Search Documents

By Z. Jin, D. DePaoli, P. Zhang

"Phosphogypsum is a byproduct created during the production of industrial wet-process phosphoric acid. This study focused on recovering rare earth elements (REEs) from a Florida phosphogypsum sample and investigated the effects of removing detrimental impurities such as phosphorus pentoxide (P2O5 ), uranium (U) and fluorine (F) during the leaching process. Experimental results indicated that REE leaching efficiency increased rapidly, reached a maximum and then began to decrease with sulfuric acid concentrations ranging from 0 to 10 percent and temperatures ranging from 20 to 70 °C. At a sulfuric acid concentration of 5 percent and leaching temperature of 50 °C, REE leaching efficiency obtained a maximum value of approximately 43 percent. Increasing the leaching time or liquid/solid ratio increased the leaching efficiency. The leaching efficiencies of P2O5, U and F consistently increased with sulfuric acid concentration, temperature, leaching time and liquid/solid ratio within the testing ranges. A fine-grain gypsum concentrate, sized smaller than 40 µm, was separated from leached phosphogypsum through elutriation, in which the P2O5, U and F content levels were reduced by 99, 70 and 83 percent, respectively, from their content levels in fresh phosphogypsum. IntroductionPhosphogypsum is a byproduct generated during the industrial wet process of phosphoric acid production, in which sulfuric acid is used to digest phosphate rock. Gypsum (CaSO4·2H2O), the main component of phosphogypsum, usually accounts for 65 to 95 percent of phosphogypsum by weight.There are small quantities of impurities in phosphogypsum, such as phosphates (H3PO4, Ca(H2PO4)2·H2O, CaHPO4·2H2O and Ca3(PO4)2), fluorides (NaF, Na2SiF6, Na3AlF6, Na3FeF6 and CaF), sulfates, trace metals and radioactive elements (Rutherford, Dudas and Arocena, 1996). Global phosphogypsum generation is estimated at 200 Mt/a (Parreira, Kobayashi and Silvestre, 2003; Yang et al., 2009), but only about 15 percent is recycled as building materials, agricultural fertilizers or soil stabilization amendments (Tayibi Choura and Lopez, 2009)."

Jan 1, 2017

MODELLING FOR DESIGN AND CONTROL AT KALGOORLIE NICKEL SMELTER Modelling at KNS has been driven by a need to have better tools to answer questions about control, design and optimisation of the plant. This paper describes a number of modelling tools developed for use at KNS and how the development of modelling tools fits with a design and control strategy. In the area of control, a thermodynamic model has been developed to allow process parameters to be calculated. The model allows for the automatic selection of data from a laboratory data base, desired operating set points are input and the operating parameters are calculated. The model has the ability to adjust the burner efficiency and the furnace heat loss depending upon conditions. To assist with the testing of proposed furnace design changes, various mathematical models of the burner and shaft have been created using PHOENICS. These models are particularly well suited to combustion heat transfer and flow aspects of both the burners and shaft. Validation of these models have been based on novel sampling and measuring techniques in the shaft and also by using scale and cold models. Overall plant energy and cost structures can be analysed using a flowsheet simulation, developed to evaluate potential alterations to the plant flowsheet. This model system allows the global evaluation of process changes.

Jan 1, 1993

By Kanhaiya Mishra, Phanil. K. Mandal, S. K. Behera, P. S. Paul, Prashant Singh, C. N. Ghosh

The techno-economic and social benefits of cemented paste backfill (CPB) resulted in its wide acceptance by the mining industry. The Ordinary Portland Cement (OPC) remains the key binder but to diminish its economical constraints, suitability of alternate binders has been examined worldwide. The present study aimed to investigate the effect of partial replacement of OPC with fly ash on the CPB’s strength and to determine the most optimal mix to achieve the required strength (1 MPa at 28 days of curing) at the most cost-effective way using the Bayesian network (BN). The CPB mixes were prepared at 72 wt.% solid concentration with mill tailings (87–91%), OPC (6–13%), and fly ash (0–4%), and instantly after mixing, fresh (slump, bleeding, density) CPB properties were measured. The strength was tested at 7, 14, 28, and 56 days of curing and initially analysed through traditional model. The traditional models follow the aleatory principle and are considered not appropriate for geotechnical engineering. Hence, the BN model was developed and tested. The reliability of two classifiers in learning model structure was compared which gives Naïve Bayes as the highest reliable tool. The CPB’s strength is most sensitive to the OPC content. The most consistent mix(s) is mill tailings: 87–88%, OPC: 9–11%, fly ash: 1–4%. Adding fly ash at 89–91wt% mill tailings possesses high failure probability of the CPB. The collinearity test indicates that the fines percentage and chemical composition of CPB’s ingredients are highly correlated with its slump, bleeding, and strength development.

Jul 14, 2022

By William E. Robinson

Why did it fail? My first reaction when assigned this topic was to say: because somebody "goofed"--then thank you all for letting me say those few words, then promptly sit down. All of you have been bandying this problem around for many years--so all of a sudden I should come up with the solution. Well, While I might not provide you with your particular answer, I think I can show you some of the resolutions to it. Somewhere along your path of experience you may have discovered that a good formula for starting a fight is to tell a group of dedicated (Nordberg Crusher) users they should be using (Allis-Chalmers), or a group of (Allis-Chalmers) 'users they should be a (Traylor). Now, if you really want a melee, get both groups together and tell them they should be using a (Stedman Cage Mill). This is one sure way you can learn how great minds arrive at logical, well thought-out conclusions, based on all the relevant facts. Why did it fail? I could go on for hours giving you specific reasons why. One of my engineering professors used to start his new class off each year by writing on the blackboard--four and two, then turn to the class and ask: What is the problem? One brave scholar would venture to answer 8. His head would shake no. Another would dare 6. Again, a head shake. Now that the ball had gotten rolling, a number would vocally decide it had to be two, which produced only another shake of the head--no. All of them had missed the question he had asked : What is the problem? What he had gotten ,were some of the possible answers to the problem.

Jan 1, 1977

By T. V. Johnson

The microstructural relationships in dolomitic fluxed taconite pellets were studied. The influence of basicity (in the range 0.75 to 2.1) and firing temperature (to 1340°C) on the grain structure, macrostructure, and mineralogical phase relationships are described. Extensive slag bonding of hematite grains begins at temperatures between 1220 and 1230°C, and results in fundamental changes in grain structure. Successive temperature increases result in little change in grain structure until 1340°C, when extensive coalescence of the hematite grains begins.' Increasing flux additions have little effect on grain structure but greatly influence pore character. The compressive strength decreases with increasing flux addition, increases with increasing firing temperature, and is related to the macrostructure of the pellet. The compositions of the slag phases are represented on the CaO-Fe2O3-SiO2 phase diagram, and the compositional path of slag development is described.

Jan 1, 1980

By Wilbert J. Huff

The organization of the Explosives Division is indicated by the accompanying chart (fig. 1). As this has been discussed in a previous report3/, it will not be considered further in this report. The activities of the various units are outlined below. I. INFLAMMABILITY OF GASES AND VAPORS4/ Determination of the Explosion Hazards of Combustible Gases and Vapors Found in Mines and Industries The Explosives Division maintains, at the Pittsburgh Experiment Station, a laboratory specially equipped for the determination of the explosion hazards of combustible gases and vapors. Of particular importance, is the determination of the chemical composition within which explosions may occur and beyond which there is no danger of explosion, combustion or inflammation. These limits, known as the limits of inflammability, as determined by this and other laboratories, have been compiled in Bulletin 279 of this Bureau. The last revised edition (1931) of this bulletin has been exhausted. Since it was published, the Pittsburgh laboratory has determined the limits of about 40 combustibles and has ascertained more precisely ant accurately many previously published limits.

Jan 1, 1938

By Daniel I. Carey

Current and potential dragline reclamation usage was evaluated for the U.S. coalfields based on data gathered and analyzed during field surveys, literature reviews and contacts with manufacturers. It was concluded that current mining plans have been adapted to federal and state strip mine and reclamation laws in ways which limit the potential for dragline reclamation systems at active mine sites. At abandoned conventional contour mine sites in steep-sloping areas such as central Appalachia, however, it was found that dragline reclamation systems have great potential application and may be the only practical solution to many reclamation problems. Alternative dragline systems were examined for restoring abandoned sites, and it was concluded that a tower excavator system offered superior characteristics and should be evaluated and developed under field conditions. A testing program was developed to provide a framework for the monitoring and analysis of cost, production and environmental data during a field demonstration of a tower excavator system.

Jan 1, 1981

By Rey B. Marquez

This paper introduces and outlines the implementation of Reliability Centered Maintenance (RCM) at Phelps Dodge Hidalgo Inc. By using a disciplined approach to the everyday maintenance functions, a proactive strategy is being developed which "raises the bar" for plant maintenance. The main objectives are: integration of Operations and Maintenance partnerships, transformation of maintenance practices from a reactive to proactive mode through the introduction of a progressive Predictive/Preventive Maintenance program (PDM/PM) paradigm changes, increased management support of maintenance functions, introduction of new indices and root cause analysis, updated; training, and definition of RCM components. RCM is the vehicle being utilized to reach the higher level of equipment availability and utilization. However, the ultimate goal is to venture beyond RCM and into the new frontier of Total Maintenance Management (TMM).

Jan 1, 1998

By K B. Bowley

This paper covers the application of a systematic maintenance plan by the Plant Engineering Department of Rio Algom Mines Limited, Milliken Division. The plan established the function of work study, developed and installed formal work planning and labour cost control procedures, and extended the existing preventive maintenance routines. In June, 1961, assisted by management consultants, a more scientific approach to maintenance was instituted. The emphasis was placed on the control of labour. The development and application of the primary control system was established with-in six months. Since then, the Department has operated for a year, consolidating the system. The procedure of the installation, the results achieved and the results to be expected will be discussed. JNTRODUCTION THE Milliken Division of Rio Algom Mines Limited operates a 3,000-ton-per-day uranium mine, in the Elliot Lake district of Ontario, which went into production in April of 1958. The lowest operating level is 3,000 feet below surface. Mining is carried out by open stopping, with planned pillar support and footwall haulage on rail.

Jan 1, 1963

By Frank G. Miller

Controlling natural-water drives to effect efficient and economic production of petroleum, through wells, from reservoir sands and rocks is a problem of major importance in the oil-producing industry. Water-drive fields are characterized by large quantities of mobile water under high pressure immediately below the oil in the flanks or extraneous parts of reservoir formations, Hence, the water, which is in fluid connection with the oil and a source of a large proportion of the energy available for moving it, advances up-structure to replace it. This phenomenon of water moving crestward into the oil-bearing parts of the reservoir and replacing oil is termed edgewater encroachment. The mechanism by which oil is flushed out and continually replaced by water as the hydocarbon content of the field is depleted must be understood if natural-water drives arc to be used successfully to, induce efficient recovery of oil from its reservoir rocks. Until recently, the function of water in the production of oil has been somewhat obscure and was not given the consideration it deserved in early petroleum production-research programs because of the greater importance associated with and the effort devoted to investigations concerning the relations of natural gas to production of oil. Thus, with virtually no fundamental information at hand, it is not surprising that at first edgewater was considered a necessary evil, and the manner in which it was dealt with depended largely on the experience of the operators. During the intervening years, however, practical information on encroachment of edgewater in oil sands has been widely disseminated as a result of studies of oil-field depletion, and many theories pertaining to petroleum-reservoir energy and performance have been advanced; these theories necessarily included consideration of edgewater as an integral -art of the reservoir fluids and a source of energy for propelling hydrocarbon fluids through the reservoir and to the surface of the ground.

Jan 1, 1941

By A. Gene Collins, Cynthia A. Pearson, Cathy J. Waters

The chemistry of selenium and tellurium is discussed , along with a method of preparing a synthetic oilfield brine , an oilfield brine sampling method , and methods for determining selenium and tellurium in complex oilfield brines . Selenium either can be reduced to the elemental form with sulfur dioxide and determined semiquantitatively by color comparison of the red amorphous form or can be converted to selenite and determined quantitatively by reacting it with 3,3 ' - diaminobenzidine and obtaining its spectral absorbance at 420 mu . Tellurium can be reduced to the elemental form with hypophosphorous acid , and the spectral absorbance of its red hydrosol can be measured at 400 mu . Less than 0.05 mg / 1 of selenium and 0.1 mg / 1 of tellurium can be determined by the described methods .

Jan 1, 1964

By A. M. Strachan

The arising and behavioural pattern of polonium-210 in the Capper Pass & Son Limited non-ferrous metal smelting and refining circuit is briefly discussed. The process developed for the removal of polonium from lead, solder and bismuth is discussed in detail, together with the essential personnel safety and environmental protection precautions which must be taken during the refining and subsequent storage of the active dross.

Jan 1, 1992

Entering June, U. S. producer pricing of 99.5 percent unalloyed aluminum ingot was divided at 53-57 cents per pound. The Kaiser Aluminum and Chemical Corp. took the initiative and raised its June 1 ingot values by 4 cents to 57 cents. Consolidated Aluminum Corp. announced plans to increase ingot prices by 4.5 cents per pound to 57.5 cents per pound effective May 15. Dealers increased their May ingot quotes by 1.5-2 cents to 50-50.5 cents. CADMIUM While producers in the United States kept May cadmium at $2.25-$2.50, dealers increased their quotes by 15-30 cents to as high as $2.15.

Jan 1, 1978

By Emanuele Osto

In late 2013, the installation of the world's first application of a break-through technology for rail hardening was started at Baogang Iron & Steel (Group) Co. Ltd. in Inner Mongolia, China, one of world's leading rail producers. The "Injector Dualphase Rail Hardening" (idRHa+) system was developed by Primetals Technologies and Centro Sviluppo Materiali S.p.A. (RINA-CSM) a Technical Center headquartered in Rome, Italy. Baogang was a key partner, providing its large expertise of premiumrail producer, including its experience with existing offline technologies. With a design based on thermal, mechanical and metallurgical models, idRHa+ can apply customized cooling protocols, so to obtain the desired microstructure and hardness distribution across the rail head, with a high degree of accurateness and operation flexibility. idRHa+ can be installed in inline or offline configurations. During 2014, the system was successfully commissioned at rail mill #2 in the city of Baotou, Inner Mongolia, and entered the regular commercial production. This paper gives an overview of the key concepts behind idRHa+'s design, the progression of its commissioning and testing till the ramp-up to consistent industrial operation. Derived from idRHa+ research and experience, other water-cooling technologies are available for different applications such as: quenching & tempering of medium-large sections, control of distorsion of merchant bars, quenching of stainless grades for improving the resistance to corrosion.

Aug 16, 2017

By V. L. Eardley-Wilmot

Diatomite as prepared for the market is a fluffy, white powder, remarkably light in weight-it weighs only 10 to 15 pounds per cubic foot, or one-tenth as much as sand. Being extremely porous and inert, it is in large and increasing demand for insulation and filtration purposes, as general filler, and for many other uses. Structure Structurally, diatomite is quite different from any other known commercial material. It is composed of myriads of microscopically small, siliceous shells of diatoms which belong to a group of flowerless aquatic plants called algae. When these plants die, the siliceous remains sink to the bottom of the water and form beds of diatomite. Over 8,000 species of diatoms are known, named, and tabulated. The intricate scroll-work and patterns on many of these are one of the marvels of nature, and yet so small are they that from 40 to 70 million separate diatoms may be contained in one cubic inch of material. However, the size and shape of these diatoms, which vary greatly (compare Figures 5 and 6), have an important bearing on the commercial use of the diatomite. The diatoms in the majority of the known deposits are so typical of that deposit that, after a micro-examination, an expert can usually tell not only from what part of the world, but also from what particular deposit, the sample has come.

Jan 1, 1931

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By Robert J. Evans

The monorail bridge conveyor (MBC) is a prototype continuous face haulage system that was surface tested and evaluated by the Bureau of Mines. The MBC consists of a series of cascading belt bridge conveyors suspended from roof-supported monorail track. Tests were conducted to determine MBC haulage capability, maneuverability, power consumption, and reliability using rigid and chain-suspended monorail track installations. Subsequent modifications to improve operation and reliability made during surface testing are described. Mining plans were devised to show potential MBC installations for room-and-pillar, longwall development, and shortwall mining sections. Compatibility tests were conducted with the Bureau's prototype hopper-feeder, to provide additional surge capacity and lump-breaking capability. Results from the surface test program, along with modifications to improve system operation and reliability, indicate that the MBC has the potential to perform success- fully in an in-mine trial.

Jan 1, 1987

By Raymond O. Dannenberg

The gas-combustion retort developed by the Federal Bureau of Mines at the Rifle Oil Shale Project near Rifle, Colo., is a continuous, gravity-feed retort. The heat required to convert the kerogen in the oil shale to liquid oil is generated by the combustion of product gas and carbonaceous residue remaining on the retorted shale after the kerogen has been converted to oil, gas, and residue. A study of the effects of the process variables on retort operation, product yields, and product properties is important to the successful solution of the problems encountered in the development of a satisfactory process. Statistical methods were used to design the experiments and analyze the effects of the rate of shale throughput, the composition of dilution gas, the height of the shale bed above the air entry, air-gas distributor design, shale size range, and the ratios of the flow rates of the various gas streams entering the retort to the rate of shale throughput.

Jan 1, 1960

By Mike Moody

"No matter what type of ore is being extracted from a mine, mucking with front loaders can be accompanied by wet fines that cling to every surface. Once loaded into a hopper or conveyer transfer chute, viscous material can quickly build up on the walls to create bottlenecks, clogging the chute and causing expensive downtime.Clearing material from hoppers, chutes, bins and vessels can be done using manpower and tools on hand, but safety experts recommend considering a solution that prevents exposing workers to potential hazards. Operators at modern mining sites, such as the Eagle Mine, located in Western Marquette County of Michigan’s Upper Peninsula, understand that using specialized equipment reduces worker exposure, offers the safest mode of production and provides the most cost-effective lasting results.“Safety is a top priority for us,” said Ted Lakomowski, lead reliability technician at the Eagle Mine. “When we experienced clogging and downtime at the processing mill, the crew naturally swung into action to resolve it, but we immediately sought a safer long-term solution.”Stope mining for nickel and copperOwned by Lundin Mining, a globally diversified base metals mining company headquartered in Toronto, ON, Canada, the Eagle Mine is the only primary nickel mine in the United States, producing 1.5 percent of the world’s total nickel production. The first operation permitted under Michigan’s Part 632 Non-Ferrous Mineral Mining Law, it opened in 2014 and is expected to produce 163 kt (360 million lbs) of nickel, 134 kt (295 million lbs) of copper and small amounts of other metals over its estimated nine-year lifespan.The company extracts approximately 2 kt/d (2,200 stpd) from the underground nickelcopper mine using a bench-and-fill stoping process. Accessed from the surface by specialized underground trucks, the vehicles carry about 45,400-kg (100,000-lb) loads through a 1.6-km (1- mile) long and 5.4-m (18-ft) diameter ramp shaft descending into the earth at a 13 percent grade. Stoping is a bottom-up method that involves systematically blasting columns of loosened ore that is then mucked by front loaders into trucks and backfilled using cemented and uncemented rockfill."

Aug 1, 2019

By Laurance L. Oden

Titanium-enriched smelter slag produced commercially by Quebec Iron and Titanium Corp., Sorel, Quebec, was evaluated as feed material for a process developed by the Bureau of Mines to prepare rutile. Glass-forming agents including P205, B203, and two binary mixtures were added individually to the as-received and preoxidized smelter slag, and the nonferrous tramp oxides were effectively partitioned into the resulting noncrystalline phase. Iron in the ferrous oxidation state was moderately soluble in the glass of reduced specimens but less soluble under oxidizing conditions. The solubility of iron oxide in phosphate glass exceeded the solubility of iron oxide in borate glass. Effective conversion of titanium oxide to rutile was not achieved in the high-iron commercial smelter slag, and 20 to 30 pct of the titanium remained as pseudobrookite, a mixed iron-titanium oxide.

Jan 1, 1973