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By Serdar Aktaş, Özgün Küçükoğlu, Burcu Nilgün Çetiner, Mehmet Hakan Morcalı

This study compares the cementation performance of metallic iron, metallic aluminum, and metallic tin in terms of the reaction conditions and parameters in synthetic antimony chloride solutions. The effects on the antimony recovery (%) caused by the cementators’ types, stirring speed, reaction time, and temperatures were explored thoroughly. The cementation kinetics of antimony were also explored for each cementator. The activation energies were determined to be 10.99, 9.09, and 13.58 kJ mol– 1 for Al, Fe, and Sn, respectively. The results reveal that the reaction is diffusion controlled, and comparable results were obtained for each cementator. At 25 °C, 40 mg of iron powder was found to reduce all antimony ions (i.e., approx. 99% recovery), but even when 100 mg of Al and Sn cementators were used, the antimony recovery did not reach 100%. This result shows that iron is the best candidate to cement antimony out of the solution.

Jan 28, 2022

By V. F. Hollister

Computer programs developed as part of the PROSPECTOR project at SRI International can indicate where the highest grade hypogene copper occurs in porphyry copper prospects. The programs are useful in selecting drilling targets in untested porphyry deposits. Because of mineralogic, structural and lithologic variations in porphyry-type deposits, three distinct computer programs have been constructed; however, this paper considers only the stockwork type in homogeneous rock (similar to the Lowell and Guilbert model). The programs represent models in the form of inference networks that utilize the mineralogic, alteration, lithologic, structural, geochemical and geophysical data normally collected prior to a drilling decision. One example of an application of the PROSPECTOR program for a stockwork-homogeneous porphyry is given: Island Cooper in British Columbia. Computations based on the surface geologic, geochemical and geophysical data for Island Copper clearly disclose the best hypogene grade of the deposit. Other deposits were tested in the programs as well, and in each case PROSPECTOR programs indicate the region with the highest hypogene grade.

Jan 1, 1983

By M Russ, J Gediga

This paper shows an economic feasible approach to implement greenhouse gas (GHG) reduction measures into the mining and metallurgy industry (MMI). The goal to improve energy consumption is directly linked to the reduction of GHG emissions in the MMI. A baseline scenario of the considered reference system and of the respective reference year has to be designed and analysed. In a second step an analysis of the same operation using the best available technology (BAT) processes is carried out to generate a basis for a benchmark system. The identified gaps will be reported and the potential GHG emission reductions will be put into relation to the investment, running cost and generated carbon credits of the new process technologies to be implemented. This economic feasibility calculation is necessary to realise a cost efficient GHG reduction roadmap decision-making for implementing new technology into the companyÆs business operations. The GHG reduction roadmap is developed using the marginal abatement curve approach.

Jan 1, 2009

By B. K. Mishra, P. Patnaik, B. C. Tripathy, I. N. Bhattacharya

Cobalt is an essential metal considering its numerous industrial applications. The demand for the metal is increasing due to its wide range of use in, for example, rechargeable batteries and as an alloying element in super alloys. Cost effective production of Co is critical. Electrowinning from aqueous sulphate solutions is the preferred technology available for the production of Co. Attempts are being made to produce uniform, smooth and bright deposits of cobalt metal. Use of organic additives in the electrolytic bath improves current efficiency and deposit morphology of the metal. We investigated the effect of quaternary amines TEABr, TPABr and TBABr during cobalt electrowinning from aqueous sulphate solutions. Among the additives studied, TEABr yielded the best results. Smooth and bright deposits of cobalt were obtained at low concentration of TEABr (10 mg/L) maintaining a very high current efficiency of 99.6%. X-ray crystallography indicated that (100) is the most preferred plane of crystal growth.

Jan 1, 2014

By K. P. V. Lei

The U.S. Bureau of Mines investigated a hydrothermal sulfidation procedure to recover lead and silver from plumbojarosite. The plumbojarosite, generated during pressure-oxidative leaching of zinc concentrate in a commercial operation, contained, in percent, 25.4 pb, 18.8 Fe, 1.4 Zn, 29.5 SO,2-, 3.2 s?, 13.4 total sulfur, and 7.4 oz/ton Ag. The sulfidation was conducted in an autoclave and converted the plumbojarosite to amorphous iron oxide and liberated the lead and silver as sulfides. The best operating conditions were using 50 9 of plumbojarosite and 7 pct s? (2.04 9 S? added) in 500 mL of 2.0 mol/L NH3, 150? C, and 1 h. The sulfidation product contained, in percent, 37 Pb, 28 Fe, 6 S2-, 2 SO,2-, and 11.2 oz/st Ag. Ferric chloride leaching extracted 98 pct Pb and 97 pct Ag from the sulfidation product.

Jan 1, 1990

By D. R. Jolley

"The selection of equipment for open-pit mining is an important decision which results in a considerable capital expenditure by the operator. The decision is complicated by the wide product range on the market. Certainly, equipment performance is an important criterion to consider in making the decision. Equally important, however, is the operating inter-relationship among the equipment. A poor balance increases production costs and waiting time as queues form at the bottlenecks. This inter-relationship is dependent on equipment performance, but it is also affected by management decisions (i.e. scheduling techniques).The purpose of this paper is to show how the computer is used to decide which equipment and operating decisions achieve the required production objectives at least cost. Actual mining of the pit is simulated over a period of time using different equipment and scheduling decisions. Production, waiting time and costs are evaluated for each alternative until the operator is satisfied that he has achieved the best result."

Jan 1, 1970

By L. M. Cumming

"The contact between dolomite of the St. George formation (Cambro-Ordovician) and limestone of the overlying Table Head formation (Middle Ordovician) is a regional disconformity. This is best illustrated from exposures on Pointe Riche Peninsula, near Table Point, and along Port au Port Bay. The contact occurs along 180 miles of the west coast of Newfoundland from St. John Island in the north to the western part of Port au Port Peninsula in the south. A disconformity of the same age occurs between the Romaine and Mingan formations on the north side of the Gulf of St. Lawrence.Dolomitic beds beneath the disconformity locally contain concentrations of base-metal sulphides. Sphalerite occurs in dolomite pseudobreccias of the St. George formation at Zinc Lake, 7 miles northeast of Daniels Harbour. The 'Western Newfoundland Lower-Middle Ordovician regional disconformity is interpreted as having originated on and near the edge of a broad platform, and to have provided an important regional geological control in the localization of zinc mineralization."

Jan 1, 1968

By Malcolm D. Flavel

As indicated in the introduction to this paper, it is a sequel to that which I gave to the last annual meeting in Atlanta in march. This paper goes further into aspects of crushing and screening, primarily from the standpoint of circuit control. There has been little published by equipment manufacturers on this subject and this is the first paper on crushing circuit control to be sponsored by Allis-Chalmers corporation. By proper control over the use of crushing energy, we will be able to produce finished products from feed materials uti¬lizing minimum capital for the lowest cost of production. The subject will be discussed as follows. Firstly, we will look briefly at what we are trying to accomplish; Secondly, what is presently available in the way of technology; Thirdly, we will look at a suggested new system of control which will best fit the parameters of the normal crushing and screening operation; As a conclusion, I will summarize the advantages of the new system.

Jan 1, 1977

The Health Tracking project is one of five projects being undertaken as part of the Minerals Industry Cooperation Initiative (MICI) û a national initiative sponsored by the Minerals Council of Australia. The aim of the Health Tracking project is to assess the practicality of ways to demonstrate the monitoring of hazardous exposures and the occurrence of related occupational illness and disease and development of management systems and strategies at a national level. This second stage of the project will be completed in 2005 and will cover four areas: pilot development of a comprehensive job exposure matrix (JEM) for the minerals industry; development of both proactive and reactive occupational illness and disease metrics; recommendations regarding appropriate health tracking models; and provision of best practices guidelines for management of occupational health. The synergies between these areas will establish the path towards an effective national occupational health surveillance system and the development of effective prevention strategies and policies.

Jan 1, 2005

By J. Yue

The particle breakage kinetics, product size and size distribution, as well as grinding limit for quartz suspensions in a horizontal stirred mill are investigated. Results of grinding studies on quartz suspensions in a horizontal stirred mill confirm "first-order" particle breakage rates. A comparison of equation fits reveal that the product size distribution from stirred mill is best represented by the Rosin-Rammler equation when compared to the Gaudin-Shuhmann equation, but results fit poorly as particle size below five microns. A method of determining breakage rates versus particle size is demonstrated which shows that the 10% top size fraction is most appropriate for the determination of specific breakage rates. The method is used to demonstrate the relationship between particle breakage rate and particle size. As the feed particle size becomes smaller, the size reduction ratio decreases and approaches a grinding limit which depends on the effective stresses created in the mill.

May 1, 2004

By A. P. Schissler

2013 has seen metals, industrial minerals, and coal all reduce in price due to market and geo-political factors. Many companies are taking write-downs to recalibrate their reserves and have enacted focused cost reduction programs. The public domain includes statements where companies have operating cost reduction goals in the $500 million range. Zero-base staffing & budget analysis is a means to achieve optimal employment and cost levels for a given level of production. The method involves measuring the work to be done similar to Lean. Lean is a method to review each step of production and remove anything that doesn?t add value or is necessary to complete finished goods. Zero-base methodology has been applied to mines worldwide producing realistic and sustainable levels of staffing and costs based on the quantity of work. The objective of this paper is to provide the framework of zero-basing with examples of application.

Feb 23, 2014

By Chetan D. Savani, Mike K. Muchard

The necessity to evaluate undocumented foundation lengths is essential in assessing the useable life, need for scour protection, retrofitting, or full reuse of existing bridge foundations. For this purpose, Parallel Seismic Testing (PST) has the best accuracy and is applicable to the widest range of foundation configurations used in bridge construction of any test method. Although not limited to bridges, PST case studies are presented involving two bridges. To preface the case study discussions, an overview of the PST method is given along with its results and analysis thereof. In one of the cases, we were afforded the rare opportunity to see the existing piles being extracted long after the PST testing program was completed. The resulting Class A prediction reaffirms the accuracy of the method. Versatility of the PST method is also exemplified in the two cases presented, where unique situations from complex foundation systems were overcome by analysis to provide successful results.

By Dean Ilievski

Mathematical modelling of the precipitation process requires that the kinetics of crystal growth, nucleation and agglomeration be known: This paper reviews the current state of knowledge on these precipitation sub-processes (ie. growth, nucleation and agglomeration) and describes a number of experimental techniques for estimating their kinetics. The experimental methods used to generate the precipitation data and the data analysis techniques used to extract the kinetics information from the data are discussed separately. There is no universal "best" technique for determining the kinetics. However, studies on multi-crystal systems are more reliable for modelling purposes than are single crystal studies. The selection of a technique will depend on which sub-processes are present. A problem with all kinetics studies is that there is generally a large uncertainty in the estimated kinetic parameters. This stems from the scatter in the experimental data being further propagated by the mathematical techniques used to extract the kinetic parameters.

Jan 1, 1996

By Martin H. Stanczyk

The Bureau of Mines studied continuous closed-circuit attrition grinding of a coarse commercial filler-grade kaolin to produce paper-coating-grade clay having a particle size analysis of at least 70 percent minus 2-micron equivalent spherical diameter (esd). The coarse clay, containing about 12 percent minus 2-micron-esd material, was ground in a Bureau-developed 10-inch-diameter attrition grinder in closed circuit with a 5-foot-diameter bowl classifier. In the best test, a finished product containing 82.7 percent minus 2-micron-esd material was obtained when grinding 20 pounds of raw clay per hour at percent solids with a 100-percent circulating load. Energy consumption was about 341 kilowatt-hours per ton of clay feed, or 487 kilowatt-hours per ton of minus 2-micron-esd material produced. Closed-circuit grinding gave some-what greater particle size reduction and lower energy consumption than either batch or continuous open-circuit grinding.

Jan 1, 1965

By Peter Dare-Bryan, Will Hunt, Lee Julian

It is well-known that blasting has an economic effect on grade control activities. However, until recently, methods did not exist for measuring the grade control value change caused by the blast. Rules of thumb were the best method to minimize ore loss and dilution, as simulation has been traditionally constrained by time and computer power. Even with these rules followed, an extensive study performed on over 150 blasts showed that the value change caused by the blasts followed a normal distribution – some blasts created value, and some blasts destroyed value. The question naturally asked was “How can we ensure the blast designs are optimized to create value?” Recent advancements in computer power have enabled real-time blasting simulations that create post-blast grade control models before the blast is fired. Understanding what will happen before it happens allows blasters and grade control personnel to iterate designs, searching for the highest value achievable.

Feb 6, 2023

By F. E. Diebold

The methodology for describing the geochemistry of elements in a coal seam have been developed. This has been applied to the Rosebud Coal Seam, which is an economically important member of the subbituminous coals of the Fort Union Formation in Eastern Montana. The method development has involved a detailed study of two popular techniques for determining the metal geochemistry of coal, namely, whole coal analyses and coal physical fractionation. The mathematically contrived element associations (whole coal analyses technique) and the element concentration trends in the float and sink fractions (physical fractionation technique) are considered to lead to only qualitative conclusions concerning the chemical associations of the elements in coals. Additionally, the processes taking place with the coal during low temperature ashing in an oxygen plasma are experimentally investigated and shown to be of sufficeint extent that the use of such low temperature ash for deciphering element geochemistry is questionable. The method developed in this study is a chemical fractionation that involves the sequential leaching of coal with water, 0.5 N HC1, 3 N HC1, 2 N HNO3, and 48% HF. These leach solutions are shown to selectively dissolve the predominate inorganic phases, sulfates, Ca and Mg carbonates, Fe sulfides and K alumino-silicates and quartz, respectively. These phases were identified with the use of XRD, SEM, EM and leaches (water and 0.3 N HC1) of whole coal and low temperature ash. The incorporation of the anion-exchange step in the leaching scheme was investigated and was observed to warrant further study of such intensity to be, at the time, unuseable. The use of this sequential leaching technique on several coal samples from the same seam generates element concentration trends that can be quantitatively interpreted with respect to the chemical associations of the minor and trace metals in the coal seam. The properties of the various seams of economic importance in the Fort Union Formation in Eastern Montana are compiled and presented. The subsequent conclusion is that there is not a large variation in the properties of these coal seams and that the variations within the Rosebud are within one order of magnitude. The chemical fractionation technique, investigated in this study, was applied to composite tipple samples of the Rosebud seam. Each composite sample represented 76,800 tons of coal. A minimum of 32% of the Ca and Mg are present as separate water soluble sulfates. An excess of the sulfate ion in the water extracts shows the predominating influence of the ion exchange capacity of the organic compounds in the coal. Based upon the CO content of the coal and the HC1 leachate data, 25 to 30% of the alkaline earth elements exist as separate carbonates and the remainder are associated with the organic compounds. The small fraction of the illite that dissolves in the HC1 and HNO3 leachates accounts for the K and Al. Slight dissolution of the pyrite in the HCl solvent occurs, the small amounts of Li and As do not relate to any known phase and Mn is present as a separate carbonate phase. Fe and a significant amount of the As exist in the pyrite that is dissolved in the HNO. Se is equally partitioned between the pyrite and the organic compound~. Most of the trace elements are found in the HF solutions. Li, V, and Cr were interpreted to be associated with the clay minerals (kaolinite and illite). Ni and Pb appear to be present as separate phases and 50% of the Hg is HF soluble but is not chemically related to any known inorganic phase.

Jan 1, 1983

By Francis Gray

Mr. F. W. Gray: It is not my intention to read my paper as it is too long, so I will touch only on the high lights. The Sydney field is the most favourable example of undersea coal mining that exists, and I have not been able to find anything like it elsewhere. The nearest approach to it is a field in England where the Whitehaven collieries are operating, but it has a lot of faults. The net result of these faults so far met with in the seaward advance of the workings has been to increase, by something over 100 feet, the gain in depth of cover, in a distance of approximately three and three-quarter miles. In the Sydney field there are no faults of any consequence. On the east side, the English measures rise. In Australia the sea bottom fell and the cover became too light. On Vancouver Island the coal ran out, and in Japan the seams are steep and contorted. The Chilian fields resemble our own to some extent. An inundation of two collieries took place there some time ago, due, it is said, to the rise workings being allowed to approach the sea bottom too closely in the vicinity of a fault. The Cape Breton undersea field has been proved over a frontage of about thirty miles and has been attacked and penetrated for a considerable distance along that front. We have passed the prospecting stage and now generally use developed land areas as points of attack to win the undersea coal. Of our mining under the sea, it can be said that, with the exception of No. 1-B and Princess colliery, Sydney Mines, no real attempt has been made to win the undersea coal.

Jan 1, 1927

By Daniel S. Witkowsky

The Pollution Prevention Act of 1990 provides few specifics to assist the non-fuel mining and mineral processing industries of the United States in achieving pollution prevention (P2) compliance. The U.S. Bureau of Mines (USBM) recognizes the absence of specific information to reduce pollution impacts from mining and mineral processing of hardrock and industrial minerals. Therefore, the USBM has prepared this publication to help reduce or eliminate environmental pollution and to assure the viability of these segments of the domestic mining industry. This report includes worksheets designed to help operators of mining and milling facilities to establish a P2 program. The report can also be used by citizen and environmental groups, State and local governments, and academia to gain an understanding of P2 as it relates to mining and mineral processing.

Jan 1, 1995

By Richard V. Ageton, Harry E. Tufft, E. A. Holbrook

When an underground excavation is made, the rock surrounding the sides and top of the opening is deprived of its natural support and tends to fall. Whenever caving takes place, the time and extent of the caving depend on the character and condition of the rock. In strong homogenous rock, such as solid granite, even a large chamber may stand indefinitely, whereas a soft material, such as clay or a loose material like unconsolidated sand, falls immediately if not supported. Weaknesses in the rocks induced by structural features, such as joints, :fissures, bedding and cleavage planes, and fractures produced by blasting, will cause the falling of insecure blocks or slabs unless means are provided to support these in place. In an unsupported mine opening, as a tunnel, the first slight settling or adjusting movement of the rocks (the "initial creep" or "set") is caused by the great weight of overlying material pressing down the rock masses above and around the roof and sides of the opening until they key together in roughly the form of an arch. The rock, after it has adjusted itself to this shape, becomes. selfsupporting. Timbering is necessa.ry in all mining only to support, therefore, those comparatively small blocks or pieces of rock which tend to loosen from the top and sides of the opening during or after the formation 'of the natural rock arch, and which lie between this natural rock arch and the opening. This statement, of course, has its limitations. For example; a layer of strong rock, like limestone, may act as a beam; then only the material under the limestone will need support. Timbering is not, as is commonly supposed by the layman, used to supp!ort the huge mass of rock between the back (roof) of an underground opening and the surface. It would be impossible to place enough timbers in a:ny underground opening to support such a mass. This fact is not'·perceived by all miners.

Jan 1, 1923

By R. E. Mussier

This investigation was made to study new methods to prepare high-purity yttrium metal, Various methods were used to prepare pure intermediate compounds, primarily chlorides, bromides, and iodides, which were subsequently reduced to metal. The process found most suitable for the preparation of pure anhydrous yttrium chloride involved thermal dehydration of a mixture of hydrated yttrium chloride and ammonium chloride while under vacuum. Yttrium bromide and iodide were prepared most effectively by the direct halogenation of yttrim carbide. Yttrim carbide was obtained by reacting and melting yttrium oxide-carbon mixtures in a carbon-arc furnace. Yttrium halides were purified by vacuum distillation and reduced by alkali or alkaline-earth metals. Lithium and sodium proved to be the best reductants from the standpoint of yield (>95 pct) and purity (>99.8 pct) of the yttrium. The product of the reduction step was sponge metal, which was consolidated readily by conventional cold-mold, arc-melting procedure. The purest yttrium obtained in laboratory scale work was prepared by sodium reduction of yttrium chloride and contained only 125 pp oxygen; other impurities did not exceed 1,000 ppm. In larger scale tests yttrium containing only 800 to 1,000 ppm total impurities was obtained by lithium reduction of yttrium chloride. The tensile properties of high-purity yttrium were determined. Mechanical tests showed that yttrium can be forged, extruded, rolled, spot welded, and deep drawn.

Jan 1, 1963