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By A. Paulin, J. Roth, S. Spaic

This experiment was carried out to see whether copper-iron ingots from Late Bronze Age hoards could have been produced by smelting ferruginous copper ores. Since ferruginous copper-ores are chalcopyritic, chalcopyritic concentrate from a present day copper mine was dead roasted in our experiment in lieu of a rich chalcopyritic ore. Charcoal was used as a reducing agent in the reduction of calcine (i.e., a product of dead-roasting), and quartz sand was used as a flux. Two separate metallic solutions, a copper-base and an iron-base alloy, were obtained as a result of two factors: the presence of carbon and the miscibility gap in the Cu-Fe-C system. The metallic melts appeared in a form of bigger or smaller droplets, enclosed by a molten slag which, during the cooling, solidified into metallic beads. The presence of both metals was noticed in the majority of the examined beads. It was therefore concluded that calcine consisted of an intimate mixture of oxides of both metals which were simultaneously reduced during the reduction process. Due to the miscibility gap in the Cu-Fe-C system, separate iron and copper regions were formed in the beads. In both regions, sulphide inclusions were found. The formed molten copper and molten iron solution were found to be saturated solutions. The metallographic analysis revealed the precipitation of iron out of copper and that of copper out of iron during the cooling and solidification of melts. The formed slag contained little iron and no copper oxide.

Jan 1, 2001

By J. A. Harle

Introduction When considering power in Alberta, there automatically come to mind ideas of either hydro or thermal generation, leaving in one's thought an uncertainty as to which one would propose. There is frequently an obvious source of power in some locations on our fastflowing rivers, the major possibilities being described in the report on Surface Water Supply and Water Power of Alberta issued by the Alberta Government in 1948, but it must be realised when reading that report that the sites so described will require extensive geological and other surveys before they can be exploited, and account must be taken also of the transmission distances involved in each instance. From a conservation point of view, where water power can be economically developed and power transmitted to the load centres, this should be done, and our thermal resources should be husbanded for our coming generations, especially if our water resources are falling owing to glacial shrinkage.

Jan 1, 1951

By B. W. Frazier

This interesting application of the laws of thermodynamics to metallurgical practice has not been discussed by any writer, within my reading, except the late Prof. Callon of Paris. In his Cours de Machines," Prof. Callon has given a short but lucid discussion of this subject in the admirably clear style for which he was remarkable. Although the interest attached. to the subject is rather theoretical than practical, I have thought that an attempt to explain the mechanical action exerted in the hot-blast oven might not be entirely devoid of utility, especially in the suggestions which it involves. The statement, that the mechanical work performed in heating the blast is, when high temperatures are produced, considerably greater than the work performed by the blowing-engine, may seem incredible to many who are practically acquainted with the subject, appearing, as it does, to conflict with the results of their experience. It is, nevertheless, literally true, and I shall attempt in this paper to prove it, and to explain why it has not rendered itself palpably manifest in practice. Before proceeding to the mathematical demonstration, it will be well to recall to mind the definitions of some terms employed by writers in mechanics and thermodynamics. The actual energy of a moving body, as defined by Rankine, is the work which it is capable of performing against a retarding resistance before being brought to rest, and is equal to the energy which must be exerted on the body to bring it from a state of rest to its actual velocity. The value of that quantity is the product of the weight of the body into the height from which it must fall to acquire its actual velocity.

Jan 1, 1879

By Scott A. Walker, Gabriel J. Alcantar, Brian Zuckerman, Ramin Golesorkhi

"The new San Francisco 49ers Levi’s Stadium is part of the next generation of sporting facilities. Constructed in Santa Clara, Calif., the new structure has 68,500 open-air bowl seats and includes a 7- story tower housing more than 150 suites. The overall project includes the stadium structure, elevated open pedestrian walkways, commercial community space, three new pedestrian bridges and improvements to the adjacent light rail station. Sustainable design for the project includes a green roof, photovoltaic panel and a ground source geothermal system. Stadium-wide next-generation Wi-Fi capability is another feature. The design-build project team included HNTB (project architect), Magnusson Klemencic Associates (MKA, structural designer) and a joint venture of Turner Construction and Devcon Construction (TDJV, general contractor).During preconstruction, the 49ers’ original design team and the design-build team formed later worked together to facilitate communication and provide continuity. This helped to meet the project’s aggressive schedule. Working directly for the 49ers, with the design-build team, Treadwell & Rollo (T&R) served as the geotechnical engineer of record for the project from preliminary to final design and through construction. Although not contracted directly to TDJV, the stadium ownership encouraged direct interaction between T&R and TDJV and improved responsiveness to geotechnical issues during design and construction.Subsurface ConditionsThe new stadium lies within the Santa Clara Valley, a deep alluviumfilled basin resulting from historic movement on the active and potentially active strike-slip and thrust faults that bind the valley. The valley is filled with Holocene age (approximately 11,000 years old to present) alluvium, consisting of levee and basin deposits, with bedrock more than 750 ft (229 m) beneath existing ground surface. The stadium site is between two of the highly-active faults in California, the Hayward Fault 6.8 mi (11 km) northeast, and the San Andreas Fault about 11.8 mi (19 km) southwest."

Jan 1, 2014

By Ben C. Gerwick

This publication is intended to document recent innovations and technologies that have the best potential for effectively improving the quality of marine foundations while reducing the cost, time and risk of construction. Marine foundations originated in Neolithic times with the Swiss Lake Dwellers who constructed pile-supported houses, safe from invading tribes. The Queen of Babylonia built the first recorded bridge in 1500 BC across the Tigris. The foundations were large flat stones laid on the river bottom. About the same time in India, builders extended their water well techniques to the construction of ?well? foundations in the beds of their rivers. These were really the first open caissons; brick walls were built up in a circular ring while divers excavated sand from the bottom, sometimes at a depth of 100 feet. The Romans extended the clay-filled cribs of the Middle East to shallow cofferdams, which they sealed by underwater concrete made with pozzolanic cement from Mt. Vesuvius.

Jan 1, 2013

By R. M. Santmayers

[This paper presents one of a series of digests of foreign mining legislation that is being prepared in advance of a general report relative to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the mining legislation of Bulgaria was prepared from a copy (in French) of the Mining Laws of Bulgaria, promulgated by Royal Decree No. 33 of I. arch. 31, 1910, and published in the "Journal Official," No. 83, April 14, 1910, and checked against a digest prepared by Maynard B. Barnes, First Secretary, American Legation, Sofia, Bulgaria, dated June 10, 1932, which was transmitted through the courtesy of the Department of State. CLASSIFICATION OF MINERAL SUBSTANCES Mineral deposits are classed either as mines or quarries. (Art. l.) Tunes are deposits, the products from which must be processed. Under this class specific mention is made of the metals (gold, silver, copper, lead, zinc, iron, chrome, titanium manganese, tungsten, tin, mercury, platinum, cobalt, nickel, cadmium, aluminum, molybdenum, bismith, uranium, antimony, arsenic), sulphur and other "analogous" mineral substances, phosphate rock, iron pyrites, sulphates, saltpeter, alum, boracic acid and its compounds, talc, asbestos, amber, graphite, merschaum and precious stories of all kinds, reek salt and other salt, peat, coal, petroleum, ozocerite, asphalt and all other bituminous substances. (Art. 2.)]

Jan 1, 1933

"The Australasian Joint Ore Reserves Committee (JORC), which is sponsored by the Australian mining industry and its professional organisations, developed the JORC Code to provide minimum standards for public reporting. JORC was first published in 1989 and later incorporated into the Listing Rules of the Australian and New Zealand Stock Exchanges making compliance mandatory for listing public companies in Australia and New Zealand."

Jan 1, 2003

By Charles B. Carpenter

For many years, studies of ground movement and subsidence accompanying subsurface mining operations have been part of the research program of the Bureau of Mines. Periodic observations by engineers of the Mining Division of the Bureau of man-built structures beneath which mining operations are conducted offer indisputable evidence of subsidence in the form of creeks in masonry structures and fractures and depressions in the surface of the earth. As the removal of subsurface rock and earth material by mining, especially by the room-and-pillar method, is equivalent to withdrawing some of the foundation of a building, subsidence of the formations above, the mining levels in certain areas is easily understood as a gravitational adjustment of the overlying earth formations.

Jan 1, 1940

By J Chan, T Baumgartl, A Plante, C Peltre, P D. Erskine

Mine soils are often organic matter and carbon poor due to disturbance, topsoil stockpiling and mixing with spoil. They present an opportunity to observe the accumulation of soil carbon arising from rehabilitation or ‘green carbon’ through organic matter inputs and may be considered for carbon credits. Soil carbon is known to improve multiple soil characteristics and is viewed as an indicator of soil health.When attempting to estimate soil carbon levels in the Australian coal mining regions, both coal and black carbon (BC) need to be quantified. Coalmine soils contain coal particles that are difficult to distinguish from organic matter using standard carbon analyses. BC, a material arising from the incomplete combustion of organic matter and fossil fuels, displays some similar characteristics to coal and is ubiquitous in Australian soils due to bushfires. The presence of coal and BC complicate the determination of green carbon levels in mine soils.A method to quantify coal and BC in mine soils from the Bowen Basin using thermal analysis and multivariate curve resolution is presented. By determining BC and coal contributions it is then possible to calculate green carbon levels in rehabilitated mine soils. Calculated green carbon levels are compared with bulk density as soil quality indicators.CITATION:Chan, J, Baumgartl, T, Erskine, P D, Peltre, C and Plante, A, 2014. Distinguishing carbon fractions in coalmine rehabilitated soils, in Proceedings Life-of-Mine 2014 , pp 491–498 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By J. W. Cox, W S. Jones, A E. Chase

For a long time the Oil Industry has been looking for a logging tool which can determine the quality of the cement job behind casing. Older methods such as Temperature Surveys and Radioactivity Surveys might detect the presence of cement behind the casing, but short of production tests, it was impossible to tell that the producing zones were adequately sealed off from adjacent zones. A new logging method, which is called the •Cement Bond Log, operates on the principle that a sonic pulse transmitted by the casing is greatly attenuated when the casing is strongly bonded to an outer annulus such as cement. The down-hole tool consists of a source of sonic energy which is detected by a receiver situated a few feet away from the source. The amplitude of the detected energy is measured and the resulting signal transmitted to the surface where it is recorded versus depth. Amplitude is a function of attenuation and thus the log is readily interpreted.

Jan 1, 1961

By P. E. Fitzgerald

SOME readjustments in the research programs of most of the oil companics and petroleum engineering schools have been made necessary by the war. The most obvious change has been the conversion from production engineering to problems more closely related to the nation's was effort. Many laboratories now devote much of their time to studies on products to be derived from petroleum. such as synthetic rubber, toluene, and substitutes for critical materials. Others are working to improve motor fuels including high-octane gasoline and the special lubricants required by the wide geographical range of the present conflict. Of great importance is the experience of the geophysicists, who are now devoting a great percentage of their time on instrument research and production or special apparatus required by the armed forces.

Jan 1, 1943

By Willard L. Cumings, Benjamin L. Miller

(Glen Summit Meeting, June, 1911.) I. THE CAMAGUEY DEPOSITS. 1. Location. THE Camaguey brown iron-ore deposit covers the top of San Felipe hill, the nearest point of which lies 14 miles NW. of the city of Camaguey. While there are several low flat-topped hills in the vicinity covered with a more or less continuous mantle of brown iron-ore, the deposit of San Felipe hill is the only one of any size and importance, and the name "San Felipe district " is proposed for the region. The deposit extends in a NW-SE. direction for a distance of about 10 miles, with an average width of 5 miles. The location is shown in Fig. 1, a sketch-map of the eastern part of Cuba. Fig. 2 is a map of the San Felipe district. 2. Description. The district is mentioned by Spencer,1 who says: "The Cubitas iron-ore fields are situated from 12 to 15 miles north of Camaguey City, in the province of Camaguey Within an area measuring roughly 10 miles east and west and 4 miles north and south, there are several flat-topped mesas rising 300 to 400 ft. above the level of an almost featureless plain which extends for many miles in all directions except toward the north." With the exception of the discrepancy in his statements as to the distance from Camaguey and the area of the hill, which is over 50 sq. miles, his description is a very good one. Kemp 2 has the following to say of ores in Carnaguey Province * Geologist, Bethlehem Steel Co. + Professor of Geology, Lehigh University. 1 Bulletin No. 540, U. S. Geological Survey, p. 324 (1908). 2 The Iron Ore Resources of the World, printed by the Eleventh International Geological Congress, vol. ii., p. 795 (1910).

Mar 1, 1911

By D van der Wal, R Dobbe, K Moeller

"Ore mineralogy and texture are primary variables controlling mill recovery efficiency in flotation plants. However, tracking daily variations of key mineralogical characteristics such as species-by-species liberation is not possible with current on stream analysers and assay lab techniques. In addition, traditional plant mineralogical analysis limited by long data turn-around times from central analysis laboratories typically provides only a time-averaged view of mill performance, e.g. by means of monthly composite feed, con or tailings analysis.This paper presents the results of a development and first field test of an on-site Automated Mineralogy solution (MLA or QEMSCAN) with the specific goal of monitoring recovery variation, ore quality and flotation performance on a mineral species-by-species and day-by-day basis, from up to twelve million direct particle observations per month. The trial was performed at a Pb/Zn-Ag operation in the US from November 2012 to April 2013. The focus of the study was three-fold: to validate the robustness of equipment and operational procedures for daily use by mine site technicians at a remote mine site to develop a methodology to boil down hundred-thousands of Automated Mineralogy particle data from size-by-size con and tailings samples to a couple of numbers meaningful to chief metallurgists to monitor recovery trend changes and correlate these to changes in the feed properties and/or flotation efficiency.The study focused primarily on the Pb/Ag rougher-concentrator circuit. Ten polished blocks of two and three size fractions of con and tailings were prepared by mine site technicians during a daily twelve hour shift. Eight hours of daily measurement time by the instrument revealed an estimate of the dayÆs recovery performance, ore quality and flotation performance for Freibergite (Ag-species) and Galena (Pb-species), within 36 hours from initial sampling. Data quality was assessed by means of calculated versus measured assay reconciliation. Cumulative sum curves of recovery performance, ore quality and flotation performance reveal trend changes with a frequency of 1 to 4 weeks. These were correlated to cumulative sum curves of e.g. locked and slimed particle classes of the mineral species of interest, attempting to identify a possible root cause of recovery performance trend changes. Systematic over-grinding and flotation chemistry issues were the primary causes of below average plant operations during the trial.CITATION:van der Wal, D, Dobbe, R and Moeller, K, 2013. Development of an on-site mineralogy solution for metallurgists, in Proceedings MetPlant 2013, pp 126-132 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 15, 2013

By C. R. Copeland

Airborne dust emission standards are receiving growing attention. This trend is motivated by significant health studies that have shown adverse health effects due to exposure to dust. Currently, the air quality standards are not specific to particles in the nanoparticulate range (<1,000 nm). However, as our understanding of health related matters increases, it is very likely that nanoparticulate standards will be adopted. It was previously believed that typical comminution and material-handling practices could not result in airborne nanoparticulates. However, experimental studies using air monitoring and SEM have verified the presence of nanoparticulates in the air as a result of comminution and material handling. This means that emerging nanoparticulate air quality standards are a real possibility for industrial operations. With this emerging problem facing the minerals industry, effective suppression methods for nanoparticulates should be explored. Systematic studies have indicated that nanoparticulates from silica can be suppressed utilizing hygroscopic reagents such as calcium chloride. This reagent was as much as 93% more effective than water in suppressing silica nanoparticulates.

Jan 1, 2007

By Herbert H. Kellogg

Graphs representing the standard free-energy of formation as a function of temperature for 21 fluorides are presented, along with estimated values for the standard free-energy of formation of 20 atedadditional fluorides. A few of the many possible uses of these data in metallurgical calculations are discussed, including the fluorination of oxides, sulphides, metallurgicaland chlorides, and the reduction of metal fluorides. RECENT papers which have presented free-energy data for oxides, sulphides, chlorides, carbonates, sulphates, and silicates in the form of free energy vs. temperature plots,1-5 have found important uses in teaching and metallurgical development work. This method of presentation of thermo-dynamic data serves to make available in readily usable form thermodynamic constants which are scattered throughout the literature, and to show by graphical means the stability relations which exist between the compounds of a given type. It is certainly desirable to have these free-energy-temperature diagrams for as many types of compounds as are of present or potential use in metallurgical processes. Thus, even though there are but few uses of metallic fluorides in extractive metallurgy today, the potential uses of fluorine processes are of great importance and serve as the principal justification of this paper. Recent developments in the production of fluoro-carbons have resulted in vastly improved methods for the production and handling of fluorine and corrosive fluorides, with consequent reduction in costs.".&apos; The extractive metallurgist should no longer overlook possible fluorine processes when development of a new process for a relatively high unit-price metal is being considered. In a previous paperv he author outlined in some detail the importance and use of free-energy data in metallurgical calculations and also discussed the properties of a standard free-energy vs. temperature diagram. The same method of presentation is adopted in this paper, and the reader is referred to the earlier work for explanations of the use of free-energy data. Thermodynamic Data This paper presents standard free-energy vs. temperature diagrams, Figs. 1 and 2, for those fluorides for which the major thermodynamic constants are known. In the calculations of the standard free-energy of formation (AGO), values of the enthalpy of formation at 298°K (?Ho,) were taken from "Selected Values of Thermodynamic Constants"8 most of the values of standard entropy at 298°K (S°298) were taken from "Selected Values"," but in a few cases the values given by Kelley9 ere preferred; data for the Phase changes came from "selected Values" and several of Kellley&apos;s publics- tions;0-12 and most of the specific-heat data were taken from Kelley.l0 The appendix gives a detailed list of the sources of the data. As explained in an earlier paper,6 he accuracy of some of the standard free-energy relationships is not high. An error of +1 kcal at 1000°C is expected in most of the curves of Figs. 1 and 2. The error may be as high as +3 kcal in some of the curves. Rather than attempt to estimate the reliability of each curve, the source of the data used is reported in the appendix, and the reader may compare these data with newer values as they become available. Figs. 1 and 2 fail to show values for the fluorides of many important metals. In most cases this is because the entropy of the metallic fluoride is unknown. For preliminary calculations it is often useful to have available the best estimate of an unknown datum, rather than no information at all. With this in mind, Table I lists estimated standard free-energy values for a number of important metallic fluorides not included in Figs. 1 and 2. The values reported in Table I were, calculated by Brewer et al.13 and are based on estimated entropy values. The estimated uncertainty of the values for each fluoride were calculated from the uncertainty values given by Brewer1&apos; for ?H°, and the entropy function.

Jan 1, 1952

By Hyunsuk Yoon, Kiho Lee, Juhyng Lee, Younghoon Jung, Junboum Park

"The environmental double pile method is presented as a device to improve the engineering properties and to clean up contamination of low-permeability soil. This method is one of the novel technologies based on the concept of one step process. It can be applied to low permeable contaminated ground for site reuse. It uses piles to improve drainage, contaminant remediation, and bearing capacity of the ground. To evaluate the on-site applicability of this technology, drainage and strength properties of the environmental double pile were assessed by a series of experiments and numerical analysis. Environmental double pile was found to be a feasible alternative method to improve contaminated soft ground.Korea is a peninsula with many coastal industrial zones. These zones are located in regions mostly underlain by soft ground with low permeability and adjacent to industrial areas that can be contaminated. Therefore, a new region-specific remediation method is required to achieve environmentally sustainable development. This research introduces the Environmental Double Pile (hereinafter, refer to as EDP) for the lowpermeability contaminated ground and focused on both contaminant remediation and soft ground improvement. Basically, the EDP is quite similar to sand compaction pile (SCP). The SCP has been studied extensively to improve soft ground (Braja 1999; Hansbo 1994; Madhav and others 1978; Taylor 1948). But unlike SCP, EDP is filled with oyster shells instead of sand and an inner pile is inserted in the center of this oyster shell filled-zone. Therefore, it is a double pile consisting of the oyster shell pile and the inner pile, as depicted in Fig. 1."

Jan 1, 2005

By W B. Edgar, S C. Dominy

High-nugget effect vein-gold systems are generally considered to be one of the most challenging of deposit types to evaluate and exploit. To potential investors and mining companies, they are viewed as high risk because of the associated uncertainties in the grade estimate and general paucity of Ore Reserves at production start-up. However, despite the well-known risks, these deposits often have a grade upside that makes them potentially attractive. The reporting of resource grade is of importance and perhaps even more so is the reporting of the associated uncertainty attached to the grade estimate. The use of the grade estimate supported by a grade range is recommended to achieve more complete and useful disclosure. The definition of the grade range can be somewhat subjective, ranging from opinion based estimates through to data-based estimates and geostatistical conditional simulation. Whichever method used, the over-riding issue must be the provision of enough data of appropriate quality and full disclosure to the public of relevant uncertainties.CITATION:Dominy, S C and Edgar, W B, 2012. Approaches to reporting grade uncertainty in high-nugget gold vein projects, in Proceedings Project Evaluation 2012 , pp 95-108 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 24, 2012

By L. Maday, V. J. Perrone, M. B. Gilbert

INTRODUCTION The Brightwater conveyance system project in King County, Washington consists of constructing about 21 km (13 mile) of effluent and combined influent and effluent tunnels. The influent tunnels will collect sanitary sewerage from the service area and convey it to the new wastewater treatment plant (WTP) site at Route 9 in Woodinville, Snohomish County, Washington. The effluent tunnels will convey treated effluent from the WTP to an outfall at Puget Sound. The tunnels will be constructed primarily under residential areas, busy suburban roads and state highways. This 21 Km (13-mile) soft ground tunneling project faced many design challenges because of the geologic and hydrostatic conditions, long tunnel reaches, and large overburden depths. Boring depths typically varied from 45.7 M (150 ft) to 114 M(375 ft) with a maximum depth of 185.6 M (566 ft) deep. Conventional empirical methods for non-mountain terrain based on a 1:1 ratio of drilled footage per foot of tunnel bore (National Research Council, 1984) for evenly spaced borings provided a good start for the Phase 1 explorations. However a continuation of this approach with closer spacing was deemed inadequate by the geotechnical team for efficiently allocating geotechnical exploration resources for the final design. This paper presents a rational approach that was used to evaluate the value of a particular geotechnical exploration boring, pump test or other in-situ test. The method of analysis, which was initially developed for rock tunnels (Einstein et al., 1978), was modified for the Brightwater project. The method considers the potential construction cost risks resulting from variable geologic conditions, the cost and reliability of the geotechnical exploration and the earned value (cost risk reduction) of performing the geotechnical exploration. PROJECT DESCRIPTION In total the land portion of the conveyance system will include approximately21 Km (13 miles) of tunnels ranging in size from 3.0 to 5.2 M (10 to 17 ft) minimum inside diameter with overburden depths of 30.0 to 168 M (100 to 550 ft) and

Jan 1, 2005

By N Bianco, D Drinkwater

The professional skills shortage is intensifying, and commentators are predicting a shortfall in supply of qualified professionals for the mining industry, ranging from thousands to tens-of-thousands by 2020 (Tuckwell, 2011; Scoble, 2011; Laurence and Hebblewhite, 2011). Human resources are already stretched, and university graduates arriving in the workplace are often moved rapidly into management positions where there is limited scope to develop their engineering proficiency. This process may well be developing excellent young managers, but our industry is producing fewer excellent young engineers (Munro and Tilyard, 2009). Many believe that it is engineering excellence that is likely to be the key to our industryÆs success in the decade to come. An innovative in-house graduate development program has been created by specialists at the JK Centre in partnership with two mining companies. This program, known as MetSkill«, has been running throughout 2012. Groups of graduates have had to identify a process plant optimisation opportunity and embark on a structured program of data collection and analysis, facilitated by a æteaching teamÆ of researchers and consultants from the Julius Kruttschnitt Mineral Research Centre (JKMRC) and JKTech. This group project culminates in a report-back session to senior company officials. Along the way, a series of short workshops and other activities provide opportunities to work on specialist skills, and support is also offered by senior technical specialists from the companies involved.This paper outlines key features of the MetSkill« program, along with a report-card on progress in 2012 and plans for further program development in 2013.CITATION:Drinkwater, D and Bianco, N, 2012. Developing minerals industry leaders by encouraging metallurgical excellence, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 287-290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By Chenyang Zhang, Zhigang Yin, Jianyong He, Yuehua Hu

"A lot of floatation reagents (collectors, inhibitors and regulators) for the beneficiation of copper ores have been well developed in the past century. However, it is still unclear about the micro interaction mechanism of these flotation reagents with copper ores. In this paper, the interaction mechanism of these flotation reagents with the copper atom on chalcopyrite has been systematically investigated by first principle DFT (density functional theory) calculations. Thirty-four specific common functional groups linked with the same hydrocarbon chain (ethyl) are optimized at a B3LYP/def2-TZVP level, the solvation effect was included with the SMD solvation model. The analysis of the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO) and nature bond orbital (NBO) charge of these reagents reveals their potential applications to other types of copper-bearing mineral. Further investigation of the thermodynamics calculations gives more reliable data to screen collectors or inhibitors for copper-bearing mineral. The flotation results from carefully reviewed literatures are in good agreement with the calculation results. This work might also shed new light on the development and discovery of highly efficient and selective flotation reagents with low cost based on the computational methods.INTRODUCTION Froth flotation,(Shean & Cilliers, 2011) a mineral processing approach, is applied to efficiently enrich valuable minerals from the mixture, which is achieved according to the dictinctive surface properties of minerals. In the past century, researchers have develped an aboundant of flotation reagents by extraction or synthetize, and many carefully selected reagents might die in the bench tests or the pilot tests before the pratice.(Bulatovic & SrdjanM, 2007) Generally, it involves a lot of cost and tedious works by conducting flotation tests to screen flotation reagents. Flotation reagents have been boomed robustly with the developing of the organic synthesis.(Liu, Yang, & Zhong, 2017) Reseachers found the specific properties of a reagent are determined by its functional groups and the length of the hydrocarbon, where the functional group is assigned as the adsorption site to adsorb onto mineral surfaces and the hydrocarbon chain is called as a hydrophobic group."

Jan 1, 2018