Search Documents

By G. F. Liu, S. Owada

Platinum Group Metals (PGMs), Pt, Pd, Rh, have been widely used as a three-way catalyst to clean discharged gas from automobiles and therefore a considerable amount of the spent catalysts is generated annually. This paper proposes a novel concentration technology of PGMs by utilizing the double-deck structure of PGM bearing alumina-ceria and cordierite phases. The applied technologies are a combination of heating-quenching, selective grinding and screening for separating alumina-ceria phase from cordierite. Temperature change as a function of quenching time and the thermal stresses applied to both phases were simulated and calculated by FEM, and it was clarified the mechanism of micro-cracks generation at the phase boundary and micro-cracks in alumina-ceria phase, which indicated that separation of alumina-ceria phase from cordierite and selective breakage of alumina-ceria phase could be achieved in the subsequent selective grinding with an attritor. This process could concentrate 46 wt% of alumina-ceria phase into fine fractions with 86 % recovery efficiency. The remaining alumina-ceria phase can be further recovered by applying flotation and so on.

Jan 1, 2015

By G. K. Manning, P. C. Rosenthal

USE of copper as an intentionally added alloy in steel and cast iron has rapidly expanded with-in the last fifteen years. It is estimated that in 1931 not more than 2000 tons of copper were so used; by 1941, however, this figure had grown to 13,000 tons. Tonnage figures during the war years have been restricted just as copper itself has been restricted, but copper-bearing cast irons and steels have played a part in the production of ordnance equipment. They are used in gun carriages, airplane landing-gear assemblies, scout cars, bulldozing equipment, army trucks, armor plate and many other instruments of war. These wartime applications have their counterpart in many peacetime applications; derricks, dredges, mine equipment, railway equipment, trucks, farm implements, automobiles, and tractors, all usually contain some parts made of copper-bearing steel or iron. An example of this is the Ford tractor which in 1940 contained over 300 lb. of copper-bearing steel castings. To this list should be added corrugated building sheet for exterior use most of which, at the present time, contains upward of 0.15 per cent copper. With the return to peacetime economy and the removal of wartime restrictions, it appears certain that copper cast irons and steels will find increasing application in civilian goods.

Jan 1, 1945

By Max Friedemann, Franziska Günther, Helmut Mischo

Ensuring adequate ventilation is a critical aspect of safety in underground mining operations. In small-scale mines in particular, key ventilation parameters such as temperature, humidity, and air velocity are often measured manually and only at infrequent intervals, typically using analog instruments. As a result, real-time monitoring of environmental changes, timely detection of hazardous situations, and demand-driven ventilation control are not feasible. This presentation discusses the selection and evaluation of modern digital ventilation measurement devices, including handheld instruments with digital data logging capabilities and continuously operating sensors with potential for real-time data transmission. The investigations focus on the challenges posed by underground environments with extremely high humidity levels, which can adversely affect sensor performance and electronic components. The results are based on testing conducted at the Research and Teaching Mine of TU Bergakademie Freiberg—an underground ore mine characterized by humidity levels exceeding 95%. Findings include assessments of measurement accuracy, reliability, and practical applicability under these demanding conditions.

Feb 22, 2026

By F. E. Block, T. T. Campbell, D. Z. Hobbs

Several methods were investigated for the preparation of high- purity elemental boron in an attempt to develop a feasible process for producing boron on a large scale . In the work described in this report , the metal was prepared by metering boron trichloride gas into a crucible containing molten metal reductants . It was necessary to remove reaction byproducts by acid and aqueous leaching . Magnesium and sodium were tested as reductants , but best results were achieved using lithium or zinc as reductants . Contaminants originating from the materials of construction were the chief impurities in boron made by this method . Impurities ranged from 0.5 to 5.0 percent . Impure boron ( 85 to 90 percent ) was also prepared by the magnesium reduction of boron trioxide in a thermite - type reaction . This product contained magnesium as the chief contaminant . Impure boron made in this way could be upgraded by fusing with potassium fluoborate or potassium acid fluoride . After acid leaching the fusion cake , a product containing 95 to 97 percent boron was obtained . Analytical techniques for accurate determination of impurities in elemental boron are a major problem , requiring solution before a valid comparison can be made of the quality of boron prepared by these various methods .

Jan 1, 1964

By Adam Bedell, Brad Crenshaw

Tunnel project contract documents often present groundwater infiltration requirements for components of the underground portions of the project. All too often these documents require quantifiable target inflows for these components, but only refer to them in subjective terms such as “dry,” “manageable,” etc. The Contractor’s definition of these terms will inevitably differ from the Engineer’s definition of these terms. The purpose of this paper is to look at common subjective terms used in documents and provide suggestions for reasonable quantifiable language. Additionally, the paper will provide information and recommendations on relative levels of cost and effort increase needed to provide increasing levels of water cutoff (i.e., achieve “dryness”?).

Dec 1, 2022

By Michael J. Beus, Jan G. Patricio

INTRODUCTION The U.S. Bureau of Mines, Spokane Mining Research Center, has been conducting and documenting rock mechanics research in the Coeur d’Alene mining district for the past ten years (1, 2, 3, 4, 14, 15). A current project combines the information gathered from rock mechanics instrumentation, geologic structure, and analytic techniques to improve shaft and support design for the deep mines of the district (3). This project required knowledge of the anticipated loads and the physical properties of the rock mass to provide accurate input data for computer design models. Several techniques have been utilized to determine the physical parameters including the USGS (U.S. Geological Survey) solid inclusion probe, the CSIR (Council for Scientific and Industrial Research) biaxial and triaxial strain cells, and the CSM (Colorado School of Mines) dilatometer. This paper describes the determination of the in situ modulus of deformation in three mines over a period of three years and the evaluation of these results as they applied to this project. The need for in-situ rock mass properties such as the modulus of deformation has stimulated research and development of a large number of instrumentation techniques. One area of continuing interest involves various methods of radial borehole dilation. This concept was pursued by Menard (9) with an apparatus known as the pressure meter, which is used frequently in soil mechanics. Other developments in rock mechanics include the CPC (cylindrical pressure cell) by Panek (11) and the dilatometer by Rocha et.al. (13) in Portugal. The CSM dilatometer, which also utilizes this technique, was chosen for this project because it required a small amount of background study, was inexpensive, and could easily be combined with other experiments being planned for the test locations. Although no previous field applications to hard rock (compressive strengths greater than 20,000 psi) has been documented, the instrument was selected since good results have been achieved in granite, oil shale, and several coal measure rocks (11, 12).

Jan 1, 1977

By Hidenori Hatta, Takero Watanabe, Hideo Yoshida

"The effect of the quenching rate on age hardening in an Al-6.0mass%Zn-0.75mass%Mg alloy sheet was investigated. The quenching rates and aging conditions were as follows: water quenching (WQ) or furnace cooling (FC) followed by pre-aging at 20°C,then artificial aging at 120, 160 or 200°Cwere performed. The peak strength of the FC and the WQ are very similarat120°C aging. It is important high strength was obtained even at the extremely slow quenching rate. On the other hand, the strength of the WQ significantly decreased compared to the FCat200°C aging. GP(I) zones were formed during the pre-aging at 20°C even if the cooling rate was very slow like the FC, and were transformed into the GP(II) ones at 70°C or higher and then into the ?’ phase. However, these zones were dissolved by reversion during heating to 200°C. Thus the strength of the WQ decreased. On the other hand, it is considered that an unknown cluster or GP zone with a thermal stability formed during the FC was not dissolved up to 200°C and was transformed into the ?’ phase. Therefore, a higher strength was obtained in the FC for the200°Caging.INTRODUCTIONAl-Zn-Mg alloys are widely available in commercial production because these alloy have lower quench sensitivity and can be produced by air cooling (AC). Heat treatable aluminum alloys are usually produced by water quenching (WQ) to increase their strength because a high cooling rate inhibits the precipitation of the stable phase during cooling and increases supersaturated solute atoms. However, Baba(1967)reported the strength of an Al-6%Zn-1.8%Mg(mass%) alloy without additional elements quenched by very slow cooling (15°C/min) was 96% of that quenched by WQ. Furthermore,the age hardening at room temperature (RT) occurs after annealing at 410°C followed by furnace cooling (FC, 0.5ºC/min or less)in these alloys. Therefore, the process of annealing at 410 to 430°C for 120 min followed by AC, and reheating at 230°C for 240 min, then cooling is recommended in the specifications (Japan Aluminum Association, 2011). Matsuda and Yoshida(1996)also recommended annealing at 300°C for Al-Zn-Mg alloy extruded products to inhibit age hardening at RT by precipitating the solute atoms and decreasing them in the matrix. It has been considered that the higher the content of excess quenched-in vacancy becomes by WQ, the higher aging rate at RT is obtained. Therefore,it is theoretically and commercially important to clarify the reason why the age hardening occurs relatively quickly in almost no excess quenched-in vacancies such as the FC, and why the same strength as the WQ can be obtained in the FC"

Jan 1, 2018

By F. C. Appleyard

As one of the more important Industrials Minerals, gypsum occupies a significant place in the economy of the United States, particularly in that segment which can be loosely called the Construction Industry. For many years, products made from gypsum have been a major building material, and the usefulness and versatility of these products is such that their widespread use is expected to continue. In 1968, according to U.S. Bureau of Mines statistics, the value of all gypsum products sold in the United States was 405,000,000 - and although this value has dipped from the 1964 high of $ 432,000,000, it is expected to trend upward in the next few years to equal and surpass this figure as the construction industry recovers from its current squeeze of "tight money" and high interest rates. There are many factors to be measured in determining the potential value of any mineral deposit, and how it might fit within its particular industry. What, then, are the qualities which a gypsum deposit must have in order to profitably participate in the four hundred million dollar plus business which is the gypsum industry? First let's consider the geology of gypsum, the geographic distribution of deposits, and the more important factors such as size, grade, capital requirements, and operating cost. Then, an understanding of the uses of gypsum, various types of products, and location of markets would be helpful, along with such other factors as the structure of the industry, price trends, etc.

Jan 1, 1970

By Dan A. Brown

The foundations at the Huey P. Long Bridge in New Orleans presented special challenges for construction due to the requirements for very deep drilled shafts in the Mississippi River beneath the existing bridge structure. Drilled shafts were constructed to depths of approximately 200ft in alluvial soils using a rotator system with full-length segmental casing, and base grouted to improve axial resistance. This paper describes the design and construction of the work platform to provide access to the restricted-access site beneath the existing bridge, the approach used to construct the drilled shafts, and the results of a load test program to verify the axial resistance.

Jan 1, 2010

By Arno C. Fieldner

The objectives of the coal-research activities of the Bureau of Mines are very well expressed in the organic act of Congress establishing the Bureau. It reads as follows: That it shall be the province and duty of the Bureau of Mines, subject to the approval of the Secretary of the Interior, to conduct inquiries and scientific and technologic investigations concerning mining, and the preparation, treatment and utilization of mineral substances with a view to improving health conditions, and increasing safety, efficiency, economic development, and conserving resources, through the prevention of waste in the mining, quarrying, metallurgical and other mineral industries; to investigate explosives and peat; and on behalf of the Government to investigate the mineral fuels and unfinished mineral products belonging to, or for the use of, the United States, with a view to their more efficient mining, preparation, treatment, and use; and to disseminate information concerning these subjects in such a manner as will best carry out the purposes of this act.

Jan 1, 1946

By Karl J. Benecke

Though the first patent on a bucket wheel excavator was granted in 1881 in the U.S. this technology was developed in Germany to the high standards of today. However, this development was only possible in parallel with the development of shiftable belt conveyors and boom stackers. The combination of these three types of equipment in the open pits of the Federal Republic of Germany has made lignite the cheapest energy source for power generating, despite the low heating value of German lignite in the order of 8500 kJ/kg (3600 BTU/lb) only. Comparing the costs for fuels used in power generating on the basis of their heating value, the relation between lignite, high quality black coal, and imported crude oil is in the order of 1 to 1.5 to 2.5, hence highly in favour of lignite. These cost advantages for lignite in Germany are due mainly to the concentration of lignite mining in a few high-output open pit mines. The largest one, Fortuna Mine in the Cologne district, produced a, total of 45 000 000 t lignite in 1976. That equals the annual fuel need of a 5750 MW power plant running 7000 hours per year at full capacity. Altogether 95 200 000 bank m3 equal to 200 000 000 t overburden had to be removed to accomplish this lignite output. The largest BWE (Fig. 1) ever built is working in the Fortuna Mine, too. At a digging height of 51 m above crawler level, the total vertical reach in relation to the face conveyor level is 98 m by means of its conveying bridge and loading unit. The hourly output is 10 400 bank m3. Its weight in operation is 13 000 t, its wheel diameter 21.6 m, as high as a 7-storey building.

Jan 1, 1977

Workers at the Consolidated Aluminum Corp. primary aluminum smelter at Lake Charles, LA walked out at midnight March 31 when their contract expired. Management personnel operated the smelter and prebaked carbon anode facilities until an agreement for a new 3-year contract was reached April 18. The Aluminum Company of America (Alcoa) began operations at its can recycling facility at Taylor, MS. The facility can process 3 million pounds per month of aluminum and steel cans. Alcoa announced plans to increase the capacity of its aluminum paste and flake production plant at Logan's Ferry, PA by 50 percent. Completion was scheduled for mid-1980.

Jan 1, 1979

By C. E. Coleman, Joseph D. Davis

During some distillation experiments conducted by the Bureau of Mines in cooperation with the Trent Process Corporation it was observed that amalgams of heavy petroleum oils and finely pulverized coal tended to produce a denser coke than that obtainable from the coal when retorted alone . Even anthracite coal when retorted with oil yielded a coke . This led the writers to believe that by mixing a lowrank coal ( sub-bituminous or even lignite ) - with asphaltic oil and retorting it, a coke suitable for domestic fuel could be made . Thus there was contemplated the production of domestic coke and the utilization of a low- grade oil in one operation . - In order to decide on the practicability of this process , it was necessary to know the value of products obtainable by such a method , as compared with those obtained by separate distillation . A laboratory method was therefore devised , and while it was realized that no small - scale testing apparatus for destructive distillation gives results that are directly applicable to commercial - scale operations , by keeping distillation conditions uniform for comparative tests , results were obtained valuable for purposes of comparison . The plan was to distill mixtures of coal and oil in a laboratory retort , and then distill the constituents separately under the same conditions . The comparative quantities of products yielded were thus directly obtained , and their quality was determined by analysis . The following are the main points investigated : ( 1 ) Quantity and quality of coke ; ( 2 ) Quantity of oils boiling below 221 °C . ( gasoline stock) and oils boiling at 221 to 300° C . ( kerosene stock) ; and ( 3) Quantity and quality of gases .

Jan 1, 1922

By Raymond M. Stateham

The Bureau of Mines used portable infrared scanners to examine the surface of pillars and faces in the Somerset mine near Somerset, Colo. Zones of temperature buildup, indicative of potential combustion, were detected with the scanners; their existence was verified by temperature measurements with conventional instrumentation. Temperatures of 32° to 6° C were measured on surfaces with normal temperatures of 26° to 35° C. The infrared instruments and techniques appeared to offer a rapid and efficient method for locating potential trouble spots in mines susceptible to fires caused by spontaneous combustion.

Jan 1, 1974

By John R. Goode

"This paper reviews options for the separation of a mixture of rare earth elements (REE) into its component elements. Earlier separations used selective chemistry such as double salt precipitation and reductive/oxidative processes – methods that still have a place in the industry. Fractional crystallization was developed for more complete separations of adjacent REE. The latter method was replaced by ion exchange (IX), which was in turn replaced by solvent extraction (SX). Two main SX chemistries are in use, solvation and cation exchangers, with several variants (mixed solvents, ionic liquids, etc.) now under investigation. SX plant configurations have evolved including advanced techniques like “hyperlinking”, novel saponification methods, and alternative stripping techniques. The classic mixer-settler is the most commonly employed device although centrifugal contactors have been pilot-tested. Non-dispersive SX options including microfluidic devices and membrane-assisted SX techniques are being developed and could revolutionize the SX option. Other REE separation techniques now being studied include Molecular Recognition Technology (MRT), Free Flow Electrophoresis (FFE), newer IX systems, and electrolytic processes. Additionally, the classical crystallization and selective precipitation methods and newer bacteria-mediated processes, chloride volatilization, high performance liquid chromatography, and magnetic separation systems have been studied. This paper reviews the options and concludes that conventional SX is the technology of choice but viable alternatives could be demonstrated and acceptable within a couple of years.INTRODUCTIONThe chemical properties of the individual REE are very similar which is why REE minerals and ore deposits almost invariably contain a mixture of all fifteen REE, i.e., La to Lu plus Y. That said, the distribution of REE in a given deposit is frequently dominated by the light REE (LREE, i.e., La to Nd). Examples include the Bayan Obo, Mianning, Lynas Mt. Weld, and Molycorp Mountain Pass deposits where heavy REE (HREE – Sm to Lu and Y) typically account for well under 5% of the REE content. The LREE operations produce some HREE but the main sources of these important elements are the ionic clay deposits of Southern China. Importantly, all of the REE recovery operations referenced above, except for cerianite-bearing ionic clay deposits, initially produce a mixed REE precipitate or calcine with a REE distribution similar to that in the ore (Goode, 2016). However, the consumers of the REE, the manufacturers of magnets, phosphors, catalysts, optical glass, etc., require separated products with purities generally ranging from 99% to as high as 99.9999% depending on the element in question and the end use. Hence there is a need to separate the individual REE one from the other. This paper is intended to review the options."

Jan 1, 2016

By J F. C L Costa, J C. Koppe

It is recognised by the major international codes that resource classification involves the interaction of numerous qualitative and quantitative criteria such as data quality, geological and grade continuity, etc. However, the difficulty in quantifying the degree of uncertainty associated with mineral resources estimation has led to the creation of a large suite of methodologies, terms and definitions, with almost every mining company having its own set of standards. It is also intuitively known that several traditionally used methods to evaluate resources do not take into account the spatial continuity of the grades, being unable to provide a reliable measure of the error associated with their estimates. Since they do not provide an error assessment, these methods are inappropriate to assess local or global uncertainty associated with an estimate. Faced with these problems, this work aims at developing a methodology for either quantitative or qualitative analysis of mineral resources estimation, through incorporation of uncertainty and the correct definition of the associated risk or error. The proposed methodology includes the development of a software code incorporating all the main classification techniques used by the mineral industry. A comprehensive study about each technique was conducted allowing a comparison of the parameters affecting mineral inventory assessment. A case study was conducted with a typical iron ore deposit data set from the Conceitpo mine of the Itabira Complex in the Iron Quadrangle, Brazil. The results showed the specific limitations of each classification system and the influence in selecting their key parameters, always based on subjective choices.

Jan 1, 2009

By P. Wanjara, M. Xiao, M. Jahazi, C. Poon

Using a robotic 4kW Nd:YAG-laser system, Inconel 718 (1 mm sheet) was welded with and without filler wire to investigate the effect of processing parameters, including power input and welding speed, on the weld geometry, microstructure and mechanical properties. By means of both nondestructive testing and microscopic examination, the weld quality was studied to determine the nature of the welding defects (porosity, cracking and bead shape) over the processing range of 3-3.5 kW for the power input and 4.5-6 m-min-1 for the welding speed. Application of the design of experiment methodology permitted the examination of the relationship between the process parameters and mechanical properties, from which the optimized laser welding conditions could be determined for joining Inconel 718. In particular, the research results indicate that Nd:YAG-laser welding technology can achieve defects free, mechanically sound welds with narrow fusion and heat effected zones.

Jan 1, 2006

By H. E. Peterson

A study was undertaken by the Bureau of Mines to develop a simple, reliable test for field detection of selenium in rocks and soils. Two methods are described for qualitative detection of selenium, dependent upon its form of occurrence and the presence of interfering constituents in the sample. Both methods involve fusion of the sample in a test tube to form elemental selenium that will volatilize and condense as a red deposit on the cooler upper portion of the test tube. The methods are sensitive to 10 parts per million, (p.p.m.) equivalent to 0.001 percent, and can be made semiquantitative by using suitable standard samples. INTRODUCTION Although selenium is widely distributed in the United States, the known deposits are either so small or so low grade that they cannot be processed economically for selenium alone-4/ At present, commercial production is a byproduct of the smelting and refining of base-metal ores, particularly copper.5/ About 0.75 pound of selenium is recovered per ton of electrolytic copper, and small amounts are recovered by special treatment of assorted smelter dusts and fume products. Since selenium is a strategic metal in short supply, new sources are being sought by both Government and private interests.

Jan 1, 1957

By P. Molera

"In Catalonia, between the 10th century and 1878, some installations were developed which at first were called ""factories"" and later ""fargas"", since they manufactured iron and steel of low carbon content. Because of its excellent quality, the fame of this metal spread from Catalonia to many countries. Fargas were started in Corsica, the Low Countries, Germany, Oriental India, Madagascar, Finland and along the rivers Orinoco and Mississippi among others. The extractive process used in these fargas has passed into history as the ""Catalan Farga Process"", ""Catalan Process"", or just ""Farga Catalana"". With this technology, raw material was obtained for the fabrication of tools, nails, weapons, grilles, etc. to supply the national and export markets. Aside from meteorites and native iron, found as metallic nodules in basalts in Greenland and Palestine, the ancient civilizations, which had no means to reach the fusion temperature of iron (1535°C), obtained iron by a direct process. Similar processes were used until quite recently (1930s) by certain tribes in Central Africa; holes in the ground were filled with iron ore and coal, and combustion encouraged by blowing air by mouth or with bellows made of animal skins. Thus without melting the iron it is possible to reduce the mineral and obtain a porous and impure metallic mass, which is purified on forging by mechanical squeezing. With a process very likely similar, the famous column at Dehli weighing 6.4 m.t. was built about 300 B.C."

Jan 1, 1999

By E. W. Greig

This paper is an account of exploration for bauxite in the Amazon Basin, Brazil, and particularly of the discovery, exploration and development by Alcan of the Trombetas deposit so a general account of the Trombetas Project has already been published in E/MJ (Anon. 1975) to which the reader is referred for details on owner-ship, infrastructure and construction as well as the proposal for mining and treating the bauxite. It is impossible to consider the Trombetas deposits in isolation. A regional account of bauxite in and around the Guyana Shield and the northern portion of the Brazilian Shield is included and it is suggested that these deposits all formed during Tertiary time under similar conditions.

Jan 1, 1977