Search Documents

By T. B. Beeton

In view of the limited reserves of good-quality coking coals in South Africa, Iscor has been involved in direct reduction since the middle sixties. Since the early seventies, its interest in direct reduction was stimulated further by a swing towards' continuous casting, which, in turn, contributed to a shortage of the scrap supply for electric-arc-furnace (EAP) steelmaking. Rock engineering The First International Conference-Rock Enginet:ring and Excavation in an Urban Environmentorganized by The Institution of Mining and Metallurgy and the Hong Kong Section of the Institution, in association with the Hong Kong Institution of Engineers, will be held in Hong Kong from 23rd to 28th February, 1986. SPOTLIGHT on Gold Fields National Engineering Awards For the Gold Fields Foundation National Engineering Awards, each university affiliated to the South African Federation of University Engineering Students (S.A.F.U.E.S.) selected a candidate who, in their opinion, presented the most outstanding design project in their final year during 1984.

Jan 1, 1985

By J. R. Thoenen

In the summer of 1937 the authors began a series of time studies of the various processes employed in the production of crushed stone. These studies, made at quarries scattered over the eastern and southeastern parts of the United States, have not been completed, but to make results available to thee industry as early as possible it was decided to publish summaries of the studies made to January 1, 1939, as a series of progress reports. The first of these reports dealt with power-shovel loading and was issued as Report of Investigations 3461 in September 1939. The present circular discusses analyses of the time Studies of the haulage systems at the same quarries. OBJECT OF STUDY The pressure of business problems frequently requires the entire attention of quarry management and in consequence internal plant economies often are neglected, Also, operating officials absorbed in their local problems are prone to overlook possible economies that would attract attention immediately were they critically examining another plant. The authors felt that similar studies of many plants by impartial engineers -would disclose possibilities for cost reduction or greater efficiency in internal plant processes.

Jan 1, 1939

By A. Sutherland Strachan

Before regulations governing the work on the mines, it was not uncommon in the Rand for a miner to die within a period of 2-3 years as the result of exposure to dust. This paper considers mine and tunnel conditions promoting silicosis and measures to avoid dust exposure in the Rand, South Africa.The relationship between blasting and lung lesions is explored. Evidence is presented that improved working conditions and lowered dust levels reduce the incidence of silicosis.

Jan 1, 1947

By S. F. Frederick, W. A. Bailey

The relationship between microstructure and mechanical properties of cast 356-type aluminum alloys was studied to determine the cause of the variations in properties resulting from differences in solidification rate. It was found that variations in strength are a consequence of variations in ductility and that ductility is inversely proportional to the dendrite cell size. A mechanism is proposed to account for this correlation based on the fracture strain of the inter-dendritic silicon particles and the differential strain across dendrite cell boundaries. IT has long been assumed that permanent mold castings of aluminum are superior to sand castings because of their finer grain structure and reduced porosity.' A systematic variation of static properties was noted during unpublished studies of fatigue-strength variations with solidification rate of A356-T6. Of particular interest was the observation that for a given composition and heat-treatment, both ductility and the ultimate strength increased with higher solidification rate. Because the A1-Si system forms the basis of many alloys used for castings and welding wire, a study was initiated to determine the details of how higher cooling rates improved mechanical properties of these alloys. The results of this study are presented here. EXPERIMENTAL PROCEDURE Specimens were prepared from 356-T6 to supplement the A365-T6 alloy data from earlier studies. This allowed a comparison of behavior of alloys with substantially different strengths but with only small differences in alloy composition. The composition and heat treatment of both alloys are given in Table I. The specimens were cut from a chill plate casting,' which is a 6 by 9-in. plate, 1 in. thick, which has one end heavily chilled, and a large riser at the other so that solidification is essentially unidirectional from the chill end to the riser. Although not measured here, solidification times measured on similar specimens by embedded thermocouples are a few seconds at the chill end and up to 5 min near the riser. Specimens were obtained by cutting slabs from the plate, parallel to the chill; these represented different cooling rates, with essentially the same composition. For the tests, either 0.125 or 0.250-in. thick slabs were cut for standard 2-in. gage length specimens. The thicker specimens were tested to failure at 2000 lb per min while the thinner specimens were tested in an Instron machine at a constant cross-head speed of 0.02 in. per min. These thin specimens were intended for trans- mission electron microscopy. Some thin specimens were tested to failure while the remainder were given various amounts of prestrain. Dendrite cell sizes were measured by the linear intercept method on photomicrographs at either X100 or X50, depending on the cell size. It was assumed that the dendrite cells were outlined by the silicon particles. Determinations were made on two mutually perpendicular planes and an rms average taken. Electron fractographs of representative tensile specimens were made in the conventional manner using the two-stage replica technique.3 Samples for transmission electron microscopy were prepared by chemical milling followed by electropolishing. RESULTS AND DISCUSSION The results of the tensile tests and the dendrite cell-size determinations are given in Figs. 1 and 2. All data show the same trends, namely, a decrease in ultimate strength and elongation with increasing distance from the chill (and solidification time), and a corresponding increase in dendrite cell size. The yield strength remains essentially constant. The constancy of the yield strength was particularly significant since it indicated that variation in the solidification rate does not affect the stress required to initiate plastic flow. By plotting true stress-true strain curves as in Fig. 3, it can be seen that both

Jan 1, 1969

By Stanley M. Moos

The Pueblo Viejo gold/silver mine, located in the Dominican Republic, started production in early 1974 processing ores averaging 4 g/tonne gold and 20 g/tonne silver at a rate of 7,250 tonnes/day. The ore milled is a silicified siltstone with average work index of about 8 that occurs as an extensive oxide capping of a primary sulfide orebody. The sulfide ores are refractory to conventional treatment process and extensive research work is now in progress to develop a treatment process for them. The ore deposit has a long history having been mined by the indigenous Arawak Indians (for some time in the early sixteenth century) prior to the arrival of the Spanish and then by the Spaniards. In the early 1950?s, Italian engineers attempted to process the sulfide ores. Mining by the Indians and Spanish was abandoned because of low grade and little coarse gold in the oxide ores and by the Italians because of the refractory nature of the sulfide ore. In 1969, Rosario Resources geologists discovered that there existed sufficient reserves of oxide ore for a viable mining operation and accordingly, the plant was designed, built and brought into production.

Jan 1, 1979

By F. M. Vokes, P. M. Ihlen

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Ore deposition was related to three major stages: continental rifting and separation (Vendian-Late Cambrian), convergence (Late Cambrian-Early Silurian) and collision (Early Silurian-Devonian). The first stage included deposition of volcanogenic massive sulphide Zn-Cu and stratabound or stratiform Fe and Zn-Pb(-Cu) on continental margins, as well as less economic Nb and Fe in carbonatites, U, Mo, Ni and V in Alum Shales and orthomagmatic Cr, Fe-Ti and Ni(-Cu). The numerous volcanogenic massive sulphides formed during convergence included Early Ordovician Cu-Zn, mature-arc Cu, Zn, Pb and Fe-oxide deposits, Besshi-type deposits dominated by Cu or Zn in gabbro-intruded sediments and minor Cu-Ni(-PGE), Cu-Mo and skarn deposits. The collisional stage is represented by epigenetic deposits including sandstone Pb deposits (Pb, Zn, Ba, F and Cu) and minor vein deposits with variable Au, Ag, Pb, Cu, Zn, Fe, As, Sb, W and Mo

Jun 19, 1905

By L. P. Weber

During the years 1983-1987, a research programme, jointly performed by the steel producers ARBED, British Steel Corporation, Peine-Salzgitter, Unimetal, and co-sponsored by the European Community for Steel and Coal (ECSC), has been carried out on steel H-piles of different shapes. The initial aim of the testing programme has been the improvement of bearing capacity, both in sandy and clayey soils. At two test sites, standard H-beams are compared to H-piles with different types of laggings or to H-piles grouted both under low and high pressure. In this paper and in view of the open european market in 1992, the H-pile capacities and their corresponding allowable loads, determined from codes, recommendations and computation procedures in use in Belgium/Luxembourg (B/L), France (F), Federal Republic of Germany (G), and the United Kingdom (UK) as well as their evaluation from dynamic CAPWAP and Case methods are compared to the static capacities measured in-situ. In addition, procedures for estimating the load/movement behaviour of H-piles from CPT, pressuremeter, and CAPWAP are compared to the measured curves.

Jan 1, 1991

By C Li, D O’Dea, R Moreno-Atanasio, T Honeyands

The behaviour of iron ore granules in the feeding process of sintering is significantly influenced by the material properties of the granulated mix. Therefore, the measurement of key material properties of the iron ore granulated mix is indispensable prior to the simulation of the sintering process based on the discrete element method (DEM). In this paper, three key property parameters of the iron ore granulated mix, apparent density, elastic modulus and rolling friction coefficient, were measured in laboratory-scale experiments. For different sintering processes, the moisture content of the granulated mix normally varies according to the specific requirements for granule size distribution and operating conditions. Therefore, understanding the effect of moisture content on the property parameters of iron ore granules is very helpful in accurately determining the property parameters for DEM simulation work. In this paper, six groups of iron ore granule samples with six levels of moisture contents were prepared through granulation and the trends in apparent density, elastic modulus and rolling friction coefficient with the increase of moisture content were plotted and analysed based on the measurement results. The results show that as moisture increases from 6.9 per cent to 9.1 per cent, the apparent density decreases from about 3000 to 2800 kg/m3. With moisture increasing within the same range, the elastic modulus first decreases from over 200 MPa to below 100 MPa and then reaches a relative constant value of about 40 MPa at higher moisture contents. Rolling friction coefficients are measured using two methods with both indicating a similar trend, with the rolling friction coefficient first decreasing and then rising as moisture increases from 6.9 per cent to 9.1 per cent. The relationship between µr and µ’r is assumed to be similar to that between static and dynamic friction coefficients.CITATION:Li, C, Moreno-Atanasio, R, O’Dea, D and Honeyands, T, 2017. Variation in property parameters of iron ore granulated mix with moisture content, in Proceedings Iron Ore 2017, pp 79–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Jeffrey L. Thompson, Kenneth A. Gutschick, Robert C. Freas, Robert S. Boynton

Lime, the "versatile chemical," is, generally speaking, a calcined or burned form of limestone commonly known as quicklime, calcium oxide or calcia, or, when water is added, calcium hydroxide or slaked lime. Almost 40 different lime products are available, a fact which has contributed to the rather loose use of the term lime as well as to much confusion and misunderstanding. The term is frequently, albeit erroneously, used to denote almost any kind of calcareous material or finely ground form of limestone or dolomite. Lime is usually made from high-calcium or high-magnesium limestone, generally having a minimum of 97% combined carbonate content. Normally, high-calcium limes contain less than 5% MgO. When the lime is produced from a high-magnesium limestone, the product is referred to as dolomitic lime. Calcination, or the production of lime, has its origins in the earliest days of alchemy, with the general reaction class having been identified in an Arabic text printed in 1000 A.D. It was much later, however, in the mid-1700s to the mid-1800s before this basic reaction became understood from a scientific perspective. The production of lime has been so basic and simple that its underlying scientific principles have over the years received only intermittent investigation. Rather, much of the thought and inquiry has been directed toward the development of kilns. Thus, it has only been in the last 15 to 20 years that lime has received any concentrated scientific investigation relative to the thermodynamics and kinetics of the calcination and hydration reactions. Calcination refers to a broad class of reactions, of which the lime/limestone reaction is just one, wherein a substance is heated to less than its melting point, resulting in a weight gain or weight loss. In the calcination of limestone to produce lime, the basic chemical reaction is as follows: [CaCO3 (limestone) + heat (1000° to 1300°C)= 100 CaO (quicklime) + CO2 T 5644 or CaCO3 • MgCO3 (limestone) 10084 + heat (900°C to 1200°C) CaO • MgO (quicklime) + 2CO2 T 56 4088] While there is nearly universal agreement about the equilibrium conditions related to the limestone/lime reaction above, there have been numerous and varied calcination models developed for the reaction. Recent investigations have resulted in the development of the model shown in Fig. 1. From this model it can be seen that calcination is a function of both temperature and CO2 pressure. It does not, however, provide any indication of the rate at which the reaction takes place. Calcination is strongly time variant with different limestones. In a very broad sense this relates to the fact that the calcination reaction starts on the exterior surface of the limestone and then proceeds toward the center. As the calcination reaction takes place, the CO2 released at the reaction interface must make its way through the lime to the exterior surface. Therefore, because calcination is limited by gas diffusion to the surface of the partially calcined limestone, natural impurities in the stone, differences in crystallinity, grain boundary chemistry, density variations, and imperfections in the atomic lattice all play a significant role in

Jan 1, 1983

By K. G. Matshika

"Nickel electroplating from sulphate electrolyte is an efficient process. To achieve good quality cathode, however, parameters such as temperature, nickel concentration, pH, electrode alignment, electrolyte flowrate and additives must be optimised, because these affect cathode morphology and current efficiency. It is also important to control the clarity and contamination of the electrolyte, as these have a considerable effect on the quality of the cathode surface. Delamination, surface roughness and pitting on the cathode surface can be caused by incorporation of solid particles or impurities form the electrolyte. Three types of solid particles were investigated: cuprous selenide, barium/ lead sulphate (co-precipitated) and ferric hydroxide. These particles can be found in industrial electrolytes, especially if there is a problem with the filtration step or contaminants have reacted to form insoluble particles. A rotating cylinder Hull cell was used for this investigation. It is found that the effects on morphology depend on the type of solid, concentration, particle size, current density and electrolyte flowrate. Cuprous selenide is the most detrimental, especially at higher concentrations, higher current densities and low flowrates. Increased rotational speed offers a uniform sheet of fine gas bubbles across the surface of the cathode which reduces the thickness of the diffusion layer of liquid adjacent to the cathode and increases the rate of mass transport to the cathode from the bulk liquid. INTRODUCTION Electrowinning operations are important when recovering associated by-products of nickel production, such as copper, cobalt and zinc, from pressure leach solutions. The base metal mineralization associated with platinum-group metal (PGM) production yields significant quantities of copper and nickel as by-products. The base metal refinery is vital in PGM processing as it increases the PGM concentration from mined ore by a factor of 400, in comparison with concentration by flotation (20 times) and pyrometallurgical processing (20 times) (Crundwell et al., 2011). Anglo American Platinum Ltd produces nickel cathodes by electrowinning and purges sodium from the base metal refinery in the form of sodium sulphate at the Rustenburg Base Metals Refinery (RBMR), as shown in Figure 1. This is the Sherritt acid leach process used in most base metal refineries to ensure no loss of PGMs and shows the subsequent purification steps for copper and nickel. Other refineries in Zimbabwe, such as Bindura and Empress, use the Outokumpu leach process (Pavlides, 2001)."

Jan 1, 2015

By Charles M. Wilk, Lori Tiefenthaler

"Information presented in this paper can be used to support deep soil mixing, subsurface grouting and slurry wall technology as sustainable construction technologies. Ordinary Portland Cement (OPC) is the default cementitious material used by Deep Foundation Institute (DFI) Members for geotechnical work. Owners, engineers and contractors can contribute to the sustainability of a geotechnical project by increasing the use blended hydraulic cements and industrial byproducts to replace some of the OPC in mix designs. Sustainability is defined as the quality of not being harmful to the environment or depleting natural resources. Production of cementitious materials consumes natural raw materials and energy while also generating air emissions and waste. Life Cycle Assessments can be used to compare the relative environmental impacts of one cementitious material to another. Blended hydraulic cements (BHCs) are interground (or blended) mixtures of Supplementary Cementitious Materials (SCMs) with OPC. Commonly used SCMs include fly ash, ground granulated blast furnace slag (GGBFS) and limestone. Examples of industrial byproducts commonly used in geotechnical work include coal combustion residuals (CCR) (aka fly ash), and ground granulated blast furnace slag (GGBFS). Much of life cycle impact of these SCMs and industrial byproducts have already been borne by the industries that generated them. There is increasing awareness to LCA and sustainability of different materials used on projects. This is evident in the application of the Leadership in Energy and Environmental Design (LEED) program. The savings in environmental impact with the use of SCMs and industrial byproducts can make proposed use of these materials in a geotechnical project more attractive in terms of sustainability. This paper presents (a) information that compares published life cycle assessment data of OPC, BHCs, and slag cement (SC) to illustrate the potential benefits to sustainability and (b) general strategies for positioning a geotechnical application, use, project design or cementitious material mix as a more sustainable alternative"

Jan 1, 2017

By R. F. Favreau, R. A. Morin, G. W. Kuzyk, P. J. Babulic, N. J. Tienkamp

"Atomic Energy of Canada Limited is constructing an Underground Research Laboratory (URL) as part of a comprehensive program to evaluate the concept of nuclear fuel waste disposal deep in crystalline rock formations. Careful blasting methods have been used to minimize damage to the excavation surfaces. Good wall quality is desirable in any excavation. In excavations required for nuclear waste disposal, the objective will be to minimize blast-induced fractures which may complicate the sealing requirements necessary to control subsequent movement of groundwater around a sealed disposal vault. The construction of the URL has provided an opportunity for the development of controlled blasting methods, especially for drilling accuracy and optimization of explosive loads in the perimeter and cushion holes. The work has been assisted by the use of blast simulations with the mathematical model Blaspa.This paper reviews the results of a recent project to develop a controlled method of full-face blasting, and compares the observed field results with the results of a blast simulator called Blaspa. Good agreement is found between the two, and the Blaspa results indicate quantitatively how the blasting may induce damage in the final excavation surface. In particular, the rock in the final wall may be stressed more severely by the cushion holes than by the perimeter holes. Bootleg of the rock between the perimeter and cushion rows occurs when the burst out velocity imparted to it by the explosive loads in the perimeter holes is inadequate. In practice, these findings indicate that quantitative rock stress and rock burst-out velocity criteria can be established to minimize wall damage and bootleg. Thus, blast simulations become an efficient way to design controlled blasting and to optimize quality of the excavation surf ace."

Jan 1, 1989

By Merle L. Bowser

An alinement (steering) sensor for continuous mining machines has been developed under a Bureau of Mines contract. A laser source in the entry projects a beam parallel to the centerline of the entry. The beam is optically shaped to a narrow, vertical fan and illuminates an array of optical sensors bunted on the mini machine. These sensors interpret the location of the beam into meter readings of heading (angle) error and lateral displacement errors. The system, which was tested for 5 months in an operating mine, appears to be fundamentally sound, and with some modification, should be applicable to remote or automatic guidance of continuous miners and other machines.

Jan 1, 1976

Results obtained from small scale tests using Australian tin concentrates indicate that metallic tin containing less than 0·1 per cent iron can be recovered by a two-stage process using hydrogen and make-up chlorine. In the first stage the concentrate is ground,. pelletized, roasted, and reacted at 650°C with HCI and H2 to volatilize the tin as SnOI2. The volatilization reaction is conducted with cocurrent gas and solids flow because it was found that the use of cocurrent flow yielded a solids residue substantially free from FeCI2. The second stage uses a technique termed "reflux reduction" during which the SnOl2 produced by volatilization is reduced by hydrogen to form tin and a gas containing HCI and H2 of sufficiently high HCI tenor for recycle to the volatilization stage. The elimination of tin ranged from 98+ to 99·7+ per cent of the tin from concentrates containing 5 to 50 per cent tin, respectively. The process should be capable of continuous operation, and a tentative calculation has shown ,that a treatment rate of 12,000 tonnes of tin concentrate per year could be obtained in a volatilization reactor 1·1 m in diameter and 6·1 m high. The process may have particular application to finely divided concentrates containing less than 20 per cent tin.

Jan 1, 1974

By J. G. Thompson

Determinations of the hydrogen content of irons and steels invariably are subject to two serious difficulties: (I) the determination of amounts of 0.001 per cent or less of any constituent requires an analytical procedure of unusual precision and accuracy, and (2) the hydrogen content of many samples is dccidedly not stable; i.e., there is no assurance that the content at the time the analysis is made is the same as it was when the sample was taken or at some previous time in the history of the piece. In respect to both the precision and speed of the determination, the vacuum-extraction procedure for the determination of hydrogen possesses advantages over the vacuum-fusion procedure, which has been the recognized standard for the detcrmination of other gaseous elements in sted-— oxygen and nitrogen for example. The basic facts upon which the vacuum-extraction procedure is based—i.e., the evolution of gas from solid steel when it is heated in vacuum, and the fact that the evolved gas is rich in hydrogen—were observed by Graham1 many years ago. Subsequent investigations have shown that hydrogen exists in steel chiefly as interstitial solid solution (i.e., in atomic dispersion) and perhaps to some extent as hydridcs that are unstable and decompose to form atomic hydrogen. In either case practically all of the hydrogen in steel at elevated temperatures exists in the atomic condition and consequently is able to diffuse readily through the metal. In contrast to this, other gaseous elements, such as oxygen and nitrogen, normally are present in steel chiefly in the form of relatively stable compounds such as oxides or silicates and nitrates; i.e., the oxygen and nitrogen atoms are fixed in stable combinations and are not free to migrate. The only oxygen or nitrogen that can diffuse in steel is the small amount in solution (atomically dispersed) and the rate of diffusion of these atoms is much less than that of hydrogen because of their greater atomic volume and lower mobility. Consequently, it is possible to extract most or all of the hydrogen from solid steel in a reasonable time at moderately elevated temperatures, but the procedure is not applicable to the determination of oxygen or nitrogen. It is only within the last decade that these observations have been developed into an analytical procedure for the determination of hydrogen. Apparatus and Procedure The apparatus used at the National Bureau of Standards,6 for the determination of hydrogen by the vacuum-extraction procedure, is shown schematically in Fig. I. The specimen, freshly cleaned and dried,* is suspended on a fine wire within the quartz furnace tube that is connected to the reservoir system and analytical train.

Jan 1, 1945

By S Jeon, K Haga, A Shibayama, L Godirilwe, C B. Tabelin, I Park, A Buronov

Open pit/underground mining and mineral processing can generate large amounts of waste that contains sulfide-type minerals such as pyrite (FeS2), and it can produce acid mine drainage (AMD) when exposed to oxygen and water. This highly acidic wastewater contains heavy metals and this is one of the most serious environmental issues after mining operations taking several decades to completely remediate with high costs. For green mining, the present study focused on the development of a recovery technique for gold from an eco-friendly solvent, thiosulfate, by utilising mine wastes, tailings. First, gold recovery experiments in ammonium thiosulfate system were carried out using model samples representatively present in tailings (ie SiO2, Al2O3, FeS2, Fe2O3, and Fe3O4). The results showed that gold recoveries were negligible when using Al2O3, SiO2, Fe2O3, and Fe3O4 while pyrite shows a recovery efficiency three-fold as high as the maximum recovery efficiency when using others. Subsequently, the study also addressed the identification of the recovery mechanisms and post-recover process. The results indicate that tailings can be sufficiently utilised for gold recovery in the hydrometallurgy process and a further sustainable process can be established.

Sep 1, 2024

By G. Cockburn

Nkomati Nickel JV exploits the ores of the Uitkomst Complex near Machadodorp in the Waterval Boven district in South Africa?s Mpumalanga Province. Due to factors such as the remote location, stellar growth in production, opencast mining methods, and ore characteristics, a number of innovative processing options were selected. Nkomati has undertaken numerous initiatives over the last few years to improve plant running times, metallurgical performance, and operational profitability. Great emphasis has been placed on effectiveness of management control systems. A number of initiatives such as short interval control and time?in-state metrics have been implemented. A focus on improvement on availability and asset utilization of key items of equipment has been particularly effective. While the ores are remarkably similar to the Merensky and UG2 reefs, the relatively high base metal sulphide content and mineralogical characteristics make metallurgical treatment somewhat different to the ores of the Bushveld Complex. The low head grades and flotation kinetics distinguish Nkomati from other base metal operations. Numerous milling and flotation optimization initiatives have resulted in dramatic improvements in throughput, recoveries, and concentrate grades. This paper discusses the metallurgical, operational, and management challenges and the outcomes obtained.

Jan 1, 2014

By H. K. Birnbaum

The effect of 1ow-temperature stabilization anneals on the structure of the 0 phase Au-Cd alloys and on the diffusionless transformations observed in these alloys was examined by X-yay diffraction techniques. A phase separation in the ß-phase region was proposed to account for the experimenta1 results. The effects of quenching from elevated temperatures on the transformation behavior of these alloys were shown to be consistent with the proposed mechanism. IT has been shown that the high-temperature ß phase (CsCl structure) of the Au-Cd alloy system transforms to a phase having an orthorhombic (D2) ß&apos; structurel1-3 for compositions near 47.5 at. pct Cd and a tetragonal (4/m, m, m) ß" structure* in the vicinity of 50.0 at. pct Cd. Both transformations are diffusionless, crystallographically reversible, and occur on cooling at about 60° and 30°C respectively. The temperature interval from the beginning to the end of the transformation is of the order of 5°C in each case. Although the transformations are normally athermal, some of them have been reported to occur isothermally.= wechsler6,7 has shown that the effects of quenching a 49.0 at. pct Cd alloy from elevated temperatures are consistent with the retention of a nonequilibrium number of lattice vacancies. Annealing of these quench effects results in a broadening of the X-ray reflections.8 After a suitable quench, the 47.5 at. pct Cd alloy transforms to a phase having not the p&apos; orthorhombic structure but another structure which has properties similar to that of the ß" tetragonal structure.5.9 This change in the type of transformation has also been obtained after long anneals in the ß-phase region at about 70oC10 The present investigation was primarily concerned with the structural changes accompanying the above transformation phenomena. The change in transformation product and accompanying physical changes during an anneal in the ß phase have been termed stabilization effects. Experimental Procedure —The results reported in this investigation were obtained with the use of a Norelco diffractometer fitted with a temperature-controlled cryostat. The specimen temperature was controlled to better than ± 0.l°C during the measurements. CrKa radiation monochromated electronically with the use of a scintillation counter and pulse height analyzer was utilized. Specimens containing 47.5 and 50.0 at. pct Cd were prepared by sintering filings obtained from homogenized ingots of the proper alloy composition. (Gold of 99.999 pct purity and cadmium of 99.98 pct purity were used). All heat treatments were carried out with the specimens capsulated in vacuum ( < 10 % mm Hg) or in a He-H gas mixture. The quenching technique used in these experiments was to drop the pyrex capsule which contained the specimen from the annealing furnace into water, the temperature of which was controlled. The pyrex capsule shattered on contacting the water resulting in a relatively rapid quench. After the heat treatment, the specimens were mounted in the diffractometer and were left undisturbed in the diffractometer specimen holder during each sequence of measurements. EXPERIMENTAL RESULTS A) Low-Temperature Annealing—The transformations which were considered "normal" for these alloys were those obtained athermally during furnace cooling at approximately 50°C per hr after an elevated temperature anneal. Under these experimental conditions, the specimens were observed to transform to phases having structures whose diffraction patterns could be indexed as the ß&apos; orthorhombic structure for the 47.5 at. pct Cd and as the 0" tetragonal structure for the 50.0 at. pct Cd alloys. The transformation temperatures on cooling were approximately 60" and 30°C, respectively. Under the "normal" conditions both transformations were observed to go to completion, i.e., the entire volume of the ß phase was transformed to the product phase. In some specimens an extremely weak ß 110 reflection was observed at 20°C indicating that a small amount of retained ß was present. The effect of low-temperature annealing on the nature of the diffusionless transformations was examined for the 47.5 and 50.0 at, pct Cd alloy. The specimens were annealed in evacuated capsules at temperatures in the vicinity of 600°C (as specified in Table I) for 24 hr and were then cooled to 100°C at a rate of 50°C per hr. The specimens were then removed from the capsules and mounted in the diffractometer without allowing the specimen temperature to drop below 80°C. Annealing at the low temperatures was accomplished in the diffractometer by means of the cryostat which was mounted around the specimen. During the low-temperature anneals the lattice parameter, integral breadth of the reflections, and ratios of the integrated intensities of the fundamental and super lattice reflections for the 0 cubic phase were periodically determined. After annealing for the required time, the specimens were slowly cooled in the diffractometer and the diffraction patterns were recorded as a function of temperature. The specimens were cooled until the phase transformations were completed, following which the specimens were heated and diffraction

Jan 1, 1960

By Satyajit A. Vaidya

This paper presents a case-study in the design and construction of deep foundation element supported mats for two residential towers on an18,000-square-foot site in Brooklyn, New York. Based on site sub-surface conditions, conventional mat foundations bearing on medium dense sand, having an allowable bearing capacity of 3 tsf, were originally anticipated for the 16 and 25-story towers. However, when the tower shear walls were relocated to the edges of the mat foundations due to architectural revisions, the significantly increased mat edge contact stresses applied to the soil subgrade resulted in calculated settlements of a magnitude that would adversely impact the proposed structures and the neighboring/bordering lot-line building and rail transit subway structures. To address this issue, deep foundation element supported mats were designed for the towers. The design was performed as an iterative process involving structural SAFE and geotechnical Plaxis finite element computer analysis to develop a coordinated geo-structural model of the foundation system. Initial presumptive design values of 45 pci and 445 kips/inch were used for the modulus of subgrade reaction and minimum deep foundation element stiffness, respectively. The designed foundation system consisted of 40 and 60-inch-thick mat foundations for the 16 and 25 story towers, respectively. Initially, the deep foundation elements were designed as 50-foot-long, 14-inch-diameter elements installed to sustain a maximum individual compressive load of 250 tons. The final deep foundation element design was subsequently refined to consist of a 48-foot-long, drilled and grouted IBO Titan 103/51 element designed to sustain a maximum load of 167 tons. Subsequent field load tests on the deep foundation elements confirmed element stiffness ranging from 1,040 to 1,530 kips/inch, with measured mobilized side shear of about 29 psi. The mat foundation reinforcement was adjusted for the pile stiffness values determined in the field load tests, and the deep foundation supported mats were constructed. The two towers were subsequently constructed, and have performed successfully.

Jan 1, 2010

By W. Lin, E. Heuze

This paper focuses on tests performed on sandstones and shales from four gas wells in the Mesaverde formation. A previous document showed a comparison of the static and dynamic laboratory moduli. This publication describes how field velocity logs were used to derive field dynamic moduli. A 3-way comparison was then performed for these stiffness properties; the results show no agreement between the three sets of values. Differences between dynamic stiffness coefficients from the field and the laboratory exceed 200%; differences between static and dynamic coefficients range up to 600%. In turn, this indicates that a reliable method of estimating mechanical rock properties for hydraulic fracturing design has not been established, and that such a task should be pursued.

Jan 1, 1986