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By Abouzar Vakili

Longwall Top Coal Caving (LTCC), as the most attractive method for thick coal seams, has been suffering from insufficient geomechanical understanding for the past few years. Cavability without doubt is the most critical geomechanical issue associated with the top coal caving method. A discontinuum method has been used for comprehensive modeling of LTCC operation by using the Universal Distinct Element Code (UDEC). In addition Particle Flow Code (PFC) and Phase2 were used as support for the caving mechanics analysis. Although the previous researches of gravity flow in caving operations neglected the effect of continuous span expansion, it has been observed in this study that face advancement has a great impact on roof symmetrical behavior. The amount of symmetry fluctuates between different face distances. Horizontal displacement seems to be the best indication for roof symmetrical evaluations. Two critical caving conditions have been modeled and parameters such as horizontal displacement, caving angle and recovery rate have been compared thoroughly. Results show that unsymmetrical behavior on the roof is closely related to face stability.

Jan 1, 2007

By Eder Salazar

Como parte del desarrollo de sus operaciones de mina de cobre subterránea, la Sociedad Minera El Brocal S.A., desarrolló el método de minado tajeo por subniveles con pilares recorridas con el fin de incrementar su producción actual. En ese sentido, el presente texto señala la implementación de un método de minado conforme a las características geomecánicas del macizo rocoso del yacimiento.

Sep 12, 2011

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional ore-processing methods that will confine and permit controlled disposal of radioactive liquid wastes. Stream and ground water pollution from radio-active nuclides, principally radium 226 and thorium 230, in liquid wastes from uranium mills can be minimized by reusing the waste solution within the mill. Such reuse of waste solution in an acid leach-resin-in-pulp flowsheet was investigated in the laboratory. The process consists of acid leaching for dissolution of the uranium, sand-slime separation and countercurrent decantation washing for recovery of a pregnant slime slurry, and the use of ion-exchange resin for recovery of uranium from the slurry. Reuse of clarified barren effluent for washing in the simulated mill circuit was carried through 55 cycles. Dissolution of uranium from the ore averaged 97.5 percent. Washing efficiency of 99.9 percent was attained when using 4.35 volume tons4 of combined barren effluent and makeup water per ton of ore. Absorption of uranium from the pregnant slime slurry by an ion-exchange resin averaged over 99.9 percent.

Jan 1, 1962

The possibility that type 430 stainless steel can become sensitized during annealing after hot-rolling was studied by simulated cycles of continuous-annealing heat treatments, and by calculation of the carbon solubility. It was found that the lower-carbon steel could be sensitized at lower annealing temperatures than the higher-carbon steel, which is in line with plant experience. The difference in sensitization behaviour is ascribed to the lower rate of recovery of the lower-carbon steel during cooling, since recovery is sensitive to the grain size. At practical heat-treatment temperatures, austenite formation does not play a role.

Jan 1, 1996

By A. A. Remes

High precision on-line particle size distribution measurement of mineral slurries has recently be-come available. It provides new tools for the development of monitoring and optimization methods for mineral grinding and separation circuits. The paper presents the development work at the Kemi chromite concentrator plant of Outokumpu Tornio Works in Northern Finland. The Kemi concentrator processes annually 1.2 Mt of chromium ore. The products are upgraded lumpy ore and metallurgical grade concentrate. The concentrate is produced using gravity separation methods, preceded by a rod mill - ball mill grinding stage. The separation process performance is strongly dependent on the particle size distribution of the grinding product at the Kemi plant. Particle size distribution has a significant effect on the concentrate grade and recovery. Currently a new laser diffraction based on-line particle size analyser is used for monitoring the grinding product. The analyser system allows the measurement of the whole cumulative particle size distribution simultaneously. It provides a wealth of new measurement information for process control. A monitoring and optimization scheme for grinding and gravity separation based on the particle size information is presented. The goal is to minimize the production of fine slime, and subsequently to improve the concentrate quality and minimize chromite recovery losses. Data-based recursively identified linear PLS process models are developed for optimization purposes. The preliminary results of the monitoring system operation in on-line use are presented.

Jan 1, 2014

By l. Bokányi

The Tóth adsorption isotherm-model was derived and has been widely used for the inhomogeneous solid surfaces. The three-parameter isotherm incorporates the effect of the interaction between the adsorbed substances as well. All classic isotherms can be clearly derived from this one. Bio sorption is the sequestering of dissolved components, i.e. metals from aqueous environment by living or dead biomass. The mechanism of the bio sorption is rather complex and predominantly refers to the affinity of the chemical functional groups: acetoamido groups of chitin, structural polysaccharides, amino and phosphate groups in nucleic acids, amino, amido sulfhydryl and carboxyl groups in proteins, hydroxyls in polysaccharides, sulphates, etc. towards the soluted substances, i.e. heavy metal ions. The physisorption, as well as the micro precipitation also play a role in the bio sorption mechanism. The description of such a complex process can be done by a model reflecting this complexity. According to our experimental results obtained using algae and immobilised algae for the sorption of heavy metal cations, the most appropriate model for such a description is the Tóth-isotherm, the parameters of which can be interpreted. Flotation process is also a very complex one, the overall result of which depends on the partial results of many micro processes and parameters. The particle interaction which very often takes place in the flotation systems makes the phenomenon even more complex. The flotation kinetic model with particle interaction was already introduced by author in 1994 and further developed in 2000. In this paper based on the experimental results obtained with metallic particles in case of recycling flotation the applicability of the Tóth-equation as an alternative flotation kinetic model for the systems with particle interaction is proved. The applicability of Tóth-model in mineral processing demonstrates again its universal character and the great talent of the late József Tóth, great Hungarian chemist. Keywords : Toth isotherm, biosorption, Langmuir, Freundlich

Sep 1, 2012

By Norman O. Lotter, Simon Yu, Tony Deng, Antonio Di Feo

"Xstrata Nickel’s Raglan operation, northern Québec, achieved paymetal recovery gains in 2007 by switching the collector from potassium amyl xanthate to sodium isobutyl xanthate. To follow on from that position, Xstrata Process Support (XPS) and A. Di Feo of Raglan proposed that a mixed xanthate system be formulated and tested towards further performance gains. This work selected ethyl and isobutyl xanthates as the candidates. An optimized ratio of these was to be determined by a designed experiment. This suggestion was based on an abundance of published literature that reported mixed collector systems outperformed single ones. A partial factorial design was used to configure four test conditions and a mid-square for the flotation work. The testwork was conducted using High Confidence Flotation Testing. The raw data were analyzed and modelled by Design-Expert software. An optimum ratio of 1.6:1.0 by mass (1.32:1.0 in molar terms) of isobutyl:ethyl xanthate was determined. Without this modelling, the optimum ratio would have been missed. Results obtained with the new baseline flotation test using this optimized mixture showed a 3.3% Ni recovery gain in the bypass concentrate and more than 1% recovery gain for PGM over the single PIBX system. This system has been proposed for and accepted as a plant scale trial in the first half of 2010.INTRODUCTIONConcentrator OperationsMilling and flotation of sulphide ores ahead of smelting and refining is a common practice. This choice results in the larger and more variable paymetal loss in the production of saleable metal [Cramer, 2001]. For this reason, it is common to see an ongoing performance improvement programme at the operations level. When successfully performed, these e"

Jan 1, 2010

By Sandro Griza

Neste estudo, foi analisado um segmento de perfil em “U” que rompeu em serviço. O perfil compunha uma estrutura metálica em treliça que sustentava uma bandeja de construção civil. Foram realizadas análises de fratura, análises de caracterização do material e estudo de rigidez do perfil. O perfil rompeu por sobrecarga estática porque foi instalado do lado inverso. Isto desfavoreceu a rigidez da estrutura.

Aug 16, 2017

By A. B. Kinzel

IT is with sincere appreciation and a deep sense of responsibility that I accept the honor of delivering the Howe Memorial Lecture. In our time metallurgical research has delved into phenomena ever more complex in character, so that much of this work must be done by organized teams. We, of the Union Carbide and Carbon Research Laboratories and the Electro Metallurgical Co., are truly a team and the lecture which is to follow is due largely to a few of the outstanding members of that team here cited and well known to you in their own right: John Lamont, whose work deserves special recognition, Walter Crafts, William Forgeng, William Binder, Robert Fowler, and David Swan. Thus it is a fitting pleasure to accept this honor for the research institution which I represent. Henry Marion Howe was truly inspirational and his breadth of view was such that he could use either the method of rigid proof or implied mechanism to further the broad understanding. But perhaps his outstanding characteristic was his sound judgment and his ability to weigh observations. The following is replete with observations and judgment as to their implication. We would like to feel that it is the type of dissertation which Howe, himself, would have enjoyed. Chromium carbides in stainless steel have, in a sense, been a key to the progress of the stainless steel industry. Brearley's first stainless steel, containing approximately 0.30 pct C, was successful because it differed from previous Fe-Cr alloys in that the carbides were present in such amount and form as to provide the stainless and cutting properties. Again, the 12 pct Cr die steels with a carbon content of 1.5 pct or more achieved their properties by virtue of the form and distribution of the chromium carbides. In the straight chromium steels with from 12 to 25 pct Cr, chromium carbide amount and distribution are once more the determinants with respect to physical properties and corrosion resistance. In each of the cases just cited the role of the carbide is in essence similar to that of iron carbide in carbon steel and this story is so well known that we need not dwell on it. In the austenitic stainless steels, the chromium carbide plays only a minor positive role with respect to mechanical properties, and for corrosion resistance the objective is to achieve maximum homogeneity. Thus the tendency has been to ever lower the carbon and correlatively the chromium carbide content of the austenitic steels. Today stainless steels with carbon less than 0.03 pct are beginning to find their true place, and this is being aided in major degree by our Company's introduction of a new type of ferrochromium having negligible carbon. The role of carbon in these austenitic steels has long been recognized, and a truly enormous amount of research has been devoted to the subject. Much has been learned about corrosion resistance, but the attack on the problem from the point of view of carbide precipitation and the nature thereof has left much to be understood. Because of its fundamental importance to the future of stainless steels, further study of the mechanism of carbide formation in austenitic steels is of interest. In the 18-8 Cr-Ni steels, which are typical of the austenitic class of steel, carbon is soluble in the aus-tenite to the extent of approximately 0.15 pct at 1832°F (1000°C). The solubility becomes less with decreasing temperature, so that at 1652°F (900°C) the solubility limit is approximately 0.06 pct, at 1472°F (800°C) it is about 0.03 pct, and at 932°F (500°C) it is approximately 0.01 pct. Obviously this is the ideal situation for the classical precipitation phenomenon. It is true that, in a sense, 18-8 austenite resulting from annealing is in a metastable state, and the phenomenon of ferritic precipitation from this austenite should be considered. However, in a so-called fully austenitic 18-8 steel this is secondary with respect to the carbides and can be neglected. A wide variety of chromium carbides is known. Only one chromium carbide, Cr,,C,,, frequently referred to as Cr,C, has been found in unmodified low carbon 18-8 steel. This, fortunately, simplifies the study of the precipitation phenomena. For this study an A.I.S.I. type 304 stainless steel of commercial quality was selected. Analysis showed C 0.07 pct, Mn 0.49 pct, Si 0.33 pct, Ni 9.34 pct, Cr 18.91 pct, and N 0.033 pct. As expected with this composition the steel was homogeneous after annealing except for a few pools of ferrite, which were disregarded in that their location was not coincident with subsequent carbide precipitation areas. On corrosion testing the steel was normal and typical of good commercial quality. Specimens 1/2xlx4 in. were annealed and subjected to precipitation heat treatment for 100 hr at 100" temperature intervals from 1000° to 1500°F and for ten selected intervals ranging from 5 min to 64 hr at 1300°F. These blocks were then cut into small pieces for metallographic studies. The first problem

Jan 1, 1953

By Walter R. Hibbard

ALTHOUGH extensive pole figure studies have been reported by Brick1 and others2,3 showing preferred orientations in rolled and annealed 70-30 alpha brass, and by Hermann and Sachs4 in 70-30 alpha brass cups, comparatively little information has been published on textures in drawn 70-30 alpha brass tubes. Crampton5 reported a (110), [III] texture in drawn brass tubes based on selected individual X ray photograms following the method of Norton and Hiller,6 but the extent and ease of developing this texture and the annealing texture have not been reported and pole figures of these structures were not found in the literature. The present investigation was further stimulated by the possible influence of textures on the mercury stress-corrosion cracking of brass tubes. According to Snoek,7 iron-nickel alloy sheet with a strong cubic texture was more resistant to corrosion than a randomly oriented sheet. Crampon5 reported that single crystals of 70-30 alpha brass drawn into tubes did not crack after 24 hr s in a standard mercurous nitrate test. Edmunds 12 found that single crystals of 70-30 alpha brass did not crack in a standard mercurous nitrate test but did crack when subjected to ammoniacal vapor. Wassermann reported a similar failure of a single crystal of brass in ammonia. A tube with a strong texture might approach single crystal behavior and tend to resist mercury cracking if the differences in orientation between adjacent grains were sufficiently slight. PREPARATION OF SPECIMENS Crampton's5 tubes drawn 28 pct reduction in area developed a slight degree of preferred orientation while in tubes drawn 48 pct it was more marked. Based on this information, in order to obtain specimens with markedly different degrees of preferred orientation but with the same final draw, two sets of 70-30 alpha brass tubes were made following the mill schedules shown in Table I. The final draw involved a large reduction in outside diameter, and a ratio of reduction in area to reduction in outside diameter similar to that reported by Crampton,5,10 to cause mercury cracking of brass tubes. The brass contained 71.31 pct copper, 0.01 pct lead, 0.01 pct iron and zinc by difference. DETERMINATION OF POLE FIGURES A 6-in. length from each tube was rotated rapidly by an electric stirrer in 25 pct nitric acid until the gauge was reduced to 0.003-0.005 in. The tubes were carefully cut longitudinally and the walls gently flattened. They were further etched in 25 pct nitric acid to 0.0015 in. thickness and (III) pole figures were determined using copper K-alpha radiation in the manner described by Brick.1 The three general types of pole figures

Jan 1, 1947

By N. R. Billette

In 1982 and 1983, a study was undertaken to analyse the applicability of Elbrond?s analytical model to suit the needs of Lake Asbestos of Quebec in their computerized open pit planning and scheduling strategy. The immediate goal was the assessment of the optimal allocation of trucks and the determination of the extra cost of in-pit blending. Data from 45 tonne trucks was used to estimate the mine capacity based on a fixed assignment policy. The tonnage yielded by the analytical model was compared with the results of a simulation program. Another point that the study high- lighted was the definition of efficiency parameters for the haulage system: shovels-trucks-crusher. The efficiency, both of the utilization of financial resources and of the operations, for the overall system reaches optimal values in very precise conditions for the number of pieces of equipment in operation. Such a parameter is proposed as a standard for the definition of an optimal number of trucks and shovels in operation. Deviations from this optimum do occur in a well-planned system for qualitative goals. These can then be quantified in terms of costs to the mining company.

Jan 1, 1986

By T. E. Warren, K. W. Bowles

"IntroductionTHE PROBLEM of producing synthetic liquid fuels from coal and other raw materials is of increasing importance in Canada as well as in the United States. This is due, to a large extent, to the continually increasing demand for gasoline and other liquid products which are now obtained solely from petroleum. The United States has reached a position where domestic supplies of crude petroleum must be augmented by imports and Canada is still a long way from self-sufficiency. In the event of war, there might well be an immediate need to find supplementary sources of liquid fuels. It is, therefore, expedient to consider alternative sources of production now -well in advance of the time when supplies of petroleum may prove inadequate to meet requirements.The purpose of the present paper is to give a short review of the history of liquid fuel production from coal, to describe briefly the research sponsored by the Federal Government on the coal hydrogenation process, and finally to evaluate the present status and future trend of the synthetic fuel industry, with special reference to necessary research work.History of the Oil-From-Coal IndustryThe history -of coal liquefaction began in 1913, in Germany, with the work of Frederick Bergius. His first approach to the subject was not deliberately planned."

Jan 1, 1952

By A H. Clemens, T A. Moore

This paper discusses a number of technical issues related to marketing coal. It outlines how the results of research undertaken in New Zealand and overseas can help producers address a range of technical factors that impact on production costs and marketability. The paper also discusses trends in coal utilisation for power generation and how new technologies may require coal with different characteristics. Research and development into options for CO2 sequestration are discussed including carbon storage in forests, and removal of CO2 from flue or fuel gas in power stations, and its disposal.

Jan 1, 1997

By I. I. Inculet, M. A. Bergougnou, J. D. Brown, R. M. Quigley, D. K. Faurschou

"Coal from Hat Creek, B. C., has been successfully beneficiated to remove ash while retaining calorific value by a dry electrostatic separation process using a fluidized bed for triboelectrification. Two samples of Hat Creek coal used in the beneficiation experiments have been characterized particularly with respect to their mineral and clay content. The calorific value recovery exceeds the simple dry coal recovery because of the heat lost in altering the clay minerals of the ash fraction during burning. Recoveries and ash contents of the beneficiated coal are comparable to recoveries by water washing, but the dry process avoids the potential water pollution problems.IntroductionProposals have been made which suggest an interim Canadian coal production target for the end of the century which will require a four- to fivefold increase over the 1977 production. This implies a nominal annual growth rate of about 6070 to achieve a production rate of 115 to 140 million tonnes/year. Whether or not this target is realistic, it is becoming increasingly evident that coal must be utilized more fully on a world-wide basis. The crisis in Iran has provided the latest stimulus to renewed interest in Canadian coals for domestic use and export.The emerging new era of coal utilization for fuel and chemical feedstock will not, however, generally tolerate the level of coal technology which prevailed prior to the availability of abundant cheap oil and natural gas. Economic, environmental and resource management considerations will necessitate, for example, the use of improved methods of beneficiating coal. Continued development and application of conventional processes, principally aqueous, involving heavy media and cyclones will solve many of the problems. However, less conventional processes may be preferable or necessary in certain applications."

Jan 1, 1980

By George R. Huebner

The present mine at White Pine has been extracting low grade copper ore by mechanized room-and-pillar methods for approximately eleven years. Increasing depth of mining is decreasing the extraction ratio. It is desirable to mine a higher grade product by extracting values only and increase recovery of the available natural resource. These factors led to the consideration of a caving method such as longwalling. GEOLOGY The White Pine orebody consists of two mineralized shale horizons separated by a relatively barren zone of shale and sandstone. These gently dipping sediments lie at the base of the Nonesuch shale formation and are of late Precambrian age.

Jan 12, 1964

By J. L. Nebreda, Z. Fan, J. B. Patel

"A380 alloy has been widely employed to produce thin-wall components via high pressure die casting (HPDC). During HPDC processing, there is a significant problem of property variation even with the very stable and precision automated casting procedure. The enlarged variation lowers the component performance and affects the steady and uniform property distribution along the whole component. In this study, high shear melt conditioning technology was developed and applied to the melt prior to pouring into the shot sleeve. Experimental results show that with application of intensive melt shearing, the variation of elongation was decreased from 21.8to 13.9%, and yield strength variation was reduced from5.5to 3.6%. The improved property variation is attributed to enhanced nucleation both in shot sleeve and the die-cavity, and to the improved distribution of porosity and secondary phases as a benefit of high shear induced grain refinement. With application of high shear, large number of the Spinel phase (MgAl2O4) particles with double size distribution in average diameter of 80and 300nm were formed. Due to the good orientation relationship and small misfit between alpha Al and MgAl2O4, the particles act as the effective nuclei in shot sleeve and die cavity, respectively.INTRODUCTIONA380 alloy had been widely used for produce automotive components by cold chamber high pressure die casting(HPDC) processing, due to its relative good mechanical properties and cast ability performance, and more important most of A380 ingots were produced by recycled Al alloys. Therefore, to promote utility of A380 will contribute to reducing emission of CO2and to the lightweight of automotive industry as well. When cold chamber HPDC was employed to produce the components, the mechanical properties of A380 alloy always have a distribution range (named variation herein), or in other words the properties were not stable. The reason was ascribed to the typical solidification characteristics occurred in HPDC processing. During HPDC processing, there are three steps of melt movement. The first step is that the melt was poured into shot sleeve at temperature of about 680°C, in which shot sleeve was preheated by few shots of melt filling, or by heater. During step one, the first solidification of melt was happened in shot sleeve and about 20% solid made of coarse a-Al grains was formed(Li, Xiong, & Guo, 2016).Such kind of grains will retain in the final products and deteriorate the properties variation. The second step is that the melt was forced moving forward slowly by plunger at about 0.2–0.3m/s until the liquid melt front to the inner gate of mold. The third step is that the melt moved very fast to complete the filling of die cavity and refilling the solidification shrinkage by fast movement of plunger about 2–3m/s. The second solidification was occurred in die cavity and fine a-Al grains will be formed by high cooling rate at about 500–1000°C/s. From the solidification point of view, the grain size was dominated by nucleation and growth. When HPDC was employed to produce components, the melt quality becomes the priority factor to control the solidification process as the other casting parameters were kept at the same."

Jan 1, 2018

By R. S. French

THE purpose of this paper is to present data that have been obtained during the past two years concerning the effects of prior cold-work and temperature and time of anneal upon the recrystallization and grain growth of 70-30 cartridge brass. It was desirable to study certain of these phases so that an accurate picture of the principles of the subject could be shown. The work is not intended to provide explicit annealing data, but to provide material examples that may help to clarify analogous problems concerning this alloy. Specifications often set limitations upon the grain size of annealed materials because of the importance of grain size upon subsequent manufacturing operations. It was, therefore, worth while to study the variables that affect the recrystallized grain size of this material. C. H. Mathewson and A. Phillips,1 W. R. Webster,2 and others have presented annealing characteristic curves of this alloy. A recent typical curve presented by R. S. Pratt3 is shown in Fig. I. The tensile properties and grain sizes are shown as functions of the annealing temperature. Such curves serve as a useful guide in determining the physical properties of annealed material, but as they are made generally under carefully controlled laboratory conditions they do not indicate the performance of metal annealed in a mill muffle, where conditions are different and the amounts of metal require necessarily longer heating times and temperatures. Study of the effect of time and temperature upon grain growth and subsequent recrystallization was made with a coil of metal having the following analysis: 70.04 per cent copper; 0.007 lead; 0.007 iron; 0.00 tin; 0.00 silicon; 0.001 nickel; 0.000 phosphorus; balance zinc. The sample coil was obtained from metal that had been rerolled from hot-rolled mill stock, and was received at 0.228-in. gauge, soft, with a grain size of 0.125 mm. This material was then rolled 43.5 per cent to 0.125-in. gauge and annealed to a 0.053-mm. grain size. In this condition, samples were cut and used in all of the experimental work reported in this paper. TIME The first study was of crystal growth at a constant temperature over a moderate length of time. Material was cut from the stock coil at 0.129-in. size and rolled 75 per cent hard to 0.032-in. gauge. From this piece small samples were cut ½ by 2 in., suitable for grain-size determinations. Twelve samples were placed in an electric furnace uniformly across the width, approximately an inch from the floor, A thermocouple was wired to the center sample, so that the approximate metal temperature could be followed. At various

Jan 1, 1944

By John T. Ryan

DEFINITE improvement in its accident fatality rate in the coal-mining industry was recorded during 1941, based on preliminary figures for the period from January through October. Total production during this ten-month period was approximately 91 percent of the total production in all of 1940. The ten-month accident rate for both bituminous and anthracite mining in 1941 was 2.15 killed per million tons of coal mined, compared with a rate of 2.66 for the full year of 1940. The bituminous rate decreased from 2.55 in 1940 to 1.99 in ten months of 1941, and the anthracite rate from 3.62 to 3.53 in similar periods. The decrease is more apparent for the bituminous branch of the industry, as the high figure in 1940 was due to seven major disasters which brought death to 276 men. The same number of major explosions during ten months of 1941 caused only 64 lives to be lost. The severity of the explosions has been lower this year but a definite need still exists for reduction in this type of accident.

Jan 1, 1942

By George M. Fowler

DURING 1937 the subject of mining geology was probably given more attention and more mining geologists were usefully employed than at any previous time. Of the many contributing factors the most important were: (1) a higher degree of prosperity in many countries, (2) a. better understanding of geologic phenomena, and (3) the apparently diminishing reserves of several important minerals. Mining companies have come to look upon geology with a growing appreciation of its aid in the more effective exploration and exploitation of mineral deposits. Most of the larger and more active companies have one or more geologists permanently attached to their staffs and some have well organized and efficiently managed geological departments. Even the smaller companies, who feel they cannot afford to employ a geologist on a permanent basis, are seeking the advice of competent men in this field with increasing frequency. One of the most significant trends has been the growing tendency to base exploratory work on more thorough geologic studies instead of empirical "hunches,"on which so much off the work in the past has relied. Likewise, mining companies are apparently more willing to expend larger sums on the basis of geologic possibilities in a district.

Jan 1, 1938

By Herman D. Mendoza

A rapid recovery/recycling process was introduced utilizing the surface-chemical properties of finely dispersed mercury and alumina (Al2O3) fibers in aqueous environment. The conventional method of amalgamation or .ball milling. involves the mixing of a substantial amount of mercury to collect free gold during the grinding stage. In effect, a portion of the mercury is transformed into minute droplets that readily float and disperse in the amalgamation effluent. The fine droplets of mercury in the dispersion readily attached onto the positively charged macroscopic alumina fibers (i.e. = pH 9.8) at conditions pH 3 to 10. When an effluent from settling procedure after an amalgamation-grinding stage is passed through a column-bed packed with alumina fibers, maximum collection of negatively charged finely dispersed mercury occurred at pH 3 to 6. The collection/attachment efficiency was 99.5%. The collected droplets of mercury, which are left in the column-bed of alumina fibers, were subsequently rinsed with alkaline solution at pH 10 to 11.5. At these conditions, both mercury and alumina fibers carry negative surface potentials and resulted in the partial detachment of mercury from the alumina fibers. The detachment efficiency was only 30-35%. The attachment/detachment mechanisms in this study were analyzed using the DLVO theory.

Jan 1, 2003