and other thermodynamic measurements. Impurities which do not remain in solution may cause even greater effects on the properties. Microscopically visible amounts of phases other than ferrite can be found in all high purity irons which have come to my attention. It can be calculated that from 50 to as little as 2 ppm of an insoluble material might be sufficient to completely film all grain boundaries in irons having grain sizes from ASTM Nos. 10 to 1. Should this occur, such films, even though invisible, may be very important in fracture problems, especially at extremes of temperature:' Studies of grain growth and diffusion normally imply consideration of a single-phase system, hence, in the presence of insoluble impurities they can be expected to give ambiguous data." High purity iron is also in demand for use as chemical and spectro-chemical standards; for work in classifying the lines of the iron spectrum; for biological work in nutrition; and for work in nuclear physics. where the presence of some sensitive

Jan 1, 1954

By C. E. Barnett, G. R. Durland

LUMINESCENT materials have been used in an increasing variety of ways in recent years. Such uses range from the screens on which the picture or image is presented in television and other cathode ray tubes to fluorescent lamps, fluorescent effects in decorative, theatrical, and display lighting, and the many applications of phosphorescence in paints, textiles, paper, and plastics. During the war the screens for a radar set or the "night-seeing" devices were not fundamentally different from those in other cathode ray tubes, but nevertheless they presented special problems for the phosphor manufacturer. It was essential that the "pips" on a radar screen continue to glow after the exciting beam had swept on, but this afterglow would be ruinous to a television screen. In the image tube used for seeing at night with infrared instead of visible light, electrons emitted by an infrared-sensitive receiving surface were amplified and converted to visible light after striking a fluorescent screen. The small size of the screen caused special problems in reducing the grain size of the phosphor to obtain adequate resolution. Other devices used phosphor surfaces which could be stimulated directly by infrared radiation to emit visible light. Energy was stored in the phosphors by prior excitation with short-wave-length radiation, and the stored energy released on subsequent exposure to infrared radiation. Maps, navigational charts, bombing manuals, and computers of various sorts were printed on fluorescent paper or lettered with fluorescent inks. Fluorescent markings excited by small ultraviolet lamps were used on airplane instrument dials. A large amount of research was done to determine the best color for the emitted light and other properties for the fluorescent materials, and on the best methods for their fabrication into the items listed above. Phosphorescent materials found wide use during blackout restrictions to mark safe passageways, to delineate traffic hazards, to identify packages, and to mark tools and other items of equipment.

Jan 1, 1948

By Hazal Melis Aytac, Lana Alagha, Fardis Nakhaei

Gallium (Ga) and Germanium (Ge) are essential strategic elements that are extensively used as semiconductors in many technological fields. Owing to their essential uses and supply disruption, Ga and Ge are deemed critical by the U.S. They are typically found as substitutions or inclusions in zinc minerals. However, their distributions within zinc minerals are not well understood. To address this, trace element and mineralogy analyses of representative samples obtained from an old high-zinc-grade tailing were performed using various qualitative and quantitative techniques. These techniques included Inductively Coupled Plasma Mass Spectrometry (ICP-MS), Tescan Integrated Mineralogical Analysis (TIMA) with Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Moreover, bench-scale froth flotation tests were conducted to enrich zinc minerals, the major hosts of Ga and Ge, using PAX as a collector, Na2S as a sulfidizer, Pb(NO3)2 as an activator, and MIBC as a frother. Comprehensive characterization analyses of the flotation products showed significant enrichment of Zn, Ga and Ge in the flotation concentrates.

Feb 1, 2025

By Shengli Wu, Mingyin Kou, Feng Chang, Laixin Wang, Hua Lu, Jianliang Zhang

Sintering dust has been regarded as an important secondary resource in a modern steel plant. Sintering dust was mechanically treated using different milling machines and experimental conditions in air atmosphere. The changes in phase constitution, particle size, specific surface area, particle morphology, and lattice parameters of activated sintering dust were determined. It was found that the agglomeration of the particles take place during extended dry milling with accessible pores for Nitrogen gas. The maximum specific BET surface area in the stirring wet grinding and planetary wet grinding increases to 43.06 and 46.45 m2/g after activated 360 min respectively. With the increasing of energy input, the intensity of diffraction peaks of dolomite and hematite gradually decreased. Furthermore, the previous phase almost disappeared eventually under any experimental conditions. In addition, Fourier transform infrared spectroscopy indicates that organic matter and carbonate decompose easier than other phases, especially under stirring wet milling.

Jan 1, 2016