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By P. Ramachandraraa, T. R. Anantharaman

THE technique developed by Duwez, Willens and Kle-ment' for rapid solidification of molten alloys in small quantities by ejecting them on to a highly conducting substrate with the aid of a shock wave has come to be known as "liquid quenching" or "splat cooling" in literature and has already been applied to alloys of many binary systems.' The very high cooling rates of the order of l060 to 1080 per sec obtained in this technique and the consequent drastic undercooling of the melt have led to such striking results as formation of new amorphous and crystalline metastable phases and extension of solid-solubility limits in many alloy systems. The cooling rates in these experiments can, however, be neither accurately measured nor effectively controlled and hence the occurrence of either more than one metastable phase or appreciable differences in constitution in splat-cooled alloys of the same composition cannot be ruled out.3 In fact, workers in two laboratories have reported formation of two different cubic metastable phases in liquid-quenched Au-Si alloys containing 17 to 20 at. pct si.4,5 The present note deals with some new and interesting results obtained in a Ag-21 at. pct Ge alloy and a Au-27 at. pct Ge alloy subjected to the liquid-quenching treatment at different cooling rates. Two alloys of nearly the same composition had earlier been rapidly solidified by the standard "gun technique" in the same laboratory and shown to solidify in nonequilibrium structures, viz., an hcp phase (a = 2.987Å;c =4.718Å) in the Ag-Ge system6,7 and both hcp (a = 2.885Å; c = 4.754Å) and tetragonal (a = 11.627A; c = 22.491Å) phases in the Au-Ge system.3 Apart from different substrates (copper and stainless steel), different melt temperatures (50º to 500°C above the liquidus), and different capillary sizes (0.4 to 1.5 mm diam) in the "gun technique", slower cooling rates of the order of l050C per sec were also obtained in the present work by replacing the substrate by water at room temperature in a modification of the technique due to Olsen and Hultgren.8 No attempt was made to measure the cooling rate in any experiment. The products varied from fine powder (>40 pct by wt—200 mesh) obtained by quenching in water to thin flakes and foils (11.0 sq mm to 4.0 sq cm) produced by splat cooling. They were subjected to the Debye-Scherrer method of X-ray examination in each case. In case of the Ag-Ge alloy, in addition to the expected metastable hcp phase,6 a coexistent tetragonal phase (a = 5.093,Å; c = 7.009Å) was detected in some experiments. Eight weak X-ray reflections from this phase could be identified, two of them being the same as reported earlier.7 With increase in the cooling rate, the dominant hcp phase seems to be first accompanied by traces of silver or germanium and then either homogeneous or mixed with traces of this new tetragonal phase. The splat-cooled Au-Ge alloy showed generally the expected hcp and tetragonal phases,3 but sometimes traces of germanium were also present. Further, two new tetragonal phases with the following lattice param ters could be clearly identified in samples quenched

Jan 1, 1970

By X Qiu

According to the temporal and spatial distribution of regional metallogenesis, thePacific Rim can be divided into four global metallogenetic systems. The Asia-Australia W-Sn metallogenetic belt is the typical representative of intracontinental metallogenetic systems. This belt resulted from Mesozoic and partly pre-Mesozoic tectonic magmatism, mainly related to S-type granite of crustal source that was generated by collisional orogeny combined with oceanic subduction in intracontinental and continental margin settings. Based on the concept of metallogenetic series, there is a group of mineralised ore types showing a definite spatial and temporal distribution from endogenetic to exogenetic. These metallogenetic series are widely distributed in the Asia-Australia W-Sn metallogenetic belt, and are well developed in Southeast China. Five metallogenetic series and two petro-minerogenesis evolution models have been established according to their tectonic settings, various types of granitoids and metallogenetic evolution.

Jan 1, 1995

By Gary A. Kingston

Rolled steel, steel forgings, and steel castings in the Pacific Northwest (Washington and Oregon) are produced principally in the Seattle, Wash., and Portland, Oreg., metropolitan areas. Steel-mill products are rolled from carbon and some alloy &eels by three companies into shapes such as reinforcing bar, rods, rounds, squares, flats, and hot-rolled strips; structural shapes, - such as angles, channels, and I-beams, also are rolled. Carbon and alloy steel ingots are poured and forged at a Seattle plant into ship shafting, drive shafts, billets, slabs, bars, rings, hooks, and other items. Static, shell, investment, and centrifugal castings are produced at 19 steel foundries in a wide range of steel specifications. All Pacific Northwest steel output is based on remelting steel scrap. Local iron ore might be used in the future to supplement steel scrap as a metal source. Ore reduction would probably be achieved by methods other than the blast furnace. Current melt-shop practice and problems are basically the same in Pacific Northwest steel plants as in cold-melt shops in other parts of the country. Quality steel production is receiving more emphasis in this region with the installation of modern analytical equipment and vacuum pouring and melting facilities.

Jan 1, 1962

By G. A. Brown

Major mining projects are developed with the assistance of lending institutions who provide hundreds of millions of dollars in funding over several years, and of course expect those funds to be returned with interest. Two Australian banks have adopted the Equator Principles, an emerging financial industry benchmark for assessing and managing environmental and social risk in project financing. Project financiers have encountered environmental and social issues that are both complex and challenging, particularly with respect to projects in the emerging markets of Asia-Pacific and elsewhere. There are many recent and historical examples of failures by resource companies to effectively manage their environmental, social, safety and security risks, some of which have caused the project to fail completely, and some of which have caused the temporary cessation of production. These events put the financial institutions' funds at risk through inadequate management capacity and non-compliance adversely affecting the ability of the borrowers to repay the loans. They can also reflect adversely on the reputation of the lending institutions. In assessing these risks, lenders are increasingly looking at the track record of the borrower in its country of origin and in other countries where it operates. Lenders are wary of companies that have one standard for operations in a developed country, where the regulatory environment may tightly control what they do, and another standard for operations in countries where the regulatory regime is perhaps less stringent. Lenders may require environmental and social reviews or audits to be conducted on their behalf by competent third parties prior to a loan being approved, and annually over the life of the relationship. The mining industry's concept of the unwritten `social licence to operate' is highly relevant in relation to the delivery of community benefits that are sustainable post-mine closure. This paper provides examples of recent practices that support financial viability and sustainable development, as well as examples of some failures that have put lenders at risk.

Jan 1, 2007

By Thomas E. Shufflebarger

Definition of glass sand prospects may be modified by constraints which range from demography to critically important product-control. Characteristics of usable raw materials, physical and chemical, are discussed; an ideal raw material is defined. Following field investigations and preliminary sampling, evaluation of selected prospects includes use of modern drilling techniques, viz.: core, percussion (air-hammer), auger, jet, rotary jet, split-spoon and other. Nearly complete core (sample) return is mandatory. Land-use regulations, availability of water and transportation continue to direct exploration in a major sense. But fitting a prospect to burdensome politics nay be considered a decidedly negative factor.

Jan 1, 1983

By J. B. Zachwieja

Cationic reagents have been utilized in mineral processing since the mid 1930's and are based upon fatty nitrogen derivatives. The initial commercial development was centered around a flotation collector capable of separating potassium chloride from sodium chloride - potash flotation. The first commercial sale for Akzo, known then as Amour and Company, was realized in the summer of 1940 to a potash producer in Carlsbad, New Mexico for the flotation of potash. The success of the potash flotation collector led to the development of other cationic mineral processing reagents. Flotation collectors for iron ore, phosphate, calcium carbonate, silica sand, feldspar, and other silicates materialized into a large commercial business. Another area that realized commercial success was the development and use of anticaking/antidusting reagents for hygroscopic salts, fertilizer mixes, and granular fertilizers. A more recent development has found use in the trona industry as a defoamer and crystal growth modifier during the crystallization of sodium carbonate liquors. A review of cationic reagent chemistry and applications will be given and the potential for new application areas will be explored.

Jan 1, 1994

By Stephan I. Zajac, Roger A. Blais, John B. Stubbins

THE iron deposits of central Labrador occur within a relatively small area, herein called the Knob Lake Iron Range, in which a northwest-trending series of low hills and ridges defines the height-of-land at the boundary between provinces of Quebec and Newfound-land. Approximately two-thirds of the deposits are in Quebec and the remainder in Labrador, with several deposits straddling the inter-provincial boundary. These deposits are being exploited in open-pit mines by the Iron Ore Company of Canada centered at Schefferville, Quebec. Since 1954 this company has produced more than 56 million tons of iron ore to become Canada's leading iron ore producer. With indicated reserves of more than 375 million tons of direct-shipping ore and large tonnages of iron formation amenable to beneficiation, this mining district is assured of a long life. This paper describes the Knob Lake iron ores and their geological settings and stresses the features that lead to a better understanding of their origin. The

Jan 1, 1961

By P. Dhar, H. R. Kota, M. Thornhill

A very high-grade calcite deposit located in northern Norway consists of CaCO3 ore with minor silicate and sulphide impurities. Cationic (Tallow-1,3-diaminopropane, Duomeen T) collector has been used in the purification of calcite by flotation with an aim of achieving calcite concentrate for its use in value-added products in a variety of industries. The feasibility of sulphide flotation from calcite by this cationic collector has been initially judged from Hallimond flotation and zeta potential on pure mineral systems and the results illustrate the removal of sulphide from calcite ore at neutral pH region. The adsorption mechanism of diamine on both the sulphide minerals was found to be the same by zeta potential studies. The variations in zeta potential are in good agreement with the adsorption of diamine molecular and ionic species as a function of pH. FTIR studies also showed the adsorption of diamine species in agreement with the zeta potential and Hallimond flotation results. Furthermore, the removal of sulphide impurities with selective flotation by diamine collector was performed in bench-scale flotation with the calcite ore and the results indeed showed that the calcite concentrate could meet the quality requirements for its use in the paper industry for coating and filler purposes.

By John A. L. Campbell

Surface dependent processes, such as froth flotation and flocculation, are important or potentially important techniques for combating some of the current major problems in coal preparation. In order to correctly apply or imporve a surface dependent process, it is of paramount importance to understand the interfacial phenomenon, especially the double layer properties, exhibited by the solid. The specific objective of this research was to determine the properties of the bituminous coal/liquid interface by an electrokinetic method, streaming potential, and to relate the findings, wherever possible, to the existing unit operations of froth flotation and flocculation. The electrokinetic properties of both the whole coal and its lithotypes were investigated. As part of the total investigation, the role played in the double layer by the reagents commonly employed in the surface dependent process was also established (1). These data will be presented at a latter date.

Jan 1, 1969

By Edward Martinez

Although the copper segregation process has been known as a method for treating oxide copper ores since the 1920's, the reactions involved in this process are still a matter of conjecture. However, the evidence turned up in a recent series of experiments at Asarco's Central Research Laboratories strongly indicates that some of the proposed reactions may not be occurring. Experimental work on oxide copper ores from the Sagasca mines in Chile led to the discovery of the copper segregation process in 1923. It was found that the reduction of the copper with coal at about 700°C occurred on the surface of the coal instead of remaining disseminated in the ore. The unusual behavior of the copper, which caused it to migrate from the ore particles to the coal, was traced to the presence of a small quantity of sodium chloride occurring in the ore. Further experiments with oxide copper ores proved that the presence of a halide, either occurring naturally or admixed with the ore, caused the copper to migrate from the ore particles and to segregate in the charge.

Jan 8, 1966

By E. D. Attanasi

Geologic resource assessments describe the location, general characteristics, and estimated volumes of resources, whether in-situ or technically recoverable. Such compilations are only an initial step in economic resource evaluation. Forecasts that assume that resources that exist in nature can be commercially produced as needed ignore economic constraints. This paper identifies, by example, the salient features of a geologic assessment that will assure its usefulness for economic analysis. These features are demonstrated with examples of coal resource assessments and coal bed gas assessments.

Jan 1, 2001

By J. P. McKinney

Benchtop experiments were performed, in which an electric field was used to enhance separation of water from phosphatic clay suspensions from a central Florida mine. A constitutive relationship was established that relates the increase in solids content to operating time and the applied electric field. An upper limit to the degree of separation was found to be a function of electric field, and the time required to achieve this limiting value was also a function of electric field. The energy requirement for removal of water ranged from 1.25 to 175 Wh/kg water removed as a function of the electric field. A mathematical model was developed that provided good agreement to the experimental values and served to validate the constitutive relationship.

Jan 1, 2011

By Y. Pan, P. Tukkaraja, R. BHARGAVA, V.V.S. VYTLA, S.J. SRIDHARAN

Panel caving is an underground bulk mining method that uses gravitational force to mine massive, steeply dipping and deep-seated ore deposits at lower operating cost. To control dust and gas emissions entering the production level during the extraction of ore from the draw points in a panel cave, relatively negative pressure is created in the cave by installing an exhaust fan in the exhaust drift located on top of the cave. As caving is a dynamic process, designing an effective ventilation system is challenging; therefore, estimating the airflow resistance offered by the broken rock inside the cave is critical. This study investigates the effect of changes in the bulk porosity of the broken rock on the cave airflow resistance using the computational fluid dynamics (CFD) approach. The results show an inverse relationship between the cave airflow resistance and the bulk cave porosity. The pressure-quantity characteristic curves presented in this paper provide valuable information for sizing and operating an exhaust fan used for a mature panel cave ventilation.

Nov 1, 2022

By Colin D. Jardine

Rapidly increasing energy costs and more rigid customer quality requirements necessitate improved control of pelletizing processes. With the introduction of dedicated microprocessor-based controllers, sophisticated control strategies are now possible. A recent application of this technology at Carol Project has resulted in fuel savings, improved pellet quality, and standardization of operating procedures. This was accomplished with no production loss by the use of a "building block" approach to design and equipment selection. Details of this approach and the results obtained are described.

Jan 1, 1982

By Albert L. Toenges

The purpose of this paper is to describe some of the methods and practices of mining coal mechanically where more than one shift is worked, with the view of determining the advantages and disadvantages of various types of equipment and mining systems now in use. This paper is in the nature of a progress report, and, as the number of mines discussed in it is limited, the conclusions drawn in the comparison of various systems are not final but may be revised after subsequent investigations. Physical conditions vary in different and in the same mining districts and determine, more

Jan 1, 1938

By C. A. Komar

The Bureau of Mines conducted oil-displacement tests in the laboratory with three water-in-oil and five oil-in-water emulsions that were created with ultrasonic energy at a frequency of 20 kHz and an acoustic intensity of approximately 100 watts per cm2. Emulsions of either crude oil or kerosine, brine, and 112 to 2 percent emulsifier were formed during 30 seconds of acoustic irradiation. Results indicate that ultrasonic energy induces greater and more uniform dispersion of one liquid in another in the presence of small amounts of chemi¬cal emulsifiers. When the emulsions were injected as a buffer slug before waterflooding, recovery of the oil-in-place was 8 to 22 percent greater than with conventional waterflooding in the test specimens, regardless of the con¬tinuous phase (oil or brine). The emulsions do not appear to be applicable to the Appalachian area; however, because the oilfields are too "tight," the clays in the formation remove the emulsifier from the displacing fluid, and not enough additional oil is produced, compared with recovery using conventional waterflooding, to warrant the increased operating costs.

Jan 1, 1969

By Erwin L. Zodrow

"The neglect of including the toxic metal mercury in the list of escaping elements (Zodrow, CIM Bulletin, September 1982, pp. 138-140) was pointed out to the author in a private letter by J.E. Rehder, dated September 21, 1982. I welcome this opportunity to present my preliminary mercury research data based on coal investigations supported by N.S.E.R.C and the University College.As mercury is a volatile element and liquid at room temperature, special analytical techniques are required to determine concentrations in whole coal. In the investigation, the coal is analyzed by flameless atomic absorption with a lower detection limit of approximately 10 parts per billion, which, however, is a function of the ash contents of the coals (personal communication, J.L. Brooker, XRAL, 1981).Coal seams of the Sydney Coalfield studied so far include: the Point Aconi, a thin shaly coal, the Upper Bonar, an overrider of the Harbour seam, and the Harbour, Shoemaker and McAulay seams, all of which are shown in stratigraphic succession in Figure 1. The seams have been channel-sampled taking 15-cm coal intervals as one sample for analysis. One channel sample has been investigated from each of the seams listed (two channels were taken from the Point Aconi seam), resulting in 38 samples. Table 1 shows the results, which include mercury contents, ash and total sulphur per sample interval. Figure 2 is a frequency distribution of the 38 determinations."

Jan 1, 1982

By Robin Burgess-Limerick

The introduction of automation to mining has great potential to reduce safety and health risks by removing people from hazardous situations. However, automation changes the tasks performed by people and may introduce new tasks. For the system to function optimally, these tasks must be designed taking human abilities and limitations into account. Humansystems integration refers to systems engineering processes that ensure that human-related issues are adequately considered during system planning, design, development, and evaluation. During procurement of automated systems, a human-systems integration program plan should be prepared that describes the human-systems integration activities that will be performed to address each of the six core domains of human-systems integration: staffing, personnel, training, human factors engineering, safety, and health.

Jun 16, 2020

By C. H. Samans, G. F. Tisinai, J. K. Stanley

The addition of nitrogen (0.10 to 0.20 pct) to Fe-Cr-Ni alloys of simulated commercial purity results in a real displacement of the u phase boundaries to higher chromium contents. The effect is small for the (Y + s)? boundary, but is pronounced for the (y + a +s)/(y + a) boundary. Although there is an indication of an exceptionally large shift of the n boundaries to higher chromium contents, especially in steels with nitrogen over 0.2 pct, the major portion of this apparent shift results from the fact that carbide and nitride precipitation cause "chromium impoverishment" of the matrices. The effect of combined additions of nitrogen and silicon to the Fe-Cr-Ni phase diagram is demonstrated also. Nitrogen can nullify the effect of about 1 pct Si in shifting the (y + o)/? phase boundary to lower values of chromium at all nickel levels from 8 to 20 pct. NItrogen can nullify this U-forming effect of about 2 pct Si at the 8 pct Ni level, but not at the 20 pct Ni level. The alloys studied were in both the cast and the wrought conditions. There are indications that the u phase forms more slowly in the cast alloys than in the wrought alloys if both are in the completely austenitic state. The presence of 6 ferrite in the cast alloys accelerates the formation of U. Cold working increases the rate of o formation in both cast and wrought alloys. THE major improvement in Fe-Cr-Ni austenitic alloys in recent years has been in the addition or removal of minor alloying elements to facilitate better control of corrosion resistance, sensitization, and heat resistance. One shortcoming of the austenitic Fe-Cr-Ni alloys, which never has been completely circumvented, is their propensity toward u formation. In the AISI-type 310 (25 pct Cr-20 pct Ni) and type 309 (25 pct Cr-12 pct Ni) steels, sufficient amounts of u phase can form, if service or treatment is in a suitable temperature range, to cause severe embrittlement. Also, there is a growing conviction that this phase may be contributory to some unexpected decreases in the corrosion resistance of certain of the 18 pct Cr-8 pct Ni-type steels. The present paper discusses the effect of nitrogen additions on the location of the (r+u)/d and the (y+a+u)/(y+a) phase boundaries in the ternary Fe-Cr-Ni system, for cast and wrought alloys of simulated commercial purity, and in similar alloys containing up to about 2.5 pct Si. The objective is to define compositional limits for alloys which will not be susceptible to u formation when used near 1200°F (650°C). An excellent review of the early studies of the u phase in the Fe-Cr-Ni system has been compiled by Foley.1 Rees, Burns, and Cook2 have determined a high purity phase diagram for the ternary system, whereas Nicholson, Samans, and Shortsleeve3 are- stricted themselves to a portion of the simulated commercial-purity phase diagram. Both groups of investigators show almost an identical position for the commercially significant (y+u)/y phase boundary. Further comparison of the work of the two groups indicates that, below the 8 pct Ni level, the commercial alloys have a decidedly greater propensity toward u formation than the high purity alloys. The two groups of workers agreed that both the AISI-type 310 (25 pct Cr-20 pct Ni) and the type 309 (25 pct Cr-12 pct Ni) steels are well within the (y+~) region and that the 18 pct Cr-8 pct Ni-type alloys straddle the U-forming phase boundaries. Nicholson et al.3 showed, in addition, that these boundaries shift toward lower chromium contents if greater than nominal amounts of silicon or molybdenum are added. The effect of nitrogen on the location of the s phase boundaries in the Fe-Cr-Ni system has not been known with any certainty. In 1942, an approach to this problem was made by Krainer and Leoville-Nowak,' but at that time they apparently were unaware of the slow rate of s formation in strain-free samples and aged their samples for insufficient times, e.g., 100 hr at 650°C (1200°F) and 800°C (1470°F). For this reason, it would be expected that their (y+ u) /y boundary would be shifted toward lower chromium contents (restricted ?-field) when equilibrium conditions were approximated more closely. Procedure for Studying the Alloys The alloys used were prepared in the following way: Heats of 200 lb each were melted in an induction furnace. A 5 lb portion of each heat was poured into a ladle containing an aluminum slug for de-

Jan 1, 1955

By R. R. Wells, G. M. Potter, R. Havens, W. W. Agey

"INTRODUCTION As part of the program of investigating possible domestic sources of manganese, ore-dressing studies were conducted at Salt Lake City, Utah, on five samples of manganese oxide ore obtained by mining engineers of the Bureau of Mines from the Havasu Lake District, California and Arizona.Two lots of radically different ores were procured from the Arizona Manganese claims 30 miles above Parker Dam, Mohave County, Ariz. One of the original 11 claims has been flooded by Havasu Lake, formed by Parker Dam. The claims are owned by R. H. Thompson, Parker Lumber Co., Parker, Ariz. The 2-ton lot of high-grade ""TA"" ore represented ore occurring as pyrolusite and psilomelane accompanied by a black calcite gangue in lenses along a series of fault planes in granite. A half-ton lot of low-grade ""TB"" ore was taken from a large lense of reddish iron-bearing material outcropping on another section of the property.A 2-ton lot of ore was taken from the Jones property, 8-1/2 miles southwest of Powell, Mohave County, Ariz. At the time of the investigation, the property was leased by J. H. Jones, of Oatman, Arix., from the owners, the Atchison, Topeka, & Santa Fe Railroad Co. The ore body was described as a re¬placement in a sandstone formation in a region that has been faulted extensively."

Dec 1, 1947