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By E. H. Mulligan

THE ERRINGTON B-I mine is located on the Errington orebody of Steep Rock Iron Mines, Limited, at Steep Rock Lake, Ontario. In 1946, this orebody entered the shipping lists of the Lake Superior iron ranges as an open-pit operation. During the period 1946 through 1953, the mine produced a total of 9,000,000 tons of iron ?ore. In 1950, as the mine approached the economic limits for open-pit operations, ground was broken for an underground development to exploit the deposit at depth. The mine is designed for an ultimate production of 1,500,000 tons per year by the block-caving system of mining. The initial shaft is 1,200 feet deep and will produce or-e from the 700 and the 900 levels. The 1,100 level will be used as a drainage level and as a haulageway for waste rock, which is hoisted to surface by skip. Ore from the two production levels moves by a system of ?ore passes to a crushing plant located below the 900 horizon and is hoisted from this point to surface by conveyor belt. At the present time, all material handling on the levels is by tramming, but as tram distances increase conveyor haulage will probably be installed. The initial stage of the Errington B-1 development is expected to produce 6,000,000 tons of ore over a period of four years. The second stage will require deepening of the shaft and development of lowe1? production levels. The conveyor hoisting plant will be extended to serve these new levels. We visualize the mining of this orebcdy down to 2,500 feet by these methods.

Jan 1, 1956

By Jr. Koch

In the Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) phase of its National Uranium Resource Evaluation (NURE) pro¬gram, the U.S. Department of Energy (DOE) samples about 1400 sites for stream sediments in each two-degree quadrangle of the National Topographic Nap Series (NTMS) and about 1200 sites for ground or stream water. Through a geological/statistical analysis, we find that NURE data are useful for assessing the uranium resources of the NTMS quadrangles. Our computer-implemented System for Uranium Resource Evaluation (SURE) calculates a score for each NTMS quadrangle based on the HSSR, geologic, and radiometric data; we score the four Colorado quadrangles--Pueblo, Montrose, Durango, and Trinidad--that comprise the study area. We interpret the scores in terms of geology and the known occurrences, which include the Hanson ore deposit with reserves of 30,000,000 lbs. U308 and the Pitch mine with reserves of 1,740,000 lbs. SURE depends in part on distinguishing mineralized or metalliferous granitoids from barren ones through "geochemical signatures."

Jan 1, 1980

By H. M. FRENCH

ARC welding can be defined as a process whereby two A pieces of metal are brought together, heated to a molten state by the heat of an electric arc, and fused into one piece. There are several kinds of arc welding: the metallic arc, the carbon arc, the atomic hydrogen arc and the shielded arc methods. A short description of each, together with its major applications, will serve to distinguish between them. Metallic arc welding involves an arc drawn between a metal electrode and the material to be welded, called the work or the "parent metal." It may be further subdivided into hand and automatic welding, depending on whether the electrode is fed to the arc by hand or by motor drive. This form of arc welding can be applied to most welding operations. Exceptions to its use consist of applications where very thin metals are to be welded; where it is desired to join the work with- out adding metal; or where extreme ductility may be required:

Jan 1, 1930

By BHAMIDIPATI S. SASTRY, ANMAYA NAIK, ASIF AHMAD, Srivatsan Jayaraman Sridharan, ADITYA PANDEY

Wet kata cooling power (WKCP) as measured by a kata thermometer is a well-known heat stress index used in the mining industry. Although, over the years, several researchers proposed different heat indices and indicated limitations of the kata thermometer, WKCP is used in the South African gold mining industry due to its simplicity and rapidity of assessment. This paper presents a comparative analysis of the newly developed empirical expression for the WKCP and some of the more commonly used empirical models. For this purpose, WKCP measurements are obtained based on experiments conducted in a low-speed wind tunnel. Based on a regression technique, the analysis presented aims to assess the disagreement between the empirical model predictions and actual measurements. The correlation is also presented between WKCP and the well-established thermoregulation models using parameters from the low-speed wind tunnel experiments, including dry-bulb temperature (Td), wet-bulb temperature (Tw), barometric pressure (P), and wind speed (v). It is found that the proposed empirical model for the WKCP represents the bioclimatic interaction quite well under the specific parameters that defines the harsh thermal environment and air condition, such as metabolic activity, clothing of the person, and the velocity of the ventilating air in which the person is working. The statistical analyses performed show that the empirical model proposed for the WKCP produces satisfactory estimates of the thermal stress experienced under lower air velocities, light clothing, and higher metabolic activity rates.

Sep 2, 2021

By Mehmet Guney

Acceptable working environments in production areas and service openings of Mindola Mine on the Zambian Copperbelt are currently maintained with an air volume of 1000 cu m/s and 5500 kW of installed refrigeration plant. It is planned to open up additional deeper areas of the mine for future production. Temperature problems, due to the increased heat generation from various underground sources are recognized as potential hinderances to efficient production. Findings of research work indicate that the present total heat output of 58,000 kW will inevitably increase by the second five-year period of the deepening program to 52,900 kW and by the fifth five-year period to 63,200 k\V. Estimated WB and DB temperatures, representing the total heat generation in stope faces and development headings during these same periods are predicted to increase to 53.8/40.2 °C and 35.5/42.1 °C respectively. It is assessed that the nominal refrigeration capacity needs to be progressively increased to 9,000 k\V This paper deals with the thermal problems in Mindola Mine, current heat output calculations, future prediction of temperature and heat load in various working areas of the mine with the application of computer programs and interpretation of data in order to find the effective solution for long-term planning of ventilation and air-conditioning.

Jan 1, 1982

By ROLLIN THOMAS CHAMBERLIN

The studies herein reported were begun as a part of researches undertaken by the United States Geologü;al Survey looking to the more effcient utilization of the coal in the United States through the reduction of waste in its extnidion, and were continued as part of further researches having regard to the conservation of the fuel resources of this country and to the lessening of injuries and fatalities in coal mining. Among other phases of the general problem to be studied were the origin of the gas whidi escapes into coal mines, its modes of occurrence in the coal and rock strata, and the conditions governing its outflow into the mines. The subject of relative danger from destructive explosions due to gas and coal dust in different mines belonging to different coal fields was to be one of the principal lines of investigation. But this work was barely under way when the series of unusually disastrous explosions in the Naomi, .Monongah, and Darr mines of Pennsylvania and West Virginia, in December, 1907, afforded an exceptional occasion to observe the behavior of explosions on a large scale. Because of the opportunities for study afforded by these terrific explosions, the inquiry originally planned was d ¡verted to the more specific investigation of the conditions in tl10SC mines, and the examinations have been directed toward finding those qualities of gas and dust which were concerned in these explosions. The following discussion, therefore, consists essentially of a report on that subject; but it is far from being exhaustive, and is to be regarded as a preliminary outline of investigations which are still in progress. The first of the three mine explosions mentioned occurred in the Naomi mine of the United Coal Company, near Bellevernon, Pa., on Sunday, December 1, at 7.40 p. m. All the men who were within the mine at the time, fortunately only 34, were killed. Less than a week later there occurred in mines Nos. fì and 8 of the Fairmont Coal Company at Monongah, W. Va., the most disastrous mine explosion yet recorded in the annals of American mining. The mines were comparatively new and well laid out. Mine No.8 had been in operation only about two years and was the pride of the Fairmont Coal Company. Mine No.6 was first opened ahout four years earlier. In order to make it possible, in case of emergency, for either mine to be ventilated by the ventilating system of the other, the two sets of workings were connected underground. The F face heading of mine K o. 6 led direetly into No.2 north heading of No.8 mine. On Friday, Dcccmber 6, at about 10.30 in the morning, an explosion of unusual violcnce swept completely through both mines, pursuing its course throughout the numerous ramifications and bursting out of the two pit mouths, located It miles apart, nearly simultaneously. The slope of mine No.6 was only slightly damaged, but at the mouth of No.8 the destruction was very great. The fan was wrecked, the engine house was demolished, and mine timbers were blown across Monongahela River: As nearly as can be determined, 361 men were killed in the two mines by the explosion. .While the inspection of the Monongah mines was still in progress, on Thursday morning, December 19, at about 11.20, a similar explosion wrecked the Darr mine of the Pittsburgh Coal Company ut Jacobs Creek, Pu.; 238 men lost their lives in this explosion, which in number of casualties is second only to the :Monongah disustcr in the history of American mining. Of ull thc men in the mine at the , time of the explosion, only one mun, who happened to be within 100 feet of the ~iUrface on an old manway in a wet, unexploded portion of the mine, succeeded in escaping alive. The underground investigation of these mines was made in cooperation with Clarence Hall and ""Valter O. Snelling, of the United States Geological Survey, and James ""V. Paul, now of the Survey but at that time chief of the department of mines for vVest Virginia, to all of whom the author is greatly indebted for valuable assistance, suggestions, and advice. Mr. Paul will rcport on the nature of these explosions, the precipitating causes, their destructiveness, and the general cüliditions in these mines following the disasters. The present report is confined essentially to the laboratory examination of some of the explosive materials collected from these mines directly ufter the explosions.

Jan 1, 1911

By K. Stankiewicz

Projects as regards state-of-the-art mechatronic systems aiming at increase of safety in the mining industry and at improvement of coal production technologies, which have been completed at the KOMAG Institute of Mining Technology, are presented. These projects cover automation, monitoring and visualization systems, systems for implementation of artificial intelligence techniques, and database recording systems. iRIS system for electronic marking, identification, and recording of components of powered roof supports, which was implemented in 31 Polish mining enterprises, is presented as an example of the work directly associated with an increase of operational safety. Specialists from KOMAG, ELSTA, Ltd., and Silesian University of Technology in Poland, have developed flexible, configurable, and scalable system for data management, which refers to all fixed assets of mining enterprises, meeting the requirements of users as regards marking and identification of fixed assets. The system for control of roadheaders using intelligent algorithms, based on artificial intelligence techniques is also the example of innovative actions. This system aims at increasing the safety and effectiveness of teamwork due to a possibility of remote, semiautonomous operation. Introduction of artificial intelligence technology enables adaptation of roadheader mining system to the present mining-and-geological conditions. Moreover, work aiming at implementation of state-of-the-art system for control of mine jig?s beneficiation node, integrating machines and equipment in one system, is carried out as regards automation, information integration, and visualization in coal beneficiation process. Work on recovery and conversion of thermal energy, which is a by-product during operation of machines and equipment, especially mine diesel drives, is presented. Systems for energy recuperation are more and more important due to the necessity of continuous increase of power production efficiency.

Aug 1, 2013

By S. C. Tadolini, P. Mills

"INTRODUCTION This research produced a shotcrete formulation that extends beyond stabilization and can be used to restore the structural integrity of damaged infrastructure. The primary challenge was to develop a shotcrete or gunite with structural strength within a few minutes to prevent parasitic loading and allow ingress into damaged structures within a few minutes of the mix formulation being applied. This also applies to mining conditions where rapid support of progressive failures can minimize failure. An additional benefit was the discovery that the product had extremely high adhesion properties in addition to high flexural strengths. The approach to product design was the development of “single bag” dry mixes that are entirely self-contained, can be rapidly transported anywhere in the field or underground, and be deployed using simple equipment. Dry mix eliminates issues relevant to high shear water mixing, as water is added in the form of a mist at the point of delivery; thus low W/C can be achieved. However, as there is no onsite powder mixing, the product must have a high degree of inherent homogeneity. A commercial version of this material is currently offered as Minova’s Tekcrete Fast® product which has been successfully deployed in the mining industry and is currently being used in civil, construction and tunneling operations. The material can rapidly stabilize unstable ground in metal/nonmetal and coal mines. This paper described the technology development, product testing results and applications in mining and civil applications. BACKGROUND The original development of this product was to complete rapid stabilization of shock damaged structures, which falls outside the purview of normal construction and mining practices, due to the critical time issue and the nature of the damaged structure. The stabilization of damaged structures requires materials and equipment that can be rapidly deployed to place materials that have very rapid strength development. These materials need to be placeable at a distance to provide some degree of safety to the responders. In addition, the materials must be able to adhere to structural surfaces that have not been specially prepared and conditioned, and may also be highly fractured, dusty, wet, and quite possibly hot or extremely cold. The technology for the rapid delivery of large volumes of cementitious materials to vertical or even overhead surfaces currently exists. Pneumatic delivery (shotcreting) has been used in construction for over 100 years (American Shotcrete Association, 2014). Shotcreting has played a major role in structures like the Washington D.C. Metro subway system and been used in underground mining applications routinely to serve as part of the primary and secondary support system when used in conjunction with traditional roof bolts. Numerous rapid setting cements are commercially available. They are used for rapid repair of surfaces such as bridge decks, pavements, and commercial floors, as well as structural repairs of vertical and overhead surfaces. Few of these products are specifically marketed for use in shotcrete applications. The majority of rapid setting cements are based on, or at least contain, Portland cement as a principle component. Other components are added that help provide early strength, such as high alumina cement (HAC), organic polymers, chemical accelerators (which can also be added during concrete batching), and calcium sulfate hemihydrate (e.g. gypsum plaster) (Lea, 1971). Cementitious mortars prepared with some of these cements can achieve compressive strengths of 6.8 – 13.8 MPa (1,000-2,000 psi) within 1 hour. However, Portland cement mortar and concrete typically require many weeks of proper curing to reach significant levels of their ultimate strengths, even when used with set accelerators. Also, high early strengths require the use of large proportions of Portland cement in the concrete mix, which can lead to high heat evolutio"

Jan 1, 2017

"1.0 INTRODUCTIONThese Guidelines reflect the state-of-the-practice of the Deep Mixing Method (DMM) in North America. DMM is an in situ mixing process that breaks down the soil structure; injects binders, fillers and reagents into the soil; and blends them with the soil. DMM is also commonly referred to as Soil Mixing. The final properties of the treated soil in situ are a function of the composition of the native soils and groundwater, the binders introduced, the mixing methods and energy, and the conditions and time of curing. Treated soils generally have increased strength and stiffness and/or reduced permeability relative to the native soils.This document addresses DMM performed by rotating single and multiple axis mixing tools, rotating cutter wheels at the end of a rigid kelly bar, or trench mixing using a rotating cutting/mixing chain around the perimeter of a rigid bar. Binder may be injected through low or high energy (velocity) jets.The treated soils created through wet DMM are heterogeneous mixtures of binder, water, soil, and groundwater. Treated soils produced by dry DMM techniques are a mixture of binder, soil, and the water already present in the native soil.DMM applications described in this document include•,Earth retention•,Liquefaction mitigation•,Groundwater seepage control and containment isolation•,Bearing capacity improvement•,Deep foundations•,Mass stabilization and contamination containment•,Embankment, levee and dam strengthening, and stabilization•,Casing replacementThis document was developed to address deep foundations applications. Use of deep mixing for seepage control is not specifically addressed. The reader is referred to documents prepared by the U.S. Army Corps of Engineers for additional information. Shallow soil mixing and the use of DMM for stabilization/solidification of contaminated soils performed at depths less than 10 feet (3 m) are mentioned briefly. Jet grouting is not covered by these guidelines."

Jan 1, 2016

A study was undertaken to remove the Se from waste solutions using a raw form of the biomass called Iota Chips derived from the seaweed, Eucheuma spinosum. Removal of Se from solutions was investigated as a function of time, pH, conc. of Se in solution (0.1 to 100 ppm) and lota Chips to liquid ratios of 10-2 to 10-5. For solutions containing initial conc. of 0.1 ppm Se, with the addition of Iota Chips at a solid to liquid ratio of 10-3, the Se conc. decreased to 0.03 ppm in about 3 hours. Iota Chips absorption capacity to the Se and its application to the treatment of the metallurgical processing effluents are discussed.

Jan 1, 1992

By Leonard Sargeant

The Pocahontas Coal Field consists of eight mineable seams of low-volatile coal in southern West Virginia and Virginia. The deeper seams, especially the Pocahontas No. 3 and No.4 Seams, under heavy cover and below drainage are notoriously gassy. Methane in the Pocahontas Field is generally thought of as being confined in the coal itself, rather than in mud slips or clay veins. Furthermore, it is characteristic of Pocahontas coal to retain its gas until the coal is broken and removed from the solid. Because of this inability for gas to escape from unmined coal, entries developed around large blocks are seldom of significant value in bleeding off methane before pillar extraction begins. This is evidenced by the fact that it is not uncommon to find gas liberated during the mining of chain pillars and barriers which have been developed for several years. The Pocahontas Fuel Company develops almost all solid coal by conventional methods with shuttle car haulage. To provide the maximum productive capacity without compromising ventilation and safety requirements, the Company has adopted standards for ventilating 5, 6 and 7-entry sections.

Jan 1, 1960

By J. Jerome MacDonald, Stephen B. Flewelling

"In the base metals industry of today, operations required to continuously improve productivity and reduce unit production costs. Consistent with these goals is the improvement of the muck haulage cycle from open stopes with the No. 12 Mine.Existing haulage from open stopes occurs with LHD units experience at Brunswick indicates that LHD units have a higher unit cost per tonne mucked than loader-truck combinations when the haulage exceeds approximately 150 m.The reintroduction of open stoping at Brunswick made existing loader-truck combinations unsuitable. It was recognized that application of recent continuous loading technology could potentially result in significant unit cost savings and productivity increases.A review of the technology resulted in the testing of the Voest Alpine AL60 loader in the open stopes located on the 1000m Le vel. Testing began in January 1988 and finished in late November 1988. The test will provide experience as well as quantified production and maintenenace parameters f or the purpose of quantifying production unit costs and system productivity, ultimately resulting in a decision to further utilize or not utilize the loader as a primarymucking unit at Brunswick .INTRODUCTIONBrunswick Mining and Smelting Corporation Ltd. produces approximately 10500 tonnes per day from the No. 12Mine located 35 km southwest of Bathurst, New Brunswick Mining is the largest (single mine) producer of zinc in the world having mined over 52 million tonnes since 1964. Many years of production still remain with proven and probable reserves in excess of 90 million tonnes. Reserves grade at an average of 3.65% Pb. 8.99070 Zn, 99g/mt Ag and 0.32% Cu . The operation employs 1446 people with approximately 800underground including operations and maintenance staff.In the No. 12 Mine two major mining methods are presently utilized . The primary method is Mechanized Cut and Fill (MCF) accounting for approximately 6500 tonnes per day from four major areas. The remaining 4000 tonnes per day is produced from open stopes with the majority of 2800 tonnes per day being produced by the 1000 level.The 1000Level contains 30 million tonnes segmented into open stope blocks 30 m high, 15m and 30 m on strike , with a transverse width of 10m to 50 m (Fig. I). Stopes are organized on a primary secondary stope arrangement along strike. Primary stopes are undercut and overcut full size with the back fully cablebolted. All stope and lateral development is driven 4.0 m high. All stopes to date are flat bottom (Fig. 2). Primary stopes are filled with cemented rock- fill , secondaries with conventional rockfill, Haulage from the stopes is primarily with 8-yard LHD units ; mucking is approximately 50% conventional and 50% remote. Haul distance to date has averaged approximately 150m with current stope haul distances of approximately 300m. Haulage is presently to a small jaw crusher situated on the 1000 Level. From August 1989on, haulage will be to a set of ore passes feeding to a large gyratory crusher situated on the 1200 Level. Start up of the gyratory crusher corresponds to an increase in tonnage from 1000 Level to 4100 tonnes per day."

Jan 1, 1989

The extremely cold weather and heavy snowstorms of January and February in northeastern Pennsylvania--with frozen mining equipment, diminished preparation and lack of railroad cars--severely hampered the production and distribution of anthracite. As a result, the previous estimates for the 2 months have been revised. On March 1, 1977, at the Porter Tunnel of the Kocher Coal Company at Tower City, Pa., an underground flash flood, which apparently broke through the wall of an adjoining abandoned shaft, swept through the mine. As of March 9, 1977, four miners were reported killed, three injured, and five trapped in the wreckage. The Kocher Coal Company began operations at the Porter Tunnel in 1968 and has had no fatalities until this current tragedy. The mine employs 20 persons on the surface and 115 miners underground, producing 750 tons of coal per day. Of the 109 underground mining operations in the anthracite region, this is the one remaining large mine that employs over 100 men.

Jan 1, 1977

Minerals are a fundamental component of the Nation" material and economic base. Without a continuous supply of minerals to meet growing and changing needs, the basic character of our society would be very different. The importance of minerals to the United States was reemphasized by the Congress in I970 when it enacted the Mining and Minerals Policy Act, which stated that it is the continuing policy of the Federal Government in the national interest to foster and encourage private enterprise in (I) the development of economically sound and stable domestic mining, minerals, metal and mineral reclamation industries, (2) the orderly and economic development of domestic mineral resources, reserves, and reclamation of metals and minerals to help assure satisfaction of industrial, security and environmental needs, (3) mining, mineral, and metallurgical research, including the use and recycling of scrap to promote the wise and efficient use of our natural and reclaimable mineral recources, and (4) the study and development of methods for the disposal, control, and reclamation of mineral waste products, and the reclamation of mined land, so as to lessen any adverse impact of mineral extraction and processing upon the physical environment that may result from mining or mineral activities.,.

Jan 1, 1977

By Richard A. Walker

This report describes the development and performance of a multi-level, multi-function Calibration Light Source designed for field-calibration of a group of specific photometers. The Calibration Source is capable of providing ±35% accuracy calibrations at all of the following levels: 0. 05 foot-Lamberts, 6 foot-Lamberts, 6 foot-candles and 20 foot-candles. The Source was found to provide constant light output to within 1% over 50 hours of lamp operation and for line voltage variations of ±25%. It is compact and light-weight (11 pounds), and can be easily transported and used by one man in normal office environments (without requiring a darkroom).

Jan 1, 1976

By Ataç Başçetin, Hasan Çelt, Hüseyin Onur Dönmez, Kürşat Hasözdemir

Phenolic foams, known for fire resistance, show broader industrial potential, particularly in mining, through property enhancements. Adjustments to the formaldehyde-to-phenol (F/P) ratio, bio-based additives like lignin, and nano-silica improve foam strength and thermal stability. Density modifications allow foams to range from flexible, low-density forms to rigid, high-density supports. In mining, enhanced phenolic foams could reduce coal ignition risks by acting as oxygen-blocking barriers. Current findings suggest these foams offer viable, sustainable solutions for safety in hazardous environments. Continued development could make them essential for thermal and mechanical applications under extreme conditions. This paper aims to provide a comprehensive overview of the mechanical characteristics of phenolic foams, current enhancement strategies, and standardized testing methods used to evaluate foam properties.

Feb 1, 2025

By Westwater, J. S.

The Mather mine of The Negaunee Mine Co. embraces nearly all of Sections 1 and 2, T47N, R27W. within the limits of the cities of Negaunee and Ishpeming on the Marquette iron range of Michigan's Upper Peninsula. Operations of the Negaunee Mine Co., the stock of which is jointly owned by Bethlehem Steel Co. and The Cleveland-Cliffs Iron Co., are under the direction of the latter company. The opening of the Mather mine was described by C. W. A1len. Mather "A" shaft was completed to an initial depth of 2352 ft in early 1943. The shaft capacity of over one million tons yearly is in prospect of being realized by orderly development and mining, and sinking of the second or "B" shaft then started in accordance with previous planning. Mather " B, " also a vertical shaft, was designed as a twin to Mather "A" shaft and the sinking technique developed at Mather "A" was utilized in "B" shaft operation.

Jan 1, 1949

By D. Krippner, C. Nexhip, D. George-Kennedy, P. Gebski, R. Kaur, W. L. Ying

ABSTRACT Water-Cooled Tapblocks Are Essential Components Of Modern Smelting Furnaces. Uninterrupted Operation Of A Tapblock Is Critical For The Optimal Operation Of A Furnace. This Critical Function, Together With Exposure To Extreme Conditions, Drives The Need For An Efficient And Reliable Means For Tapblock Monitoring. The Main Objective Of Tapblock Monitoring Is To Help Optimize The Life Of The Tapblocks By Better Scheduling Inner Refractory Relining And Protecting Operators By Preventing Sudden Deterioration Of The Tapblock. A Taphole Acoustic Monitoring (TAM) System Was Developed To Meet The Above Requirements. This Paper Describes The Principles Of The TAM System And Selected Case Studies.

Jan 1, 2013

By Yi Yang, Xiuzhu Su, Wei Sung Ng, Shuiping Zhong, Miao Chen

With over 260 tons of gold reserves, the Shuiyindong gold mine is one of the largest Carlin-type gold deposits in China. A particular challenge in the processing of the ore is the presence of carbonaceous compounds, which can cause substantial losses in recoveries via the preg-robbing and adsorption of gold. To investigate the structural properties of the native carbon and to compare between different characterization techniques for such compounds, pre- and post-flotation mineral samples containing 0.9–4.8% non-carbonate carbon from the Shuiyindong mine have been examined via mineralogical and thermogravimetric approaches, as well as spectroscopic techniques, including X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine edge structure spectroscopy (NEXAFS), solid-state 13C nuclear magnetic resonance (NMR) spectroscopy, diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, Raman spectroscopy and preg-robbing measurements. NEXAFS and DRIFT yielded the most reliable results, indicating that 60–75% of the organic carbon in all samples consist of aliphatic alkenes with substantial unsaturated content, highly similar to activated carbon, with the remainder being graphitic and humic. Speciation by XPS was sub-optimal due to spectral overlaps between graphitic and aliphatic carbon, and between carboxylic and carbonate functionalities, while NMR spectroscopy could not provide reliable speciation of the carbon groups. The preg-robbing strength was strongly correlated to the aliphatic content and structural disorder in the carbon, while no such relationship was found with the graphitic and humic content.

Nov 29, 2021

By E. Z. Casassa

There has been a recent revival of interest in concentrated coal/water slurries as a substi¬tute for fuel oil or for coal/oil mixtures, particularly in electric power generation. The idea is not a new one. Coal/water slurries were transported by pipeline in the U.S. in the early nineteen-sixties, and the Black Mesa coal pipeline has been in operation for several years, while in Germany, coal/water slurries were being burnt for power generation in the early nineteen-seventies, as described by Merten and Höner (1972). Since coal is not a pure substance but a carbonaceous mixture, the different chemical and physical behavior of coal/water dispersions from different deposits must be understood in order to optimize the properties of the result¬ing slurry fuels. Since minerals which are minor constituents of coal may also strongly affect slurry properties, coal chemistry may vary considerably even within a single deposit. Thus it is unlikely that there will be a single formula for optimizing the slurry properties of all coals, and even the answer for coal from a single source may change with time.

Jan 1, 1983