Search Documents

By J. E. Pahlman

Spontaneous oxidation and combustion of sulfides and resultant fires are serious problems in underground mines. The Bureau of Mines has con-ducted fundamental thermal gravimetric analysis (TGA) research to deter-mine the mechanisms and factors governing the rate of low-temperature pyrite oxidation, and to identify possible inhibitors to spontaneous oxidation and combustion. The mechanism of low-temperature pyrite oxidation was found to be topochemical, meaning that the oxidation process is controlled by the chemical reaction at the interface between pyrite (FeS2) and iron sulfate (FeS04)' An activation energy of 8.9 kcal/mol FeS2 was obtained for oxidation of minus 500-mesh pyrite in an atmosphere of 60 vol pct water vapor and 40 vol pct . Water-vapor content of the atmosphere was found to be the critical factor in the rate of spontaneous oxidation of pyrite, with a water-vapor content greater than 20 vol pct needed for accelerated oxidation. An atmosphere of pure oxygen resulted in negligible oxidation. The rate of pyrite oxidation is also greatly affected by the particle size of pyrite. Pyrite-oxidation rate increased drastically for particles less than 40 ~m. Room-temperature pyrophoric behavior was observed for freshly ground unoxidized pyrite (55 pct minus 5 ~m) upon exposure to air. Addition of water-adsorbing materials such as activated alumina (Alz03) decreased the rate of pyrite oxidation.

Jan 1, 1986

By Daniel Eduardo Parodi

Para acompañar el plan de aumento de producción de slabs de Siderar, fue necesario proyectar una nueva unidad separadora de aire para incrementar la generación de oxígeno, nitrógeno y argón. La premisa que direccionó este proyecto fue la integración y sinergia de la nueva unidad con el sistema de la Central Termoeléctrica y Altos Hornos, con el objetivo de salvar condicionamientos, obtener beneficios energéticos y aumentar la confiabilidad operativa. Como resultados de esta línea de trabajo se espera: Optimizar el aprovechamiento de gases de proceso, mejorando así el balance energético y la ecuación económica en la producción de los gases industriales; Mejorar el aspecto ambiental disminuyendo el quemado de gases en antorcha, reduciendo el consumo de combustibles fósiles y la compra de energía eléctrica; y aumentar la confiabilidad en el suministro de gases y del sistema de aire soplado a Altos Hornos.

Sep 25, 2017

By E. G. King

This publication presents original thermal data for a typical variety of perlite and supplies basic information for use in computing energy requirements in processes for expanding perlite. Perlite has been defined by Raiston 4/ as any silicious lava containing dissolved water in sufficient amount to errand into bubbles when the material is quickly heated to a suitable point in the softening range." The uses of expanded perlite in) the construction and ceramic industries have been discussed by Ralston 4/ and King. 5/ The work described here had a dual purpose: (1) It was desired to ascertain quantitatively, using a typical variety of perlite, just how firmly the contained water is held, and (2) it was desired to obtain basic thermal data sufficient for energy-requirement calculations in processes for expanding perlite.

Jan 1, 1948

By ManhKha Trinh, Neal Pyke

Dofasco was the first company to adopt oxygen steelmaking in North America in 1954, two years after the first LD vessel installed and operated successfully in Linz, Austria. Since then, Dofasco has investigated and implemented several strategies to maximize hot metal usage and minimize overall cost. Some key strategies -low hot metal silicon, combined blowing conversion, vacuum degassing tank upgrade and BOF slag carryover control - are discussed. Post combustion, scrap preheat, carbon injection trials along with current operating philosophies are described.

Jan 1, 2004

By E. R. MARBLE

THE introduction of a new fuel, such as natural gas, necessitates careful study where it has not been used previously. At the El Paso smelter natural gas required the installation of apparatus with which no one at the plant was familiar, either as to the type of equipment needed or as to the burning of the gas in it. Observation of existing installations of a similar character and assistance from gas engineers served as a basis to determine what was advisable to use. The gas line entering the plant goes to a metering station equipped with a duplicate system of pressure regulators, a temperature recorder and the gas company and smelter orifice meters in tandem. There are three distribution lines that can be inter-connected at a later date, if necessary, to assist in equalizing the plant load. All the larger lines are of heavy

Jan 1, 1930

By R. F. Hinds

A pressurizing system was designed and built to apply a radial pressure of 5.000 psi to rock samples. Samples of the Bradford, Weir and Kirkwood sandstones were subjected to radial pressures parallel and perpendicular to the bedding in the system and the changes in conductivity, porosity and permeability were deter-mined. Asymptotic decreases in conductivity, porosity and Klinkenberg permeability were observed over the 0- to 3,500-psi range. From these data, the increase of formation factor over the same range was calculated. The cementation exponent expressed in the Archie equation was found to increase with pressu,re. The rate of change varied from formation to formation. Only small differences were observed for samples taken parallel to the bedding as comnared to those taken perpendicular to it except for the Bradford sand. Above 3,500 psi the data are not good enough to tell if the properties continue to fall-off asymptotically or in a different manner. A possible explanation for the probable litnit of the asymptotic rate around 3,500 to 4,500 psi is that this represents the maximum pressure which the formations have unrdergone during their geological life as a result of burial. INTRODUCTION For many years measurements have been made in the laboratory of the properties of oil-bearing sandstones with little consideration being given to whether these properties had been changed when the samples were moved from their original position in the ground to the laboratory. Relatively little has been reported in the literature on the effect of pressure on the properties of sandstones. The changes in permeability for eight typical consolidated oil-bearing sandstone samples with overburden pressure (0- to 15,000-psi range) was presented by Fatt and Davis' in graphical form. In 1953 Fatt' also reported the relationship between porosity and overburden pressure for four typical consolidated oil-bearing sandstone samples (0- to 5,000-psi range). Fatt later described the changes of formation factor and porosity of 20 typical oil-bearing sandstone samples with overburden pressure changes (0- to 5,000-psi range) giving the values of the coefficients and exponents in the Archie' equation, and the more general Winsauer equation', where C, k and m are empirical constants, F is the formation factor, and + is the porosity. During the experiments of this investigation the core was contained in a neoprene rubber sleeve as shown in Fig. 1. It was held between two steel end members which were mounted in a steel cylinder. The unassembled pressure cylinder with its component parts is shown in Fig. 2. The core was insulated from the two steel end members by a Teflon sleeve with a small hole in the

By QUANWEN PU, Yonggang Wei, Bo Li

With the advancement of industrial science and technology, more and more catalysts are used. The spent catalysts produced are solid waste products, which cause environmental pollution if they are not treated. At the same time, the spent catalysts contain some precious metals such as platinum in concentrations that are often higher than in their ore resources. Therefore, the recovery of valuable metals in spent catalysts is a hot research topic at present. However, due to the complex structure of the spent catalysts, dealing with them is a lengthy process. The first step of recovery, enrichment of the spent catalyst, becomes particularly important. In this paper, a pressure solution method is investigated for this purpose, in which the alumina carrier is dissolved and platinum is enriched in the leaching residue.

By Man-Chao He

One of the critical problems involved in deep coalmines is unusual gas emissions. Many researchers agree that there is a relationship between coal gas emissions and geological features such as tectonics or geological disturbances, gas content, properties of the coal and rock and the mininginduced stress state in the coal seam and rock. Thus, the present paper intends to investigate complex mechanical phenomena during the process of gas emission in underground coal-mines. A program of laboratory testing was undertaken to study the effects of temperature and pressure on mechanisms of gas emission. It must be noted that this paper describes new techniques developed to simultaneously measure deformation and gas pressure, as well as flux during the test, taking the characteristics of gas transport into consideration under certain temperature and pressure conditions. The results indicate that under certain temperature and pressure conditions, gases adsorbed to coal start to desorb, and increase the pore pressure. High pressure gases entering coal fractures can generate high tensile stresses near the crack tips, leading to crack propagation and coalescence, which in turn can cause the specimen to dilate. From the experimental viewpoint, these test results may help us discern why mining seismic events can trigger gas emissions.

Aug 1, 2013

By Emilie Lapointe, Fernando Famania

"A reliable determination of the in-placed cement factor, as defined by mass of cement over volume of final element of treated soil, allows the optimization of cement usage to achieve treated soil requirements. Cement determination tests were performed on soil-cement samples, both fresh (as per ASTM D5982) and hardened (as per ASTM C1084). This paper reviews the calibration work required for the D5982 determination of cement content by the heat of hydration method used on soil-cement samples obtained by wet-grabbing. Using the correlation curves in the field provides a rapid assessment of cement content hence optimizing the cement injection rate to match laboratory tests previously conducted. Cement determination tests on hardened soil-cement specimens from wet-grabs and cores were performed using the oxides method. Samples, both cored and wet-grabbed, were tested in a given cement-treated element, and in different soils to inform on the expected variation in cement content from field installation. Results indicate that both cement determination methods are valid for forensically determining cement contents and that they provide better assessment than the conventional field reporting methods. The methods can be used to optimise the cement usage as well as for Quality Assurance, especially when coring quality is poor.INTRODUCTIONThe degree of improvement, and inherent strength, which is attained in a deep-mixed soil is a function of many factors. The binder type, the existing soil, the mixing conditions and the curing conditions are the categories of factors influencing the strength of a given cement-treated soil as agreed by the deep mixing community and as summarized by the Coastal Development of Technology [CDIT] (2012). Given a site with existing soils and conditions requiring soil improvement using a given binder, the designer and/or contractor can control the mixing conditions. Mixing conditions are inclusive of the degree of mixing, mixing duration and the quantity of binder. Once a deep mixing method has been chosen to mix optimally the in-situ soil, the quantity of binder is the only remaining factor to be optimized. The quantity of binder, in the construction industry is commonly referred to as the field binder factor [ar] and defined by the mass of binder over the volume of soil treated with kg/m3 as unit. In research, the quantity of binder is referred to as the binder content [Cc] and expressed as a ratio of the mass of binder over the mass of dry soil mixed."

Jan 1, 2015

By B. J. Sauer

Variable frequency drives (VFD’s), or adjustable frequency controls (AFC’s) as they are more precisely identified, have been available to the mining industry for over 20 years. However, in recent years as the push to cut production costs has become ever so crucial, AFC usage has become more widespread. This paper seeks to provide professionals in mineral processing plant design and operation with an introduction to AFC’s, insight as to why AFC control for AC induction motors can be advantageous, and specification and design considerations.

Jan 1, 2002

By Junhyun Choi, Allan Gomez-Flores, Chonbuk National University, Siyoung Q. Choi, Gahee Kim, Seungkon Kim

In this study, to confirm the effect of depletion attraction on the flotation, we theoretically and experimentally investigate the effect of the depletion attraction force on flotation. While varying the concentration of the depletion agent (polyethylene glycol), three different systems are studied: pure malachite, pure silica, and a 1:1 mass ratio of malachite and silica binary system. We find that recovery increases significantly as the concentration of the depletion agents increases for all three systems, as the depletion agent facilitates the adsorption of the particle on the bubble surface. However, the recovery suddenly decreases in a certain concentration range, which corresponds to the onset of the decreased surface tension when high concentrations of the depletion agent are used. This non-monotonic overall recovery trend implies the surface adsorption of the depletant on a surface. The decreased surface tension of the air/water interface suggests that the recovery rate is lowered due to the adsorption of the depletion agent to the bubble surface, acting as a polymer brush. Based on our observations, we conclude that the depletion force can greatly improve particle adsorption, as predicted in the accompanying theory paper, while simultaneously the adsorption of the depletion agent on the bubble surface plays an important role because it hinders particle adsorption. We also perform experiments in the presence of a small amount of a collector, sodium oleate. An extremely small amount of the collector leads to the increase in the overall recovery, which eventually reaches nearly 100 percent. Nevertheless, the grade worsens as the depletant provides the force to silica particles as well as target malachite particles.

Jan 1, 2016

By W. E. Howlett, R. L. Slobod

Jan 1, 1965

By T. Kerr, C. Mattich, J. Wilson

"In refractory gold concentrates, gold is occluded in sulphide minerals preventing efficient cyanide leaching. Hence, roasting is used to oxidize sulphur and organic carbon, the latter being necessary to minimize recovery loss through the preg-robbing effect. In 2009, Outotec commissioned the circulating fluidized bed roaster at Syama gold mine in Mali. Since 2013 Resolute and Outotec have been implementing improvements to the roaster performance with the capacity increasing from 8000 t/month in 2013 to above 13,000 t/month in 2016, while achieving a residual sulphide sulphur and organic carbon contents of below 0.1 wt.% and 0.4 wt.%, respectively. Thus a gold recovery in the CIL of above 90% is attained. In 2016, Outotec audited the Syama roaster. The analysis resulted in the Low Carbon Roaster (LCR) upgrade concept which (i) allows re-processing of calcine dust from the spray cooler and ESP after pelletization and (ii) allows the roasting of a further fine-organic carbon rich feed, i.e. de-slime circuit tailings. The LCR upgrade aims to reduce organic carbon to <0.2 wt.% and increase roaster-leaching gold recovery by >3%. Project development included extensive testwork. The LCR process is expected to become operational during FY 2019.INTRODUCTION Double refractory sulphide ores exhibit the characteristics of gold locked within pyrite grains, in the presence of preg-robbing natural (organic) carbon. Hence, to achieve high recovery during subsequent processing steps, i.e. cyanide leaching, oxidation of sulphide sulphur is required, producing a porous calcine by way of a roasting step. This allows for the gold contained within the pyrite grains to be accessible during cyanide leaching. Furthermore, it is necessary to oxidize the organic carbon. Oxidizing the organic carbon is essential as gold recovery loss occurs as a result of gold-cyanide complexes being adsorbed on organic carbon, this phenomenon is termed as preg-robbing (Miller et al., 2016). The gold absorbed on the organic carbon is lost, reporting to the tailings stream. Hence, the aforementioned oxidation of sulphide sulphur and organic carbon is the process goal. Nonetheless, the latter must occur at a controlled temperature which is concentrate/ ore specific, since the pores of the produced calcine should not sinter, as this makes the gold contained in the calcine less accessible during leaching, leading to gold recovery loss. The tight temperature control requirement is a decisive factor in the choice of a Circulating Fluidized Bed (CFB) as the roasting reactor, due to the excellent mixing characteristics of the CFB which results in temperature homogeneity of (+/-10°C). Roasting of double refractory ores, as described above, can be included in the flowsheet after comminution and grinding, a process termed as whole ore roasting, or by including a flotation circuit termed as concentrate roasting. Roasting the flotation concentrate results in less solid flow, increased sulphide sulphur grade and organic carbon content resulting in a higher heating value and higher gold content. A typical composition of the Syama ore and concentrate is given in Table 1. Ore average values presented correspond to the period 2015, while concentrate values are typical for the flotation performance throughout the period 2012–2015."

Jan 1, 2017

By AIME AIME

OVER-ALL operations of the oil industry, as measured by production of crude oil and consumption of products, are almost exactly of the same magnitude as a year ago. Does this mean that the great oil industry has been undisturbed by the war? Has this industry, so vital to the prosecution of the war and to the maintenance of our way of life, been unaffected in its operations? No indeed - changes within the industry are great. It has been called upon to revamp its trans¬portation methods so as to move about one fourth of the total amount of crude and refined products by railroad tank car instead of by ocean-going tankers. Its fundamental internal economy, based on maximum gasoline yield from a barrel of crude, has been relegated to memories of the past. Rationing of oil products, which has been forced upon us in face of an abundant supply, is not only disagreeable medicine but is in itself completely disruptive to the marketing end of the-business.-

Jan 1, 1942

By A. S. Tawadrous

This paper is an evaluation of Artificial Neural Networks (ANN) as a tool in the design of the geometry of surface blast patterns. The built model uses eight different parameters, which affect the design of the pattern. Those parameters are rock type, stratification, blasthole diameter, bench height, type of explosive, priming position, powder factor and fragmentation size required. The network was trained to predict burden and spacing of the blast pattern. The model was built and trained (back-propagation technique) using 43 case histories collected from the literature. The model has then been validated using 16 cases from operational quarries.

Jan 1, 2006

By W. P. Yana, J. B. Littlefield

"INTRODUCTION AND OBJECT OF EXPERIMENTAn explosion in and rupture of a gas-tight switch box on an electric loader in a mine located near Pittsburgh indicated that the cause was an internally generated inflammable gas-air mixture. This led to the suspicion that moisture condensation or ""other unusual conditions might have caused a spark or are across the surface of the material and that the heat may have created a carbonized path across the synthetic plastic base which would then conduct a large current with the generation of considerable heat and thermal decomposition of the base materials base in the box which exploded gave every indication that this series of events had taken place, and accordingly it was desired to determine what explosive gases such a decomposition of these insulating materials would produce.ACKNOWNLEDGMENTSThe desirability of making this investigation was suggested to the authors by L. O. Ilsley, supervising engineer, electrical section, Bureau of Mines, to whom the occurrence of an explosion in a switch box had been reported. The writers also acknowledge with thanks the assistance of L. B. Berger, chief scientific aide, health laboratory section, Bureau of Mines, in checking the calculations in the tables. DESCRIPTION OF MATERIAL INVESTIGATEDThe ten materials used in the tests, identified by letters A to J inclusive, are described in a succeeding list of materials. All the materials except I had a phenolic odor, especially when freshly cut."

Dec 1, 1932

By A. S. Speirs

Over the last few years, the never-ending search for mineral wealth has taken the exploration efforts of Canadian mining companies further and further into the High Arctic and isolated locations where regularly scheduled transportation and communication facilities are nonexistent. Names such as Black Angel, Nanisivik, Asbestos Hill, New Quebec Raglan, Rabbit Lake, and Arvik are today frequently mentioned in mining publications. Twenty years ago, mining in these locations was unheard of, mainly due to logistic problems. However, improvements in the design and use of helicopters, STOL aircraft, and icebreakers in northern areas have helped to overcome these problems, making these locations more attractive to mining companies. Since 1969, when Redpath completed its first Arctic project at Texas Gulf&apos;s Scrathcona Sound property on the northern tip of Baffin Island, Redpath has been actively involved in contracting and engineering projects in three general areas: the High Arctic, Ungava and Greenland. A map showing some of these projects is shown in Figure 1. In these areas, permafrost conditions exist from a depth of 274 metres in Ungava to a depth of approximately 610 metres in the Little Cornwallis Island area, with rock temperatures ranging from -5°C to -13°C. Outside temperatures range from a low of -50°C in the winter to a high of 21°C in the summer. High winds in the winter result in wind chill factors lower than -73°C

Jan 1, 1980

By Jr. Norman

Thermoelectric properties of depleted uranium selenides and tellurides were investigated from room temperature to 700 C. Several depleted uranium monoselenides and monotellurides were doped with selected cationic and anionic materials to determine the effect of impurity additions on the thermoelectric properties. The undoped uranium selenides and tellurides were semimetallic conductors exhibiting low Seebeck coefficients and electrical resistivities. Partial or complete degeneracy was in evidence, indicating a charge carrier energy distribution similar to that in a metal. Doping increased the Seebeck coefficients of the uranium monoselenides and monotellurides; however, the corresponding change in the power factor in the figure of merit was small because of the increase in electrical resistivity.

Jan 1, 1965

By Ravi Sahu, Brad Gyngell, Oktai Radzhabov

Design machine learning approach to simulate the process of muckpile throw distribution before blasting.

Feb 1, 2020

By AIME AIME

THE PAPER, "Surface Effects on Assay Beads Caused by Metals of the. Platinum Group," presented by J. L. Byers, before the Institute of. Metals Division at the February meeting of the Institute, is the subject of interesting discussion, an abstract of which follows. The original paper is available at Institute headquarters as a Preprint. Member-What assurance have you that the percentage of metals, as stated, is really an accumulation?

Jan 1, 1932