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By K. C. Corin, Z. G. Song, J. Y. Liu, M. W. Zhang, State Key Laboratory of Mineral Processing-BGRIMM, J. G. Wiese

"In the present study effect of grinding media on flotation of two mineral systems have been investigated, viz. sulphide minerals (including a pure chalcopyrite and pyrite mineral, and two different base metal sulphide ores), and oxide minerals (quartz, hematite and cassiterite). It was shown that mild steel media milling produced lower recoveries in the case of chalcopyrite and pyrite, as compared to the case of milling using ceramic media. For oxide minerals, the effects of using mild steel media as opposed to ceramic media were not as significant as was for the sulphides, although, after mild steel milling, at acidic pHs their recoveries were significantly reduced. For two base metal sulphide ores, viz. Nkomati and Dexing ores, the differences resulting from different milling media , although marginal, were opposite for each of these ores.For oxide minerals XPS showed that oxides and hydroxides of iron (e.g. FeOOH) adsorbed on the surfaces of the minerals. In the case of the Nkomati ore, adding Fe2+ or F3+ ions after milling with chrome steel media resulted in reduced talc (gangue) recovery, but increased water recovery and reduced concentrate grades. Further investigations are currently in progress to examine the Fe ions effect on the talc surfaces and froth properties.INTRODUCTIONGrinding of ores is necessary to liberate the valuable minerals from its gangues to allow for their selective recovery during mineral processing such as flotation. The grinding process inevitably involves contact of the ores with the surface of the grinding device and the grinding media. Accompanied by grinding, several phenomena can occur including the grinding medium wear, formation of precipitated species on the ore surfaces, chemical reaction, galvanic effects, changes in the Eh of solution, etc. There is a considerable body of literature on the differences observed in the flotation of various ores after milling using various grinding media. Laboratory studies have used balls or rods made from mild steel, ceramic, stainless steel or chrome steel to investigate the effects of different grinding media on mineral flotation. It is found that the interactions between the ore and the grinding environment can affect flotation separation of sulphide (Wei and Sandenbergh, 2007; Bruckard, 2011), oxide (He et al., 2014) and carbonate minerals (Song, 2009 and 2010). For example, mild steel milling produces relatively high concentrations of Fe ions in the pulp, affecting the recoveries of minerals compared to the case of ceramic media. On the other hand, the stainless steel media or chrome media are reported to be beneficial to the recovery of sulphides, when compared to the cases of using mild or carbon steel media (Rey and Formanek, 1960; Peng et al., 2003a,b; Huang and Grano, 2006; Bruckard, 2011). It is not clear, however, whether these Fe ions may affect the surface properties of the minerals involved or the general pulp/froth behaviour and hence their floatability. In addition, in the study of an low-S PGE ore carried out by Miettunen et al. (2012), forged media grinding in the CO2 atmosphere led to the highest Pt and Pd grades and recoveries, but the high chrome grinding media gave lower flotation recoveries than those using the forged media."

Jan 1, 2016

By L. R. van Wert

CAREFUL research into the nature of the metallic state has yet to discover, with any certainty, its essential quality. We do riot yet know, for sure, what it is that makes the metallic elements different from, if not actually unique among, all created things. We do know, of course, that metals have certain more or less characteristic properties-they are hard, strong, and tough, and good conductors of heat and electricity, and these so-called metallic properties provide a definition of a sort. How- ever, it is the structure rather than the behavior of the metals which gives the really fundamental information necessary to the understanding of metallicity. But this information is not easily obtained. Nature has a way of keeping secrets. But happily we do possess some knowledge of how a metal is built up, and it is this matter, rather than the presentation of a formal definition, that will be discussed here.

Jan 1, 1937

By James C. Foley

In-situ characterizations of green state part density and sintering state have long been desired in the powder metal community. Recent advances in non-contact electromagnetic acoustic transducer (EMAT) technology have enabled in-situ monitoring of acoustic amplitude and velocity as sintering proceeds. Samples were made from elemental powders of Al (99.99%), Al (99.7%), Ag, (99.99%), Cu (99.99%) and Fe (99.9%). The powders were pressed in a uniaxial die and examined with acoustic waves for changes in velocity and amplitude during sintering. The changes in acoustic properties were correlated with mechanical properties. Evolution of a series of reverberating echoes during sintering is shown to provide information on the state of sintering, changes in sintering kinetics as well as having the potential for detection of interior flaws.

Jan 1, 2001

By Axel Preusse

A high advance rate of the longwall face increases inevitably the mining dynamics within the rock and on the surface. Measures to limit the mining dynamics are the adjustment of the face advance rate to stretch the influences of mining over time and continuous winning to maintain a uniform influence of mining. This paper deals with the dynamics of mining subsidence within the range of a transmission overhead line for transportation of gasoline, diesel, kerosene, heating oil, mineral oil and other hydrocarbons. In a certain segment of the 24"-pipeline it was possible to predict, due to technical, operational and laying conditions, that undermining the pipeline would cause local stress maxima within the pipeline string. To limit these expected local stress maxima, the face advance rate of panel 497 was adjusted to the sensitivity of the pipeline towards the influences of mining. Comparison of the predicted mining dynamics, using the theory of stochastic media, with the measured ground movements led to the conclusion that the effects of dynamical influences which occurred within the range of the transmission overhead line and acted on it were low. This confirmed that the decision to adjust the face advance rate to the sensitivity of the transmission overhead line was correct (Kateloe et a)., 2002). A later relaxation cut in range of the pipeline siphon scarcely produced relaxation movements of the pipeline. The appointed sensitivity data of the undermined pipeline and the according maximum admissible face advance rate were thus correctly measured.

Jan 1, 2003

By Douglas Rudenko

Have you ever had a neighbor complain about a blast one day, but says the next day’s blast was better, even though the Peak Particle Velocity (PPV) increased? How about neighbors that complain about a small trimming shot, but don’t complain about a big production shot? Have you ever reduced the pounds/delay and gotten more complaints? Mine operators are often bewildered when trying to correlate blast design parameters to homeowner complaints.

Jan 1, 2002

By J. A. Finch

The photographic measurement of bubble diameter is tedious and restricted to vessels with transparent walls and relatively low bubble concentrations. A new method for predicting bubble diameter in a flotation column has been developed and confirmed by comparison with measured mean bubble diameter (Yianatos et al., 1987) Flotation columns are not mechanically agitated. This note describes an extension of Ms method to a mechanically agitated flotation machine. A recent publication by Szatkowski (1987) provided sufficient data to calculate bubble diameter by the proposed method and compare with values determined photo- graphically. Method In a two-phase system (gas and liquid), bubble diameter (db), superficial gas rate (Vg) and liquid rate (Vl), and gas holdup (Eg) are linked by two relationships (see the nomenclature at the end of the paper for definitions of symbols). [ ] Equation 1 is the definition of slip velocity (relative gas to liquid velocity) for a countercurrent gas-liquid system, and equation 2 is an adaptation (Yianatos et al., 1987) of the expression of Masliyah (1979) for hindered settling in a multispecies system. The solution for bubble diameter is by repetitive substitution of estimates of db in equation 2 until the calculated Ubs is equal to the measured Ubs in equation 1. Results and discussion Table 1 presents the data obtained by Szatkowski (1987) from a mechanically agitated laboratory flotation machine. The machine generated bubbles by directing a gas stream into the vicinity of a disk rotating at Ngh speed (up to 8000 rpm) in the flotation slurry. The air was completely dispersed in a swarm of fine bubbles. A photographic technique was used to determine the distribution of bubble size. The mean diameter and standard deviation were then calculated. Table 1 provides all the information necessary for computing bubble diameter (Vl is assumed zero). The calculated bubble diameter is presented in Table 1 as d;. Figure 1 plots measured versus calculated bubble diameter and shows reasonable agreement between values. There is an apparent tendency to undercalculate the small bubbles and overcalculate the large ones.

Jan 1, 1987

By J. J. Forbes

The original organic act establishing the Federal Bureau of Mines in 1910 and the amended act of 1913 indicated that promotion of the health and safety of mine workers was to be ore of the chief functions4/ of the Bureau. Many of the field and laboratory studies pursued by the Bureau are designed to improve conditions under dish minors must work. As the Bureau has no legal authority to enforce safety rules, it must rely upon cooperation of employer, employees, State mining or other departments, and labor organizations for success in promulgating its finding and making recommendations. The staff of the Safety Division, which is essentially a service organization of the Bureau, is composed of 28 safety instructors, 29 engineers, 18 clersk, and 7 others engaged in promotion of an educational program in an effort to improve conditions in the mining industry. The work is directed from 14 safety stations in the United States and 1 in Alaska. The work of the personnel, of the mine safety car that operates in. the anthracite region of Pennsylvania was supervised and directed by the district engineer in charge of the Wilkes-Barre (Pa.) Safety Station.

Jan 1, 1940

By Kentaro Kuraji

INTRODUCTION Background Tokyo, the capital of Japan, is one of the largest cities of the world. As many as 33 million people live in Tokyo and three neighboring prefectures although the city occupies only 0.6% of the area of the country. The network of Metropolitan Expressways serves as a major artery for daily physical distribution in Tokyo. The Central Circular Route of the Metropolitan Expressway (MECCR) is located innermost among the three circular routes in Tokyo (Figure 1). Once completed, MECCR is expected to drastically mitigate traffic congestion in the central Tokyo area and provide drivers wider varieties of options in route selection. Alleviating congestion is estimated to reduce 400,000 tons of carbon dioxide emissions annually. The eastern and northern sections and part of the western section of MECCR have been completed with the total length reaching 33 km. The western section will be extended southward by approximately 4 km in the spring of 2010. An 11-km-long western section of MECCR that is currently being constructed is composed mostly of tunnels. A large number of power supply, gas supply, telephone, drinking water and sewerage pipes have been placed under the Yamatedori avenue along which MECCR is being constructed. The shield tunneling method has therefore been adopted for constructing tunnels along the route. The method involves the advancement of a shield tunnel boring machine (TBM) through the ground simultaneously assembling segmental rings within the shield. The method not only enables the building of highway tunnels more quickly and efficiently than other methods but also minimizes the effects of construction work on the surrounding area and the environment. Constructing the tunnel using the conventional cut-and-cover method might have required large amounts of time and cost because relocating the numerous objects buried under the Yamatedori avenue might have been necessary during tunnel construction. It was also considered desirable to place the tunnel at a depth of 30 m or more from surface to prevent tunnel construction from adversely affecting railways because the tunnel was expected to cross eleven railways and subways. This is one of the reasons for selecting shield tunneling as an effective method. The shield tunneling method was finally adopted for a length of 7 km in the 11-km western section of MECCR. The shield tunneling method was also employed in the Ohashi Tunnel located southernmost in the 11-km western section of MECCR. This paper describes the construction of the Ohashi Shield Tunnel.

By M. Murakami, Y. Murakami, O. Kawano

The formation and growth of Guinier-Preston zones in Al-Zn alloys containing 4.4, 6.8, 9.7, and 12.4 at. pct zn have been studied by the X-ray small-angle scattering method. Particular attention was paid to the effects of small amounts of third elements silver, silicon, and magnesium on the formation and growth of G.P. zones. It was noticed that an appreciable number of G.P. zones were formed during the course of rapid cooling and that the size, volume fraction, and number of these G.P. zones were influenced by the existence of the third elements. During subsequent aging it was also found that the addition of both silver and silicon lowered the temperature for the growth of G.P. zones, whereas the addition of magnesium raised it. These results were explained in terms of the mutual interactions among zinc atoms, vacancies, and the third elements. A number of studies on the formation and growth of Guinier-Preston zones in Al-Zn alloys have been reported.1-4 Panseri and Federighii have found that the initial stages of zone growth take place at temperatures as low as around -100°C. For investigation of the mechanism of the initial stages of zone growth, growth studies must be carried out at low temperatures. In order to investigate the possibility of the formation of G.P. zones by the nucleation mechanism or the spinodal decomposition during quenching which was reported by Rundman and Hilliard,5 the examination of the as-quenched structure must be performed. In this paper the investigation of the early stages of the formation and growth were determined by means of the X-ray small-angle scattering method. With this technique, change of X-ray scattering intensities was measured while quenched specimens were heated slowly from liquid-nitrogen temperature to room temperature. At as-quenched state and after heated to room temperature, investigation of zone size, volume fraction, and zone number per unit volume was carried out. Measurements on these specimens yielded information on the early stages of zone formation and growth. Measurements were made also on specimens quenched to and aged at room temperature. From these measurements the previously reported model6 for the later stages of growth is confirmed; namely, the larger zones grow at the expense of smaller ones. Three elements, silver, silicon, and magnesium, were chosen as the third elements for the following reasons: Silver. In the binary A1-Ag alloy the spherical disordered 77' zones were observed immediately after quenching.7 Therefore, in the Al-Zn-Ag alloys, it is suggested that silver atoms might induce cluster formation during quenching. Also, since the migration energy of the zinc atoms was found to be raised by the addition of silver atoms,' silver atoms may have a great effect of the zinc diffusion, especially during low-temperature agings. Silicon. The effects of the addition of silicon atoms were found to be marked, especially at low-tempera-ture aging. In the binary Zn-Si system, no mutual solid solubilities between silicon and zinc9 and no in-termetallic compounds10 are reported to exist. Shashkov and Buynov11 investigated the behavior of silicon atoms in Al-Zn alloys and showed that silicon was not in the G.P. zones. The interaction between silicon atoms and vacancies is strong enough to increase the quenched-in vacancy concentration.* Magnesium. Magnesium atoms are reported to trap quenched-in vacancies and after much longer aging times these trapped vacancies will become free and act as diffusion carriers.13 Therefore at intermediate aging times, the diffusion of zinc atoms in Al-Zn-Mg alloys will be slower than in the binary Al-Zn alloys, whereas at longer times zinc diffusion will become faster. EXPERIMENTAL PROCEDURE The alloys used in this investigation had compositions of 4.4, 6.8, 9.7, and 12.4 at. pct Zn with or without 0.1 and 0.5 at. pct Ag, Si, or Mg. The alloys were prepared from high-purity aluminum, zinc, silver, silicon, and magnesium, with each metal having a purity better than 99.99 pct. The analyzed composition of the specimens is given in Table I. The measurements of the X-ray small-angle scattering were carried out with foils of 0.20 mm thick. The change of the scattering intensity was always measured at the fixed scattering angle of 20 = 2/3 deg. This angle exists nearly on the position of the intensity maximum. The value of the interparticle interference function14 which has large effect in this range of angles may not change abruptly in the case of the spherical shape of small zones. Therefore, from the above considerations, it is concluded that an increase of the intensity measured at this constant angle corresponds to an increase of the average radius and volume fraction of G.P. zones. The specimens were homogenized at 500°, 450°, and 300°C for 1 hr in an air furnace. For the study of the formation and growth at low temperatures, the foil

Jan 1, 1970

By Fred D. Wright

The objectives of this research were: 1. to determine the stability relationships of coal mine roof rocks which are cut by fractures or intersecting joints with and without roof bolts, under various sets of conditions including horizontal formation pressures, inclination and coefficient of friction of joints, bolt loads, roof spans and rock properties; and 2. to develop criteria for the design of roof bolt sys terns for such roofs. The problem was studied by mathematical finite element models and by laboratory models. From the results of the mathematical and laboratory models, equations were derived to express the relationships listed above for cracked, single-layered roof beams and design tables for such beams are included. The analysis was then extended to include multi-layered cracked beams reinforced by roof bolts and a method for analyzing and designing bolting patterns for such roof rocks is presented.

Jan 1, 1974

By Dyson N. F

Mixed cobalt-nickel sulphides precipitated from ammoniacal process liquors derived from nickel sulphide concentrates, mattes, and reduced nickeliferous laterites have been characterized.The mixed sulphides are prone to oxidation on standing and are rapidly leached under relatively mild conditions. The kinetics of the leaching reactions are controlled principally by temperature and oxygen partial pressure. Although the samples have different CO:Ni ratios and have undergone varying degrees of oxidation, there is little difference in their leaching behaviour. The results suggest that a single plant would be able to process mixed sulphides of varying composition. Any copper and zinc present in the mixed sulphides as impurities also go into solution and must be removed prior to recovery of the cobalt and nickel in metallic form.

Jan 1, 1981

By d&apos, K. Mukherjee, C. R. Antonio, R. J. Maciag, G. J. Fischer

Tensile data indicate that over the range of strain rates 10-5 to 10-1 sec-1 and in the temperature range 298° to 743°K the flow stress at a given temperature may be expressed as: C0 = Cem where m changes abruptly at a critical strain rate of 10-2 sec-1. The Zener-Hollomon parameter was tested and found to be invalid except at temperatures exceeding 700° K. Values of AH calculated for temperatures above 700°K ranged from 30 to 47.5 kcal per g-mole. ThE flow characteristics of aluminum and aluminum alloys as a function of temperature and strain rate have been of interest to various experimenters for many years. Trozera et al.1 determined tensile flow curves for pure aluminum and concluded that the combined effect of temperature and strain rate on the flow stress could be related using the Zener-Hollomon parameter. More recently, Hockett2 proposed a relationship between compressive flow stress, temperature, and true strain rate which could be represented by a surface. Holt et al.3 studied strain rate effects on flow stress in a number of aluminum alloys at room temperature. It was determined that there is a critical strain rate above which a strain rate effect is observed. It was also reported that the strain rate sensitivity was significant in aluminum alloys in the "0" condition only. In a recent review paper McQueen4 has considered a number of mathematical expressions which have been used to describe the relationship between stress, strain rate, and temperature. These expressions have been applied to the flow characteristics of a number of different metals and alloys including aluminum. In the present work the strain rate sensitivity of 7075-0 aluminum was determined in the temperature range of 298° to 743°K. The tensile flow stress at 0.2 pct offset was obtained over a nominal strain rate range of 10-5 to 10-1 sec-1. EXPERIMENTAL Threaded tensile specimens were cut from a single heat of 7075-T6 aluminum. The composition of this heat is given in Table I. The test bars had a gage section 1.5 in. long by 0.250 in. diam and conformed to ASTM specification E-8-57T. After machining, the bars were annealed at 413° ± 10°C for 2 hr. They were then cooled to 260°C in 3 hr, and finally air cooled to room temperature. This treatment is commonly used to produce the "0" condition. Load-time curves at constant crosshead speeds were obtained at various temperatures using an Instron testing machine. Crosshead speeds ranged from 0.002 to 40 in. per min. A three-zone resistance tube furnace was used for the elevated-temperature tests. Temperatures were measured at three points along the gage length by means of suitably placed thermocouples. Each tensile bar was held at temperature for 30 min prior to testing and the maximum temperature variation along the gage length was kept below 1°C. In all, 275 samples were tested and each data point plotted is an average of at least two tests. In many cases the point represents up to six tests. RESULTS AND DISCUSSION Values of the flow stress at 0.2 pct offset at six different temperatures are plotted vs strain rate on log-log coordinates in Fig. 1. Over discrete ranges of strain rate, the data for each temperature fit the expression:

Jan 1, 1969

By Charles Sabine

The U.S. Bureau of Mines studied mines and prospects in the Bristol/Granite Mountains Wilderness Study Area (WSA) in 1982. The 45,000 acre WSA, located in the eastern Mojave Desert of California, is underlain by Mesozoic plutonic rocks with scattered roof pendants of Paleozoic (?) metasedimentary rocks. Two mines and six prospects are identified; one mine, the Silver Lode Mine, and a prospect of unknown name are adjacent to the area. The Silver Lode Mine has occurrences of silver, lead and zinc. Within the study area, the Comanche Mine has occurrences of iron and copper and the Iron Victory Prospect has an occurrence of iron. None are large enough to constitute a resource. Occurrences of magnesian marble at the Comanche Mine, Iron Victory Prospect, and elsewhere in the area contain too much MgO for commercial use other than agricultural soil supplements or crushed stone. Transportation costs to markets would exceed the value of the rock. At the Comanche Mine, situated in a roof pendant of marble, about 10 tons remain of a 110-ton pod of magnetite which contained 42.5% iron, and less than 50 tons remain of a mineralized fault breccia which averaged 2.5% copper and 0.3 oz/ton silver. Magnesian marble contained 41 to 45% CaO and 14 to 16% MgO. Primary and secondary silver, lead, zinc, and copper minerals are disseminated along altered joints and in quartz veins in quartz monzonite at the Silver Lode Mine, adjacent to the WSA. Analytical data are sporadic; samples contained as much as 0.12 oz/ton gold, 1.8 oz/ton Silver, 1.1% lead, 3.8% zinc, and 0.3% copper. Mineralized zones in the workings are not resources, but they might indicate possible silver-lead-zinc resources at depth. At the Iron Victory Prospect, lenses of magnetite and hematite with some chalcopyrite occur in a skarn lone in a marble roof pendant. About 110,000 tons of iron-rich rock, averaging 47.2% iron, are present; the largest lens contains about 30,000 tons. About 150,000 tons of magnesian marble, averaging 41.0% CaO and 11.7% MgO, are also present. Deposits of stone, and sand and gravel in the WSA are too distant from markets to be resources. Occurrences of energy minerals were not identified.

Jan 1, 1984

By G. R. St. Pierre, A. J. Wilhelem

In connection with the reduction of hematite or magnetite to metallic iron, it appeared desirable to study the rate of reduction of each oxide to the next lower oxide under conditions which excluded all other condensed phases. For this purpose, pellets of Fe,O,, Fe,O,, and oFeOo were prepared. A gas train for the preparation of Ar-Hz-H20 mixtures was employed to establish a continuous flow of a controlled atmosphere over a pellet suspended on a balance. In this manner the following individual reduction steps could be studied: For example, pellets of hematite were reduced solely to magnetite by adjusting the gas atmosphere such that it was oxidizing to wustite. In other words, the reaction was complete when the hematite pellet had been totally converted to magnetite. The pellets were prepared from Baker Chemical ferric oxide. The ferric oxide powder was moistened and handrolled. Air sintering at 950°C produced Fe,0, pellets with a density of 3.65 g per cm3. The pellets ranged in size from 0.6 to 1.2 cm diam. The magnetite and

Jan 1, 1962

By J. E. Armstrong

"IntroductionT'HE PRODUCTION of gravel and sand may be considered to be the major mining operation in the Lower Fraser Valley of British Columbia. At least thirty pits are in operation with a yearly production probably in excess of two million yards and a value in excess of one million five hundred thousand dollars before crushing, washing, and sizing. The value of the finished products would probably be double the above figure.Since 1949, the writer and his co-workers have been engaged in the geological investigation of the Lower Fraser valley and adjoining Coast mountains for the Geological Survey of Canada. The study, which is not yet completed, includes both bed-rock geology and geology of the unconsolidated sediments lying above bed-rock. In a rapidly expanding industrial area, .an advance knowledge of the geology may• greatly aid in future 'planning, and in many cases may .prevent not only the wastage of large sums of money, 'but possible disaster. Some of the present and future applications in which geological information in the Lower Fraser valley should be of value are as follows: the development of domestic, irrigation, industrial, and municipal groundwater supplies; drainage for industrial sites,, roadbeds, and farmlands; flood control along the Fraser river and smaller streams in the area; the location of dam sites, of major tunnels for water supply •and sewage, of road-beds, of foundation sites for large buildings .and other engineering undertakings in which geology may aid; the evaluation of oil and gas •possibilities; the production of building stone; and the production of sand and gravel, the subject with which this paper is primarily concerned."

Jan 1, 1953

As REVISED IN CONFERENCE FEB. 17, 1931 REPORT OF SUBCOMMITTEE ON MINE VENTILATION CODE OF A, I. M. E. COMMITTEE ON VENTILATION ALFRED W. HESSE, Chairman THOMAS G. FEAR GEORGE S. RICE E. A. HOLBROOK WILLIAM A. ROWE HOWARD ECKFELDT R. V. NORRIS CADWALLADER EVANS, JR. H..1. SMITH, Secretary REALIZING, from the safety and health standpoint, the need of furnishing air of good quality to workers underground and of diluting and carrying away dangerous and noxious gases, the following code is offered to unify regulatory measures in coal mine ventilation, so far as is practicable, in the United States of America.

Jan 1, 1931

By Sterling J. Anderson

To define the technical competence and capabilities of a nonexplosive excavation concept, the Bureau of Mines conducted reduced-scale laboratory tests of a mechanical excavation tool called a rock splitter. Hydraulically actuated splitters, capable of generating both radial and axial loads on a predrilled hole, were designed and fabricated. Through paired variable testing and drifting simulation, reduced-scale splitter performance was evaluated in concrete. Testing proved that the rock splitter is capable of excavating within the highly confined drift set-ting and that it offers a distinct advantage over splitters that can generate radial loads only.

Jan 1, 1982

By S. M. Runke

An ever-increasing demand for beryllium and beryllium alloys has directed attention to the milling of low-grade domestic deposits as a possible means of supplying part of the Nation's ore requirements. The United States generally produces less than 10 percent of its annual supply. For example, new supply in 1953 was estimated at about 9,250 tons, of which the United States imported 8,500 tons. Domestic production was only 750 tons.2/ Since record high prices for beryl in 1952 and 1953 did not greatly increase domestic product ion, the United States must develop mechanical beneficiation processes to use low-grade deposits and reduce dependence on foreign sources

Jan 1, 1954

By Batric Pesic

A hydrometallurgical process for recovery of Zn and Mn from Bunker Hill Water Treatment Plant sludge was developed. The process is unique because it treats an unusual combination of metals, Zn and Mn. Another non-standard feature of the process is that leaching takes place with ~S04 in the presence of a reductant (SO2). Zn and Mn are recovered simultaneously by electrowinning, Zn on a cathode and Mn on an anode, as MnO2 The major purpose of the process is to detoxify the sludge by removing toxic heavy metals. The recovered metal values could be marketed to offset the overall costs of water and sludge processing. This work is presented in two separate parts, 1. Leaching and Solution Purification, and II. Electrowinning. This paper covers only the first part of the hydrometallurgical process: Leaching and Solution Purification. Initially, the paper briefly discusses the history of the pollution problem at the Bunker Hill Superfund Site, the origin of heavy metals in the mine waters, and the development and use of the water treatment plant. The leaching of sludge was examined as a function of the following parameters: constant vs. initial pH, initial vs. delayed addition of SO2, temperature, and pulp density. It was found that leaching with H2SO4 at pH 2.0 for 15 minutes (at 60°C), followed by S02 addition for another 15 minutes, could completely dissolve Zn and Mn. Solution purifIcation was done in three stages. In the first stage iron was removed by adjustment of pH (to pH 5.0) and oxidation offerrous to ferric iron (with H2O2). In the second stage, Cu and Cd were removed by Zn dust cementation. Finally, Co and Ni were precipitated with the organic reagents 1-2 nitroso-naphthol and nitroso, respectively. Electrowinning of Zn and Mn is discussed separately in Part II of this paper.

Jan 1, 1996

?AARONSON, ALFRED E, .Vice-Pres, Mid-Co Petroleum Co , Mid-Co Bldg, Tulsa, Okla '18 ABADIE, EMILE R, Min Engr - Box 927, Porterville, Cal '76 ||ABADILLA, QuiRiCo A, Student, Colorado School of Mines, Golden, Colo. '20 ABBOTT, CLARENCE E, Gen'l Supt, Iron Mines Div, Tenn Coal, Iron & R R Co , 1405 Minnesota Ave, Bessemer, Ala. '04 ABBOTT, Louis BENJAMIN, Chief Engr, Consolidation Coal Co-, Elkhorn Div, Jenkins, Ky '15 ABBOTT, ROBERT R Met. Engr, Peerless Motor Car Co, Cleveland, Ohio. '12 ABE, ASAKA Fujita Min Co, Dojima, Osaka, Japan '14 ABEEL, GEORGE H, JR, Cons Min Engr, 633 St Paul Ave, Los Angeles, Cal '18 ABEL, ALBERT E, Mgr., Pittsburgh Dist, Valley Mould & Iron Corpn, 28th St & R R Ave, Pittsburgh, Pa '19 ABEL, W D, Min. Engr. 3897 Sacramento St , San Francisco, Cal. '19 ABELL, 0 J, Pres & Treas, Abell-Howe Co, 332 South Michigan Ave, Chicago, Ill '19 ABERNATHY, G E Willow Springs, Mo '20 ABEY, HIROSHI, Min & Met Engr, Arakawa Mine, Mitsubishi Co, Senpoku-gun, Akitaken, Japan '17

Jan 1, 1923