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By B. D. Pandey, M. S. Kim, B. S. Kim

The recovery of Sn from used Pb-free solder (Sn, 3~4 % Ag, < 0.9 % Cu, < 1.2 % Pb) has been investigated by electrorefining in sulfuric acid solutions containing small amount of hydrochloric acid. This involved preparation of the anode material by melting and casting the used solder followed by refining. During electrorefining, dendritic tin was deposited on stainless steel cathode. Increasing the amount of hydrochloric acid up to 0.3 mol /L in the electrolyte enhanced the current efficiency to 92.2 % and the enrichment ratio of silver to 94.3 % in the anode slime which was otherwise 84.7% and 81.6 % in absence of HCl, respectively. The electrolyte containing hydrochloric acid has also prevented the precipitation of tin oxide in the bath. In the scale-up experiment using 1.6 kg anodes, 84.3 % current efficiency and close to 100 % Ag enrichment ratio were obtained, while the purity of electro-refined tin was over 99.9 %. The energy consumption of the winning process was found to be 0.151 kWh /kg-Sn which is competitive as compared to commercial tin electrorefining processes.

Jan 1, 2014

By R. M. Caitlin

QUITE a number of years ago in looking for basic facts, it seemed obvious, in view of an unquestion-able supply of raw material and an extensive requirement probable in the near future, that the funda-mental requirement of any shale-oil industry was mass production &apos;by a continuous process. This decision greatly simplified matters, as it eliminated all considera-tion of externally-heated retorts, and all batch processes, which only utilize a part of the capacity of the interior space because, unless the ashes are removed as rapidly as formed, the space occupied by them is dead, instead of being occupied either by shale in active distillation or in drying out and heating up preparatory thereto. A second imperative and basic necessity soon appeared as a natural sequence, namely, the fixed carbon of the spent shale must be utilized to supply the heat for the eduction of the oil. PRODUCTION OF THE CRUDE As the production of the crude oil is the first and most important step in the utilization of oil-shale, being the only source from which the multitude of possible by-products can come, each by a special treatment of the crude oil, I will devote the time allotted to me to the subject of crude oil production-its cost expressed in terms of tons treated per man per shift. The costs of mining the shale and refining the crude shale oil vary with local conditions and are not specially influenced by the source of the crude. But the cost of distilling the shale in terms of tons per man shift seems to be the basis of any proper comparison of costs. After considerable experimenting, ranging from laboratory tests up to and including quantities of fifteen to twenty tons, it was evident that a plant might be made up of an indefinite number of units operating in concert. The economic size of the units, however, would .have to be determined by experiment. The general theory of our process contemplates a regulated combus-tion of the fixed carbon in the spent shale, in its incan-descent condition after all the oil has been driven out of it; and a transfer of the resultant heat to the mass of raw shale above.

Jan 1, 1927

By E. D. Gardener, Byron O. Pichard

"Methane, frequently called fire damp or marsh gas, is very well known to coal miners but to thy average gold miner it means nothing, as it is not associated generally with the rock formations in which gold is found.We have recently been conducting a study of mine air in typical gold mines on the Pacific Coast, and out of five California mines in which the air was sampled, three showed methane. Each of these three mines, referred to below as mines A, B, and C, have had accumulations great enough to be ignited. An authentic report from another California, gold mine, which has not yet been sampled, states that recently the superintendent was seriously burned by the ignition of a pocket of gas. This mine is later mentioned as mine D.Mine A is an old mine which had been abandoned for several years and permitted to fill with water. It has been unwaterad recently, and is now being developed at greater depths. During the unwatering, gas bubbles formed on the water and upon being ignited burned freely. It is reported that two men were seriously burned from accidentally igniting the gas. Samples of the bubbles on analysis showed high percentages of methane. Since the mine has been unwatered, no trouble has been experienced through gas being ignited. However, out of a total of six air samples which we took recently in scattered working places, all showed small amounts of methane, the methane content being 0.06, 0.04, 0.05, 0.04, 0.04 and 0.07 per cent, respectively. When these samples were taken methane was not suspected, but its general presence in the mine air indicates that it is being given off constantly."

Dec 1, 1921

By Neil Rowlands

Particle liberation studies are commonly used in the determination of the proportion of locked and liberated phases in ground ores at various stages of mineral processing. These studies may range from a qualitative assessment of a polished specimen in an optical microscope to a full quantitative analysis of the liberation characteristics of fine grained complex sulfide ores using scanning electron microscopy and high level image analysis. However, the conversion of quantitative data to meaningful information on a mill operations level is by no means a simple task. This paper reviews the errors inherent in the SEM/Image Analysis technique and looks at the various methods available to minimize errors in data collection.

Jan 1, 1992

By A P. Brown

Access arrangements required with landowners and occupiers; relaxation on size of permits; lack of confidentiality for information provided; one-stop shop under RMA, removal of standing; plethora of controls; post-closure; funding for long-term security.

Jan 1, 1997

By Y. Q. Zhang, S. S. Peng

Numerical modeling was used to design the pillars and bolting plan for a mine with weak roof and multi-seam stress condition. Previous mining experience, pillar/roof yielding and in-situ horizontal stress were considered in the models. By modeling the upper seam yielding and vertical stress transfer, a multi-seam influence zone was obtained. Appropriate pillar sizes were designed for conditions with and without upper seam stress influences. Roof support for the track and belt entries, using fully-grouted resin bolts and cable bolts, was proposed and implemented in the model. The bolting plan was evaluated under the weak roof condition.

Jan 1, 2004

By David Regalado

En los últimos años se presentaron pérdidas en el proceso de ejecución de chimeneas principales (por derrumbes y rehabilitaciones) en Unidad Minera Orcopampa. Este artículo muestra cómo se viene superando el problema con un proyecto basado en el conocimiento de la geología del terreno y la aplicación de conceptos y herramientas de geomecánica, de forma tal que la ejecución de una chimenea principal —bien sea para ventilación con Raise Bore o Raise Climber (Alimak)— cumpla su función y perdure a través del tiempo.

Feb 28, 2019

By F. K. Letowski

Leaching of zinc sulphide concentrate by nitric acid which is simultaneously regenerated by oxygen in the reactive froth has been investigated. The reactive froth was formed by a recycled zinc sulphate electrolyte containing nitric acid, a mixture of gaseous 02 and NOx, entrapped in the foam and particles of the zinc concentrate suspended in the foam. In the reactive froth the multiple regeneration of nitric acid proceeded owing to the encapsulated oxygen and amount of nitric acid used can be considerably lower than in the continuous liquid phase. 93 to 97% of zinc was extracted to a solution containing 30 to 409/1 HNO, during 40 to 60 min of leaching in a batch reactor without regeneration of nitric acid. 50 to 100% of the consumed nitric acid was regenerated during continuous leaching in froth carried out in the ‘flotation column’-type reactor at 80 to 90°C and under pressure of 100 to 200kPa. The rate of HNO, regeneration in the froth was proportional to oxygen pressure and inversely proportional to nitric acid concentration in the froth. A two-stage process flowsheet is proposed. In the first, the reduction stage, removal of nitric acid from the leach solution directed to standard purification and electrolysis is carried out by its reduction to nitric oxide using fresh concentrate in the froth. In the second, the oxidation stage, nitric acid is continuously regenerated by oxygen in the froth.

Jan 1, 1995

By Albert E. Ketler

The AirBoss*200 is a unique ambient airflow sensor with important improvements in accuracy, especially in the critical low end, 0-61 m/min (0-200 fpm) where MSHA regulations apply. All solid state, its design is rugged, and there are no moving parts or delicate filaments. An on-board microprocessor calculates air velocity, linearizes and corrects for temperature, while driving voltage and current loop analog outputs to .3 meters/minute (1 ft/min) resolution. Recent developments also cover both positive and negative flow directions. A hand held computer is available to readout data and to adjust stored range selection, alarm set points, calibration data and the speed of response. Installation in hazardous areas is covered by MSHA Classes G, H and L.

Jan 1, 1993

It is possible to closely simulate the product sizing distribution from an industrial rod mill by the correct choice of parameters in laboratory batch milling. For laboratory batch rod milling, changes in per cent critical speed and per cent rod volume cause the product sizing distributions to move in parallel at a constant slope. For ball milling, larger sized media in batch milling grind more coarse material giving a closer simulation to the industrial rod mill product. Changing the feed size distribution by removal of coarse particles or addition of fine particles changes the product sizing distribution, but would not normally be practiced in laboratory testing. These data should be applicable to many instances where laboratory simulation of an industrial product size distribution is required.

Jan 1, 1998

Coal bursts are one of the least understood yet the most critical hazards in underground coal mines. The ground motions induced by seismic events can trigger unstable failure of coal and rock mass and degrade the surroundings of an excavation. Therefore, the characteristics of ground motions should be fully investigated for an improved burst risk management. This paper analyzes ground motion features of a longwall panel from a typical underground burst-prone coal mine in China. The results showed that most of the ground motions on roadways were hardly initiate coal bursts due to insignificant energy input to the damage. The intensity of ground motions in near-field zone were nearly 20 times higher than those in far-field zone. The strongest vibration on roadway was induced by a coal burst with energy of 28,600 kJ, which can cause ground motion of 0.77 m/s and equivalent dynamic stress of 14.69 MPa. The findings of this paper can improve the assessment of seismic risks and its management.

Jan 7, 2020

By Dave Tahija

"Many investigations are being performed with the goal of removing carbon dioxide from the atmosphere and permanently storing it in geologically stable settings. At the same time, carbon dioxide in the form of dissolved carbonate is steadily accumulating in the world's oceans. Both carbon dioxide sequestration and oceanic accumulation are constrained by the aqueous thermodynamics of the carbonate system. These constraints are illustrated using the STABCAL computer model to generate potential-pH and aqueous distribution diagrams of seawater in contact with various pressures of carbon dioxide gas. STABCAL diagrams and titration simulations are also used to model some potentially useful cation-carbonate sequestrationsystems.IntroductionAtmospheric carbon dioxide concentrations have risen dramatically in the past couple of centuries and are rising still, primarily as a result of human activities, especially the burning of fossil fuels. Increased atmospheric carbon dioxide concentrations have been implicated as a main cause of global warming but have other effects as well.Rising levels of atmospheric carbon dioxide result in increased concentrations of dissolved carbonate complexes in water, including the oceans. These dissolved carbonates interact with other dissolved substances, altering overall seawater chemistry, most noticeably causing lowered pH levels.Some of these chemical changes are observed directly, for instance the general drop in oceanic pH, [1], while others can be inferred and predicted using thermodynamic modeling. The chemistry of dissolved carbonate in seawater is not especially intricate, as such chemical systems go, but neither is it simple enough to be worked out on the back of an envelope. Interactions between the several simple carbonate species and all the major dissolved cations in seawater should be considered, as well as the effects of competing anions, especially chloride and sulphate, since they are much more abundant than carbonate in seawater."

Jan 1, 2011

The flotation of nickel sulphide minerals is normally difficult in the presence of serpentine minerals due to the coating of serpentine particles on the nickel mineral surface. To improve the flotation, dispersants such as polyphosphate and carboxy methyl cellulose are normally used to remove the slime coating. However, in the flotation using high ionic strength process water, these dispersants are invalid due to their ionic nature. In this study, a new type of non-ionic dispersants, Pluronic triblock copolymers were examined with an objective of improving the flotation of ultrafine pentlandite (a nickel sulphide mineral) in the presence of lizardite (a serpentine mineral) in saline water. Three Pluronic triblock copolymers varying in solubility and hydrophile-lipophile balance (HLB) values were studied by flotation tests, settling tests and froth measurement. It was found that two of the copolymers improved pentlandite flotation against lizardite, and one copolymer deteriorated the flotation. The effect of Pluronic triblock copolymers on the flotation was actually linked to their dispersibility and foamability, which were governed by their physical properties. The two copolymers with a higher solubility or HLB value produced more stable mineral suspensions and more stable froth in the flotation resulting in better nickel grade and recovery in both rougher and cleaner flotation. Keywords: ultrafine particle, flotation, slime coating, dispersion, saline water, triblock copolymers

Sep 1, 2012

Some 15 years ago, Dr. Adolf Schmidt, director of the Magnetic Observatory in Potsdam, Germany, developed an instrument, which was a modification of Lloyds balance, for the measurement of the vertical component of the earth&apos;s magnetism in the field. There was a keen demand for this because (1) it was desirable to have a field instrument that would measure the component of the earth&apos;s magnetism which stands in the closest and simplest relation to the configuration of the subterranean magnetic formations-the vertical component; (2) it was desirable to have an instrument that was not only more sensitive but also more reliable than the existing vertical magnetometers (the dip needle, for instance). The application of the magnetometer in oil geology demanded such an instrument, because the magnetic disturbances produced by most types of magnetic formations associated with the occurrence of oil (salt domes, faults, anticlines with crystalline core, etc.) are too small to be detected with the ordinary dip needle. The writer can prove, by some investigations recently made for the U. S. Bureau of Mines, that these instruments may be used also to very great advantage in mining, because they are capable of measuring anomalies which are as great as twice the normal strength of the earth&apos;s magnetic field. Even for such anomalies, the field balance is more advantageous than the dip needle. First, the instrument rests on a firm support and can be adjusted in the proper azimuth, which insures measurement of the vertical intensity only, without a part of the horizontal intensity, which is very important for the interpretation. The readings give the vertical intensity in linear terms and not as a function of an angle; and the field balance is insensitive to temperature when used with scale values that are adequate for the determination of large anomalies. In another phase of mining, the gold placer work, the field balance has also shown excellent results for which the dip needle is not adequate. What has been said about the dip needle holds also, though to a lesser extent, for two other types of vertical variometers recently used, the Tiberg balance and the Thomson-Thalen magnetometer.

Jan 1, 1929

By P. D. P. Hamilton

IT is perhaps obvious to most individuals who are interested in the mining industry that a producing mine has been subjected to several phases of engineering attention. In this paper it is the author&apos;s hope that a thoughtful survey of these various engineering phases will emphasize certain points of value and interest which may sometimes be overlooked. The points which we will bring out are being made in an analytical sense and are not in any way a reflection on any individuals or organizations which might see in these illustrations a similarity co chair particular conditions. In other words, we are drawing on our general experience to illustrate the points which we chink are worthy of mention, and which we believe are of a type sufficiently frequent co be emphasized. It is well co point out chat, in this paper, we are not concerned with the relative importance of such theoretical questions as to whether or not a geologisc is more important than a prospector, or the office manager than the surface foreman. We are, however, interested in analyzing the various types of engineering experience required in the bringing of a mining enter-prise from the early prospect stage in co-production, and their importance to the project as a whole. In order to simplify our analysis of the subject, it has seemed best to outline a simple mining organization. In using the terms &apos;industry&apos; and &apos;business&apos;, we feel chat frequently those engaged in mining do not always appreciate that mining is actually an endeavour, or a business, which has the same economic fundamentals as any other business. In the mining industry, the field and producing engineering are counter-parts of the research and production phases of any other type of business. Once this is realized, it is fairly obvious that mining, like any other industry, is a matter of economically acquiring raw materials, processing them, and finally marketing the resultant commodities as favourably as possible. The points may be discussed in a little more detail as follows.

Jan 1, 1938

Anticipating the increasing importance of establishing working conditions on a scientific basis, the Department of Labor created the Working Conditions Service. This service is distinct from that performed by the Mediation and Conciliation branch, which deals with working conditions and industrial relations as controversial issues between employers and employees. The work of the Service is conducted through three coordinated divisions; Division of Industrial Hygiene and Medicine, Division of Labor Administration, and Division of Safety Engineering. The Division of Industrial Hygiene and Medicine will develop standards of sanitation and medical practice in industries. The personnel of this Division is detailed from the United States Public Health Service. The Division of Labor Administration will advise employers as to employment systems and labor management policies, and assist in putting into operation standard policies.

Jan 2, 1919

By Virgil A. Marple

The objective of this contract was to investigate time-integrated and real-time methods for determining the diesel exhaust particulate concentration in underground mines, in particular, coal mines. The microorifice uniform deposit impactor (MOUDI) is recommended for obtaining the time-integrated measurement of the size distribution. The mass concentration of diesel exhaust particles can be obtained from the particle size distribution of mine aerosols. On a mass basis, diesel exhaust particles are primarily in the submicrometer size range while coal dust particles are larger. Size distribution measurements made in the laboratory and in three underground coal mines exhibited two distinct modes with the diesel exhaust particles in the smaller particle mode and the coal particles in the larger particle mode. The point of separation between the two modes occurred in the 0.7 to 1.0 pm size range. The separation was found to be independent of mass fraction of the diesel exhaust particles, particle concentration and sampling site. Methods recommended for further consideration as real-time monitors of diesel exhaust aerosols in mines are photometers and filter pressure drop techniques. A preclassifier would be required in both cases to separate the larger dust particles from the sample. The Metrex Mineral/Diesel Photometer should also be investigated further once the electronics problems are eliminated.

Jan 1, 1986

By Stuart McTavish

"Noranda's Goldstream mine is a 1,500 ton per day copper-zinc mine located 60 miles north of Revelstoke, B.C.The orebody which contains 3.69% Cu and 2.69% Zn was discovered in 1972. Construction of the mine and mill was completed in 1982 and start up was achieved in May 1983.This paper will describe the flowsheet and related equipment 1n the crusher and mill, in particular the dewatering section where two Larox pressure filters are used to dry the concentrates.INTRODUCTIONThe Goldstrean property is located 60 miles north of Revelstoke, B.C. in the Goldstream River Valley (Figure #1). It was discovered during the construction of a logging road in 1972. Exploratory drilling was initiated in 1975, and in 1976 a portal was collared to obtain underground data. Samples were taken from the underground workings for metallurgical bench tests and a pilot plant run.Due to economic conditions, the decision to go into production was delayed until 1980. Concentrator construction and underground development progressed simultaneously during 1981 and 1982, and were completed by the end of 1982. Start up of the concentrator was achieved on May 2, 1983.The ore typically contains about 40% sulphides, which are chalcopyrite 10%, sphaletite 6%, pyrrhotite 20%, and pyrite less than 5%. The sulphide minerals have a high degree of intergrowth. Most of the sphalerite occurs in micron sized grains which are embedded in the pyrrhotite and, to a lesser degree in the chalcopyrite. There is also some fine dissemination of the chalcopyrite in the pyrrhotite. The waste rock is made up of about 30% quartz, 20% guange silicates, and 10% carbonates. The ore has a specific gravity of 3.2 and a natural pH of 8.2."

Jan 1, 1985

By W. T. Millar

Field reconnaissance and laboratory tests an clay from South Windsor, Hartford County, Conn., indicate that the clay is suitable for lightweight aggregate raw material. Exploration of the deposit supports the conclusion that the reserves of clay are sufficient for economical mining operations to produce lightweight aggregate. Preliminary tests indicated that the clay has a short bloating range. Initial expansion occurred at 2,000° F, and at 2,100° F the clay was slightly overfired and sticky. Rotary kiln tests verified the preliminary data, and these tests showed that the clay would make a good lightweight aggregate if the processing temperature and the kiln feed sizes were closely controlled. Lightweight concrete made from the processed aggregate had properties comparable to those of concrete made from a commercial clay aggregate.

Jan 1, 1964

By John D. Foulkes, David A. Curtis, Robert L. Lagace, John L. Rothery

An investigation is made of the feasibility of developing compact transmit antennas and/or other means to efficiently couple VLF to MF band radio energy between portable wireless communication units in coal mines. The completely wireless communication ranges between two portable radios equipped with practically-sized reference loop antennas in representative coal mine environments are estimated. Antenna technology is assessed with respect to transmit moment, range, intrinsic safety, battery and wearability requirements to deter- mine the most suitable antenna types for use by miners. It is concluded that air-core bandolier loop antennas, and perhaps ferrite-loaded loop antennas, having peak transmit moments of about 2.5 ampere-m5 will be the most effective antenna choices for portable units. This choice, however, will not allow the range goal of 1350 feet to be attained in mines having unfavorable signal attenuation and noise environments. Rectangular air-core loops are compared with grounded horizontal-wire and vertical-wire mode exciters for fixed station applications. The potential for significantly increasing the wireless communication range by inductively coupling to communications and power lines in a mine is evaluated and found to be considerable based on theoretical coupling equations. Lastly, the theoretical performance of a hybrid noise cancelling diversity receiving technique that utilizes both the electric and magnetic field components of the ambient noise to improve the receiver output signal-to-noise ratio under certain adverse conditions is estimated and shown to be favorable when the magnetic and electric field noise components are highly correlated.

Jan 1, 1977