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By CHAS. A. R. LAMELY

In the extreme northeast corner of the State of Washington, on the Canadian border, lies the Metaline mining district. This district is old in history, but young in production. The Metaline district is a zinc-lead area of the replacement type in dolomite and limestone. The ore bodies of the Josephine horizon are in many ways similar to the ore bodies of the famous Tri-State zinc fields. The beds are faulted and folded and have varyng low dips in varying directions, and underlie large areas of the district. Production started in 1927 on a very limited basis. The property is now mining and milling 700 tons per day. The mine is opened by adit tunnels and a vertical shaft. As the ore horizons gained depth, it was necessary to sink inclines to follow the ore horizon (see Fig 1). From 1927 to date, approximately 600,000 ft of diamond drill was put down This work indicated that sufficient tonnage existed to justify a redesigning of the whole operation, surface and under- ground. After four years of general study, the following program was planned :

Jan 1, 1949

By Diego Moisés Maciel Vieira

Aços resistentes à abrasão possuem alta dureza, sendo largamente utilizados em aplicações nas quais o componente é submetido a situações em que é exigida alta resistência mecânica e resistência ao desgaste. Podem ser empregados para fabricação de implementos rodoviários, implementos agrícolas e na indústria de mineração. O presente trabalho visa analisar a influência da espessura dos corpos de prova de Charpy-V na energia de impacto absorvido em amostras de aço resistente à abrasão da série 450HB. Os corpos de prova foram usinados com as dimensões padronizadas pela norma ASTM E23 [1]. Os resultados obtidos demonstram uma redução nos valores de tenacidade ao impacto com a redução da espessura, explicitando a importância do método da energia relativa absorvida para análise dos resultados dos ensaios que abordam variação de espessura.

Aug 16, 2017

By A. Ang-Ug, L. Gurieff

"The Phu Kham Cu-Au mine in Laos is owned and operated by Phu Bia Mining Limited. The deposit is a complex and low grade Cu-Au porphyry ore. The rougher feed has a particle size distribution of 80% passing 110 µm, and the rougher concentrate is reground for cleaning to 80% passing 25 µm. The Cu losses in the cleaning circuit are primarily in the <12 µm fraction. A randomised paired ON-OFF test of magnetic conditioning in one of the two parallel cleaner 1 circuits was undertaken. The results showed that with magnetic conditioning there was approximately a 10% reduction in the <12 µm Cu distribution in the cleaner 1 tail to a 98% level of confidence. The Cu distribution in the <12µm fraction is a less variable measure of changes in the <12µm Cu recovery, therefore, this was used to evaluate the impact of magnetic conditioning. Subsequently, magnetic conditioning was installed in both cleaner 1 circuits and the plant results monitored after this installation. Comparing the plant results immediately before and after this installation showed that there was a 20% reduction in <12µm Cu losses to the cleaner tail. INTRODUCTION The Cu-Au, Phu Kham Mine (PKM) is located within PanAust's Phu Bia Mining Contract Area in Laos, approximately 140 kilometres from the capital city, Vientiane. PKM is PanAust's flagship operation and the significant cash flow generated by PKM has supported PanAust’s growth, while contributing to a strong balance sheet. PKM comprises an open-pit mine and a conventional milling and flotation operation that produces and exports a Cu and precious metals concentrate. The concentrate contains around 23% Cu, 6 ppm Au and up to 35 ppm silver. Process Overview The PKM deposit consists of complex heterogeneous mineralogy horizons of Cu-Au stockwork and skarn mineralisation. It contains areas of soft-leached zones, overlying transition zones and supergene chalcocite dominant secondary Cu mineralisation and clay-rich gangue. Areas of high As and Zn also pose a challenge in treating the highly variable ore. In addition, hardness of the ore increases with deposit depth. The ROM is hauled to a primary gyratory crusher to produce a coarse ore stockpile with size distribution suitable for the 13 MW semi-autogenous mill. The SAG product feeds two parallel ball mills each equipped with a cyclone cluster producing a product particle size distribution of 80% passing 110 µm. The conventional flotation circuit consists of two parallel rougher banks. The rougher concentrates feed the regrind cyclone where the underflow is split and reports to two parallel, 3MW, M10000 IsaMills. The regrind mill discharge combines with the regrind cyclone overflow with a product particle size distribution 80% passing 25 µm and reports to the Jameson cell."

Jan 1, 2018

By G A Brown

Environmental legislation is changing rapidly throughout Australia at the present time, and with that change comes additional responsibilities for the mining and petroleum industries. Among the many changes that are being made are increased penalties for both criminal and accidental environmental impairment. The defences for criminal offences are limited and for other offences the laws may impose strict liability - in effect the offender is guilty until proven innocent. Mines may be included under contaminated land legislation, creating additional liabilities for clean-up, rehabilitation and long-term management. It is not unknown in Australia for the value of a mortgaged property to be less than the amount of the environmental liability acquired by a mortgagor in possession due to contamination of the site. An essential part of the management program for resource projects is now the regular conduct of an environmental audit, the results of which assist in the management of the legal and financial liabilities facing company directors and managers. The audit can also assist with negotiations with government agencies, staff, unions, insurers, Aboriginal and other community groups. An environmental audit may also help to ensure that companies are claiming the maximum allowable deductions for environmental works under the tax laws, and provide evidence in support of such claims. Environmental legislation affecting resource industries Environmental legislation in Australia is changing rapidly and can impose massive constraints, substantial administrative costs, and considerable liability on directors, managers and the corporation. Pollution control legislation Every State and Territory of Australia has a range of pollution control legislation contained in either individual acts relating to air, water, noise and land, or embodied in a single environment protection act. Pollution control legislation provides a critical management baseline for resource industries throughout Australia, often requiring the full-time attention of an environmental manager or an environmental department. In general, it is an offence to discharge effluents into water, or emit gases into the atmosphere above prescribed limits, cause noise above a regulated level, or contaminate land without a licence. A licence determines how much of a substance can be discharged, the location, the receiving environment, the quality, and the time at which discharges can be made or noise can be caused. Planning legislation Planning legislation controls where a project is located, how it will be constructed and operated, how large it is allowed to be, and what will happen once the project is completed. Development consents or approvals will generally contain a range of conditions controlling the preparation of the site, the construction of the facility and the way it is operated throughout its expected life time. Resource projects may be regarded under legislation as scheduled or designated developments requiring special treatment during the decision-making process. Under planning legislation, it is usual for resource projects to be subject to an environmental impact assessment process. Resource legislation Resource legislation specifically covering mining and petroleum in Australia, also contains requirements regarding protection of the environment during exploration for and extraction of minerals and oil. A mining or petroleum production lease usually contains numerous conditions regarding protection of the environment and rehabilitation of the site during and after the life of the extractive process.

Jan 1, 1994

By Adam Zagorski, Rusty Lucido, Curt Scheyhing

"The current California Department of Transportation (Caltrans) practice based on AASHTO LRFD Bridge Design Specifications is to use the O’Neill and Reese method (FHWA, 1999) for calculating the side resistance and base resistance of Cast-in-Drilled-Hole (CIDH) piles / drilled shafts. In this calculation, end bearing is typically neglected for piles constructed using a wet method due to questionable reliability of end bearing resulting from soil disturbance and inadequate cleaning of the base. Pressure grouting below the tips of drilled shafts in cohesionless soils has long been used worldwide to provide reliable end bearing capacity, but for decades it was relatively unused in this country. It has been used increasingly in the United States over the last decade. Before this project tip grouting has not been utilized on or accepted by Caltrans to maximize piles end bearing capacity. This project proved that tip grouting to mobilize reliable base resistance can be successfully implemented on a full-scale bridge project requiring over 350 large diameter shafts.For the Gerald Desmond Bridge Replacement Project, Shimmick/FCC/Impregilo, JV utilized a temporary Oscillator casing to the full depth to install CIDH piles. Piles were constructed by the wet method and then pressure grouted below the pile tip. A tip grouting procedure for these large diameter shafts was developed and tested to specifically address the geology and constraints of the project. This procedure was then proven during the Load Testing of test piles during the Test Shaft construction phase of the project. Tests showed a minimum reliable base resistance of 150 ksf could be mobilized in very dense sand at a downward movement of 5% of the pile diameter for piles ranging from 4.9 to 8.2 feet in diameter. By tip grouting, the length and diameter of the piles were significantly reduced."

Jan 1, 2017

By G. Goellner

The thick alluvial sand and gravel deposits along the base of the San Gabriel mountain range in Southern California area have been mined for construction aggregates for over 100 years. Encroachment of high-density urban populations in this area has led to concentrated mining in a handful of open pit mines with single production faces reaching up to 55 m (175 ft) in height, and long transportation distances from the pit to the processing plant. Aggregate producers have responded to these challenges by developing innovative mining systems which enable low-cost, full-face mining of the alluvial material, and low cost delivery of this material to the plant.

Jan 1, 2004

By M. G., Corson

1. In addition to the alloys of copper with iron previously found by Hanson and Ford to show an increase in the concentration of the alpha range with increase in temperature the following binary and ternary systems have been found by the author to exhibit: the same feature: (a) Copper-chromium. (b) Copper-cobalt. (c) Copper-silicon. (d) Copper-nickel-silicon and its pseudo-binary section Cu-Ni2Si (formula of compound definitely established). (e) Copper-cobalt-silicon and its pseudo-binary section Cu-Co2Si (formula of compound established with some probability but not as definitely as for Ni2Si). (f) Copper-chromium-silicon; formation of a compound definitely established (compare Figs. 1 and 2). The formula of this compound may be either Cr2Si or Cr3Si. (g) Copper-iron-silicon; presence of a phase containing both iron and silicon established in an indirect way only. No definite microconstituents observed. 2. RANGES OF SOLID SOLUBILITY (percentage at various tempera¬tures). (a) For copper-chromium: 0.8 at 1000° C.; 0.5 at 900° C.; 0.25 at 800° C.; 0.05 to 0.1 at 500° C. (b) For copper-cobalt: 3.4 at 1000&apos;C.; 2.4 at 900&apos;C.; 1.7 at 800&apos;C.; 0.9 at 600°C.; 0.35 at room temperature. (c) For copper-silicon (Fig. 3) : 6.8 ± 0.1. per cent. at 800° C.; 3 per cent. at 400° C. and probably below 2 per cent. at room temperature if sufficiently long annealed. (d) For copper-cobalt silicide: 3.3 at 1000° C.; 2.4 at 900° C.; 1.6 at 800° C.; 0.7 at 600° C.; 0.3 at 300° C. (e) For copper-nickel silicide (Fig. 4): 8.2 at 1000° C.; 5.5 at 900° C.; 3.6 at 800° C.; 1.6 at 600° C.; 0.7 at 300° C.

Jan 1, 1927

By J. E. Tress

The Bureau of Mines prepared submicron tungsten powder by reducing tungsten hexachloride with hydrogen. The particle diameters of the resulting tungsten powders ranged from 0.015 to 0.046 micron. Within the limits of the variables investigated, no clear-cut correlation was found between process conditions and final size of the powder. Oxygen was the major contaminant in the product; being present both as an adsorbed gas and as suboxides of tungsten. Studies showed that the powder yielded compacts of approximately 45 per-cent of theoretical density when compacted mechanically. Low-temperature sintering produced more rapid densification in these compacts than in compacts prepared from conventional powders. Adding up to 20 percent ultrafine powder to conventional tungsten powder caused an increase in density upon compaction with maximum densification occurring at approximately 12 percent ultrafine powder.

Jan 1, 1966

By Jerry W. Ramsey

The Bureau of Mines studied two Pennsylvania anthracites using low-temperature carbon dioxide adsorption. A modified form of the Brunauer-Emmett-Teller equation was used to calculate specific surface areas. Two mesh sizes of each anthracite were used to determine how gamma irradiation at 106 and 108 rads, both in vacuum and in the presence of air, affected the carbon dioxide surface areas. Results show that anthracites have a system of pores that are essentially all interconnected rather than isolated; that anthracites differ from one another in specific surface, which may correlate with density; and that irradiation in vacuum has no discernible effect on specific surface of anthracite, but irradiation in air does produce changes in specific surface.

Jan 1, 1966

By S. A. Saki, J. F. Brune

"INTRODUCTION Longwall coal mining leaves large areas where the coal has been made removed and the roof rock strata collapse, forming a zone of broken rock rubble called the gob. Figure 1 shows a typical longwall gob area along with the gate roads. The ventilation pattern for progressively sealed longwall panels follows a simple “U” pattern where fresh air is coursed inby to the headgate, flows along the face and exhausts through the outby tailgate as shown in figure 1(a). An important variation of this pattern is the back return (BR) arrangement where the exhaust air from the face is drawn inby and around the nearest open cross cut before it turns in the outby direction towards the exhaust fan. Figure 1(b) illustrates the use of back return. This arrangement moves the point of low pressure from the tailgate corner up to 60 m inby and thus maintains fresh air in the tailgate region that could otherwise be contaminated with gob air.The gob area may contain remnants of unmined coal or parts of overlying coal beds that continue to release methane, eventually filling the gob area with methane in concentrations far above the explosive range of about 4.5 to 15%. Many gob areas must be equipped with gob ventilation boreholes (GVBs) to extract methane, and GVBs often exhaust methane at concentrations from 50% to 90% (Saki, 2016). Due to oxidation processes occurring in the gob, the oxygen content is reduced to a low level, with nitrogen and CO2 making up the major remaining components of the gob atmosphere. FORMATION OF EXPLOSIVE GAS ZONES IN GOBS Since the longwall face area is ventilated with fresh air below 1% methane and the face and gob areas are not separated, an explosive fringe will form where the methane content lies within the explosive range and oxygen content remains above 12%. Figure 2 shows a typical development of such an EGZ. This figure is based on a computational fluid dynamics (CFD) model developed by CSM researchers to analyze gas concentrations and flow patterns in longwall mining. Figure 2(a) shows the formation of EGZ in the gob with a U type ventilation scheme, where EGZ lies right behind the shields in the tailgate corner. Figure 2(b) shows the formation of EGZ in the gob combining U type ventilation scheme with BR, where EGZ is pushed away from the face deep into the gob. The CFD modeling parameters and boundary conditions have been verified with field data from two cooperating, active longwall mines (see Worrall 2012, Marts 2015, Gilmore 2015 and Saki 2016). Other mine geometries, methane inflow rates and gob permeability distributions can be modeled to establish representative gob atmospheric conditions. Two GVBs were operating in the model, extracting 0.165 m3/sec each. The methane in the working areas and returns was kept below 1%. Methane flowing into the model from a rider coal bed above the mined seam was at the rate of 0.55 m3/sec."

Jan 1, 2017

By Tianzu Yang, Weifeng Liu, Shu Bin, Lin Chen, Wanda Bin

"Vanyukov Process has been mainly applied for processing copper and nickel sulfide ore for more than 30 years. Based on the understanding of the Vanyukov Process, researchers from China introduced the technology into the areas of lead, antimony and bismuth extraction by changing the furnace structure and technical flow, which greatly extended the application area and raised the processing efficiency, thus developed the oxygen-rich side-blow bath smelting (OSBS) technology in 2000. This contribution reviews the history of OSBS technology from four respects: the quantity, the furnace structure, the process flow and the application area. Its potential research direction and industrial application are also summarized.IntroductionVanyukov bath smelting furnace and related bath smelting technology were developed by researchers from Soviet Union who devoted comprehensive research on fundamental theory as well as engineering technology [1,5]. Vanyukov process has been applied for large industrial production since the 1970s and it is still one of the major methods in modem pyrometallurgy process. The appearance ofVanyukov double district furnace and joint double furnace in the past ten years, which are applied for copper smelting, is the most valuable advances of the Vanyukov process [7,8,9]. However, the application ofVanyukov process was limited in copper and nickel sulfide ore smelting, and few countries adopted this process except Soviet Union."

Jan 1, 2013

By H. P. Greenwald

[For sarno years past the Safety in Minbr. Resaarch J30ard of Great Bri tr-dn ha:1 been making ar.. intensive Gearch for, traterials that \.&apos;ould be 1!\ore ef-ficient than rock dust and th t &apos;could l1eplace it Jholly or in El:}rt as a muans of prevEll&apos;ltine the propa &apos;tion&apos; of &apos;c63.1~dust exnlosions in. mines21 In the course of this \o.&apos;ork several rock c.ur--ts md numerous inorganic compounds I,/ere tested. The result w place incombus.ti ble substFlnces in two main groups~ (1) r.:ho se who sa effect&apos; in suppre aeina Jlihe cor.lbustion of coal dUDt i 0 pro-]

Jan 1, 1940

By Tianming Sun, Gabriella Tranell, Ragnhild E. Aune, Mark William Kennedy

Rare Earth Elements (REEs) are critical for the production of many advanced materials and products. Mining and primary production of REEs are generally associated with significant environmental impacts. By recovery of REEs from secondary sources, through recycling or as a byproduct, the adverse environmental impacts may be partly avoided. In the present study apatite concentrate originating from iron ore beneficiation done by LKAB in Kiruna, Sweden, is explored as a possible source for REEs. The composition and distribution of the REEs within the concentrates are studied using ICP-MS, XRD and SEM-EDS/EPMA, as well as the melting point and heat of fusion using DTA-TGA-MS. The behavior of the material during melting has also been studied through wetting and slag saturation experiments. The overall aim of the study is to evaluate the implications for future smelting experiments aimed at concentration and recovery of the REEs.

Jan 1, 2015

By R. Srikanth

Dust control in high production longwalls is a major problem requiring, among other things, careful attention to the design of operating practices, and ventilation schemes. Several studies have shown that the shearer is the major source of dust on a longwall face. Support movement has not been regarded as a major source of dust in U.S. longwalls; yet under certain conditions, 31 percent of the shearer operator&apos;s dust exposure can be due to support movement. Several methods have been developed for the control of shield-generated dust. Yet the need for better methods is apparent. In this paper, the amount of airborne respirable dust generated per shield move is estimated from specially designed experiments on longwall faces. A total of ten experiments were conducted in five longwall faces in four different mines. Each experiment involved one face visit and lasted three to six hours. The contribution of shield movement to the airborne respirable dust concentration immediately downwind of the shield moved, varied between 0.12 and 1. 75 mg/m3 in the five longwall faces. The mass of airborne respirable dust generated by shield movement was found to vary between 39 and 386 milligrams per shield move. The results from this study reveal that control of dust from longwall shields requires a combination of approaches involving alternative operating practices, reducing shield dust generation rate, increasing face air flow, and decreasing personnel exposure.

Jan 1, 1994

By J. Chelsey Dawson

In presenting a thesis on this subject it is advisable to explain a few of the reasons for its seeming incompleteness. World progress has brought us to a position where approximations are not only to be condoned, but regarded as absolute essentials. Production in anticipation of demand is always accompanied by mistakes on the part of the producers. Only through trial and sometimes erring hypotheses may there be evolved the true course and theory upon which the steady triumphant march of world-wide industry depends. The average person likes to have everything placed ?before him in a clear and convincing manner. It is the impossibility of doing this which, in many cases, arises to confound the writer on shales. All that one can do is to present, as lucidly as possible, the known hypotheses&apos; and theories on the subject and leave the reader to study and work out the truth for himself. Many theories have been advanced on the origin of oil-shales ; some may be correct in certain instances and not in others; however, the writer will attempt no decision as to which are and which are not correct, but .will merely point out the relative merits of each. The figures given for reserves of oil and shale in different countries are only approximations and give but a rough idea of the true conditions.

Jan 1, 1925

By N. Ahern, L. Manoukian

"Cyanide is a leaching agent for precious metals commonly used in gold ore processing. Cyanide exists in various forms (including free, complexed as weak or strong complexes, and as ions such as cyanate and thiocyanate), so its detection, speciation and analysis in processing or environmental samples can be complex. This paper will review best practices for cyanide sampling and preservation in the field, interferences and pretreatment methods required prior to sample analysis and analytical methods that are used for cyanide species. Titrimetric, flow injection ligand exchange, spectrophotometric, colorimetric, potentiometric, amperometric, and chromatography techniques will be discussed and their chemistries, detection limits, advantages and limitations will be described.INTRODUCTION Cyanide is well known to be an extremely toxic species. Accurate cyanide measurement in effluent from mines is critical from an environmental perspective. Its measurement is also an important control parameter in the recovery of gold using cyanidation. Cyanide chemistry is diverse and complex, and cyanide analysis can be challenging as a result of and because of limitations in understanding of analytical methods. Various chemical mechanisms can form or destroy cyanide, and the sample matrix or preservation chemicals can also affect analytical results. These interferences make the collection of reliable cyanide measurements challenging and can start as soon as the sample is collected, during laboratory pre-treatment and during analysis. This paper reviews different methods of cyanide measurement. The basic chemistry of cyanide, best practices for sampling and preservation, as well as various methods of analysis will be discussed.CHEMISTRY The complexity of cyanide chemistry is well known (Beck, 1987; Delgado, Botz, Bucknam, Milasovljevic, & Staley, 2008; Botz, Milosavljevic, & Ward, 2013) and is attributed to the ability of cyanide to undergo: •,Volatilization •,Precipitation •,Adsorption •,Complexation with metals •,Oxidation to cyanate, ammonia, or cyanogen chloride •,Reaction with sulfur or sulfide minerals to form thiocyanate •,Redox reactions leading to the formation of cyanogen and cyanate •,Redox reactions (of some cyano complexes) •,Photochemical reactions (of some cyano complexes)"

Jan 1, 2017

By Larry Diaz

A single stage ball mill-cyclone circuit was extensively tested for its reactions to step changes in three controllable variables: feed rate, water to cyclones, and water to the ball mill. A series of carefully designed tests are to be carried out in order to determine relationships between the various ball mill and cyclone parameters. Cyclone overflow particle size distribution is to be continuously monitored during the tests using an ultrasonic device. Other circuit variables that are to be measured and recorded are feed rate, ball mill mass flow, cyclone feed and overflow densities, cyclone feed sump level, water flows, etc. Once the circuit performance is defined, two types of grinding circuit control systems will be evaluated: (a) mass flow-based; (b) particle size- based. Results obtained by each approach in terms of feed rate and cyclone overflow size distributions are discussed. The high sensitivity of continuous particle size measurements to grinding circuit disturbances is emphasized.

Jan 1, 1971

By Charles A. Mitke

Discussion of the paper by CHARLES A. MITKE, presented at the San Francisco meeting, September, 1915, and printed in Bulletin No. 105, September, 1915, pp. 1941 to 1958. GERALD SHERMAN, Bisbee, Ariz.-Mr. Mitke justly might have made much stronger his claim for increase in efficiency of labor due to the introduction of forced ventilation. The product per man shift in stoping in the Gardner division has practically doubled. While it is true that improved methods have been responsible for a great part of this gain, and what is due to better ventilation cannot be definitely known, yet it is also true that the results could not have been obtained in that division as it was in 1912. . The paper discusses the two systems of ventilation in use, exhaust and pressure. In both the object is the same, to take foul air or gas out of the mine by the most direct course and replace it by fresh. In coal mines, the exhaust system is in almost universal use, and since the most advanced work in ventilation has been in that class of mines, it was naturally the first one to be considered. It has the advantage of leaving all adits, shafts, or other openings free for use. Doors are only needed to direct the course of the air, and not to confine it. Its disadvantages appear in case of fire, or if the ground over the mine is much broken by subsidence. The fan must work in gas in the case of a -fire, and may be. damaged or destroyed either by heat or by corrosive gas. At the time of the fire in the Lowell division of the Copper Queen, a small exhaust fan was placed over a ventilating raise, but the vanes and housing were destroyed by sulphurous gases within a few weeks. If the ground above the mined area is much broken, as is frequently the case when the ore deposit is thick vertically, a good deal of air is likely to pass through it, particularly if it is near the surface. Leakage from this source is a loss to the exhaust system by short circuiting, which is exaggerated by a contraction or block in the air course. It serves as an added outlet in the pressure system. This is strikingly shown at the United Verde, where many jets of steam may be seen coming up through the ground above the stoped country on a cold day.

Jan 12, 1915

By Ruddle R. W.

Solid mattes are generally held to be either (a) eutectiferous mixtures of the component sulphides Cu2S and FeS or (b) mixtures of complex sulphides. This chapter shows that liquid mattes consist essentially of a homogeneous phase in which iron, copper and sulphur are present. The amount of sulphur is generally less than that required to account for all the metals as stoichiometric sulphides; mattes cannot therefore be regarded as mixtures of FeS and Cu2S. Some iron oxide may be dissolved in the sulphide phase and magnetite is often present as a second phase. If the sulphur content of the matte is reduced the composition enters the miscibility gap in the ternary system and either an iron- or copper-rich solution (depending upon the composition of the matte) separates as a new phase. On solidification any one of four phases (iron, copper, Cu2S and FeS solid solutions) may crystallize as primaries. The remainder of the matte solidifies as a ternary eutectic. It is possible that iron oxides enter into this eutectic. Knowledge of the ternary Cu-Fe-S system is far from complete and nothing is known of the quaternary system Cu-Fe-S-O

Jan 1, 1953

By José Luiz Rodrigues Bravo

The production of electrolytic copper with assured quality corresponding to international standards, in a conventional electrorefkery of a custom smelter, is a hard and cautious task, if no advanced technologies for selective control of electrolyte impurities are available. The improper control of the amount of As , Sb and Bi in the anode that enter the tankhouse , attributable either to a bad schedule of concentrate input or to the unavailability of clean concentrates in the international market , as well as the lack of means to maintain the suitable level of these elements in the electrolyte together with other operational circumstances, can result in off-grade copper, as well as affect the starting sheet chemically and physically. This paper presents in a practical way the relationship between the operational conditions and the cathode and starting sheet quality produced at CMSA, covering the period of the last five years of operation, discusses the technologies available in the market for antimony and bismuth removal and compare the results of testwork, achieved in the laboratories of CMSA, using two resins not associated with patented technologies.

Jan 1, 1997