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By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

L&M have been involved on the Shotover since 1980 when we joined Jack and Barney Ryan, who had started in 1972 with gold at $45 per ounce after a successful career as roading and demolition contractors in Christchurch. The first 85 tonne plant was a typical NZ trammel-riffle table plant with an armour plated hull for surviving Shotover floods, and was fed by a 53 tonne UH20 excavator. All this gear had to be carted in over the Skippers road on a small truck or sledge for the heavy loads. This operation was successful and generated the cash flow to sample the lower section of river and plan a second plant. To reduce fine gold losses this was planned to be a jig recovery plant and also included a vibrating screen which saved space and weight over a trammel. There are five flowlines of primary jigs and one secondary, followed by two Knudsen bowls for cleanup.

Jan 1, 1985

By William S. Sanner

A demonstrated reserve base (DRB) of bituminous coal suitable for cokemaking has been estimated based on the latest published information on U.S. coal reserves. Bureau of Mines analyses of raw coalbed samples were used to classify the coals as low-, medium-, and high-volatile bituminous and grade them as premium, marginal, and latent coking coals. Coal rank was used as the basis for identifying coking coals, and ash and sulfur content were used to determine coking coal grade. The demonstrated reserve base of coking coal for the entire United States is 162.67 billion tons. However, only 18.96 billion tons are premium (metallurgical) grade, and between 80 and 99 percent occurs in the Eastern States. The demonstrated reserve base of marginal-grade coking coal is 31.3 billion tons; more than half the marginal reserve base is in the Eastern States, and most of the medium- and low-volatile marginal coals are in the Eastern States. The Eastern and Midwestern States contain most of the latent-grade DRB of 112.4 billion tons; most (106.6 billion tons) is high-volatile coal, and 98 percent of the medium- and low-volatile latent coals occur in the Eastern States. Based on the worst assumption, which assumes that only premium-grade coals are used for cokemaking, the DRB for high-volatile coal would suffice for 127 years, the medium-volatile coal for 80 years, and the low-volatile coal for 83 years.

Jan 1, 1979

By O. J. C. Runnals

The intermetallic compounds NpAl2, NpAl3, and NpAl have been prepared, and examined by X-ray diffraction methods. The compounds are isostructural with the corresponding U-Al compounds. NpAl3 is face-centered cubic with a = 7.785A and has the MgCu2 structure. NpAl is simple cubic with a = 4.2624 and has the AuCU3 structure. NpAl4 is body-centered orthorhombic with a = 4.428, b = 6.268, and c = 13.71A. The published description for the atomic positions in UAl, applies also to NpAl4 THE U-Al system has been examined by Gordon and Kaufmann.1 They identified the following intermetallic compounds: UAI2, UAl3, and a third, tentatively identified as UAl5. A structure analysis of the latter compound by Borie2 proved that the formula UAl4 was more consistent with the X-ray data. The crystal structures of UAl2 and UA have been reported by Rundle and Wilson.3 UAl2 was found to be isostructural with MgCu. The atomic positions in the simple cubic UA1, cell were found similar to those in the AuCu3 structure. Three analogous compounds exist in the binary system Np-Al. X-ray data for the compounds NpAl2, NpAl3, and NpAl4 are reported below. The neptunium used in the investigation was supplied through the courtesy of the Argonne National Laboratory as neptunium (V) nitrate. It was stated to have a radioactive content of 99.25 pct Np237. The impurity limits had been established by a spectrographic analysis given in Table I. Any titanium, boron, or bismuth impurity should be effectively removed during the fluorination of NpO2 to NpF4, and sodium, lithium, magnesium or strontium during the alloying procedure. The oxalate ignition technique, described by Westrum for the preparation of finely-divided reactive PuO2, was used.The neptunium (V) nitrate solution, containing 100 mg Np, was evaporated to dryness on oxalic acid crystals. The resulting oxalate was calcined to NpO, by heating in platinum at 650°C for 2 hr. An equimolar mixture of anhydrous hydrogen fluoride and purified hydrogen was passed over the NpO2 for 2 hr at 500°C. According to Fried and Davidson" the above fluorination conditions should produce the purple-black fluoride, NpF3 However, the light-green product showed only NpF4 lines on an X-ray diffraction pattern and contained only an estimated 5 pct of finely dispersed black NpF3 particles on microscopic examination. NpAl3: An intimate mixture of 50 mg of neptunium fluoride and aluminum powder (99.99 pct pure, —28 to $60 mesh) was heated to 900°C in a BeO crucible in vacuum by a tungsten coil for 2 hr, to allow the following reaction to proceed: NPF4 + 7Al + NpAl, + 4AlF. [1] The formation and sublimation of aluminum mono-fluoride in this system was verified from an X-ray diffraction analysis of the sublimate. The diffraction pattern was similar to one obtained in the aluminum reduction of UF4 to UF3,6 showing both Al and AlF3 lines. The resulting alloy was sintered at 1100°C for 1 hr. A powdered specimen of the crystalline product was sealed in a thin-walled quartz capillary for X-ray examination. The photograph was taken on a 14.32 cm General Electric powder diffraction camera, using filtered copper radiation. The films were calibrated in terms of a NaCl standard pattern. The wavelengths used in the calculations were 1.5418A for Cu K and 1.5405A for Cu K The powder diffraction pattern showed that NpAl is simple cubic with a = 4.262 % 0.005A, and is isostructural with UA13 where a = 4.27A1 or a =

Jan 1, 1954

By Enver Alan

This Research & Development (R&D) study was conducted in the field of applied blasting engineering in Ethiopia, within the AKH Railway Project, which was built in Girena, within the boundaries of the province of Mersa, in the Basalt Quarry at km 346, Ashangi Formation, occured in Eocene geological time in the aphanitic trachibasalt. Under the scope of the study, which has been performed to determine the effects of the artificial discontinuities at different depths and the effects of artificial discontinuities through structural damage risk, three test areas, at the same location and same formation, were considered. Six numbers of artificial discontinuities, each 10 m (32, 81 ft) transverse, were created by using pre-splitting and drilling-blasting technology. The number of sequential artificial discontinuities on each test area is two and they have the same length. The length of artificial discontinuities are; 6,80 m (22,31 ft) at the first test area, 13,60 m (44,62 ft) at the second test area and 17,00 m (55,77 ft) at the third test area respectively. The distance between sequential artificial discontinuities is 8 m (26,25ft) on each test area. Thirty-one shots were executed in order to produce vibration (10 shots on the first test area, 11 shots on the second area, 10 shots on the third test area). One hundred and twenty-three seismic recordings were obtained during the execution of the shots by using 4 seismographs. The closest distance between the shot points and the nearest measuring station is 5,30 m (17,39 ft). During the shots, the rock was cracked and there was no fragmentation and/or fly rock. At the first test area, measured PPV values are between 25,40-127,00 mm/s (1-5 inch/s) before the first artificial discontinuity and less than 50,80 mm/s (2 inch/s) after the second artificial discontinuity. At the second test area, measured PPV values are between 76,20-177,80 mm/s (3-7 inch/s) before the first artificial discontinuity and less than 76,20 mm/s (3 inch/s) after the second artificial discontinuity. At the third test area, measured PPV values are between 50,80-279,40 mm/s (2-11 inch/s) before the first artificial discontinuity and less than 50,80 mm/s (2 inch/s) after the second artificial discontinuity. Peak reduction rates in Peak Particle Velocity (PPV) values determined by measuring as follows: In the first test area 95,77% (106,00 mm/s to 4,48 mm/s) (4,17 in/s to 0,18 in/s), in the second test area 79,77% (176,00 mm/s to 35,60 mm/s) (6,93 in/s to 1,40 in/s), in the third test area 95,85% (from 205,00 mm/s to 8,55 mm/s) (from 8,07 in/s to 0,34 in/s). The arithmetic mean of the differences of PPV values (decrease rate) is 82,66% in the first test area, 69,37% in the second test area, and 92,03% in the third test area. The highest sound value is 138,50 dB and is defined as “noise”. When the measured parameter values are examined it was determined on the USBM norm graphs that these vibrations carry a risk of structural damage in the region before the first artificial discontinuity. While passing through artificial discontinuities the vibrations progress by losing energy and the vibrations passing through two artificial discontinuities do not carry structural damage risk under current conditions.

By W P. Player

The legislative operating environment, or the mineral regime, that a country has to offer is one of the key determinants that a company wanting to invest in an area takes into account in formulating its investment decision.   The New Zealand Government recognises this and the importance of getting the regime right in order to provide for continuing investment in mineral exploration and mining in New Zealand . In recent years, the Government has given considerable attention to developing legislation which provides for investment to take place; for those making the investments to have a stable, fair and open investment environment with government intervention only when considered absolutely necessary because other approaches are not working; and for the people of New Zealand to know that investment must meet acceptable health and safety standards and have acceptable impact on the environment. Also of key importance is having a clearly defined mining regime which includes rules on how to obtain a permit and rules in respect of ongoing permit compliance, rights to develop a mineral resource and permit conditions (in particular, the royalty regime). In New Zealand , these matters will all be addressed in what are referred to as 'minerals programmes'.   The Crown Minerals Act 1991, which is the legislation governing the allocation and management of permits for Crown owned minerals, requires that the Minister of Energy prepare minerals programmes. Minerals programmes establish the policies, procedures and provisions that the Minister shall follow in exercising his or her functions and powers under the Crown Minerals Act. Minerals programmes set out the principal reasons for and against adopting these policies, procedures and provisions and also restrictions on prospecting, exploration and mining for Crown owned minerals. Essentially minerals programmes define the mining regime for the minerals to which they apply, other than the taxation regime, environmental and health, safety provisions, land access matters and general matters concerning the investment climate.

Jan 1, 1995

By L. Béjar-Gómez

The aim of this research work is to study and characterize the precipitates in structural microalloyed steel by transmission electron microscopy and analysis by low resolution. Microalloyed steel with niobium was produced by casting in an electrical induction oven of 25 Kg capacity. Carbon content in steel was less than 0.1 % and 0.036% of niobium. Steel was processed thermomechanically; reheated to 1250 °C and hot rolled on a laboratory mill to a 13.0 mm thick plate with a finish rolling temperature of 900ºC and a thickness reduction of 80% . This work shows what precipitates are present in steel, the type of precipitates and their morphology. Analysis by transmission electron microscopy of low resolution was applied to obtain the chemical analysis of precipitates and the matrix. Spectroscopy of dispersive energy (STEM - EDS) was applied to obtain the element profile of precipitates. Particles of precipitates of NbC were found; with cubic morphology and size from 70 to 130 nm, circular morphology and size from 10 to 70 nm, polygonal morphology and size from 10 to 80 nm.

Jan 1, 2006

By Alejandro Freyre Belliki

El presente trabajo describe las causas del abandono de mineral, las razones de su recuperación de las antiguas explotaciones, así como el estudio de las técnicas más adecuadas para realizar dicha operación. Entre las causas del abandono de mineral tenemos: la variación de precios de metales, calidad y complejidad del mineral, seguridad, derrumbes y el método de explotación. También se mencionan los casos de recuperación de materiales útiles como rellenos antiguos, mineral "in situ", derrumbes y minerales dejados en mantos. Finalmente, se evalúa la posibilidad de hallar reservas recuperables y por ende, examinar la factibilidad de su recuperación. Asi también, las zonas recuperables son generalmente las más altas, ya que la aplicación de métodós con relleno hidráulico tomado directamente de los relaves de la Planta, debe considerar la diferencia de nivel entre ella y los tajeos re-explotables.

Aug 20, 1965

By P Holtham, K Duffy, W Valery, A Jankovic

As high grade ore deposits are depleted, remaining deposits are generally lower grade and require the mining and processing of larger volumes of material per tonne of product. These low grade deposits often contain a large proportion of barren gangue. Pre-concentration aims to remove this barren material at as coarse a particle size and as early in the process as possible. This has the potential to reduce processing costs, energy and water consumption, increase production and improve resource utilisation.There are several technologies that may be applicable for pre-concentration. This paper looks specifically at bulk ore sorting and how it can be integrated into existing or new mining operations to improve profitability and reduce environmental impact. Bulk ore sorting is the separation of barren gangue from a fully loaded conveyor belt based on the grade as measured or inferred from a sensor measurement. It may be used to increase the production rate through fixed plant capacity, or increase production and/or reduce the size of downstream processing equipment in Greenfield operations. Marginal ore sub-economic reserves may be upgraded, making them economic to treat and improving the resource utilization. Bulk ore sorting could also be used to reduce dilution and ore loss in mining operations by improving grade control, or to separate ore types to treat via different process routes. Various applications of bulk ore sorting are discussed in this paper, and three cases are investigated considering the impact on the overall operation and the associated benefits.CITATION:Duffy, K, Valery, W, Jankovic, A and Holtham, P, 2015. Integrating bulk ore sorting into a mining operation to maximise profitability, in Proceedings MetPlant 2015, pp 273–287 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By Francisco Sena Leite, Pedro Brito, Auã Kiahla, Raquel Carvalhinha, Tomi Kouvonen, Vinicius Miranda

Shockwaves that generate vibration in the surrounding environment of a blast, are one of the most important factors to control drill & blasting works near delicate buildings as well as in sensitive structures (wall control). On top of the damage to the buildings themselves, sensitive equipment such as computers, measurement apparatus and medical devices can be also compromised. The most commonly measured values from vibration are PPV (peak particle velocity), acceleration and displacement. Some devices and techniques have been developed in the last decades to measure the impacts of these vibratory phenomena. This information can be used to predict levels of vibration for future blasts and improve their quality of design using the attenuation law. From traditional studies to modern seismographs, a range of solutions are used for this propose. The main problem of applying this kind of technology is the high cost associated with each measurement device. In order to measure the ground vibration using new technologies while lowering the cost, a device has been developed using a microcontroller and electronic sensors commonly found on the market. This new equipment was tested side by side with traditional seismographs and the results were sent to a server for analysis. After several blasts, the necessary data was generated for the validation of the prototype. Through numerical mathematical processing (Taylor’s approach and numerical derivation) the original data supplied by the accelerometer’s sensors was transformed into velocity and, after the data mining, a statistics residue analysis was applied in order to evaluate if the data from the prototype and from the traditional seismographs were similar. The data from each system was used to estimate the attenuation law and the results are shown in this paper.

By W. J. Kennedy

Energy management in industry has recently achieved notice as a way to reduce costs without decreasing production. The same approach used in industry can be used in mining, even though the processes are different. This approach is based upon a three phase system of data collection, implementation, and monitoring, all aimed at gathering and evaluating information in such a way as to have a maximum impact on energy costs. This approach has these advantages: (1) attention is directed toward the part of each mining system where the most energy is used, (2) input is collected systematically from all persons involved in the operation of each system, and (3) a means of monitoring the progress toward established goals is created. The mining systems considered are truck haulage, conveyor haulage, blasting and crushing, and lighting. After describing the general procedure, the authors have described a specific method for improving the efficiency (and hence the energy consumption) of round-trip truck haul age systems.

Jan 1, 1982

By S. H. Morar

Froth flotation is a physico-chemical separation process that takes place in two phases; pulp and froth phase. It is widely recognised as a complex process, due to the range of interactions present within the system. Of critical importance is the role of the froth phase within the system. The pulp kinetics governs the maximum potential recovery within a flotation cell, while the froth phase governs the selectivity via the froth?s stability. Higher froth stability improves recovery at the expense of grade, and lower froth stability improves selectivity. It is well known that the two major factors affecting froth stability are attached particles and solution chemistry. This paper looks at a flotation bank at different froth depth and frother concentrations. The air recovery to the concentrate is determined at each condition and relates the effect of the operating conditions on froth stability and transport to the amount of solids that are recovered to the froth and concentrate by true flotation. The results presented show that, for a given process objective, which in this case was a consistent mass pull profile, depending on the operating conditions, solids recovery in the pulp is affected by the air rate required to maintain the target mass pull. To a smaller extent, the changes in the pulp composition affect down-stream pulp recovery. The variation in solids recovered into the froth drives the froth stability at the start of the flotation bank, while the frother drives the froth stability at the end of the bank. The performance in between these two extreme conditions arises from an interaction of these two effects. The consequences of these interactions can give rise to counter-intuitive responses that can confound efforts to optimise the performance of the bank.

Jan 1, 2014

By Qingchun Yu, Baoqiang Xu, Yongnian Dai, Bin Yang, Fulong Zhu

"In this paper, the mechanism of the carbothermic reduction-chlorination process to extract aluminum from alumina in vacuum was investigated. The carbon monoxide (CO) content of the gas, phases of the reduction slag, surface morphology of the reduction slag and the product aluminum were measured by means of gas chromatography (GC), XRD, and SEM. The experimental results indicated that the content of CO in the gas decreased, but Al4C3 increased with time at 1773K during the carbothermic reduction process of alumina. AlCl(g) and graphite (C) were produced by the reaction between Al4C3 and AlCh(g) at 1773K, and then aluminum beads generated after the decomposition of AlCl(g). It implied the mechanism of alumina carbothermic reduction-chlorination process in vacuum involves three steps as follows: the carbothermic reduction of A}z03 to produce Al4C3, the chlorination of Al4C3 by AlCh(g) to produce AlCl(g), and the decomposition of AlCl(g) to produce Al(l).IntroductionAluminum is the basic raw material for many industries [1], and it is used extensively because of various excellent properties such as light weight, good malleability, high strength, excellent thermal conduction, high corrosion resistance and so on [2]. Industrial production of aluminum currently includes refining alumina and electrolytic aluminum processes. However, its development has been effected by some factors such as high energy consumption and heavy environmental burdens [3]. In the past several decades, there had been numerous attempts to produce aluminum by new methods. Extracting aluminum from alumina or bauxite directly by carbothermic reduction-chlorination process had been studied [ 4-6]. Although the alumina carbothermic reduction process [7~9] had been studied, the mechanism of the carbothermic reduction-chlorination process had not been systematically elucidated.In order to investigate the mechanism of the carbothermic reduction-chlorination process in vacuum, GC, XRD and SEM techniques will be used to determine the CO content and to characterize the surface morphology and composition of the slags at various temperatures."

Jan 1, 2011

By T. B. Szwilski

ISO 14000 series are voluntary international standards that address environmental management system standards, environmental auditing, environmental labeling, environmental performance evaluation, and life-cycle assessment. An environmental management system (EMS) is a facet of an organization's structure that addresses the immediate and long-term impact of a company's products, services, and processes on the environment. Many companies in the United States are taking a cautious wait-and-see approach before embracing ISO 14000. A few mining companies are reviewing the standards and using them as guidelines. The paper outlines the status, possible benefits to the mining industry, and options available to a company wanting to become involved in the ISO 14000 standards.

Jan 1, 1997

By N Mangadoddy, P Jampana, S Diddi

The study of air-core dynamics in hydrocyclone operation is essential for predicting separation efficiency in mineral processing. Electrical resistance tomography (ERT) allows non-invasive measurements of hydrocyclone internal flow dynamics. Existing regularisation methods such as Gauss-Newton and TV norms rely on optimisation techniques which have very high computational cost for very fine meshes. In contrast, the monotonicity method has much lower computational cost as it does not solve such minimisation problems. In this paper, results from the monotonicity method, Gauss-Newton (GN) (Tikhonov) and Total-Variation (TV) norm-based minimisation methods for estimating the air-core diameter in hydrocyclones are compared. We study these methods on the laboratory hydrocyclone experimental two-phase flow data. The results obtained are validated against High-speed video (HSV) imaging and Computational Fluid Dynamics (CFD) results. The results on different mesh sizes, in particular for very fine meshes with the number of cells ranging from 30 000 to above 100 000 are also investigated. The data used in this study is obtained from ITS Z8000 ERT system. This system does not measure the voltages on the current carrying electrodes. Since these voltage values are required for the monotonicity method, we implement an interpolation method to compute them. The results show that the monotonicity method provides a closer approximation of the interface between air and the water phases.

Aug 24, 2022

By E. P. Ferrero

Crude oils from fields throughout the world are analyzed by the Bureau of Mines to determine the characteristics of the oils and their contribution to the petroleum resources of the world. Analyses are reported for 169 foreign crude oil samples from 122 oilfields in Africa, Asia, Australia, the Caribbean, Europe, North America, and South America. Tables show the geographic and geo- logic origin of the samples, names of companies that supplied the samples, annual production for the fields, general characteristics and analytical and computed data, hydrocarbon-type data, cumulative production of the larger fields, and references to sources of geological and field development information. The analyses were made by the Bureau of Mines routine method and comparisons may be made with more than 8,000 other such analyses.

Jan 1, 1972

By Angus D. Campbell

"IntroductionThe subject assigned to me tonight gives unlimited scope. The material available is so voluminous and leads into so many ramifications, and the memories of the Camp are so vivid and treasured, that it is difficult to decide just what to use. Then, too, the geologists are the story-tellers of our tribe - I am only a hard rock miner.Members of the Cobalt Branch and Cobalters everywhere will agree without question that this Cobalt camp has been the greatest of all influences on Canadian mining. To those who do not know Cobalt, our opinion may seem prejudiced and our statement exaggerated.Be that as it may, discussion on this subject can be profitable, since it is worthwhile now and then to think on 'whence we came' and 'where we are going'.In the revival of interest in the Cobalt camp, we hope our guests may feel some of the old Cobalt Spirit, which has become the Spirit of the North.Visitors may even, while here, catch a glimpse of that whimsical little guardian spirit of the camp - the original goblin, the Kobold - for which Cobalt was named.While Kobold brings that good luck which plays so important a part in mining, he can have his evil moments, as in his original German home. There, when he made the silver disappear from their good ore, they cursed the grey ore, calling it Kobold.Although this little goblin bas frequently upset our best mining plans and geological calculations, be has played the game as well. He placed •some silver on the surface, and when he hid ~t at depth he left dues .for its finding. He has rewarded many who sought his treasure and is still rewarding those who have persevered and had faith in him. t:lis influence and that of Cobalt camp has probably had a greater influence on your work and your mining areas than you realize"

Jan 1, 1950

By Frank C. Andreuzzi

The Federal Bureau of Mines conducted a demonstration project to reclaim 125 acres of abandoned strip-mined land in Lackawanna County, Pa., for public recreational, historical, and educational use as a park. The Bureau was involved in the development of the general site plan, and engineered and supervised the basic land rehabilitation. The park's Facilities include outdoor recreational activities, picnic grounds, children's play areas, primitive overnight camping, and winter sports. A major attraction is the Anthracite Museum constructed by the Pennsylvania Historical and Museum Commission The project may serve as a prototype for reclaiming existing and future surface-mined lands.

Jan 1, 1976

China has made great progress in thick coal seam mining, commonly characterized by longwall top-coal caving mining and single-pass longwall mining with a large cutting height. At present, the maximum mining thickness of longwall top-coal caving reaches 20 m while that of single-pass longwall mining approaches 8.8 m. The top-coal caving–related technologies have significantly improved the mining efficiency of thick coal seams and have also made a great contribution to the centralized underground mining of coal. Thus, the number of underground coal mines is greatly reduced in China. However, due to the increase of the mining height and the changes in mining operations, the overburden movement caused by the mining of thick coal seams is more intense, and the influence scope is larger, which brings a series of new problems on ground control of longwall faces. In order to enhance ground control and improve the mining efficiency of thick coal seams

Jul 28, 2020

By Licheng Zhou

The use of aquatic plants for the removal of heavy metals from wastewater has gained high interest. In this study, batch experiments were conducted to evaluate the adsorption of copper ions in aqueous solution by P. pectinatus L. under various conditions of contact time, initial pH of the solution, metal concentration and adsorbent dosage. The results showed that the maximum adsorption amount of copper ions by P. pectinatus L. was 22.60 mg/g when the initial copper ions concentration was 98.41 mg/L at pH 4.5. The Langmuir and Freundlich models were used to describe the adsorption equilibrium of copper ions on P. pectinatus L. and the adsorption followed the Langmuir isotherm. The adsorption kinetic was well-fitted with pseudo-second-order sorption equations.

Jan 1, 2009