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By Gerald R. Smith

Because of continuing concerns regarding the effects of cumulative quantities of materials in the environment, the Bureau of Mines has initiated a series of studies to evaluate, to the fullest extent possible, all aspects of the materials flow sequence fur selected commodities. Although tungsten and its compounds do not pose a significant health hazard to the environment, they do represent valuable resource materials to which appropriate conservation considerations must be given. The present study includes a description of recent trends in the consumption, loss, and recycling of tungsten-containing materials in the United States during the period 1974 to 1991 and an estimation of the cumulative loss of tungsten to the environment since 1910. Obsolete tungsten is recycled primarily as cemented tungsten carbide components that have been used in cutting and wear-resistant applications. The quantity recycled, as a of annual U.S. consumption of tungsten, was estimated to have increased from 10% in 1974 to 341a in 1991. An estimated 58% of the 148,000 metric tons of primary tungsten consumed since 1910 was lost to the environment through means such as dissipation, discard, and dilution.

Jan 1, 1994

By J. B. Gayle

The rate of oxidation of coals with nitric acid has been used by earlier investigators4 5 6/ for determining fusain and for studying petrographic composition. These workers accumulated considerable evidence indicating that, for coals ranging from lignite to low-volatile in rank, the method gives values for fusain that agree satisfactorily with those obtained by optical methods. One group5/even concluded that, when discrepancies are noted between results obtained by chemical and microscopic methods, the results based on the oxidation reaction are probably the more reliable. Unfortunately, after concluding that the method was valid, most of these workers apparently lost interest. As a result, no attempt to exploit or apply the method to problems of utilization has been reported. Recent studies of the influence of inert petrographic constituents on the properties of cokes made from various coals7/ have indicated a need for additional means of characterizing coals and blends used for carbonization.

Jan 1, 1960

By L. Yan, D. Yantek

Federal regulations require refuge alternatives in underground coal mines to sustain life for 96 h while maintaining an apparent temperature below 35 °C (95 °F). Research by the U.S. National Institute for Occupational Safety and Health (NIOSH) has shown that heat and humidity buildup is a major concern with refuge alternatives because they have limited ability to dissipate heat, and high internal air temperature and relative humidity (RH) may expose occupants to heat stress. The heat transfer process within and surrounding a refuge alternative is complex and not easily defined, analytically or experimentally. To investigate heat and humidity buildup in refuge alternatives, NIOSH conducted multiple in-mine, 96-h tests on a 10-person tent-type refuge alternative, a 23-person tent-type refuge alternative and a six-person metal-type refuge alternative. The results show that when moisture was introduced to represent perspiration and respiration from miners (wet tests), the average temperature at midheight increased by 10.5 °C (18.9 °F) and the RH approached 88 percent for the 10-person tent-type refuge alternative; the average temperature at midheight increased by 9.4 °C (16.9 °F) and the RH approached 94 percent for the 23-person tent-type refuge alternative; and the average temperature at midheight increased by 7.7 °C (13.9 °F) and the RH approached 95 percent for the sixperson metal-type refuge alternative. For the dry tests, where no moisture was introduced, the average internal temperature increased by 12.6 °C (22.7 °F) for the 10-person tent-type refuge alternative, by 10.3 °C (18.5 °F) for the 23-person tent-type refuge alternative and by 8.4 °C (15.1 °F) for the six-person metal-type refuge alternative. These results may provide refuge alternative manufacturers and mine operators with guidelines and considerations for evaluating temperature profiles for portable refuge alternatives. The information may then be used to make decisions on occupancy ratings and heat mitigation strategies based on the thermal environment in which the refuge alternatives will be installed.

Jan 10, 2018

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By D Maconochie, S Pradhan, M Reed

The Waterview Connection will provide a high-quality strategic alternative to State Highway One and complete Auckland’s Western Ring Route connecting State Highways 20 and 16. The project includes twin three-lane motorway tunnels 2.4 km long and 13.1 m internal diameter (ID). The tunnel construction started in November 2013 using the tenth largest earth pressure balance (EPB) tunnel boring machine (TBM) in the world. The tunnels will pass beneath urban and greenfield areas as well as a major local arterial road. The project is being delivered by an alliance of constructors, designers and the New Zealand Transport Agency. This paper describes some of the key innovative and cost saving design solutions that have been achieved through collaboration in the alliance environment with the construction team, owner’s verifier, the segmental lining precast suballiance and the M&E suballiance for the underground works. The key design elements of the tunnel comprise a three-lane roadway, invert culvert and backfill, precast segmental lining, sixteen mined cross passages including a low point sump cross passage and steel segments for opening to the cross passages. This paper reviews interdisciplinary design integration and the economies achieved in the permanent works tunnel lining design, including reduction in lining thickness and optimising reinforcement, cross passage separation of 150 m, efficient design of the invert culvert and backfill design, main drainage pipe and low point sump. The paper also describes the attributes of the TBM and the invert culvert construction methodology.CITATION:Pradhan, S, Maconochie, D and Reed, M, 2014. Tunnel design in an alliance for Waterview Connection, New Zealand, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 425–430 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By John H. Hild

This is a report on work done and results obtained in a minerals exploration program conducted by the Bureau of Mines on the lead-zinc deposits in the Ross Basin-Lake Como district, San Juan County, Colo., in 1948, 1949, and 1950. Four large veins--the Seven Thirty, Red Rogers, Cashier-Shorts top-Canandaigua, and Queen Anne--and several narrow spur veins were explored at relatively shallow depths with core-drill holes. Thirty-nine holes, totaling 10,491.5 feet, were drilled, and the core samples were assayed at the Bureau of Mines station at Salt Lake City, Utah.

Jan 1, 1959

By H. R. Babitzke, H. Kato, R. E. Siemens, G. Asai

The purpose of this investigation was to develop a wide variety of columbium and tantalum alloys and to determine their suitability for use at elevated temperatures . Sixty - nine columbium and tantalum alloys were investigated . For this study , columbium was alloyed with two or more of the following : nium, tungsten , vanadium , titanium, and zirconium . Tantalum was alloyed with vanadium or hafnium, or hafnium and carbon . The fabricability was determined by an arbitrary procedure . Hardness measurements , elevated - temperature tensile properties , and oxidation- resistance studies were made . Of the alloys studied , Cb - 15 Hf - 5W, Cb - 15Hf - 5W- 10Ti , Cb - 15Hf - 10W- 10Ti , Cb - 10V - 5W, Ta - 30V , and Ta - 20 to 33Hf exhibited excellent high - temperature properties . These alloys were not only easy to fabricate , but they also had good oxidation resistance and excellent high- temperature strength .

Jan 1, 1964

By H. C. Ko

Calorimetric determinations of low-temperature heat capacities and the standard enthalpy of formation were made by the Bureau of Mines for aluminum sulfide, A12S3. The standard entropy (S°), enthalpy of formation (?Hf°), and calculated Gibbs energy of formation (?Gf°) at 298.15 K are 27.93±0.05 call deg-mole, -155.6±0.9 kcal/mole, and -153.0±1.0 kcal/mole, respectively.

Jan 1, 1976

By Teuku A. R. Putra, Patrick R. Taylor

Various pyrometallurgical methods for treating copper concentrates that contain appreciable arsenic are reviewed. Various aspects of the engineering of these treatment methods are discussed. The methods discussed include: complete oxidation with arsenic fixation; selective volatilization of arsenic; acid baking, soda ash roasting, and others methods. Methods for the ultimate disposal, or marketing, of the arsenic are discussed.

Jan 1, 2014

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By Eric Reale

The New York City Department of Environmental Protection (DEP) is currently building City Water Tunnel #3 beneath the city. The purpose of this tunnel is to improve water distribution to the city and to allow the DEP to inspect the older tunnels and make the necessary repairs. These older tunnels have been in continuous operation since the early 1900's. Construction on the Third Tunnel is planned in four stages. The Nelson Street Shaft, which is the focus of this paper, is part of the second stage.

Jan 1, 1989

By P. Bissert, L. Yan, D. Yantek

"Federal regulations require refuge alternatives (RAs) in underground coal mines to sustain life for 96 hours while maintaining an apparent temperature (AT) below 35°C (95°F). NIOSH research has shown that heat and humidity buildup is a major concern with RAs because they have a limited ability to dissipate heat, and high internal air temperature and relative humidity (RH) may expose occupants to heat stress. The heat transfer process within and surrounding an RA is very complex and is not easily defined analytically nor experimentally. To investigate heat and humidity buildup in RAs, NIOSH conducted multiple in-mine 96-hour tests on a 6-person metal-type RA, a 23-person tent-type RA, and a 10-person tent-type RA. The test results show that when moisture was introduced into the tests to represent perspiration and respiration from miners (wet tests), the average measured internal air temperature at midheight increased by 7.7°C, 9.4°C, and 10.5°C, and the RH approached 95%, 94%, and 88%, respectively. For the dry tests when no moisture was introduced, the average internal temperature increased by 8.4°C, 10.3°C, and 12.6°C, respectively. INTRODUCTION If an accident occurs in an underground coal mine, miners who cannot escape from the mine can enter an RA for protection from adverse conditions, such as high carbon monoxide levels. One of the main concerns with the use of mobile RAs is the thermal environment inside the RA. The metabolic heat of the occupants and the heat released by the CO2 scrubbing system will cause the interior air temperature to increase. Moreover, the humidity within the RA will increase through occupants’ respiration and perspiration and from the chemical reaction within the CO2 scrubbing system. The internal thermal conditions can subject miners to heat stress, which can lead to heat exhaustion, heat stroke, or even death depending on duration and magnitude of exposure. MSHA regulations require that RAs must be designed to ensure that the internal apparent temperature does not exceed 35°C (95°F) when the RA is fully occupied [1]. Apparent temperature (AT) is a temperature-humidity metric for the perceived temperature caused by the combined effects of air temperature, relative humidity (RH), and wind speed. It is used to assess the perception of indoor temperatures when workplaces are not sufficiently heated, cooled, or insulated to provide comfortable or healthy conditions. Before a mobile RA can be deployed at an underground mine for emergency usage, it must be tested to show that its internal AT when fully occupied will not exceed the 35°C (95°F) limit. For practical reasons, RA manufacturers usually conduct their tests at above-ground test facilities. To investigate RA thermal response in an in-mine environment, NIOSH conducted multiple 96-hour tests on a 6-person metal-type RA, a 23-person tent-type RA, and a 10-person tent-type RA in its underground coal mine facility. The work described in this paper could be used by RA manufacturers to determine a final temperature rise based solely on dry and time-reduced testing."

Jan 1, 2017

By Xun Zhang, Hang Qiu, Andrea R. Gerson4, Shaomin Lei, Yubiao Li, Yu Meng, Zhenyu Pei, Min Lin

Efficient separation of trace muscovite from the surface/interface of quartz grains was accomplished during oxidizing calcination and catalytic pressure leaching of the hydrothermal quartz. Experimental results suggest that 98.97% or more of the muscovite was separated when quartz sand was calcined at 900 °C for 5 h and then leached by hydrochloric acid and ammonium chloride solutions as substitutes for leaching agents containing fluorides. The chemical processing techniques show high selectivity in purifying quartz sand by transforming mineral muscovite into active structures during oxidizing calcination, and then dissolving the active substances during catalytic pressure leaching

By David J. Boron

The United States has the largest total (364 billion metric tons) and recoverable (182 billion metric tons) coal reserves in the world.1 However, progressive coal utilization in this country has been hampered by environmental constraints, such as restrictions on sulfur dioxide, nitrogen oxides, and particulate emissions. New technologies are being pursued both to appease these environmental concerns and improve economic performance and process efficiency. These technologies, however, have not reached the level of effectiveness required for optimum operation. If more stringent emission standards are imposed, it is likely that the coal industry, and the industrial and utility sectors will look increasingly toward the successful development of new and advanced coal cleaning technologies in order to continue and promote the use of coal in this country. The EPA New Source Performance Standards In 1979, the Environmental Protection Agency in response to the amendments to the Clean Air Act of 1977 issued new source performance standards (NSPS) for utility and industrial boilers. The NSPS set emission standards for sulfur dioxide, nitrogen oxides, and particulates affecting boilers of 250 MM Btu per hour heat input or 'greater that started construction after September 1978. Plants starting construction or in operation before September 1978 remained subject to the provisions of the regulations promulgated in 1971, i.e., SO2 emissions of 1.2 15/MM Btu. The NSPS for SO2 emissions provides a sliding scale for SO2 reduction depending on the sulfur content of the run-of-mine coal, with an upper limit of 1.2 lb of SO2 per million Btu and a minimum emission level based on 70% SO2 removal. Table 1 summarizes the EPA NSPS for SO2 emission standards.

Jan 1, 1983

By Robert Morgan

The mind-set that only blasters and their helpers need training in explosives can result in risk to other employees working at mine or construction sites where blasting is conducted. Misfires are not always immediately obvious during postblast examinations performed by the certified blaster in charge; the presence of undetonated explosives may not appear until well within the muckpile as was the case in the photo, right. To avoid accidents involving misfires, follow safety procedures specified in mine safety regulations, and the ISEE Blaster’s Handbook that include the following:

Jan 1, 2004

By R. V. Ramani

This volume is the fourth of a four-volume final report on research carried out under a contract from the U.S. Bureau of Mines on the development of a computer simulation model for surface mine reclamation planning. The other volumes are titled as follows: Volume I: Ore Reserve Estimation, Volume II: Dragline Model, and Volume III: Mine Coordinate Generator System. The Open Pit Materials Handling Simulator (OPMHS) was first developed" in 1971 and modified and updated in 1975. The present work is an update of the 1975 version and provides a direct link between the geology and reserves system and the various activities of the mining equipment in a mining system. Also, the modeling techniques in OPMHS/2 have incorporated a flexible method for describing various equipment (shovels, trucks, belts, trains, etc.), locations, their sequence of operations, place changes, and their interactions. These features allow for studying mining equipment selection, mining method analysis and reclamation planning. This report describes the Open Pit Materials Handling Simulator Version 2 (OPMHS/2). The report details the program features, operation, and application. Through an extensive set of appendices, the data input sequence, input variable definitions, sample data listing and program output are presented in detail.

Jan 1, 1985

By H. Hubert

THE first attempts at direct utilization of blast-furnace gas in engines were made in 1895. For a considerable time the gas had been burnt in Cowper stoves for heating the blast for the furnace, and under the boilers which supplied steam to the blowing-engines, and others serving the furnaces. It was natural, therefore, that the idea of directly employing it in gas-engines should have occurred simultaneously to several engineers, notably to Lürmann and to Lencauchez, who had pointed out the blast-furnace as a powerful -gas-producer. Nevertheless, nowhere had any attempt been made to apply it to this purpose up to the end of 1894, when Thwaite proposed it to Mr. James Riley, of the Glasgow Iron & Steel Company. About the same time investigations were being made in Belgium and in Germany, independently of Thwaite's experiments, which were not generally known on the Continent. The industrial world, which up to that time had hardly favored the idea, had thus been gradually prepared to receive it. The gas-engine, long restricted to small sizes and dependent upon the use of an expensive fuel obtainable only in large centers, now began to make headway. At the Paris Exhibition of 1889 two engines of 100 h.p. were shown and excited much interest among engineers. One had four cylinders, and was made at the celebrated works of the Deutz Company, and the other was a single-cylinder engine, exhibited by two French designers, Messrs. Delamare-Deboutteville and Malandin. In the meanwhile the design of gas-producers had made important progress, completely freeing the new engine from its

Nov 1, 1906

By Ernst Lindemann

The SMS group has developed the ultrasound technology “HD scan” for inspection of the internal quality of as-cast products. This method of sample analysis requires less preparation work and is safer than the current, most common technique of etching and/or sulphur printing. Furthermore, this technology offers a three-dimensional view into the sample of the cast product and thus more representative information for a better quality evaluation. The internal quality evaluation can be performed automatically and objectively by software based on clear statistical methods. A quantitative centerline segregation rating can be assigned to each sample, based on the size and distribution of segregates detected by the unit. Internal crack statistic (length, position, orientation, etc.) and narrow side profile can also be measured. Grain macrostructure can also be visualized which allows for a potential optimization of casting parameters like strand cooling, soft reduction or electromagnetic stirring. The accuracy of the new method was proven by parallel metallographic investigations of more than 100 samples of different steel grades and sample shapes. Automatic defect evaluation and classification was compared against macroetching results. It was found that HD scan identified more defects and the visualization of the macro structure could be performed in more cases than with macro etching. All tests, comparisons, further developments and analyses for various steel producers and steel treatment companies have been conducted at the HD scan unit, located at the SMS group headquarters in Düsseldorf, Germany (Figure 1). Based on the results, SMS group has designed a unit which can be used in industrial scale.

Aug 17, 2017

By ALEX. S. THOMAS

HOWEVER good a furnace may be in regard to design, etc., or however excellent in the quality of the gas used, a suitable heat for the successful working of the metal cannot be obtained unless the melt be coated with a proper quantity of slag. This coating may be excessive or it may be deficient in quantity. The right degree of heat is the essential condition of successful working, for the quality of the steel made is never very good when the metal is allowed to simmer in the furnace for an excessive period, and this heat cannot be obtained if the metal is not protected by a proper covering of slag. This is not only to prevent the metal being over-oxidized and wasted, but also to prevent the metal being chilled when exposed with only a thin covering of slag. The slag may be obtained in either of two ways : 1, naturally, by the presence of sufficient silicon in the iron used, to unite with iron oxide to form a staple slag ; or, 2, by the addition of slag or free silica. In the first case the slag is formed naturally by the action of the oxygen in the flame - i.e., the oxidizing atmosphere of the furnace-on the silicon in the metal when melting. The charge then melts, as it is termed, "thick," and protects the banks from being cut. If too much silicon be present, however, and an excessive quantity of slag be formed, it will be found to be rather infusible, and unless care be taken to add the oxides quickly and follow the furnace up-thus rendering the slag more fusible by the extra iron oxide-the furnace bottom is liable to be pulled up. In such cases the author has frequently been able to warn

Nov 1, 1906

By J. L. Wiley

[NOTE. - P before the number indicates that the ab tract appears in patent section. Abstract numbers without. P appear in literature section. A Abietic acid, hydrogenolysis - 404 Acetone, recovery - P-4024 Acetylacetonate catalyst - P-3352, P-3664, P-6067 Acetylene, production - P-2556, P-3169, P-4064, P-4221, P-4222, P-5002 Acid catalyst - P-4584 Salts - P-4555 See also Specific acid. Acid treatment. See Procedure. Adsorption. See Hydrogen, adsorption. Agitation. See Equipment, agitators; Procedure. Alcohols: Decomposition -1128 Hydrogenation - P-3288, P-4743 In motor fuel - 1486]

Jan 1, 1952